Minerals

5 pages, 159 KiB

Open AccessEditorial

Editorial for Special Issue “Adsorption Properties and Environmental Applications of Clay Minerals”

by Dušan Vopálka and Bin Mu

Minerals 2025, 15(8), 791; https://doi.org/10.3390/min15080791 - 28 Jul 2025

Clay minerals play a fundamental role in various environmental processes, particularly in controlling the movement of various ions and molecules in soils, waters and natural and/or engineered barriers of waste storage facilities [...] Full article

(This article belongs to the Special Issue Adsorption Properties and Environmental Applications of Clay Minerals)

16 pages, 5933 KiB

Open AccessArticle

Chemical Peculiarities of Quartz from Peralkaline Granitoids

by Karel Breiter, Jindřich Kynický, Michaela Vašinová Galiová and Michaela Hložková

Minerals 2025, 15(8), 790; https://doi.org/10.3390/min15080790 - 28 Jul 2025

Abstract

Quartz from four typical but contrasting peralkaline quartz-saturated granite systems (Khan Bogd and Khalzan Buregte plutons (Mongolia), Ivigtut stock (Greenland), Europa and Madeira plutons (Pitinga magmatic province, Brazil)) was analyzed using LA-ICP-MS to define the range of selected trace element content and trends [...] Read more.

Quartz from four typical but contrasting peralkaline quartz-saturated granite systems (Khan Bogd and Khalzan Buregte plutons (Mongolia), Ivigtut stock (Greenland), Europa and Madeira plutons (Pitinga magmatic province, Brazil)) was analyzed using LA-ICP-MS to define the range of selected trace element content and trends in their evolution and to compare this content with published data from granitoids of other geochemical types. The evaluation of about 1100 analyses found the studied trace elements mostly in ranges <0.01–18 ppm Li (median 2.41 ppm), 1.2–77 ppm Ti (median 8.2 ppm), 8.3–163 ppm Al (median 42 ppm) and 0.05–5.7 ppm Ge (median 0.98 ppm) (in all cases 5% of the lowest and 5% of the highest values were omitted). Quartz from geochemically less evolved riebeckite-bearing granite plutons shows no Ti/Ge fractionation and displays either a positive Ti–Al correlation or no Ti–Al correlation. More fractionated and potentially mineralized peralkaline magmatic systems were formed within two distinct magmatic episodes: quartz from the older phases is relatively Ti-rich and evolved via Ti decrease with no possible Ge enrichment, while quartz from younger phases is Ti-poor from the beginning and has the ability of enrichment in Al and Ge. Relative enrichment in Al and increase in Ge/Ti value of quartz can serve as a supporting method for the identification of potentially ore-bearing magmatic systems. Full article

(This article belongs to the Special Issue Physicochemical Properties and Purification of Quartz Minerals)

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37 pages, 22971 KiB

Open AccessArticle

Sedimentary Facies and Geochemical Signatures of the Khewra Sandstone: Reconstructing Cambrian Paleoclimates and Paleoweathering in the Salt Range, Pakistan

by Abdul Bari Qanit, Shahid Iqbal, Azharul Haq Kamran, Muhammad Idrees, Benjamin Sames and Michael Wagreich

Minerals 2025, 15(8), 789; https://doi.org/10.3390/min15080789 - 28 Jul 2025

Abstract

Red sandstones of the Cambrian age are globally distributed and represent an important sedimentation phase during this critical time interval. Their sedimentology and geochemistry can provide key information about the sedimentation style, paleoclimatic conditions, and weathering trends during the Cambrian. In the Salt [...] Read more.

Red sandstones of the Cambrian age are globally distributed and represent an important sedimentation phase during this critical time interval. Their sedimentology and geochemistry can provide key information about the sedimentation style, paleoclimatic conditions, and weathering trends during the Cambrian. In the Salt Range of Pakistan, the Khewra Sandstone constitutes the Lower Cambrian strata and consists of red–maroon sandstones with minor siltstone and shale in the basal part. Cross-bedding, graded bedding, ripple marks, parallel laminations, load casts, ball and pillows, desiccation cracks, and bioturbation are the common sedimentary features of the formation. The sandstones are fine to medium to coarse-grained with subangular to subrounded morphology and display an overall coarsening upward trend. Petrographic analysis indicates that the sandstones are sub-arkose and sub-lithic arenites, and dolomite and calcite are common cementing materials. X-ray Diffraction (XRD) analysis indicates that the main minerals in the formation are quartz, feldspars, kaolinite, illite, mica, hematite, dolomite, and calcite. Geochemical analysis indicates that SiO₂ is the major component at a range of 53.3 to 88% (averaging 70.4%), Al₂O₃ ranges from 3.1 to 19.2% (averaging 9.2%), CaO ranges from 0.4 to 25.3% (averaging 7.4%), K₂O ranges from 1.2 to 7.4% (averaging 4.8%), MgO ranges from 0.2 to 7.4% (averaging 3.5%), and Na₂O ranges from 0.1 to 0.9% (averaging 0.4%), respectively. The results of the combined proxies indicate that the sedimentation occurred in fluvial–deltaic settings under overall arid to semi-arid paleoclimatic conditions with poor to moderate chemical weathering. The Khewra Sandstone represents the red Cambrian sandstones on the NW Indian Plate margin of Gondwana and can be correlated with contemporaneous red sandstones in the USA, Europe, Africa, Iran, and Turkey (Türkiye). Full article

