Minerals

22 pages, 6432 KB

Open AccessArticle

Minerals as Windows into Habitability on Lava Tube Basalts: A Biogeochemical Study at Lava Beds National Monument, CA

by Dina M. Bower, Amy C. McAdam, Clayton S. C. Yang, Feng Jin, Maeva Millan, Clara Christiann, Mathilde Mussetta, Christine Knudson, Jamielyn Jarvis, Sarah Johnson, Zachariah John, Catherine Maggiori, Patrick Whelley and Jacob Richardson

Minerals 2025, 15(12), 1303; https://doi.org/10.3390/min15121303 (registering DOI) - 14 Dec 2025

Abstract

Lava tubes on Earth provide unique hydrogeological niches for life to proliferate. Orbital observations of the Martian surface indicate the presence of lava tubes, which could hold the potential for extant life or the preservation of past life within a subsurface environment protected [...] Read more.

Lava tubes on Earth provide unique hydrogeological niches for life to proliferate. Orbital observations of the Martian surface indicate the presence of lava tubes, which could hold the potential for extant life or the preservation of past life within a subsurface environment protected from harsh conditions or weathering at the surface. Secondary minerals in lava tubes form as a combination of abiotic and biotic processes. Microbes colonize the surfaces rich in these secondary minerals, and their actions induce further alteration of the mineral deposits and host basalts. We conducted a biogeochemical investigation of basaltic lava tubes in the Medicine Lake region of northern California by characterizing the compositional variations in secondary minerals, organic compounds, microbial communities, and the host rocks to better understand how their biogeochemical signatures could indicate habitability. We used methods applicable to landed Mars missions, including Raman spectroscopy, X-ray diffraction (XRD), Laser-Induced Breakdown Spectroscopy (LIBS), and gas chromatography–mass spectrometry (GC-MS), along with scanning electron microscopy (SEM) and metagenomic DNA/RNA sequencing. The main secondary minerals, amorphous silicates, and calcite, formed abiotically from the cave waters. Two types of gypsum, large euhedral grains with halites, and cryptocrystalline masses near microbial material, were observed in our samples, indicating different formation pathways. The cryptocrystalline gypsum, along with clay minerals, was associated with microbial materials and biomolecular signatures among weathered primary basalt minerals, suggesting that their formation was related to biologic processes. Some of the genes and pathways observed indicated a mix of metabolisms, including those involved in sulfur and nitrogen cycling. The spatial relationships of microbial material, Cu-enriched hematite in the host basalts, and genetic signatures indicative of metal cycling also pointed to localized Fe oxidation and mobilization of Cu by the microbial communities. Collectively these results affirm the availability of bio-essential elements supporting diverse microbial populations on lava tube basalts. Further work exploring these relationships in lava tubes is needed to unravel the intertwined nature of abiotic and biotic interactions and how that affects habitability in these environments on Earth and the potential for life on Mars. Full article

(This article belongs to the Special Issue Exploring Novel Interactions Between Microbes and Minerals)

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16 pages, 964 KB

Open AccessArticle

Mineralogical and Geochemical Insights into Formation of the Muji Carbonic Springs, NW China

by Li Zhang, Yuxin Guo, Guodong Zheng, Yuanyuan Shao, Alireza K. Somarin, Vasilii Lavrushin and Xiangxian Ma

Minerals 2025, 15(12), 1302; https://doi.org/10.3390/min15121302 (registering DOI) - 13 Dec 2025

Abstract

The Muji carbonic springs on the northeastern margin of the Pamir Plateau provide a natural window into tectonically controlled CO₂ degassing within a continental collision zone. Through mineralogical and geochemical analyses, this study constrains the formation mechanisms and regional geological significance of [...] Read more.

