Minerals

The tight gas reserves in the Hangjinqi area are estimated at 700 × 109 m³. Since the exploration of the Hangjinqi, numerous wells are already drilled. However, the Hangjinqi remains an exploration area and has yet to become a gas field. Identifying a paleo-depositional framework such as braided channels is beneficial for exploration and production companies. Further, braided channels pose drilling risks and must be properly identified prior to drilling. Henceforth, based on the significance of paleochannels, this study is focused on addressing the depositional framework and sedimentary facies of the first member (P²x¹) of the lower Shihezi formation (LSF) for reservoir quality prediction. Geological modeling, seismic attributes, and petrophysical modeling using cores, logs, interval velocities, and 3D seismic data are employed. Geological modeling is conducted through structural maps, thickness map, and sand-ratio map, which show that the northeastern region is uplifted compared to northwestern and southern regions. The sand-ratio map showed that sand is accumulated in most of the regions within member-1. Interval velocities are incorporated to calibrate the acoustic impedance differences of mudstone and sandstone lithologies, suggesting that amplitude reflection is reliable and amplitude-dependent seismic attributes can be employed. The Root Mean Square (RMS) attribute confirmed the presence of thick-bedded braided channels. The results of cores and logging also confirmed the presence of braided channels and channel-bars. The test results of wells J34 and J72 shows that the reservoir quality within member-1 of LSF is favorable for gas production within the Hangjinqi area. Full article

This short communication presents a methodology to detect abnormal gas dispersion conditions in flotation machines. These abnormal conditions are characterized by the significant presence of cap-shaped bubbles. The approach considers the use of a bubble size analyzer to measure gas dispersion at industrial scale. The detection of abnormal conditions is critical when estimating bubble size by automated software. Otherwise, the estimates are significantly biased, since irregular bubbles are typically removed from the analysis. From the recorded images and the respective black and white representation, the variability of the shadow percentage caused by the bubbles in the vision field, abruptly increases in the presence of cap-shaped bubbles. Experimental conditions with coefficients of variation lower than 60–70% in the shadow percentage represent spherical and spherical-ellipsoidal regimes. In the former, automated bubble sizing software has proved to be sufficiently effective in obtaining reliable results. In the latter, different segmentation techniques have been proposed to obtain satisfactory results. Abnormal conditions are detected under coefficients of variation greater than 80% in the shadow percentage. The presence of cap-shaped bubbles causes inefficiencies in the collection of hydrophobic minerals in the pulp zone as well as disturbances in the separation stage (froth zone). Therefore, the detection of these irregular bubbles is suitable to provide feedback to flotation processes, allowing gas dispersion to be driven towards normal operating conditions. Full article

The marine controlled-source electromagnetic method (MCSEM) has attracted considerable attention as an approach to explore marine oil and gas resources and geological structures. This study presents a new wavelet Galerkin method (WGM) to solve the forward modeling problem of 2D MCSEM data incorporating conductivity anisotropy. The method uses Daubechies wavelets that may be differentiated based on the need to solve the governing field equations of MCSEM. A quasi-minimal residual method was adopted by combining an incomplete LU preconditioner to solve the WGM equations. The numerical results were compared with the analytical solution and those obtained by the finite difference and element methods. The results show that the proposed WGM is superior to the finite element and difference methods in terms of computing time and memory requirements. This algorithm can be applied to solve the forward modeling problem of MCSEM. The conductivity anisotropy of the background medium affects the MCSEM response more than the reservoir anisotropy. The match between the modeled results and measured data for the simplified real model demonstrates the necessity for using the anisotropic model to interpret data. Although this study used the proposed algorithm for 2D models, it may also be used for 3D models. Full article