(This article belongs to the Section Mineral Geochemistry and Geochronology)

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13 pages, 3716 KiB

Open AccessArticle

Mineralogy and Preparation of High-Purity Quartz: A Case Study from Pegmatite in the Eastern Sector of the North Qinling Orogenic Belt

by Deshui Yu, Yameng Ma, Shoujing Wang, Chi Ma and Fushuai Wei

Minerals 2025, 15(8), 788; https://doi.org/10.3390/min15080788 - 27 Jul 2025

Abstract

High-purity quartz (HPQ), an indispensable industrial mineral, serves as a critical raw material for advanced technology sectors. Derived from natural quartz precursors through processing, HPQ preparation efficiency fundamentally depends on raw material selection. Two pegmatite samples (muscovite pegmatite and two-mica pegmatite) sampled from [...] Read more.

High-purity quartz (HPQ), an indispensable industrial mineral, serves as a critical raw material for advanced technology sectors. Derived from natural quartz precursors through processing, HPQ preparation efficiency fundamentally depends on raw material selection. Two pegmatite samples (muscovite pegmatite and two-mica pegmatite) sampled from the eastern sector of the North Qinling Orogenic Belt were investigated through a suite of analytical techniques, as well as processing and purification, to evaluate their potential as raw materials for high-purity quartz. Muscovite pegmatite is predominantly composed of quartz, plagioclase, K-feldspar, muscovite, and garnet, with accessory phases including limonite and kaolinite. However, in addition to quartz, plagioclase, K-feldspar, muscovite, garnet, and limonite, two-mica pegmatite contains minerals such as biotite and calcite. The fluid inclusions in both muscovite and two-mica pegmatite quartz are small, but the former has fewer fluid inclusions. Compared with muscovite pegmatite, surface discontinuity (i.e., cracks, pits, cavities) development is more pronounced in two-mica pegmatite purified quartz, which may be related to its high content of fluid inclusions. Following purification, the total concentration of trace elements decreased significantly. However, the concentrations of Al and Ti appeared to remain the same. Titanium enrichment in purified two-mica pegmatite quartz likely derives from biotite, while Na and Ca concentrations may be related to fluid inclusions or microscopic mineral inclusions. The trace element content (27.69 ppm) in muscovite pegmatite is lower than that (45.28 ppm) of two-mica pegmatite, we thus suggest that muscovite pegmatite quartz is more likely to have the potential to produce high-purity quartz. Full article

(This article belongs to the Special Issue Physicochemical Properties and Purification of Quartz Minerals)

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22 pages, 8515 KiB

Open AccessArticle

Preparation and Performance Study of Alkali-Activated Conductive Mortar via Response Surface Methodology

by Wenfang Lv, Wenhua Zha, Tao Xu and Minqian Sun

Minerals 2025, 15(8), 787; https://doi.org/10.3390/min15080787 - 26 Jul 2025

Abstract

In this study, alkali-activated coal gangue-slag material (AACGS) was prepared using coal gangue and slag as precursors, and its feasibility as conductive mortar substrate material was preliminarily investigated. Firstly, this study employed Response Surface Methodology (RSM) to develop statistical models correlating the alkali [...] Read more.

In this study, alkali-activated coal gangue-slag material (AACGS) was prepared using coal gangue and slag as precursors, and its feasibility as conductive mortar substrate material was preliminarily investigated. Firstly, this study employed Response Surface Methodology (RSM) to develop statistical models correlating the alkali equivalent, water-to-binder ratio, and slag content with the compressive strength, flexural strength, and resistivity of AACGS, aiming to identify the optimal mix proportions. Secondly, based on the optimal ratio identified above and using carbon fibers (CF) as the conductive phase, an alkali-activated conductive mortar (CF-AACGS) was prepared, and its compressive strength, flexural strength, and resistivity were tested. Lastly, XRD and SEM-EDS were conducted to characterize the mineral composition and microstructure of CF-AACGS. The results indicate that when the alkali equivalent, water-to-binder ratio, and slag content are 13.34%, 0.54, and 57.52%, respectively, the AACGS achieves compressive strength, flexural strength, and resistivity of 72.5 MPa, 7.0 MPa, and 62.41 Ω·m at 28 days. Under the action of the alkali activator, coal gangue and slag undergo hydration reactions, forming a denser N, C-(A)-S-H gel. This effectively improves the interface transition zone between the CF and AACGS, endowing the CF-AACGS with superior mechanical properties. Furthermore, the AACGS matrix enhances the conductive contact point density by optimizing CF dispersion, which significantly reduces the resistivity of the CF-AACGS. Full article

(This article belongs to the Special Issue Development in Alkali-Activated Materials and Applications)

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15 pages, 2134 KiB

Open AccessArticle

Integrated Characterization of Sediments Contaminated by Acid Mine Drainage: Mineralogical, Magnetic, and Geochemical Properties

by Patrícia Gomes, Teresa Valente and Eric Font

Minerals 2025, 15(8), 786; https://doi.org/10.3390/min15080786 - 26 Jul 2025

Abstract

Acid mine drainage, a consequence of exposure of sulfide mining waste to weathering processes, results in significant water, sediment, and soil contamination. This contamination results in acidophilic ecosystems, with low pH values and elevated concentrations of sulfate and potentially toxic elements. The São [...] Read more.

