Materials

A comprehensive analysis of the notch toughness of Electron Beam Powder Bed Fused (EB-PBF) Ti-6Al-4V was conducted, which focused on the influence of build orientation and correlations with key mechanical properties. Horizontal and vertical specimens were fabricated with optimized process parameters and reused powder. The microhardness and microstructure of the metal were examined and both profilometry and scanning electron microscopy were used in evaluating the fracture surfaces. Results showed that the metal with vertical build orientation absorbed ~46% higher impact energy than the horizontal orientation due to crack propagation perpendicular to the prior-β grains, lower microhardness, and greater ductility. The importance of ductility to the vertical specimens was evidenced by greater shear lip width (~51%) and height (~35%), greater shear lip length (~18%), and higher roughness of the fracture surface (~15%). Shear width measurements showed the highest correlation with absorbed impact energy. Overall, results show that the notch toughness of EB-PBF Ti-6Al-4V is dependent on the build orientation due to differences in microstructure and the bulk mechanical properties. The notch toughness is well correlated with tensile properties as well. Lastly, a framework for relating the notch toughness in dynamic loading and quasi-static fracture toughness for EB-PBF Ti-6Al-4V is proposed.

The catalyst in methanol oxidation plays a pivotal role in direct fuel cell reaction. The aim of this work is to study the influence of polypyrrole polymer (PPy) added in the carbon Vulcan support for the methanol oxidation reaction. The catalytic active phase synthesized was nickel-based materials, which have been demonstrated to exhibit remarkable chemical stability in alkaline solutions. The metallic-active phase was supported at the PPy-carbon Vulcan matrix. PPy is a conductor polymer and the research of electric conduction in synergy with a carbon Vulcan and a Ni catalyst is scarcely reported. The morphology characterization of composite catalytic material was carried out by XRD, XPS, and TEM techniques. In turn, the catalytic activity of the composite is characterized by means of cyclic voltammetry (CV). Electrochemical impedance spectroscopy (EIS) showed the influence of PPy on the charge transfer resistance (Rch. t.). The results indicate that a decrease in the Rch. t. was associated with an increase in methanol oxidation; therefore, higher amounts of charge transfer is produced. Furthermore, the DEMS technique corroborates the EIS results, confirming elevated conversion toward oxidation products. In turn, the selectivity of the composite-catalytic support on the methanol oxidation was elucidated using in situ Raman spectroscopy.

This study aims to elucidate the deterministic correlation between the microscopic fracture mechanisms and the multi-domain characteristics of acoustic emission in reinforced concrete beams under cyclic loading. Cyclic incremental tests were designed and conducted, with synchronized application of digital image correlation and AE techniques to capture the entire damage evolution process and corresponding signal responses throughout. The findings reveal that the damage stage division based on mechanical responses is consistent with that based on AE responses. Damage accumulation and irreversible processes can be clearly characterized by AE activity, and the systematic decrease in the Felicity ratio quantitatively verifies the irreversible accumulation of damage. Under cyclic loading, different microscopic fracture mechanisms generate AE frequency-domain signatures with statistically significant differences. A damage identification model integrating the Felicity ratio and multi-band energy features was developed, achieving an accuracy of 88.89% in identifying macroscopic damage stages. This research quantitatively confirms the effectiveness of AE characteristics as reliable identifiers of microscopic fracture mechanisms, providing a new basis for advancing structural health monitoring technologies grounded in fracture mechanism recognition.