Materials

Modeling of thermodynamic properties, like heat capacities for stoichiometric solids, includes the treatment of different sources of data which may be inconsistent and diverse. In this work, an approach based on the covariance matrix adaptation evolution strategy (CMA-ES) is proposed and described as an alternative method for data treatment and fitting with the support of data source dependent weight factors and physical constraints. This is applied to a Gibb’s Free Energy stoichiometric model for different magnesium sulfate hydrates by means of the NASA9 polynomial. Its behavior is proved by: (i) The comparison of the model to other standard methods for different heat capacity data, yielding a more plausible curve at high temperature ranges; (ii) the comparison of the fitted heat capacity values of MgSO₄·7H₂O against DSC measurements, resulting in a mean relative error of a 0.7% and a normalized root mean square deviation of 1.1%; and (iii) comparing the Van’t Hoff and proposed Stoichiometric model vapor-solid equilibrium curves to different literature data for MgSO₄·7H₂O, MgSO₄·6H₂O, and MgSO₄·1H₂O, resulting in similar equilibrium values, especially for MgSO₄·7H₂O and MgSO₄·6H₂O. The results show good agreement with the employed data and confirm this method as a viable alternative for fitting complex physically constrained data sets, while being a potential approach for automatic data fitting of substance data. Full article

The cold roll forming process is broadly used to produce a specific shape of cold-roll formed products for their applications in automobiles, aerospace, shipbuilding, and construction sectors. Moreover, a proper selection of strip thickness and forming speed to avoid fracture is most important for manufacturing a quality product. This research aims to investigate the presence of longitudinal bow, the reason behind flange height deviation, spring-back, and identification of thinning location in the cold roll-forming of symmetrical short U-profile sheets. A room temperature tensile test is performed for the commercially available AA5052–H32 Al alloy sheets using Digital Image Correlation (DIC) technique, which allows complete displacement and strain data information at each time-step. The material properties are estimated from the digital images using correlation software for tested samples; the plastic strain ratios are also calculated from samples at 0, 45, and 90 to the rolling direction. The tested sample’s surface morphology and the elemental analysis are conducted using scanning electron microscopy (SEM) method and energy-dispersive X-ray spectroscopy (EDS) analytical technique combined with element mapping analysis, respectively. The cold roll forming experiments are systematically carried out, and then finite element analysis is utilized to correlate the experiment with the model. The performed cold roll forming numerical model outcome indicates a good agreement with the experimental measurements. Overall, the presented longitudinal strain was observed to influence the geometry profile. The spring-back is also noticed at the profile tail end and is more pronounced at high forming speed with lower strip thickness. Conversely, while the forming speed is varied, the strain and stress variations are observed to be insignificant, and the similar results also are recognized for the thinning behavior. Full article

In this study, the high-temperature test (i.e., temperature to 1000 °C) is conducted on 600 MPa seismic steel bars, and its residual mechanical properties and constitutive relations are investigated though three cooling rates, i.e., under air, furnace, and water-cooling conditions. Results show that three cooling methods have significant effects on the apparent characteristics of 600 MPa steel bars, when the heating temperature is greater than 600 °C. In addition, the ultimate and yield strength of steel bars have been significantly affected by different cooling methods, with increasing heating temperature. However, the elastic modulus is significantly not affected by temperature. Furthermore, the elongation rate after fracture and the total elongation rate at the maximum force do not change significantly, when the heating temperature is less than 650 °C. The elongation rate, after fracture, and the total elongation rate, at the maximum force, have different changes for three cooling methods. The degeneration of the stress–strain curves occurs when the heating temperature is high. The two-fold line, three-fold line, and Ramberg–Osgood models are developed based on the stress–strain curve characteristics of steel bars after cooling. The fire resistance of 600 MPa steel bars of reinforced concrete structure is analyzed, which provides a basis for post-disaster damage assessment, repair, and reinforcement of the building structure. Full article

Arcan shear tests with digital image correlation were used to evaluate the shear modulus and shear stress–strain diagrams in the plane defined by two principal axes of the material orthotropy. Two different orientation of the grain direction as compared to the direction of the shear force in specimens were considered: perpendicular and parallel shear. Two different ways were used to obtain the elastic properties based on the digital image correlation (DIC) results from the full-field measurement and from the virtual strain gauges with the linear strains: perpendicular to each other and directed at the angle of π/4 to the shearing load. In addition, the own continuum structural model for the failure analysis in the experimental tests was used. Constitutive relationships of the model were established in the framework of the mathematical multi-surface elastoplasticity for the plane stress state. The numerical simulations done by the finite element program after implementation of the model demonstrated the failure mechanisms from the experimental tests. Full article