Acid mine drainage, a consequence of exposure of sulfide mining waste to weathering processes, results in significant water, sediment, and soil contamination. This contamination results in acidophilic ecosystems, with low pH values and elevated concentrations of sulfate and potentially toxic elements. The São Domingos mine, an abandoned site in the Iberian Pyrite Belt, lacks remediation measures and has numerous waste dumps, which are a major source of contamination to local water systems. Therefore, this study examines sediment accumulation in five mine dams along the São Domingos stream that traverses the entire mine complex. Decades of sediment and waste transport since mine closure have resulted in dam-clogging processes. The geochemical, mineralogical, and magnetic properties of the sediments were analyzed to evaluate the mineralogical controls on the mobilization of potentially toxic elements. The sediments are dominated by iron oxides, oxyhydroxides, and hydroxysulfates, with jarosite playing a key role in binding high concentrations of iron and toxic elements. However, no considerable correlation was found between potentially toxic elements and magnetic parameters, highlighting the complex behavior of these contaminants in acid mine drainage-affected systems. Full article

(This article belongs to the Section Environmental Mineralogy and Biogeochemistry)

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19 pages, 8002 KiB

Open AccessArticle

3D Forward Simulation of Borehole-Surface Transient Electromagnetic Based on Unstructured Finite Element Method

by Jiayi Liu, Tianjun Cheng, Lei Zhou, Xinyu Wang and Xingbing Xie

Minerals 2025, 15(8), 785; https://doi.org/10.3390/min15080785 - 26 Jul 2025

Abstract

The time-domain electromagnetic method has been widely applied in mineral exploration, oil, and gas fields in recent years. However, its response characteristics remain unclear, and there is an urgent need to study the response characteristics of the borehole-surface transient electromagnetic(BSTEM) field. This study [...] Read more.

The time-domain electromagnetic method has been widely applied in mineral exploration, oil, and gas fields in recent years. However, its response characteristics remain unclear, and there is an urgent need to study the response characteristics of the borehole-surface transient electromagnetic(BSTEM) field. This study starts from the time-domain electric field diffusion equation and discretizes the calculation area in space using tetrahedral meshes. The Galerkin method is used to derive the finite element equation of the electric field, and the vector interpolation basis function is used to approximate the electric field in any arbitrary tetrahedral mesh in the free space, thus achieving the three-dimensional forward simulation of the BSTEM field based on the finite element method. Following validation of the numerical simulation method, we further analyze the electromagnetic field response excited by vertical line sources.. Through comparison, it is concluded that measuring the radial electric field is the most intuitive and effective layout method for BSTEM, with a focus on the propagation characteristics of the electromagnetic field in both low-resistance and high-resistance anomalies at different positions. Numerical simulations reveal that BSTEM demonstrates superior resolution capability for low-resistivity anomalies, while showing limited detectability for high-resistivity anomalies Numerical simulation results of BSTEM with realistic orebody models, the correctness of this rule is further verified. This has important implications for our understanding of the propagation laws of BSTEM as well as for subsequent data processing and interpretation. Full article

(This article belongs to the Special Issue Geoelectricity and Electrical Methods in Mineral Exploration)

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22 pages, 9529 KiB

Open AccessArticle

Geochemistry and Geochronology of the Late Permian Linxi Formation in the Songliao Basin, China: Tectonic Implications for the Paleo-Asian Ocean

by Xin Huang, Haihua Zhang, Liang Qiu, Gongjian Li, Yujin Zhang, Wei Chen, Shuwang Chen and Yuejuan Zheng

Minerals 2025, 15(8), 784; https://doi.org/10.3390/min15080784 - 25 Jul 2025

Abstract

The Central Asian Orogenic Belt (CAOB) represents a crucial area for understanding the tectonic evolution of the Paleo-Asian Ocean and surrounding orogenic systems. This study investigates the petrology, geochronology, and geochemistry of volcanic and clastic rocks from Well HFD3 in the northern Songliao [...] Read more.