The Muji carbonic springs on the northeastern margin of the Pamir Plateau provide a natural window into tectonically controlled CO₂ degassing within a continental collision zone. Through mineralogical and geochemical analyses, this study constrains the formation mechanisms and regional geological significance of carbonic spring systems. The formed deposits are dominated by calcite and aragonite, with minor dolomite, quartz, and gypsum. The compositions of major elements are consistent with the observed mineral assemblages, reflecting that the carbonate deposition was mainly governed by CO₂ degassing intensity and associated kinetic effects under cold-spring conditions. Carbon isotopes of the deposits are consistently enriched in heavy carbon with δ¹³C values of +3.5‰ to +9.1‰, indicating a persistent contribution of deep-sourced CO₂, most likely derived from metamorphic decarbonation of the crustal carbonates. Calcite exhibits moderate δ¹³C values due to rapid precipitation limiting isotope enrichment, whereas aragonite records higher δ¹³C signatures under subdued degassing and stable hydrodynamic regimes. The narrow δ¹⁸O range (−10.7‰ to −12.6‰), closely matching that of the spring waters, indicates that the tufas record the δ¹⁸O of the spring waters through DIC-water oxygen exchange. Trace element distributions (Sr–Ba–U) reveal systematic enrichment in deep-sourced fluids and progressive downstream geochemical alteration driven by spring–river mixing. The HD springs show high Sr and δ¹³C values, indicating minimal dilution of ascending CO₂-rich fluids, while MJX and MJXSP groups record variable degrees of shallow mixing. Collectively, the Muji system exemplifies a coupled process of “deep fluid input–shallow mixing–precipitation kinetics.” Its persistent heavy δ¹³C and trace-element enrichments demonstrate persistent metamorphic CO₂ release through fault conduits under ongoing compression. These findings establish the Muji springs as a key non-volcanic analogue for deep CO₂ degassing in continental collision zones and provides new insights into crustal carbon recycling and tectonic–hydrochemical coupling at plateau margins. Full article

(This article belongs to the Section Mineral Geochemistry and Geochronology)

22 pages, 1920 KB

Open AccessArticle

GC-FSegNet: A Flotation Froth Segmentation Network with Integrated Global Context Awareness

by Pengcheng Zhu, Zhihong Jiang, Zhen Peng and Gaipin Cai

Minerals 2025, 15(12), 1301; https://doi.org/10.3390/min15121301 - 12 Dec 2025

Abstract

Precise segmentation of flotation froths is a critical bottleneck to achieving intelligent perception and optimal control of process operations. Traditional convolutional neural networks (CNNs) are inherently limited by local receptive fields, making it challenging to accurately segment adhesive and multi-scale froths. To address [...] Read more.

Precise segmentation of flotation froths is a critical bottleneck to achieving intelligent perception and optimal control of process operations. Traditional convolutional neural networks (CNNs) are inherently limited by local receptive fields, making it challenging to accurately segment adhesive and multi-scale froths. To address this fundamental issue, this paper proposes a deep segmentation network with integrated global context awareness, termed GC-FSegNet, which establishes a new paradigm capable of jointly modeling macro-level structures and micro-level details. The proposed GC-FSegNet innovatively integrates the Global Context Network (GCNet) module into both the encoder and decoder of a Nested U-Net architecture. The GCNet captures long-range dependencies between froths, enabling macro-level modeling of clustered foam structures, while the Nested U-Net preserves high-resolution boundary details. Through their synergistic interaction, the model achieves simultaneous and efficient representation of both global contours and local details of froth images. Furthermore, the Mish activation function is employed to enhance the learning of weak boundary features, and a combined Dice and Binary Cross-Entropy (BCE) loss function is designed to optimize boundary segmentation accuracy. Experimental results on a self-constructed copper–lead flotation froth dataset demonstrate that GC-FSegNet achieves an mDice of 0.9443, mIoU of 0.8945, mRecall of 0.9866, and mPrecision of 0.9705, significantly outperforming mainstream models such as U-Net and DeepLabV3+. This study not only provides a reliable technical solution for high-adhesion froth segmentation but, more importantly, introduces a promising “global–local collaborative modeling” framework that can be extended to a wide range of complex industrial image segmentation scenarios. Full article

(This article belongs to the Section Mineral Processing and Extractive Metallurgy)

19 pages, 2024 KB

Open AccessArticle

Study on Low-Temperature Adaptability of High Fly Ash Content-Based Backfill Material

by Wei Wang, Gaofeng Ren, Shishan Ruan, Runing Han and Chao Yang

Minerals 2025, 15(12), 1300; https://doi.org/10.3390/min15121300 - 11 Dec 2025

Abstract

To address the issues of high cost and poor low-temperature adaptability in cement-based backfill materials, this study developed a high-volume fly ash-based solid waste cementitious backfill material (FAPB) along with a specialized low-temperature admixture. Investigated the fundamental properties and microscopic curing mechanisms of [...] Read more.