Abstract: FRP (Fiber Reinforced Polymer) Bar reinforced coral concrete beam is a new type of structural member that has been used more and more widely in marine engineering in recent years. In order to study and predict the flexural performance of CFRP reinforced coral concrete beams, the flexural rigidity, crack morphology and failure mode of concrete were studied in detail. The results show that under the condition of similar reinforcement ratio, the flexural rigidity of CFRP reinforced coral concrete beam is significantly lower than that of ordinary reinforced concrete beam. Increasing the cross-section reinforcement ratio within a certain range can increase the bending stiffness of the test beam or reduce the deflection, but the strength utilization rate of CFRP reinforcement is greatly reduced. The short-term bending stiffness of the CFRP reinforced coral concrete beam calculated by the existing standard formula is obviously higher. This paper proposes a modified formula for introducing the strain inhomogeneity coefficient (Ψ) of CFRP bars and considers the relative slip between CFRP bars and coral concrete to predict the short-term flexural stiffness of coral concrete beams reinforced by CFRP bars. The formula was verified with the test results, and it was proved that the formula has a good consistency with the test results. Full article

Plastic waste reduction and recycling through circular use has been critical nowadays, since there is an increasing demand for the production of plastic components based on different polymeric matrices in various applications. The most commonly used recycling procedure, especially for thermoplastic materials, is based on thermomechanical process protocols that could significantly alter the polymers’ macromolecular structure and physicochemical properties. The study at hand focuses on recycling of polyamide 12 (PA12) filament, through extrusion melting over multiple recycling courses, giving insight for its effect on the mechanical and thermal properties of Fused Filament Fabrication (FFF) manufactured specimens throughout the recycling courses. Three-dimensional (3D) FFF printed specimens were produced from virgin as well as recycled PA12 filament, while they have been experimentally tested further for their tensile, flexural, impact and micro-hardness mechanical properties. A thorough thermal and morphological analysis was also performed on all the 3D printed samples. The results of this study demonstrate that PA12 can be successfully recycled for a certain number of courses and could be utilized in 3D printing, while exhibiting improved mechanical properties when compared to virgin material for a certain number of recycling repetitions. From this work, it can be deduced that PA12 can be a viable option for circular use and 3D printing, offering an overall positive impact on recycling, while realizing 3D printed components using recycled filaments with enhanced mechanical and thermal stability. Full article

The paper presents the possibility of detecting low H₂S concentrations using CuWO₄. The applicative challenge was to obtain sensitivity, selectivity, short response time, and full recovery at a low operating temperature under in-field atmosphere, which means variable relative humidity (%RH). Three different chemical synthesis routes were used for obtaining the samples labeled as: CuW1, CuW2, and CuW3. The materials have been fully characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). While CuWO₄ is the common main phase with triclinic symmetry, different native layers of CuO and Cu(OH)₂ have been identified on top of the surfaces. The differences induced into their structural, morphological, and surface chemistry revealed different degrees of surface hydroxylation. Knowing the poisonous effect of H₂S, the sensing properties evaluation allowed the CuW2 selection based on its specific surface recovery upon gas exposure. Simultaneous electrical resistance and work function measurements confirmed the weak influence of moisture over the sensing properties of CuW2, due to the pronounced Cu(OH)₂ native surface layer, as shown by XPS investigations. Moreover, the experimental results obtained at 150 °C highlight the linear sensor signal for CuW2 in the range of 1 to 10 ppm H₂S concentrations and a pronounced selectivity towards CO, CH₄, NH₃, SO₂, and NO₂. Therefore, the applicative potential deserves to be noted. The study has been completed by a theoretical approach aiming to link the experimental findings with the CuW2 intrinsic properties. Full article