The Central Asian Orogenic Belt (CAOB) represents a crucial area for understanding the tectonic evolution of the Paleo-Asian Ocean and surrounding orogenic systems. This study investigates the petrology, geochronology, and geochemistry of volcanic and clastic rocks from Well HFD3 in the northern Songliao Basin, which provides key insights into the tectonic development of this region. Zircon U–Pb dating of tuff samples from the Linxi Formation provides an accurate age of 251.1 ± 1.1 Ma, corresponding to the late Permian. Geochemical analyses show that the clastic rocks are rich in SiO₂ (63.5%) and Al₂O₃ (13.7%), with lower K₂O/Na₂O ratios (0.01–1.55), suggesting low compositional maturity. Additionally, the trace element data reveal enrichment in light rare earth elements (LREEs) and depletion in Nb, Sr, and Ta, with a negative Eu anomaly, which indicates a felsic volcanic arc origin. The Chemical Index of Alteration (CIA) values (53.2–65.8) reflect weak chemical weathering, consistent with cold and dry paleo-climatic conditions. These findings suggest that the Linxi Formation clastic rocks are derived from felsic volcanic arcs in an active continental margin environment, linked to the subduction of the Paleo-Asian Ocean slab. The sedimentary conditions reflect a gradual transition from brackish to freshwater environments, corresponding with the final stages of subduction or the onset of orogeny. Full article

(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)

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14 pages, 12586 KiB

Open AccessArticle

Three-Dimensional Mineralization Prediction Using the Information Value Method: A Case Study of the Bainiuchang Ag Polymetallic Deposit, Southwest China

by Fuju Jia, Guolong Zheng, Guangzhi Meng, Long Jian, He Chang, Ping Pan, Jianguo Gao, Zhixiao Wu and Ceting Yang

Minerals 2025, 15(8), 783; https://doi.org/10.3390/min15080783 - 25 Jul 2025

Abstract

Three-dimensional geological modeling combined with the information value method offers a powerful approach for predicting mineralization in complex geological settings. This study applies these techniques to the Bainiuchang Ag polymetallic deposit in Southwest China. We constructed a detailed 3D geological model to identify [...] Read more.

Three-dimensional geological modeling combined with the information value method offers a powerful approach for predicting mineralization in complex geological settings. This study applies these techniques to the Bainiuchang Ag polymetallic deposit in Southwest China. We constructed a detailed 3D geological model to identify key geological factors influencing mineralization, such as the F₃ fault, secondary faults, and the middle Cambrian Tianpeng Formation. Using the information value method, we evaluated the mineralization potential of each unit in the study area. Receiver operating characteristic (ROC) curves and fractal analysis were employed to determine an optimal threshold (information value > 2.6) for delineating high-potential exploration targets. Our results identified three priority targets (A1, A2, and A3), demonstrating the effectiveness of integrating 3D modeling with probabilistic mineral prospectivity mapping. This approach provides a robust framework for deep and peripheral exploration in structurally complex deposits, offering valuable insights for future mineral exploration efforts. Full article

(This article belongs to the Special Issue Editorial Board Members’ Collection Series: "Critical and Strategic Minerals", 2nd Edition)

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18 pages, 2688 KiB

Open AccessArticle

Eco-Friendly Leaching of Spent Lithium-Ion Battery Black Mass Using a Ternary Deep Eutectic Solvent System Based on Choline Chloride, Glycolic Acid, and Ascorbic Acid

by Furkan Nazlı, Işıl Hasdemir, Emircan Uysal, Halide Nur Dursun, Utku Orçun Gezici, Duygu Yesiltepe Özçelik, Fırat Burat and Sebahattin Gürmen

Minerals 2025, 15(8), 782; https://doi.org/10.3390/min15080782 - 25 Jul 2025

Abstract

Lithium-ion batteries (LiBs) are utilized in numerous applications due to advancements in technology, and the recovery of end-of-life (EoL) LiBs is imperative for environmental and economic reasons. Pyrometallurgical and hydrometallurgical methods have been used in the recovery of metals such as Li, Co, [...] Read more.

Lithium-ion batteries (LiBs) are utilized in numerous applications due to advancements in technology, and the recovery of end-of-life (EoL) LiBs is imperative for environmental and economic reasons. Pyrometallurgical and hydrometallurgical methods have been used in the recovery of metals such as Li, Co, and Ni in the EoL LiBs. Hydrometallurgical methods, which have been demonstrated to exhibit higher recovery efficiency and reduced energy consumption, have garnered increased attention in recent research. Inorganic acids, including HCl, HNO₃, and H₂SO₄, as well as organic acids such as acetic acid and citric acid, are employed in the hydrometallurgical recovery of these metals. It is imperative to acknowledge the environmental hazards posed by these acids. Consequently, solvometallurgical processes, which involve the use of organic solvents with minimal or no water, are gaining increasing attention as alternative or complementary techniques to conventional hydrometallurgical processes. In the context of solvent systems that have been examined for a range of solvometallurgical methods, deep eutectic solvents (DESs) have garnered particular interest due to their low toxicity, biodegradable nature, tunable properties, and efficient metal recovery potential. In this study, the leaching process of black mass containing graphite, LCO, NMC, and LMO was carried out in a short time using the ternary DES system. The ternary DES system consists of choline chloride (ChCl), glycolic acid (GLY), and ascorbic acid (AA). As a result of the leaching process of cathode powders in the black mass without any pre-enrichment process, Li, Co, Ni, and Mn elements passed into solution with an efficiency of over 95% at 60 °C and within 1 h. Moreover, the kinetics of the leaching process was investigated, and Density Functional Theory (DFT) calculations were used to explain the leaching mechanism. Full article