To address the issues of high cost and poor low-temperature adaptability in cement-based backfill materials, this study developed a high-volume fly ash-based solid waste cementitious backfill material (FAPB) along with a specialized low-temperature admixture. Investigated the fundamental properties and microscopic curing mechanisms of the FAPB at different temperatures. The results indicate that the yield stress and plastic viscosity of FAPB slurry increase with higher contents of the curing agent and admixture, and rise as the temperature decreases. The variation in slump flow aligns with the rheological parameters, with the minimum slump flow being 14.5 cm (>10 cm). Bleeding rate increases with decreasing amounts of curing agent and admixture content, as well as lower temperatures, reaching a maximum bleeding rate of 9.26% (T5C10). Setting time decreases with increased amounts of curing agent and admixtures, and significantly increases with decreasing temperature. Strength increases with curing time and curing agent content, but decreases significantly as temperature drops. Adding admixtures can compensate for strength deterioration caused by low temperatures, with an optimal dosage of 3%. Microstructural analysis showed that the main hydration products of hardened backfill include AFt, C-S(A)-H, and Ca(OH)₂. Low temperature (5 °C) restricts hydration product formation, and the admixture facilitates continuous polycondensation of C-S(A)-H gel, resulting in sustained strength gain. This study provides a theoretical basis for the preparation and application of low-temperature-resistant Fly ash-based backfill materials, holding significant importance for advancing green mining practices in cold regions. Full article

(This article belongs to the Special Issue Rheological, Mechanical and Hydration Properties of Cemented Paste Backfill)

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4 pages, 148 KB

Open AccessEditorial

Editorial for the Special Issue “Native Gold as a Specific Indicator Mineral for Gold Deposits, 2nd Edition”

by Galina A. Palyanova

Minerals 2025, 15(12), 1299; https://doi.org/10.3390/min15121299 - 11 Dec 2025

Abstract

This Special Issue (v [...] Full article

(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits, 2nd Edition)

23 pages, 15659 KB

Open AccessArticle

Depositional Environment and Biological Activity Implications of the Jining BIF, Western Shandong Province, China: Evidence from Elements and C-O Isotopic Compositions

by Rongzhen Tang, Xinkai Chen, Jiashuo Cao and Yanjing Chen

Minerals 2025, 15(12), 1298; https://doi.org/10.3390/min15121298 - 11 Dec 2025

Abstract

In the early Paleoproterozoic, the Earth’s atmosphere–ocean system shifted from a reducing to an oxidizing state, triggering the extensive deposition of banded iron formations (BIFs) in the Siderian period (2.5–2.3 Ga). As a key sedimentary formed during the hydrospheric oxidation stage, BIFs are [...] Read more.

In the early Paleoproterozoic, the Earth’s atmosphere–ocean system shifted from a reducing to an oxidizing state, triggering the extensive deposition of banded iron formations (BIFs) in the Siderian period (2.5–2.3 Ga). As a key sedimentary formed during the hydrospheric oxidation stage, BIFs are expected to preserve abundant microbial fossils or organic carbon. However, evidence for contemporaneous widespread biological activity remains limited. This paper focuses on C-O isotopes and the trace element geochemistry of the 2.5 Ga Jining BIF to constrain the redox state of paleo-oceans and associated biogeochemical cycling during BIF deposition. The δ¹³C_carb values of the BIF samples range from −18.6‰ to −9.6‰, with an average of −12.7‰, exhibiting a notable negative value, and TOC contents (0.04–0.19 wt.%) are extremely low. This suggests the incorporation of oxidized organic carbon to pore water via ferrihydrite reduction during early diagenesis process. The globally negative δ¹³C_carb value of BIFs and iron-rich carbonates reflect enhanced biological activity at ~2.5 Ga. REE patterns reveal negative Ce/Ce*_(SN) and Eu/Eu*_(CN) anomalies, and the presence of primary hematite mesobands together indicate that the Jining BIF records a redox transition in seawater from reducing to oxidizing conditions. Full article

(This article belongs to the Special Issue Geochemical, Isotopic, and Biotic Records of Banded Iron Formations)