In the mining industry, with numerical simulation analysis of stope roof stability, stope exposed area computation, and pillar buckling collapse simulation, backfill body creep damage mechanism research is becoming the most popular method in the field of backfill mining techniques. In this paper, we first summarized and analyzed the current application status and the existing problems of numerical simulation for solving mining engineering technical problems; then, based on the practical engineering problems of mining phosphate rock resources under high and steep rock slopes (HSRS), we carried out a true-3D numerical simulation study for different underground mining methods, to determine the appropriate mining method. Therefore, this paper, taking Dingxi Mine in China as an example, highlights the advantages of the backfill mining method with a high and steep slope; meanwhile, it also points out how to improve the accuracy of a numerical simulation and make it more consistent with the actual situation of the mining engineering application site. This paper only serves as a guide, in order to start a conversation, and we hope many more experts and scholars will become interested and engaged in this field of research. Full article

Due to an extensive history of mining activities common to Mexico, Chile and Australia there is a vast mine waste legacy. Whilst these wastes present ongoing challenges regarding their management, they may represent a source of elements supporting the transition towards a low carbon future. Hence, our study aims to demonstrate the value of establishing a chemical database from publicly available tailings data collated from the three countries to assess their potential as a secondary resource of elements classified as critical or with high economic relevance. Overall, 2976 data samples were identified, analysed and georeferenced from 159, 642 and 7 Mexican, Chilean and Australian deposits, respectively. Data analysis shows that Mexico has significant potential for Bi, Sb, W, In, Zn and Mo with outstanding values in Sonora State, while Chile has significant potential for Bi, Sb, W and Mo, mostly from northern to central regions and Zn to the south. Whilst data from Australia are still being compiled, the potential for Co was recognised. The research exposes that available information is insufficient and highlights the need for an international report or assessment code for mine waste that encourages resource recovery from these resources and circular economy practices. Full article

The use of ceramic solid particle technology in TES-integrated CSP plants offers a high solar-to-electricity ratio and enhanced storage densities, thanks to their high operational temperatures and wide temperature ranges. Metallurgical slags with composition similar to that of the state-of-art bauxite particles can be used as a sustainable and economical secondary raw material to prepare solid particles. In this study, the as-received state and the high-temperature phase and microstructural changes of two fayalite slags from copper and lead production were elucidated by XRD and SEM/EDS methods in a comparative manner. Solid particles were prepared from slags by the oil dropping method, with subsequent heat treatment. Solar-thermal-application-related functional properties of slag particles, such as heat capacity, absorptance, and thermophysical properties, were evaluated by differential scanning calorimetry (DSC), spectrophotometer, heating microscope, and high-temperature compressive tests, respectively. Owing to the formation of more stable Fe-rich phase components and less amount of glassy phase, copper slag is found to be a more promising secondary resource than lead slag in terms of material and functional properties. Full article

The present study aims to assess Abu Rusheid and Um Naggat albite granite’s natural radioactivity in the Central Eastern Desert, Egypt, using an HPGe laboratory spectrometer. A total of 17 albite granite samples were detected for this study. The activity concentrations were estimated for ²³⁸U (range from 204 to 1127 Bq/kg), ²²⁶Ra (range from 215 to 1300 Bq/kg), ²³²Th (from 130 to 1424 Bq/kg) and ⁴⁰K (from 1108 to 2167 Bq/kg) for Abu Rusheid area. Furthermore ²³⁸U (range from 80 to 800 Bq/kg), ²²⁶Ra (range from 118 to 1017 Bq/kg), ²³²Th (from 58 to 674 Bq/kg) and ⁴⁰K (from 567 to 2329 Bq/kg) for the Um Naggat area. The absorbed dose rates in the outdoor air were measured with average values of 740 nGy/h for Abu Rusheid albite granite and 429 nGy/h for Um Naggat albite granite. The activity concentration and gamma-ray exposure dose rates of the radioactive elements ²³⁸U, ²²⁶Ra, ²³²Th and ⁴⁰K at Abu Rusheid and Um Naggat exceeded the worldwide average values that recommend the necessity of radiation protection regulation. Moreover, the corresponding outdoor annual effective dose (AED_out) was calculated to be 0.9 and 0.5 mSv y⁻¹ for Abu Rusheid and Um Naggat albite granite, respectively, which are lower than the permissible level (1 mSv y⁻¹). By contrast, the indoor annual effective dose (AED_in) exceeded the recommended limit (3.6 and 2.1 for Abu Rusheid and Um Naggat, respectively). Therefore, the two areas are slightly saving for development projects concerning the use of the studied rocks. The statistical analysis displays that the effects of the radiological hazard are associated with the uranium and thorium activity concentrations in Abu Rusheid and Um Naggat albite granites. Full article