(This article belongs to the Special Issue Waste Valorization: Recycling and Recovery of Critical and Strategic Metals)

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40 pages, 18210 KiB

Open AccessArticle

Geological Significance of Bulk Density and Magnetic Susceptibility of the Rocks from Northwest Himalayas, Pakistan

by Fahad Hameed, Muhammad Rustam Khan, Jiangtao Tian, Muhammad Atif Bilal, Cheng Wang, Yongzhi Wang, Muhammad Saleem Mughal and Abrar Niaz

Minerals 2025, 15(8), 781; https://doi.org/10.3390/min15080781 - 25 Jul 2025

Abstract

The present study provides a detailed compilation and analysis of the bulk density and magnetic susceptibility of the rocks from the northwest Himalayas, Pakistan. The area is tectonically extremely complex and comprises sedimentary, metamorphic, and igneous rocks. These rocks range in age from [...] Read more.

The present study provides a detailed compilation and analysis of the bulk density and magnetic susceptibility of the rocks from the northwest Himalayas, Pakistan. The area is tectonically extremely complex and comprises sedimentary, metamorphic, and igneous rocks. These rocks range in age from Early Proterozoic to Recent. During the fieldwork, 476 rock samples were collected for density measurements and 410 for magnetic susceptibility measurements from the major rock units exposed in the study area. The measured physical parameters reveal a significant difference in the density and susceptibility of the rocks present in the investigated area. The sedimentary rock units belonging to the Indian Plate show the lowest mean values for bulk density, followed by metasedimentary rocks, Early Proterozoic rocks, igneous and metaigneous rock units of the Indian Plate, Indus Suture Melange Zone, and Kohistan Island Arc rocks, respectively. The magnetic susceptibility of sedimentary rock units of the Indian Plate has the lowest mean values, followed by metasedimentary rocks of the Indian Plate, igneous and metaigneous rock units of the Indian Plate, Early Proterozoic rocks of the Indian Plate, Kohistan Island Arc rocks, and Indus Suture Melange Zone. In brief, the sedimentary rocks of the Indian Plate have the lowest bulk density and magnetic susceptibility values, whereas the Kohistan Island Arc rocks have the highest values. Overall, the bulk density and magnetic susceptibility of rock units in the study area follow those predicted for different types of rocks. These measurements can be used to develop possible potential field models of the northwest Himalayas to better understand the tectonics of the ongoing continental-to-continental collision, as well as for many other geological analyses. Full article

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24 pages, 7393 KiB

Open AccessArticle

Thermodynamic Modeling Constrains the Alteration and Mineralization Patterns of the Pulang Porphyry Cu-Au Deposits in Eastern Tibet

by Shaoying Zhang, Wenyan He, Huaqing Wang and Yiwu Xiao

Minerals 2025, 15(8), 780; https://doi.org/10.3390/min15080780 - 25 Jul 2025

Abstract

Thermodynamic simulations of fluid–rock interactions provide valuable insights into mineral deposit formation mechanisms. This study investigates the Pulang porphyry Cu-Au deposit in the Sanjiang Tethys Orogen, employing both Gibbs energy minimization (GEM) and the Law of mass action (LMA) method to understand alteration [...] Read more.

Thermodynamic simulations of fluid–rock interactions provide valuable insights into mineral deposit formation mechanisms. This study investigates the Pulang porphyry Cu-Au deposit in the Sanjiang Tethys Orogen, employing both Gibbs energy minimization (GEM) and the Law of mass action (LMA) method to understand alteration overprinting and metal precipitation. The modeling results suggest that the ore-forming fluid related to potassic alteration was initially oxidized (ΔFMQ = +3.54~+3.26) with a near-neutral pH (pH = 5.0~7.0). Continued fluid–rock interactions, combined with the input of reduced groundwater, resulted in a decrease in both pH (4.8~6.1) and redox potential (ΔFMQ~+1), leading to the precipitation of propylitic alteration minerals and pyrrhotite. As temperature further decreased, fluids associated with phyllic alteration showed a slight increase in pH (5.8~6.0) and redox potential (ΔFMQ = +2). The intense superposition of propylitic and phyllic alteration on the potassic alteration zone is attributed to the rapid temperature decline in the magmatic–hydrothermal system, triggering fluid collapse and reflux. Mo, mainly transported as HMoO₄⁻ and MoO₄⁻², precipitated in the high-temperature range; Cu, carried primarily by CuCl complexes (CuCl₄⁻³, CuCl₂⁻, CuCl), precipitated over intermediate to high temperatures; and Au, transported as Au-S complexes (Au(HS)₂⁻, AuHS), precipitated from intermediate to low temperatures. This study demonstrates that fluid–rock interactions alone can account for the observed sequence of alteration and mineralization in porphyry systems. Full article