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14 pages, 14223 KB

Open AccessCommunication

Alkali-Activated Binders from Copper–Nickel Slag and Fly Ash: A Synergistic Effect

by Alexander M. Kalinkin, Elena V. Kalinkina, Ekaterina A. Kruglyak and Alla G. Ivanova

Minerals 2025, 15(12), 1297; https://doi.org/10.3390/min15121297 - 11 Dec 2025

Abstract

The cement industry’s significant carbon footprint has driven research into sustainable alternatives like alkali-activated materials (AAMs). This study investigates the synergistic effect of blending copper–nickel slag (CNS) with fly ash (FA) to produce high-performance AAMs. Mechanically activated mixtures of CNS and FA, with [...] Read more.

The cement industry’s significant carbon footprint has driven research into sustainable alternatives like alkali-activated materials (AAMs). This study investigates the synergistic effect of blending copper–nickel slag (CNS) with fly ash (FA) to produce high-performance AAMs. Mechanically activated mixtures of CNS and FA, with FA content varying from 0 to 100%, were alkali-activated with sodium silicate. A distinct synergy was observed, with the blend of 80% CNS and 20% FA (AACNS–80) achieving the highest compressive strength (99.9 MPa at 28 days), significantly outperforming the single-precursor systems. Analytical techniques including thermogravimetry, FTIR spectroscopy, and SEM–EDS were used to elucidate the mechanisms behind this enhancement. The results indicate that the AACNS–80 formulation promotes a greater extent of reaction and forms a denser, more homogeneous microstructure. The synergy is attributed to an optimal particle packing density and the co-dissolution of precursors, leading to the formation of a complex gel that incorporates magnesium and iron from the slag. This work demonstrates the potential for valorizing copper–nickel slag in the production of high-strength, sustainable binders. Full article

(This article belongs to the Special Issue Characterization and Reuse of Slag)

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19 pages, 3608 KB

Open AccessArticle

Transforming Low-Value Quartz into Electronic-Grade Spherical SiO₂ via a Morphology-Directed Hydrothermal Alkaline Process

by Yiqin Zhang, Hongjuan Sun, Tongjiang Peng, Saeed Rehman, Shize Chen, Lingyan Chu and Tao Chen

Minerals 2025, 15(12), 1296; https://doi.org/10.3390/min15121296 - 11 Dec 2025

Abstract

The conventional production of electronic-grade, high-purity, spherical silicon dioxide (SiO₂) faces challenges of high raw material costs and poor control over particle morphology. This study presents an alternative route using low-cost, powdered quartz as a starting material. The quartz was first [...] Read more.

The conventional production of electronic-grade, high-purity, spherical silicon dioxide (SiO₂) faces challenges of high raw material costs and poor control over particle morphology. This study presents an alternative route using low-cost, powdered quartz as a starting material. The quartz was first purified by flotation to remove any associated minerals, such as talc. Subsequently, deep purification was achieved through a hydrothermal alkaline process, which leveraged the distinct leaching kinetics of SiO₂ and impurity ions (Al³⁺, Ca²⁺, Fe³⁺) under precisely controlled hydrothermal conditions (10 mL/g liquid-to-solid ratio, 3 mol/L NaOH, 200 °C, 8 h). This step yielded a sodium silicate solution with a purity of 99.999%. Spherical SiO₂ particles were then synthesized from solutions of varying moduli via chemical precipitation. The condensation kinetics of silicate anionic species (Qn) during acidification were investigated, revealing how the Qn distribution governs the final particle size and morphology. The optimal product exhibited excellent characteristics: a sphericity ≥ 0.98, a median particle size (D₅₀) of 400–500 nm, and a narrow particle size distribution (polydispersity index, PDI of 0.178–0.192). These properties surpass the requirements for the QYG-H Type 002 grade specified in the Chinese National Standard GB/T 32661-2016 (“Spherical Silica Powder”) and meet the standard for electronic-grade spherical SiO₂. This work provides a fundamental insight into morphology control and a feasible technical pathway for the value-added utilization of powdered quartz and the production of electronic-grade spherical SiO₂ with a narrow particle size distribution. Full article

(This article belongs to the Section Mineral Processing and Extractive Metallurgy)

