15 November 2026
The family of diimine-type copper(II) ternary complexes consists of many molecules, with more than 9000 crystallographic reports in the CCDC. Their proven anticancer properties largely explain this interest. Although most of the same type of ternary...
Since their development in the 1930s, Schiff-base complexes have played an important role in the field of coordination chemistry. Here, we report the synthetic, spectral, structural, magnetic and electrochemical studies of two new pentacoordinated ne...
Casiopeinas are a family of copper(II) coordination compounds that have shown an important antineoplastic effect and low toxicity in normal cells. These compounds induce death cells by apoptosis through a catalytic redox process with endogenous reduc...
The new ligand HMeATSM, derived from condensation of 2-3-butanedione with 4-methyl-3-thiosemicarbazide and 2,4-dimethyl-3-thiosemicarbazide, has been synthesized. Its reactivity with nickel(II) and zinc(II) nitrates was explored and the resulting com...
A new Cu(II) paddle-wheel-like complex with 4-vinylbenzoate was synthesized using acetonitrile as the solvent. The complex was characterized by X-ray crystal diffraction, FT-IR, diffuse reflectance spectroscopy, thermogravimetric, differential scanni...
The electronic and excitonic properties of a single exciton confined in nanoscopic CdSe quantum dots with different geometries are investigated using a self-consistent Schrödinger-Poisson approach within the effective mass and Hartree approximat...
This study investigates the coordination chemistry of the tetradentate pyridine-containing 12-membered macrocycles L1-L3 towards Platinum Group metal ions PdII, PtII, and RhIII. The reactions between the chloride salts of these metal ions and the thr...
Six examples of 2-(1-arylimino)ethyl-9-arylimino-5,6,7,8-tetrahydrocycloheptapyridine-cobalt(II) chloride complexes, [2-(1-ArN)C2H3-9-ArN-5,6,7,8-C5H8C5H3N]CoCl2, (Ar = 2-(C5H9)-6-MeC6H3 Co1, 2-(C6H11)-6-MeC6H3 Co2, 2-(C8H15)-6-MeC6H3 Co3, 2-(C5H9)-4...
Ethylene cross-bridged tetraazamacrocycles have been used to stabilize first-row transition metal complexes for applications under harsh conditions, such as biomedical imaging and aqueous oxidation catalysis. We have applied these ligands to the synt...
The incubation of a solution of horseradish peroxidase (HRP) enzyme either below the apex or near the base of an inversely oriented square pyramid (inverted square pyramid; ISP) has been found to influence the enzyme’s aggregation and adsorptio...
In recent years, the topic of progressive structural collapse has received more attention around the world, and the study of element importance is the key to studying progressive collapse resistance. However, there are many elements in truss structur...
The mini-review highlights the innovative development of hetero-dinuclear metallic complexes, with a specific focus on zinc(II) metal centers arranged in a square-pyramidal configuration. The work presented, stemming from our research group in collab...
Classical molecular dynamics (MD) simulations have been performed to investigate the effects of substitutions in the octahedral sheet (Mg for Al) and layer charge on an atomistic model of the montmorillonite edge. The edge models considered substitut...
We perform a thorough study of the ground state magnetic properties of nickel-based
A novel heterotrinuclear complex [Cu2(L)Na(µ-NO3)]∙CH3OH∙CHCl3 derived from a symmetric bis(salamo)-type tetraoxime H4L having a naphthalenediol unit, was prepared and structurally characterized via means of elemental analyses, UV-Vis, FT-IR, f...
The array of regular square pyramid microstructures with zero-spacing features is an ideal structural topology for building superhydrophobic functional surfaces due to its excellent anti-wetting performance and low surface adhesion properties. In the...
Two new hetero-trinuclear 3d-4f complexes [Zn2(L)Ho(μ2-OAc)2(OAc)(MeOH)]·CH2Cl2 (1) and [Zn2(L)Er(μ2-OAc)2]OAc (2), derived from a bis(salamo)-based ligand H4L, were synthesized and characterized via elemental analyses, IR, UV–Vis, fluorescence spect...