(This article belongs to the Special Issue Thermal History and Preservation Mechanisms of Porphyry-Cu Deposits: Evidence from Thermochronology, Mineral and Isotopic Geochemistry)

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21 pages, 3652 KiB

Open AccessArticle

Mechanical Loading of Barite Rocks: A Nanoscale Perspective

by Hassan Abubakar Adamu, Seun Isaiah Olajuyi, Abdulhakeem Bello, Peter Azikiwe Onwualu, Olumide Samuel Oluwaseun Ogunmodimu and David Oluwasegun Afolayan

Minerals 2025, 15(8), 779; https://doi.org/10.3390/min15080779 - 24 Jul 2025

Abstract

Barite, a mineral composed of barium sulphate, holds global significance due to its wide range of industrial applications. It plays a crucial role as a weighting agent in drilling fluids for the oil and gas industry, in radiation shielding, and as a filler [...] Read more.

Barite, a mineral composed of barium sulphate, holds global significance due to its wide range of industrial applications. It plays a crucial role as a weighting agent in drilling fluids for the oil and gas industry, in radiation shielding, and as a filler in paints and plastics. Although there are significant deposits of the mineral in commercial quantities in Nigeria, the use of barite of Nigerian origin has been low in the industry due to challenges that require further research and development. This research employed nanoindentation experiments using a model Ti950 Tribo indenter instrument equipped with a diamond Berkovich tip. Using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX), we gained information about the structure and elements in the samples. The load–displacement curves were examined to determine the hardness and reduced elastic modulus of the barite samples. The SEM images showed that barite grains have a typical grainy shape, with clear splitting lines and sizes. XRD and EDX analysis confirmed that the main components are chlorite, albite, barium, and oxygen, along with small impurities like silicon and calcium from quartz and calcite. The average hardness of the IB3 and IB4 samples was 1.88 GPa and 1.18 GPa, respectively, meaning that the IB3 sample will need more energy to crush because its hardness is within the usual barite hardness range of 1.7 GPa to 2.0 GPa. The findings suggest further beneficiation processes to enhance the material’s suitability for drilling and other applications. Full article

(This article belongs to the Special Issue Characterization of Minerals and Raw Materials Resources Replenishment)

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17 pages, 6395 KiB

Open AccessArticle

Fe–P Alloy Production from High-Phosphorus Oolitic Iron Ore via Efficient Pre-Reduction and Smelting Separation

by Mengjie Hu, Deqing Zhu, Jian Pan, Zhengqi Guo, Congcong Yang, Siwei Li and Wen Cao

Minerals 2025, 15(8), 778; https://doi.org/10.3390/min15080778 - 24 Jul 2025

Abstract

Diverging from conventional dephosphorization approaches, this study employs a novel pre-reduction and smelting separation (PR-SS) to efficiently co-recover iron and phosphorus from high-phosphorus oolitic iron ore, directly yielding Fe–P alloy, and the Fe–P alloy shows potential as feedstock for high-phosphorus weathering steel or [...] Read more.

Diverging from conventional dephosphorization approaches, this study employs a novel pre-reduction and smelting separation (PR-SS) to efficiently co-recover iron and phosphorus from high-phosphorus oolitic iron ore, directly yielding Fe–P alloy, and the Fe–P alloy shows potential as feedstock for high-phosphorus weathering steel or wear-resistant cast iron, indicating promising application prospects. Using oolitic magnetite concentrate (52.06% Fe, 0.37% P) as feedstock, optimized conditions including pre-reduction at 1050 °C for 2 h with C/Fe mass ratio of 2, followed by smelting separation at 1550 °C for 20 min with 5% coke, produced a metallic phase containing 99.24% Fe and 0.73% P. Iron and phosphorus recoveries reached 99.73% and 99.15%, respectively. EPMA microanalysis confirmed spatial correlation between iron and phosphorus in the metallic phase, with undetectable phosphorus signals in vitreous slag. This evidence suggests preferential phosphorus enrichment through interfacial mass transfer along the pathway of the slag phase to the metal interface and finally the iron matrix, forming homogeneous Fe–P solid solutions. The phosphorus migration mechanism involves sequential stages: apatite lattice decomposition liberates reactive P₂O₅ under SiO₂/Al₂O₃ influence; slag–iron interfacial co-reduction generates Fe₃P intermediates; Fe₃P incorporation into the iron matrix establishes stable solid solutions. Full article

(This article belongs to the Section Mineral Processing and Extractive Metallurgy)

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17 pages, 5410 KiB

Open AccessArticle

Mineral Phase Transformation and Leaching Behavior During the Roasting–Acid–Leaching Process of Clay-Type Lithium Ore in the Qaidam Basin

by Xiaoou Zhang, Jing Zhao, Yan Li, Dong An, Huaigang Cheng, Yuliang Ma and Huiping Song

Minerals 2025, 15(8), 777; https://doi.org/10.3390/min15080777 - 24 Jul 2025

Abstract

To address lithium extraction from clay-type lithium ore from the Qaidam Basin, this study identified key controlling factors through particle fractionation, acid-leaching–roasting experiments, and mineral characterization. The results demonstrate that particle size optimization enriched the lithium to 87.65 ppm, where a 74% leaching [...] Read more.