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19 pages, 10310 KB

Open AccessArticle

Grokhovskyite, CuCrS₂, a New Chromium Disulfide in Uakit Iron Meteorite (IIAB), Buryatia, Russia

by Victor V. Sharygin, Grigoriy A. Yakovlev, Yurii V. Seryotkin, Nikolai S. Karmanov, Konstantin A. Novoselov and Maxim S. Karabanalov

Minerals 2025, 15(12), 1295; https://doi.org/10.3390/min15121295 - 11 Dec 2025

Abstract

Grokhovskyite, CuCrS₂, was observed in small sulfide inclusions (up to 50–80 µm) in Ni-rich iron (kamacite) of the Uakit iron meteorite (IIAB) in the Republic of Buryatia, Russia. The grain sizes of this mineral are usually less than 5 μm, and [...] Read more.

Grokhovskyite, CuCrS₂, was observed in small sulfide inclusions (up to 50–80 µm) in Ni-rich iron (kamacite) of the Uakit iron meteorite (IIAB) in the Republic of Buryatia, Russia. The grain sizes of this mineral are usually less than 5 μm, and the biggest detected crystals are 10 × 5 μm in size. It is commonly associated with daubréelite, troilite, schreibersite, and, sometimes, with carlsbergite and uakitite. Within inclusions, the mineral forms elongated splintered crystals, or, rarely, needle-shaped grains in daubréelite. The grokhovskyite-containing associations in the Uakit meteorite seem to form due to high-temperature (>1000 °C) separation of Fe-Cr sulfide liquid, which is locally enriched in Cu, from Fe-Ni metal melt. Physical and optical properties of grokhovskyite are quite similar to those of synthetic CuCrS₂: yellow–brown and non-transparent phase with metallic luster; Mohs hardness ≈ 4; gray to light gray color with yellow tint in reflected light; weak to medium bireflectance, anisotropy, and pleochroism; density (calc.) = 4.559 g/cm³. Grokhovskyite is structurally related to the Cr-containing disulfide minerals with general formula Me⁺CrS₂ (where Me⁺ = Na, Cu, Ag), including caswellsilverite, NaCrS₂; schöllhornite, Na_0.3CrS₂·H₂O; and cronusite, Ca_0.2CrS₂·2H₂O. Structural data were obtained for one grokhovskyite crystal using the EBSD technique. Fitting of the EBSD patterns for a synthetic α-CuCrS₂ model (trigonal R3m; a = 3.4794(8) Å; c = 18.702(4) Å; V = 196.08(10) Å³; Z = 3) resulted in the parameter MAD = 0.57–1.16° (good fit). Analytical data for grokhovskyite (n = 36, in wt.%) are as follows: Cu—32.97; Cr—27.65; Fe—3.69; Ni—0.16; S—35.71; Na, Zn, V, Mn, and Co—below detection limit (<0.005 wt.%). The empirical formula is (Cu_0.930Cr_0.952Fe_0.118Ni_0.005)_2.005S_1.995; however, different concentrations of Fe are indicated in two individual grains of grokhovskyite (0.09–0.17 apfu). Such variations may be explained by Fe incorporation in the grokhovskyite structure according to the scheme ^IVCu⁺ + ^VICr³⁺ → ^IVFe²⁺ + ^VIFe²⁺. The three main bands (near 110, 250, and 310 cm⁻¹), which are common of synthetic CuCrS₂, were observed in the Raman spectra of grokhovskyite. Full article

(This article belongs to the Collection New Minerals)

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10 pages, 5106 KB

Open AccessArticle

Sb-Rich Avicennite from the Khokhoy Gold Deposit (Aldan Shield, Russia)

by Galina S. Anisimova, Larisa A. Kondratieva, Veronika N. Kardashevskaia, Anatoly V. Kasatkin and Vladislav V. Gurzhiy

Minerals 2025, 15(12), 1294; https://doi.org/10.3390/min15121294 - 10 Dec 2025

Abstract

Sb-rich avicennite (first discovery in Russia) was found at the Khokhoy gold deposit, 120 km west of Aldan, Aldan district, Republic of Sakha (Yakutia), Eastern Siberia, Russia. The mineral of critical metal thallium forms irregularly shaped grains up to 0.25 mm in size, [...] Read more.