In static acrobatic gymnastics pyramids, maintaining stability in a multi-person system is critical, yet unconstrained floor baselines and base-to-top pairing mechanics remain poorly quantified. This study evaluated postural stability in shoulder-sta...
In this study, two simple Schiff base copper complexes [Cu(H2O)2(HL)]·2H2O (Complex 1) (H3L = 2-OH-4-(OH)-C6H2CH=NCH2CO2H) and [Cu(py)2(HL)] (Complex 2) (Py = pyridine) were initially achieved and authenticated by single-crystal X-ray structure analy...
Copper(II) complexes with 2,2′:6′,2″-terpyridines (terpys) are promising candidates for anticancer therapy and catalysis. Their structural and optical properties can be tuned by modifying the terpy backbone, including a substitution...
It is important to estimate the exact depth from 2D images, and many studies have been conducted for a long period of time to solve depth estimation problems. Recently, as research on estimating depth from monocular camera images based on deep learni...
Terrain rendering is an important issue in Geographic Information Systems and other fields. During large-scale, real-time terrain rendering, complex terrain structure and an increasing amount of data decrease the smoothness of terrain rendering. Exis...
In the last decades, optimizing implant properties in terms of materials and biointerface characteristics represents one of the main quests in biomedical research. Modifying and engineering polyvinylidene fluoride (PVDF) as scaffolds becomes more and...
It is necessary to perform the robustness design for the progressive collapse resistance of grid structures. However, there is a lack of a comprehensive index to evaluate the member importance. An evaluation method on element importances is proposed...
A single crystal of Bi6Te2O15 was obtained from the melt of the solid-state reaction of Bi2O3 and TeO3. Bi6Te2O15 crystallizes in the Pnma space group (No. 62) and exhibits a three-dimensional network structure with a =10.5831(12) Å, b = 22.694...
This article introduces novel methodologies, coordinate systems, and procedures in computational geometry that further develop a Euclidean-based relationalistic framework. The objective is to describe tools using object-oriented relational elements w...
This review presents representative examples illustrating how the Lewis acidic character of the Zn(II) metal center in Zn(salen)-type complexes, as well as in complexes of other tetradentate ligands, and the nature of the medium govern their supramol...
There are many bars in grid structures, and their topological relationships are complex, so the workload of calculations involved in researching their reliability is large. In this paper, based on the geometric topological relationship within a grid...
A design method for a broadband and wide-angle metamaterial absorber is proposed based on optimal tiling of rhombus carbon pixels on and implantation of metal cylinders inside an acrylic substrate for which the backside is blocked by the perfect cond...
The simulation of microwave absorption and external thermal flow is an essential aspect of the vacuum thermal testing process for Synthetic Aperture Radar (SAR) antenna. This paper proposes a novel integrated method for simulating microwave absorptio...
A Ka-band dual-polarization magnetoelectric (ME) dipole antenna array based on three-dimensional (3D)-printed technology with low sidelobe level (SLL) is proposed in this paper. The metal posts and cross-slots are explored to build a novel subarray w...
Herein, we report the synthesis and structural characterization of a complex with extended aromaticity based on a naphthalene-bridged Schiff base complex with two metal binding pockets. In a first step, the Zn(II) complex (ZnL), {6,6′-dimethoxy-2,2′-...
The newly designed butterfly-shaped hetero-tetranuclear CuII-NaI coordination compound, [Cu3(HL)2Na]∙Pic (Pic− is abbreviation of picrate) (1) which is derived from a naphthalenediol-based bis(Salamo)-type chelating ligand H4L have been synthes...
Five mono-nuclear Cu(II) and Ni(II) complexes and one dinuclear Zn(II) complex were synthesized from the Schiff bases N,N'-bis(3-ethoxy-2-hydroxybenzylidene)-1,2-phenylenediamine (H2LOEt-phda) and 2-ethoxy-6-({2-[(3-ethoxy-2-hydroxybenzylidene)amino]...