Eramet uses a combination of physical and hydrometallurgical treatment to recycle lithium-ion batteries. Before hydrometallurgical processing, mechanical treatment is applied to recover the Black Mass which contains nickel, cobalt, manganese and lithium as valuable elements as well as graphite, solvent, plastics, aluminium and copper. To evaluate the suitability for hydrometallurgical recycling, it is essential to analyse the Black Mass chemically but also with respect to size, shape and composition of particles in the Black Mass. The Black Mass of various battery recyclers was investigated by using a combination of SEM/QEMSCAN^® analyses. This specific QEMSCAN^® database contains 260 subgroups, which comprise major and minor chemical variations of phases. The database was created using millions of point analyses. Major observations are: (1) particles can be micro-texturally characterised and classified with respect to chemical element contents; (2) important textural and chemical particle variations exist in the Black Mass from several origins leading to different levels of quality; (3) elements deleterious to hydrometallurgical processing (i.g. Si, Ca, Ti, Al, Cu and others) are present in well liberated particles; (4) components can be quantified and cathodes active material compositions (LCO, different NMC, NCA, LFP, etc.) that are specific for each battery type can be identified; (5) simulation of further physical mineral processing can optimise Black Mass purity in valuable elements. Full article

Minerals and rocks are important natural resources that are formed over a long period of geological history. Spectroscopy is the basis of the identification and characterisation of rocks and minerals via proximal sensing in the field or remote sensing systems with multi- and hyper-spectral capabilities. However, spectral data is scattered around different institutions worldwide and stored in various formats, resulting in poor data usability and an unnecessary waste of time and information. To improve the usability and performance of mineral spectral data, we developed an integrated open mineral spectral library (Rock Spectral Library, RockSL). Shared spectral data and related information were collected worldwide, and data cleaning measures were performed to retain the qualified spectra and merge all qualified data (raster, vector, and text formats) in a common framework to establish a reliable and comprehensive digital data set for an easy sharing and matching service. A software system was developed for the RockSL to manage, analyse, and apply the spectral data of minerals and rocks. We demonstrate how the information encoded in RockSL can determine the species of unknown rocks and describe specific mineral compositions. We also provide a reference scheme of the work chain and present key technologies for building different spectral libraries in diverse fields using RockSL. New contributions to RockSL are encouraged for this work to be improved to provide a better service and extend the applications of geo-sciences. This article introduces the characteristics of RockSL and demonstrates an experimental application. Full article

In this paper, the chemical composition and crystalline properties of mammoth ivory and ivory were systematically analyzed. The results revealed that the microscopic crystalline hydroxyapatites are the major component of minerals in mammoth ivory and ivory. The Ca/P ratios of the samples studied are obviously lower than apatite. Refined cell parameters showed a similar value between mammoth ivory (a = 9.4148 Å and b = 6.8821 Å) and ivory (a = 9.4166 Å and c = 6.8841 Å). Individual crystal sizes in mammoth ivory and ivory are estimated to be 20.41–23.16 and 18.92–21.50 nm, respectively. The calculated crystallinity of two kinds of ivory (mammoth ivory: 1.55; ivory: 1.4) is far lower than geological mineral fluorapatite due to the impact of tissue function and organic matrix. Full article