Sb-rich avicennite (first discovery in Russia) was found at the Khokhoy gold deposit, 120 km west of Aldan, Aldan district, Republic of Sakha (Yakutia), Eastern Siberia, Russia. The mineral of critical metal thallium forms irregularly shaped grains up to 0.25 mm in size, in association with amgaite, weissbergite, goethite, gold, and unidentified Tl-bearing phases. Aggregates of colloform structure prevail, represented by rhythmic-, concentric-zonal, kidney-shaped, and spherulitic varieties. Avicennite is black in color, with metallic luster, and it fractures unevenly. No cleavage is observed. The density value of avicennite, obtained using its empirical formula and the unit cell parameters calculated from the powder X-ray diffraction data, is 8.548 g/cm³. In reflected light, avicennite is light gray and isotropic. Internal reflections are absent. Reflection is very low; the reflectivity curve is of mixed type with a small maximum in the blue part. Its chemical composition (average value on 10 analyses, wt.%): Tl₂O₃—85.36, V₂O₅—0.73, As₂O₅—0.85, Sb₂O₅—12.98, Total—99.92; It corresponds to the following empirical formula (calculation for three atoms of O): Tl_1.40Sb⁵⁺_0.30V⁵⁺_0.03As⁵⁺_0.03O₃. The unit cell parameters calculated from the powder X-ray diffraction data are as follows: the mineral is cubic, a = 10.496(6) Å, V = 1156(2) Å3. Full article

(This article belongs to the Special Issue Critical Metal Minerals, 2nd Edition)

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21 pages, 7129 KB

Open AccessArticle

Characterization and Enrichment of Rare Earth Element and Heavy Mineral-Bearing Fractions from the Hantepe Placer Deposit, Çanakkale, Türkiye

by Mustafa Özer, Gülperi Gümüş, Ali Tugcan Unluer, Zeynep Doner, Şenel Özdamar, Ozan Kökkılıç and Fırat Burat

Minerals 2025, 15(12), 1293; https://doi.org/10.3390/min15121293 - 10 Dec 2025

Abstract

Placer deposits constitute important secondary resources for economically valuable minerals, including rare earth elements (REEs) and heavy minerals such as zircon, rutile, and ilmenite. In this study, representative samples from the Hantepe placer deposit (Çanakkale, Türkiye) were processed to investigate the occurrence, distribution, [...] Read more.

Placer deposits constitute important secondary resources for economically valuable minerals, including rare earth elements (REEs) and heavy minerals such as zircon, rutile, and ilmenite. In this study, representative samples from the Hantepe placer deposit (Çanakkale, Türkiye) were processed to investigate the occurrence, distribution, and beneficiation potential of REE-bearing minerals. The ore was subjected to size classification, followed by gravity concentration on a shaking table and subsequent magnetic separation using a low-intensity disc separator. The resulting products were characterized by X-ray diffraction and X-ray fluorescence. The dominant REE-host minerals were identified as titanite, zircon, apatite, monazite and, allanite, accompanied by magnetite, hematite, quartz, and feldspar as gangue constituents. The non-magnetic final concentrate achieved substantial upgrading of critical elements, with Ce increasing from 868 g/t to 5716 g/t, Nd from 308 g/t to 2308 g/t, and Zr from 1435 g/t to 9748 g/t. Additionally, the magnetic concentrate (7.0 wt.%) was strongly enriched in Fe₂O₃ (70.26%) and V (2359 g/t), indicating its potential suitability as an Fe–V source. Overall, the results demonstrate that combined gravity and magnetic separation constitutes an effective beneficiation strategy for critical mineral recovery from placer systems. These findings establish a strong basis for future pilot-scale studies and the techno-economic evaluation of the Hantepe deposit as an emerging source of strategic and industrially relevant heavy minerals. Full article

(This article belongs to the Section Mineral Processing and Extractive Metallurgy)

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16 pages, 14759 KB

Open AccessArticle

Basalts from Zhangzhongjing Seamount, South China Sea and Their Linkage to a Plume-Modified Mantle Reservoir

by Rong Lu, Hao Zheng, Lei Yang, Anyuan Xie, Xi He, Cong Peng, Zhengyuan Li and Huizhong He

Minerals 2025, 15(12), 1292; https://doi.org/10.3390/min15121292 - 10 Dec 2025

Abstract

Basement rock samples were collected from the Zhangzhongjing intraplate seamount in the Southeast sub-basin of the South China Sea (SCS). These alkaline basalts are enriched in light rare earth elements (LREE). The Sr-Nd-Pb-Hf isotopic compositions of the basalts suggest that their parental melts [...] Read more.