To address lithium extraction from clay-type lithium ore from the Qaidam Basin, this study identified key controlling factors through particle fractionation, acid-leaching–roasting experiments, and mineral characterization. The results demonstrate that particle size optimization enriched the lithium to 87.65 ppm, where a 74% leaching rate was achieved with 65 ppm extraction, which established intermediate-sized samples as optimal. During acid leaching, adsorbed lithium ions with a phyllosilicate interlayer were released via the ion exchange process instead of mineral dissolution, as verified by the Li-O/S-O peak shifts in the FTIR spectra. The roasting induced hydroxyl elimination, carbonate decomposition, and silicate restructuring but triggered lithium encapsulation via mineral phase reorganization, which caused a sharp leaching rate decline. Effective lithium extraction requires integrated particle size screening, acid-leaching optimization, and roasting-induced phase encapsulation disruption. This study established theoretical foundations for clay-type lithium ore exploitation. Full article

(This article belongs to the Section Mineral Processing and Extractive Metallurgy)

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43 pages, 20293 KiB

Open AccessArticle

Volcanic Stratigraphy, Petrology, Geochemistry and Precise U-Pb Zircon Geochronology of the Late Ediacaran Ouarzazate Group at the Oued Dar’a Caldera: Intracontinental Felsic Super-Eruptions in Association with Continental Flood Basalt Magmatism on the West African Craton (Saghro Massif, Anti-Atlas)

by Rachid Oukhro, Nasrrddine Youbi, Boriana Kalderon-Asael, David A. D. Evans, James Pierce, Jörn-Frederik Wotzlaw, Maria Ovtcharova, João Mata, Mohamed Achraf Mediany, Jihane Ounar, Warda El Moume, Ismail Hadimi, Oussama Moutbir, Moulay Ahmed Boumehdi, Abdelmalek Ouadjou and Andrey Bekker

Minerals 2025, 15(8), 776; https://doi.org/10.3390/min15080776 - 24 Jul 2025

Abstract

The Ouarzazate Group in the Anti-Atlas Belt of southern Morocco, part of the West African Craton (WAC), is a significant Proterozoic lithostratigraphic unit formed during the late Ediacaran period. It includes extensive volcanic rocks associated with the early stages of Iapetus Ocean opening. [...] Read more.

The Ouarzazate Group in the Anti-Atlas Belt of southern Morocco, part of the West African Craton (WAC), is a significant Proterozoic lithostratigraphic unit formed during the late Ediacaran period. It includes extensive volcanic rocks associated with the early stages of Iapetus Ocean opening. Zircon U-Pb dating and geochemical analyses of the Oued Dar’a Caldera (ODC) volcanic succession in the Saghro Massif reveal two major eruptive cycles corresponding to the lower and upper Ouarzazate Group. The 1st cycle (588–563 Ma) includes pre- and syn-caldera volcanic succession characterized by basaltic andesite to rhyolitic rocks, formed in a volcanic arc setting through lithospheric mantle-derived mafic magmatism and crustal melting. A major caldera-forming eruption occurred approximately 571–562 Ma, with associated rhyolitic dyke swarms indicating a larger caldera extent than previously known. The 2nd cycle (561–543 Ma) features post-caldera bimodal volcanism, with tholeiitic basalts and intraplate felsic magmas, signaling a shift to continental flood basalts and silicic volcanic systems. The entire volcanic activity spans approximately 23–40 million years. This succession is linked to late Ediacaran intracontinental super-eruptions tied to orogenic collapse and continental extension, likely in association with the Central Iapetus Magmatic Province (CIMP), marking a significant transition in the geodynamic evolution of the WAC. Full article

(This article belongs to the Special Issue Large Igneous Provinces, Carbonatites, Kimberlites, and Associated Ore Deposits of Africa)

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15 pages, 2127 KiB

Open AccessArticle

Accessible Interface for Museum Geological Exhibitions: PETRA—A Gesture-Controlled Experience of Three-Dimensional Rocks and Minerals

by Andrei Ionuţ Apopei

Minerals 2025, 15(8), 775; https://doi.org/10.3390/min15080775 - 24 Jul 2025

Abstract

The increasing integration of 3D technologies and machine learning is fundamentally reshaping mineral sciences and cultural heritage, establishing the foundation for an emerging “Mineralogy 4.0” framework. However, public engagement with digital 3D collections is often limited by complex or costly interfaces, such as [...] Read more.