During the Aptian-Albian transition, an extensional phase of the Central Atlantic which affected the Prebetic carbonate platform (South Iberian Continental Margin, northwestern margin of the Tethys) occurred. A graben morphology was developed in the platform coeval to a relative sea level fall. As a consequence, palustrine facies characterized by rhizoliths and some pond deposits of black lutites were established. Over these palustrine sediments, a second shallow carbonate platform was built during the early Albian. However, this process was not abrupt, as several levels with orbitolines and rudists were deposited intercalated between the continental facies, recording the transition to a new shallow marine carbonate platform developped during the Early Albian. The presence of these continental palustrine sediments between two episodes of shallow carbonate platform is described for the first time in the Prebetic. The demise of an upper Aptian isolated shallow carbonate platform drove to the deposition of these palustrine sediments in an extensional tectonic regime. Full article

In this study, we investigated the localized and concomitant precipitation of calcium (Ca)/magnesium (Mg)-bearing species and iron oxides/oxyhydroxides, and their depression characteristics to the pyrite floatability in flotation process at pH 9 and pH 10.5 with prolonged pre-oxidation. Contrary to the depression characteristics at pH 9, the incipient (within aeration times of 30 min) depression of pyrite floatability in Ca/Mg-bearing solutions was more obvious at pH 10.5, while the subsequent decline was only slightly when the pre-oxidation time was expanded to 120 min and 360 min. The competitive adsorption among Ca/Mg-bearing species and potassium amyl xanthate (PAX, C₆H₁₁OS₂K, collector) at specific sites onto the pyrite surface was demonstrated by the regularly decreased zeta potential of the pyrite surface pretreated in Ca/Mg-bearing solutions. Further scanning electron microscopy-energy dispersive spectrometry demonstrated the concomitant secondary Ca/Mg/Fe-bearing precipitates on the pyrite surface. X-Ray photoelectron spectroscopy suggested strong reprecipitation of iron oxides/oxyhydroxides on the pyrite surface via acid–base complexation among Ca/Mg hydroxy species and iron hydroxy species. Incipient occupation efficiency of specific reaction sites by Ca/Mg-bearing species, which were mainly controlled by the metastable distribution of Ca/Mg hydroxy species and their electrostatic affinity with pyrite surface, was the crucial factor that influenced the competitive adsorption of xanthate and pyrite floatability. More obvious incipient depression at pH 10.5 rather than at pH 9 contributed to more effective Ca/Mg-bearing species and their higher affinity to pyrite surface at pH 10.5. The localized and concomitant precipitation of secondary Ca/Mg/Fe-bearing species leads to a slightly increased hydrophilic coverage upon the pyrite surface, thus a slowly decreased pyrite floatability with increasing pre-oxidation time. Full article

Archean banded iron formations (BIF) represent a major contributor to better constraining and assessing the paleogeography and evolution of Archean cratons. In this context, we conducted an exhaustive sampling and analysis campaign of BIF units in the Congo Craton, covering several greenstone belts within the Ivindo, Kelle-Mbomo, and Chaillu blocks. The REE + Y patterns suggest: (1) Interaction of seawater with Fe-oxyhydroxides, as illustrated by strong REE enrichment coupled with La and Y enrichment; (2) contributions from high-temperature (>250 °C) hydrothermal fluids, illustrated by positive Eu anomalies; and (3) detrital input as suggested by relatively consistent REE concentrations and a chondritic Y/Ho ratio. These observations suggest a typical environment of Algoma-type BIF deposition. Moreover, assessment of the Ce anomalies in a combination of HREE enrichment indicates that some basins in the Chaillu and Ivindo blocks may have known potential oxygen-rich episodes in the early Archean during the deposition of these BIFs. Full article