The article presents characteristics of wood/polypropylene composites, where the wood was treated with propolis extract (EEP) and innovative propolis-silane formulations. Special interest in propolis for wood impregnation is due to its antimicrobial properties. One propolis-silane formulation (EEP-TEOS/VTMOS) consisted of EEP, tetraethyl orthosilicate (TEOS), and vinyltrimethoxysilane (VTMOS), while the other (EEP-TEOS/OTEOS) contained EEP, tetraethyl orthosilicate (TEOS), and octyltriethoxysilane (OTEOS). The treated wood fillers were characterized by Fourier transform infrared spectroscopy (FTIR), atomic absorption spectrometry (AAS), and X-ray diffraction (XRD), while the composites were investigated using differential scanning calorimetry (DSC), X-ray diffraction (XRD), and optical microscopy. The wood treated with EEP and propolis-silane formulations showed resistance against moulds, including Aspergillus niger, Chaetomium globosum, and Trichoderma viride. The chemical analyses confirmed presence of silanes and constituents of propolis in wood structure. In addition, treatment of wood with the propolis-silane formulations produced significant changes in nucleating abilities of wood in the polypropylene matrix, which was confirmed by an increase in crystallization temperature and crystal conversion, as well as a decrease in half-time of crystallization parameters compared to the untreated polymer matrix. In all the composites, the formation of a transcrystalline layer was observed, with the greatest rate recorded for the composite with the filler treated with EEP-TEOS/OTEOS. Moreover, impregnation of wood with propolis-silane formulations resulted in a considerable improvement of strength properties in the produced composites. A dependence was found between changes in the polymorphic structures of the polypropylene matrix and strength properties of composite materials. It needs to be stressed that to date literature sources have not reported on treatment of wood fillers using bifunctional modifiers providing a simultaneous effect of compatibility in the polymer-filler system or any protective effect against fungi. Full article

This article deals with the possibility of utilization of secondary-raw materials as a natural sand replacement in concrete. Four types of waste construction materials were examined—recycled aggregate from four different sources. The natural aggregate was examined as well as used as the reference sample. All the samples were tested to evaluate the water absorption, particle size distribution, and particle density. The basic chemical reactions in the view of ecotoxicology are investigated and measured based on Czech standards. Chemical analysis, Lemna growth inhibition test, freshwater algae, daphnia acute, and mustard germination toxicity test were made and discussed in this paper. Based on the physical and geometrical properties and ecotoxicology of examined waste materials, this work evaluated them as suitable for utilization in concrete as a sand replacement. Full article

Laser peen forming (LPF) is suitable for shaping sheet metals without the requirement for die/mold and without causing high temperatures. An analytical model for estimating the bending curvatures of LPF is convenient and necessary for better understanding of the physical processes involved. In this paper, we describe a new analytical model based on internal force balance and the energy transformation in LPF. Experiments on 2024 aluminum alloy sheets of 1–3 mm thickness were performed to validate the analytical model. The results showed that for 1 mm and 3 mm thick–thin plates, the curvature obtained by the analytical model changes from −14 × 10⁻⁴ mm⁻¹ and −1 × 10⁻⁴ mm⁻¹ to 55 × 10⁻⁴ mm⁻¹ and −21 × 10⁻⁴ mm⁻¹, respectively, with the increase of laser energy, which is consistent with the experimental trend. So, when either the stress gradient mechanism (SGM) or the shock bending mechanism (SBM) overwhelmingly dominated the forming process, the analytical model could give relatively accurate predicted curvatures compared with the experimental data. Under those conditions where SGM and SBM were comparable, the accuracy of the model was low, because of the complex stress distributions within the material, and the complex energy coupling process under these conditions. Full article

This work is dedicated to the description of the degradation of GaAs solar cells under continuous laser irradiation. Constant and strong exposure of the solar cell was performed over two months. Time-dependent electrical characteristics are presented. The structure of the solar cells was studied at the first and last stages of degradation test. The data from Raman spectroscopy, reflectometry, and secondary ion mass spectrometry confirm displacement of titanium and aluminum atoms. X-ray photoelectron spectroscopy showed a slight redistribution of oxygen bonds in the anti-corrosion coating. Full article

The stress-based finite element method is proposed to solve the static bending problem for the Euler–Bernoulli and Timoshenko models of an elastic beam. Two types of elements—with five and six degrees of freedom—are proposed. The elaborated elements reproduce the exact solution in the case of the piece-wise constant distributed loading. The proposed elements do not exhibit the shear locking phenomenon for the Timoshenko model. The influence of an elastic foundation of the Winkler type is also taken into consideration. The foundation response is approximated by the piece-wise constant and piece-wise linear functions in the cases of the five-degrees-of-freedom and six-degrees-of-freedom elements, respectively. An a posteriori estimation of the approximate solution error is found using the hypercircle method with the addition of the standard displacement-based finite element solution. Full article