The increasing integration of 3D technologies and machine learning is fundamentally reshaping mineral sciences and cultural heritage, establishing the foundation for an emerging “Mineralogy 4.0” framework. However, public engagement with digital 3D collections is often limited by complex or costly interfaces, such as VR/AR systems and traditional touchscreen kiosks, creating a clear need for more intuitive, accessible, and more engaging and inclusive solutions. This paper presents PETRA, an open-source, gesture-controlled system for exploring 3D rocks and minerals. Developed in the TouchDesigner environment, PETRA utilizes a standard webcam and the MediaPipe framework to translate natural hand movements into real-time manipulation of digital specimens, requiring no specialized hardware. The system provides a customizable, node-based framework for creating touchless, interactive exhibits. Successfully evaluated during a “Long Night of Museums” public event with 550 visitors, direct qualitative observations confirmed high user engagement, rapid instruction-free learnability across diverse age groups, and robust system stability in a continuous-use setting. As a practical case study, PETRA demonstrates that low-cost, webcam-based gesture control is a viable solution for creating accessible and immersive learning experiences. This work offers a significant contribution to the fields of digital mineralogy, human–machine interaction, and cultural heritage by providing a hygienic, scalable, and socially engaging method for interacting with geological collections. This research confirms that as digital archives grow, the development of human-centered interfaces is paramount in unlocking their full scientific and educational potential. Full article

(This article belongs to the Special Issue 3D Technologies and Machine Learning in Mineral Sciences)

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21 pages, 14467 KiB

Open AccessArticle

Mineral Characterization of Gold Ore Occurrences in the Khaptasynnakh Ore Zone, Anabar Shield, Far East Region, Russia

by Boris Gerasimov and Larisa Kondratieva

Minerals 2025, 15(8), 774; https://doi.org/10.3390/min15080774 - 24 Jul 2025

Abstract

Mineral characterization of gold-bearing metasomatites in the Khaptasynnakh ore zone of the Anabar Shield is provided in detail. The following ore formation sequence of mineral associations in the Khaptasynnakh zone was found: pyrite and pyrrhotite → gersdorffite and molybdenite → chalcopyrite, sphalerite, and [...] Read more.

Mineral characterization of gold-bearing metasomatites in the Khaptasynnakh ore zone of the Anabar Shield is provided in detail. The following ore formation sequence of mineral associations in the Khaptasynnakh zone was found: pyrite and pyrrhotite → gersdorffite and molybdenite → chalcopyrite, sphalerite, and galena → bornite and chalcocite → tellurides, native gold, stibnite, cinnabar, and native bismuth. Native gold is characterized by varying fineness (550 to 926‰) and Cu impurity (up to 7.87%) values. Most often, it forms symplectite intergrowths with Au telluride–calaverite. Native gold and Au tellurides showed inclusions of chalcocite, bornite, altaite, tellurobismuthite, rickardite, petzite, and clausthalite. A two-stage formation process of the examined gold is suggested: Low-fineness gold was introduced into the system during early potassium metasomatism, while higher-fineness gold related to silica metasomatism resulted from its additional mobilization by fluid during late-stage formation. The low-temperature gold–telluride association observed in the mineral paragenesis of ore-bearing rocks, as well as its inclusions in native gold, suggests epithermal gold–telluride mineralization. Mineral inclusions examined in placer gold validate a genetic relation between the examined ores and gold placers in the Khaptasynnakh ore zone. Full article

(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits, 2nd Edition)

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15 pages, 10214 KiB

Open AccessArticle

Comparative Evaluation of X-Ray Transmission and X-Ray Luminescence Sorting Technologies for Fine Diamond Recovery

by Zachary Lang, Shafiq Alam, Lucy Hunt, Antonio Di Feo, Chris Robben, Yuri Kinakin and Russell Tjossem

Minerals 2025, 15(8), 773; https://doi.org/10.3390/min15080773 - 23 Jul 2025

Abstract

A study of 300 diamonds in the 2–4 mm size range revealed that X-ray transmission demonstrated a predictable relationship for detecting diamonds, with all diamonds being identified. In contrast, X-ray luminescence showed no consistent relationship between diamond characteristics and detection, and not all [...] Read more.

A study of 300 diamonds in the 2–4 mm size range revealed that X-ray transmission demonstrated a predictable relationship for detecting diamonds, with all diamonds being identified. In contrast, X-ray luminescence showed no consistent relationship between diamond characteristics and detection, and not all diamonds were identified using this method. When comparing the X-ray transmission response of diamonds to common gangue minerals found in dense media separation concentrates, X-ray transmission was found to incidentally detect small amounts of gangue particles. However, no such gangue detection occurred with X-ray luminescence, which responded only to diamonds. In pilot-scale tests, a belt-fed X-ray transmission sorter with a pressurized air ejection mechanism and a chute-fed X-ray luminescence sorter with a mechanical paddle ejection system were evaluated. The X-ray transmission sorter produced an average of 0.28 kg of concentrate per gram of diamonds separated, while the X-ray luminescence sorter generated 0.37 kg of concentrate per gram of diamonds separated. The X-ray transmission sorter achieved 99% diamond recovery, whereas the X-ray luminescence sorter achieved 91% diamond recovery. The higher concentrate mass obtained from the X-ray luminescence sorter is attributed to the ineffectiveness of the mechanical paddles, despite the superior contrast between gangue and diamonds in detection. Full article

(This article belongs to the Section Mineral Processing and Extractive Metallurgy)

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