DNA aptamers are important tools for molecular recognition, particularly for a new generation of tools for biomedicine based on nucleic acid nanostructures. Here, we investigated the relative abilities of different shapes and sizes of DNA polyhedra t...
Four new drug-based oxidovanadium (IV) complexes were synthesized and characterized by various spectral techniques, including molar conductance, magnetic measurements, and thermogravimetric analysis. Moreover, optimal structures geometry for all synt...
The present work reports the synthesis and structural design of three novel Zn(II) complexes [Zn(L1)(CH3COO)(H2O)] (1), [Zn(L2)2] (2), and [Zn(L3)2] (3) with carbazate ligands, 2-acetylpyridine-methylcarbazate (HL1), 2-acetylpyridine-ethylcarbazate (...
A new series of ternary metal complexes, including Co(II), Ni(II), Cu(II), and Zn(II), were synthesized and characterized by elemental analysis and diverse spectroscopic methods. The complexes were synthesized from respective metal salts with Schiff&...
Microcline is an important rock-forming mineral in the Earth’s crust, and characterizing its structural behavior under compression is essential for understanding the high-pressure response of feldspar minerals under geological conditions. In th...
Vibrational measurements play an important role for structural health monitoring, e.g., modal extraction and damage diagnosis. Moreover, conditions of civil structures can be mostly assessed by displacement responses. However, installing displacement...
This study reports the synthesis and characterization of a dinuclear zinc(II) complex, [Zn2(L1)2(L2)]·DMF·Et3N (C45H54F2N10O5S2Zn2), constructed from a fluoro-substituted thiosemicarbazone Schiff base ligand (2-(3-fluoro-5-hydroxybenzyl...
A new copper(II) complex was synthesized using chromone-2-carboxylic acid as the main ligand, and coordinated pyridine molecules. The complex was successfully crystallized and structurally characterized by single crystal X-ray diffraction. This revea...
Salinomycin is a polyether ionophorous antibiotic with promising antineoplastic properties. Published studies have revealed that the compound also exerts pronounced antidotal activity against cadmium (Cd) and lead (Pb) intoxications. It has been prov...
Deterministic channel models are essential for high-frequency communication system design in complex urban environments, where multiple propagation mechanisms including reflection, diffraction, and vegetation scattering coexist. This paper proposes a...
The synthesis and X-ray crystal structure analyses of the azido complex [Zn(N3)(Arg)2](N3)·3H2O, where Arg is L-arginine, were presented. The molecular structure of the complex was further studied using FT-IR spectra as well as atoms in molecu...
This study investigates the rational design of a dinuclear zinc(II) coordination polymer, (C36H34Br2N8O4S2Zn2), to explore how halogen substitution and ligand choice modulate structural architecture, contributing to the development of functional coor...
In this paper, we propose a vision-based feature tracker for the autonomous hovering of an unmanned aerial vehicle (UAV) and present an area-efficient hardware architecture for its integration into a flight control system-on-chip, which is essential...
The detection of the impurity rate in machine-picked seed cotton is crucial for precision agriculture. This study proposes a novel Cotton-YOLO-Seg cotton-impurity instance segmentation algorithm based on the you only look once version 8 small segment...
Opioid drugs are extremely potent synthetic analytes, and their abuse is common around the world. Hence, a rapid and point-of-need device is necessary to assess the presence of this compound in body fluid so that a timely countermeasure can be provid...
Two novel zinc(II) compounds with curcuminate (abbreviated as cur−), [Zn(CH3COO)(cur)(bpy)](1)·CH3OH·2H2O (bpy = 2,2′-bipyridine) and [Zn(PhCOO)(cur)(bpy)] (2)·CH3OH, have been synthesized and characterized. Their composition has been determined by s...
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