The origin and geodynamic settings of the Ust’-Sema Formation and the Barangol Complex are some of the most controversial issues in the Early Paleozoic history of the Altai–Sayan Fold Belt. The Ust’-Sema Formation volcanic rocks are enriched in high-Ca clinopyroxene phenocrysts and were classified as ankaramites and diopside porphyry basalts. In this work, we first present LA-ICP-MS analyses of the clinopyroxenes, along with studies of the petrography, mineral composition, and whole-rock chemistry of the Ust’-Sema Formation and related Barangol Complex rocks. An LA-ICP-MS clinopyroxene study showed a slight depletion of light rare-earth elements (La/Yb)_N = 0.1–1.0 (on average 0.4); and strong depletion of the high-field-strength elements (Zr, Hf, and Nb) and large-ion lithophile (Rb) elements. An Sr anomaly showed a positive correlation with Mg#. Major- and trace-element composition of the clinopyroxene cores show that these clinopyroxene grains were not captured from the mantle rocks as previously assumed and that the Ust’-Sema Formation and the Barangol Complex rocks were formed from magma with island arc characteristics. The increased titanium and light rare-earth element contents in the phenocryst rims from Biyka volcano suggest an active interaction of the ankaramitic magma with rocks or melts of OIB type. Full article

The TTZ-South seismic profile follows the Teisseyre-Tornquist zone (TTZ) at the SW margin of the East European craton (EEC). Investigation results reveal the upper lithospheric structure as representing the NW-vergent, NE-SW striking overthrust-type, Paleoproterozoic (~1.84–1.8 Ga) Fennoscandia-Sarmatia suture. The Sarmatian segment of the EEC comprises two crustal-scale tectonic thrust slices: the Moldavo-Podolian and Lublino-Volhynian basement units, overriding the northerly located Lysogoro-Radomian unit of Fennoscandian affinity. The combined results of the TTZ-South and other nearby deep seismic profiles are consistent with a continuation of the EEC cratonic basement across the TTZ to the SW and its plunging into the deep substratum of the adjacent Paleozoic platform. Extensional deformation responsible for the formation of the mid to late Proterozoic (~1.4–0.6 Ga), SW-NE trending Orsha-Volhynia rift basin is probably also recorded. The thick Ediacaran succession deposited in the rift was later tectonically thickened due to Variscan deformation. The Moho depth varies between 37 and 49 km, resulting in the thinnest crust in the SE, sharp depth changes across the TTZ, and slow shallowing from 49 to 43 km to the NW. The abrupt Moho depth increase from 43 to 49 km is considered to reflect the overlying lower crust tectonic duplication within the suture zone. Full article

Humans are dependent upon soil which supplies food, fuel, chemicals, medicine, sequesters pollutants, purifies and conveys water, and supports the built environment. In short, we need soil, but it has little or no need of us. Agriculture, mining, urbanization and other human activities result in temporary land-use and once complete, used and degraded land should be rehabilitated and restored to minimize loss of soil carbon. It is generally accepted that the most effective strategy is phyto-remediation. Typically, phytoremediation involves re-invigoration of soil fertility, physicochemical properties, and its microbiome to facilitate establishment of appropriate climax cover vegetation. A myco-phytoremediation technology called Fungcoal was developed in South Africa to achieve these outcomes for land disturbed by coal mining. Here we outline the contemporary and expanded rationale that underpins Fungcoal, which relies on in situ bio-conversion of carbonaceous waste coal or discard, in order to explore the probable origin of humic substances (HS) and soil organic matter (SOM). To achieve this, microbial processing of low-grade coal and discard, including bio-liquefaction and bio-conversion, is examined in some detail. The significance, origin, structure, and mode of action of coal-derived humics are recounted to emphasize the dynamic equilibrium, that is, humification and the derivation of soil organic matter (SOM). The contribution of plant exudate, extracellular vesicles (EV), extra polymeric substances (EPS), and other small molecules as components of the dynamic equilibrium that sustains SOM is highlighted. Arbuscular mycorrhizal fungi (AMF), saprophytic ectomycorrhizal fungi (EMF), and plant growth promoting rhizobacteria (PGPR) are considered essential microbial biocatalysts that provide mutualistic support to sustain plant growth following soil reclamation and restoration. Finally, we posit that de novo synthesis of SOM is by specialized microbial consortia (or ‘humifiers’) which use molecular components from the root metabolome; and, that combinations of functional biocatalyst act to re-establish and maintain the soil dynamic. It is concluded that a bio-scaffold is necessary for functional phytoremediation including maintenance of the SOM dynamic and overall biogeochemistry of organic carbon in the global ecosystem Full article