Plasma polymer films typically consist of very short fragments of the precursor molecules. That rather limits the applicability of most plasma polymerisation/plasma-enhanced chemical vapour deposition (PECVD) processes in cases where retention of longer molecular structures is desirable. Plasma-assisted vapour thermal deposition (PAVTD) circumvents this limitation by using a classical bulk polymer as a high molecular weight “precursor”. As a model polymer in this study, polylactic acid (PLA) has been used. The resulting PLA-like films were characterised mostly by X-ray photoelectron spectroscopy (XPS) and nuclear magnetic resonance (NMR) spectroscopy. The molecular structure of the films was found to be tunable in a broad range: from the structures very similar to bulk PLA polymer to structures that are more typical for films prepared using PECVD. In all cases, PLA-like groups are at least partially preserved. A simplified model of the PAVTD process chemistry was proposed and found to describe well the observed composition of the films. The structure of the PLA-like films demonstrates the ability of plasma-assisted vapour thermal deposition to bridge the typical gap between the classical and plasma polymers. Full article

One of the major benefits of biomedicine is the use of biocomposites as wound dressings to help improve the treatment of injuries. Therefore, the main objective of this study was to develop and characterize biocomposites based on bacterial cellulose (BC) with different concentrations of collagen and starch and characterize their thermal, morphological, mechanical, physical, and barrier properties. In total, nine samples were produced with fixed amounts of glycerol and BC and variations in the amount of collagen and starch. The water activity (0.400–0.480), water solubility (12.94–69.7%), moisture (10.75–20.60%), thickness (0.04–0.11 mm), water vapor permeability (5.59–14.06 × 10⁻⁸ g·mm/m²·h·Pa), grammage (8.91–39.58 g·cm⁻²), opacity (8.37–36.67 Abs 600 nm·mm⁻¹), elongation (4.81–169.54%), and tensile strength (0.99–16.32 MPa) were evaluated and defined. In addition, scanning electron microscopy showed that adding biopolymers in the cellulose matrix made the surface compact, which also influenced the visual appearance. Thus, the performance of the biocomposites was directly influenced by their composition. The performance of the different samples obtained resulted in them having different potentials for application considering the injury type. This provides a solution for the ineffectiveness of traditional dressings, which is one of the great problems of the biomedical sector. Full article

Porous Al₂O₃ membranes were prepared through a phase-inversion tape casting/sintering method. The alumina membranes were embedded with finger-like pores perpendicular to the membrane surface. Bare alumina membranes are naturally hydrophilic and underwater oleophobic, while fluoroalkylsilane (FAS)-grafted membranes are hydrophobic and oleophilic. The coupling of FAS molecules on alumina surfaces was confirmed by Thermogravimetric Analysis and X-ray Photoelectron Spectroscopy measurements. The hydrophobic membranes exhibited desired thermal stability and were super durable when exposed to air. Both membranes can be used for gravity-driven oil/water separation, which is highly cost-effective. The as-calculated separation efficiency (R) was above 99% for the FAS-grafted alumina membrane. Due to the excellent oil/water separation performance and good chemical stability, the porous ceramic membranes display potential for practical applications. Full article