Basement rock samples were collected from the Zhangzhongjing intraplate seamount in the Southeast sub-basin of the South China Sea (SCS). These alkaline basalts are enriched in light rare earth elements (LREE). The Sr-Nd-Pb-Hf isotopic compositions of the basalts suggest that their parental melts originated from an Indian Ocean-type mantle source that was mixed with enriched EMII components. Semi-quantitative geochemical modeling indicates that the parental melts of the studied basalts formed through heterogeneous melting starts at depth in the garnet facies and, during its uprising, continue at shallow levels in the spinel facies. Furthermore, qualitative isotopic modeling indicates that the inferred EMII components were most likely derived from the nearby Hainan plume. This study provides invaluable insights into the extent to which the Hainan diapir influenced the geochemical and isotopic composition of the upper mantle beneath the East Sub-basin of the SCS. Full article

(This article belongs to the Special Issue Geochronology and Geochemistry of Alkaline Rocks)

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22 pages, 9176 KB

Open AccessArticle

Ore Genesis of the Wunuer Zn-Pb-Ag-Mo Deposit from the Central Great Xing’an Range, NE China: Constraints from Geochemical, Isotopic, and Geochronological Features

by Wei Mei, Hongyu Liu, Yiming Chang and Xiaofeng Cao

Minerals 2025, 15(12), 1291; https://doi.org/10.3390/min15121291 - 10 Dec 2025

Abstract

The Wunuer deposit is an important hydrothermal Zn-Pb-Ag-Mo polymetallic deposit in the central Great Xing’an Range, NE China. The zinc–lead polymetal mineralization is closely hosted by the volcanic rocks of the Manketouebo formation (rhyolite and lithic crystal tuff) and related to the Mesozoic [...] Read more.

The Wunuer deposit is an important hydrothermal Zn-Pb-Ag-Mo polymetallic deposit in the central Great Xing’an Range, NE China. The zinc–lead polymetal mineralization is closely hosted by the volcanic rocks of the Manketouebo formation (rhyolite and lithic crystal tuff) and related to the Mesozoic granite porphyry. Field evidence and petrographic observations have identified three mineralization stages within this deposit from deep to shallow: (1) late magmatic stage with vein-type Mo mineralization characteristics and mainly related to the deep granite porphyry; (2) magmatic–hydrothermal transition stage characterized by breccia-type Zn mineralization, which occurred within a steep cryptoexplosive breccia; and (3) hydrothermal stage featured by vein-type Zn-Pb-Ag mineralization hosted by the ore-bearing fractured zone. In this contribution, we present the mineralogy, zircon U-Pb age, sphalerite Rb-Sr dating, whole-rock geochemistry, and Hf-S-Pb isotopes of the Wunuer deposit. LA-ICP-MS zircon U-Pb dating of the ore-related granite porphyry, rhyolite, and lithic crystal tuff suggests that the Mo mineralization from the late magmatic stage occurred between 144.8 Ma and 145.8 Ma. The Rb-Sr isochron dating of sphalerite indicates that the hydrothermal stage Zn mineralization age is 121 ± 2.3 Ma, which is related to the volcanism of Baiyin’gaolao Formation in the Wunuer area. The concentrated and positive δ³⁴S_V-CDT values (0.17‰~5.40‰) of sulfides, as well as uniform Pb isotope compositions of granite porphyry intrusion and galena, jointly imply a magmatic source of metallogenic materials for Pb-Zn mineralization. Whole-rock geochemistry and Hf-Pb isotopes reveal that the granite porphyry and rhyolite both originated from a mantle-derived juvenile component and assimilated by minor ancient crustal material in an extensional setting. Our study demonstrates the prospect of further exploration for two mineralization events in the hydrothermal polymetallic deposits of the central Great Xing’an Range. Full article

(This article belongs to the Section Mineral Deposits)