The goal of the present work was to evaluate the possibility of improving the efficiency of the stirred tank reactor biooxidation of sulfide gold-bearing concentrate by means of addition of carbon sources required for the constructive metabolism of microorganisms. Biooxidation experiments were performed on gold-bearing pyrite-arsenopyrite concentrate in continuous mode at 45 °C to determine the influence of additional carbon sources (carbon dioxide and molasses) on sulfide mineral oxidation. The use of CO₂ allowed increasing the efficiency of the biooxidation and the extents of sulfide sulfur (Ss) oxidation and gold recovery were 79% and 84%, respectively. Biooxidation in a control experiment (without additional carbon sources) and when using molasses allowed achieving 39% and 66% oxidation of Ss as well as 73% and 81% of gold recovery. Analysis of the microbial populations formed in biooxidation reactors using NGS methods demonstrated that CO₂ application led to an increase in the relative abundance of the genus Sulfobacillus. Thus, it was determined that application of additional carbon source makes it possible to manage the biooxidation process, affecting both sulfide mineral oxidation and microbial population composition. Full article

The oxidation state of iron in minerals is an important part of analysis. Especially for minerals used as a raw material for metallurgical processes, the oxidation state has a significant impact on the process. One crucial impact is the varying carbon requirement in smelting furnaces, which can be significantly different if the oxidation state is not assessed correctly. Compared to methods usually used to determine the oxidation state, a relatively simple and fast thermogravimetric method is proposed in this article. As a sample, a detailed analyzed chromite sample from Turkey is used. Bulk chemical analysis, Raman spectroscopy, X-ray diffraction, and QEMSCAN^® are used to determine the preconditions of the sample. Mössbauer spectroscopy is used as a reference method to determine the oxidation state of iron in the sample. Uncertified wet chemical methods are investigated as well in this paper and the results are compared with the reference measurement. Using a thermochemical simulation tool, parameters for the thermogravimetric method are investigated and the limitation of this method is examined. The mean ferrous ratio in the sample determined by the proposed method is 75.205%, which is only slightly lower than the ferrous ratio of 76% determined by Mössbauer spectroscopy. Full article

Coal and rock dynamic disasters have been the main concern in underground engineering because these seriously threaten the safety of miners and industrial production. Aiming to improve the EMR and AE monitoring technology, the refined nonlinear characteristics of EMR and AE during coal splitting failure are studied using Hilbert-H and multifractal theory, and valuable information pertaining to coal fracture law contained in EMR and AE waveform was revealed. The results show that the EMR and AE of coal splitting failure are related to the process of coal crack propagation. They possess the same initiation time and frequency band, however, the signal duration of EMR is comparatively longer than AE, and the main frequency of AE is higher than EMR. The EMR of coal splitting failure has the same excitation source as AE; nonetheless, the excited forms display different behavior. In terms of signal duration, the distribution of EMR signal is relatively uniform, the proportion of large-signal is less, the amount of information is more than that of AE, and the multifractal characteristics are more complicated. During the coal splitting failure, AE is mainly generated in the process of wall vibration caused by crack propagation, while the generation of EMR includes piezoelectric effect, charge separation, free charge vibration, charge neutralization and other processes, making EMR more complicated than AE and has a relatively low frequency. The research provides an effective method for studying nonlinear refinement characteristics of coal EMR and AE, and can provide an important basis for the study of the mechanism of EMR generation. Full article