The aim of this work was to investigate the microstructure and the mechanical properties of laser-welded joints combined of Dual Phase DP800 and DP1000 high strength thin steel sheets. Microstructural and hardness measurements as well as tensile and fatigue tests have been carried out. The welded joints (WJ) comprised of similar/dissimilar steels with similar/dissimilar thickness were consisted of different zones and exhibited similar microstructural characteristics. The trend of microhardness for all WJs was consistent, characterized by the highest value at hardening zone (HZ) and lowest at softening zone (SZ). The degree of softening was 20 and 8% for the DP1000 and DP800 WJ, respectively, and the size of SZ was wider in the WJ combinations of DP1000 than DP800. The tensile test fractures were located at the base material (BM) for all DP800 weldments, while the fractures occurred at the fusion zone (FZ) for the weldments with DP1000 and those with dissimilar sheet thicknesses. The DP800-DP1000 weldment presented similar yield strength (YS, 747 MPa) and ultimate tensile strength (UTS, 858 MPa) values but lower elongation (EI, 5.1%) in comparison with the DP800-DP800 weldment (YS 701 MPa, UTS 868 MPa, EI 7.9%), which showed similar strength properties as the BM of DP800. However, the EI of DP1000-DP1000 weldment was 1.9%, much lower in comparison with the BM of DP1000. The DP800-DP1000 weldment with dissimilar thicknesses showed the highest YS (955 MPa) and UTS (1075 MPa) values compared with the other weldments, but with the lowest EI (1.2%). The fatigue fractures occurred at the WJ for all types of weldments. The DP800-DP800 weldment had the highest fatigue limit (348 MPa) and DP800-DP1000 with dissimilar thicknesses had the lowest fatigue limit (<200 MPa). The fatigue crack initiated from the weld surface. Full article

Prevention of bacterial inflammation around dental implants (peri-implantitis) is one of the keys to success of the implantation and can be achieved by securing the gingival tissue-abutment interface preventing penetration of bacteria. Modern dental practice has adopted zirconia abutments in place of titanium, but the adhesion of gingival tissue to zirconia is inferior to titanium. The aim of this study was to assess and improve the adhesion of mucosal tissues to zirconia posts using sol-gel derived TiO₂ coating following dynamic mechanical testing. The posts were cultivated with porcine bone-gingival tissue specimens in vitro for 7 and 14 days and then subjected to dynamic mechanical analysis simulating physiological loading at 1 Hz up to 50 μm amplitude. In parallel in silico analysis of stresses and strains have been made simulating “the worst case” when the fixture fails in osseointegration while the abutment still holds. Results show treatment of zirconia can lead to double interface stiffness (static shear stiffness values from 5–10 to 17–23 kPa and dynamic from 20–50 to 60–125 kPa), invariant viscostiffness (from 5–35 to 45–90 kPa·s^α) and material memory values (increased from 0.06–0.10 to 0.17–0.25), which is beneficial in preventing bacterial contamination in dental implants. This suggests TiO₂-coated zirconia abutments may have a significant clinical benefit for prevention of the bacterial contamination. Full article

A new material model of magnesium alloys, combining both Hill’48 yield function and Cazacu’06 yield function, was developed and programmed into LS-DYNA using user subroutine, in which both slip dominant and twinning/untwinning dominant hardening phenomena were included. First, a cyclic load test was performed, and its finite element analysis was carried out to verify the new material model. Then, the deformation behaviors of the magnesium crash box subjected to the compressive impact loading were investigated using the developed material model. Compared with the experimental results, the new material model accurately predicted the deformation characteristics of magnesium alloy parts. Additionally, the effect of the thickness distribution, initial deflection and contact friction coefficient in simulation models on deformation behaviors were investigated using this validated material model. Full article

Mineral trioxide aggregates (MTA) have been developed as a dental root repair material for a range of endodontics procedures. They contain a small amount of bismuth oxide (Bi₂O₃) as a radiopacifier to differentiate adjacent bone tissue on radiographs for endodontic surgery. However, the addition of Bi₂O₃ to MTA will increase porosity and lead to the deterioration of MTA’s mechanical properties. Besides, Bi₂O₃ can also increase the setting time of MTA. To improve upon the undesirable effects caused by Bi₂O₃ additives, we used zirconium ions (Zr) to substitute the bismuth ions (Bi) in the Bi₂O₃ compound. Here we demonstrate a new composition of Zr-doped Bi₂O₃ using spray pyrolysis, a technique for producing fine solid particles. The results showed that Zr ions were doped into the Bi₂O₃ compound, resulting in the phase of Bi_7.38Zr_0.62O_12.31. The results of materials analysis showed Bi₂O₃ with 15 mol % of Zr doping increased its radiopacity (5.16 ± 0.2 mm Al) and mechanical strength, compared to Bi₂O₃ and other ratios of Zr-doped Bi₂O₃. To our knowledge, this is the first study of fabrication and analysis of Zr-doped Bi₂O₃ radiopacifiers through the spray pyrolysis procedure. The study reveals that spray pyrolysis can be a new technique for preparing Zr-doped Bi₂O₃ radiopacifiers for future dental applications. Full article