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21 pages, 17743 KB

Open AccessArticle

Garnet Geochemistry of the Tietangdong Breccia Pipe, Yixingzhai Gold Deposit, North China Craton: Constraints on Hydrothermal Fluid Evolution

by Junwu Zhang, Jing Lu, Juquan Zhang, Fangyue Wang and Xian Liang

Minerals 2025, 15(12), 1290; https://doi.org/10.3390/min15121290 - 9 Dec 2025

Abstract

The Yixingzhai deposit is a giant gold system containing four cryptovolcanic breccia pipes, several of which host significant porphyry-type gold orebodies at depth. A key exploration target is the Tietangdong cryptovolcanic breccia pipe, characterized by skarn alteration in its upper zones. However, the [...] Read more.

The Yixingzhai deposit is a giant gold system containing four cryptovolcanic breccia pipes, several of which host significant porphyry-type gold orebodies at depth. A key exploration target is the Tietangdong cryptovolcanic breccia pipe, characterized by skarn alteration in its upper zones. However, the evolution of early hydrothermal fluids and their implications for gold enrichment potential remain poorly understood. This study employs an integrated approach—combining petrography, electron probe microanalysis, laser ablation-inductively coupled plasma–mass spectrometry (LA-ICP-MS), and LA-ICP-MS elemental mapping—to analyze zoned garnets within the Tietangdong skarn, with the aim of deciphering changes in magmatic–hydrothermal composition and physicochemical conditions, as well as their influence on gold enrichment. Textural and compositional data reveal three distinct generations of garnets. Garnets from generations I and III consist of a grossular–andradite solid solution and commonly exhibits optical anisotropy. In contrast, generation II garnet is predominantly andraditic and optically homogeneous. LA-ICP-MS elemental mapping of generations I and III indicates that both generations contain significant Al and Fe, with their optical anisotropy attributed to a high degree of Fe³⁺/Al³⁺ cationic ordering. Compared to generations I and III, generation II garnet displays distinct geochemical characteristics, including enrichment in Fe, As, Sn, W, and U, patterns enriched in light rare earth elements, a positive Eu anomaly, and a wide range of Y/Ho ratios. Garnets from generations I and III crystallized under relatively high-pressure, high-temperature, and low-oxygen fugacity conditions, whereas generation II garnets formed under lower pressure–temperature conditions and higher oxygen fugacity. Moreover, concentrations of Co, Ni, and Cu increase systematically from generation I to generation III. We interpret the sharp compositional break at generation II as recording of the pulsed injection of magmatic–hydrothermal fluids, which enhanced the potential for gold mineralization. The zoning patterns in garnet provide a robust record of the temporal evolution of physicochemical conditions and fluid composition in the hydrothermal system. Full article

(This article belongs to the Special Issue Genesis and Metallogeny of Non-Ferrous and Precious Metal Deposits, 3rd Edition)

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19 pages, 5695 KB

Open AccessArticle

Research on Digital Core Characterization and Pore Structure Control Factors of Tight Sandstone Reservoirs in the Fuyu Oil Layer of the Upper Cretaceous in the Bayan Chagan Area of the Northern Songliao Basin

by Yilin Li, Qi Liu, Hang Fu and Zeqiang Wang

Minerals 2025, 15(12), 1289; https://doi.org/10.3390/min15121289 - 9 Dec 2025

Abstract

The tight sandstone reservoir of the Fuyu Oil Layer in the Quantou Formation of the Cretaceous in the Bayan Chagan area displays intricate microscopic pore structures and pronounced heterogeneity, limiting hydrocarbon exploration and development efficiency. Utilizing core CT scanning digital core technology integrated [...] Read more.

The tight sandstone reservoir of the Fuyu Oil Layer in the Quantou Formation of the Cretaceous in the Bayan Chagan area displays intricate microscopic pore structures and pronounced heterogeneity, limiting hydrocarbon exploration and development efficiency. Utilizing core CT scanning digital core technology integrated with field emission scanning electron microscopy (FE–SEM) and whole-rock/clay mineral X-ray diffraction (XRD) analysis, this research performs multi-scale quantitative characterization on 15 representative rock samples from the study area, systematically elucidating reservoir pore structure diversity and its formation mechanisms. The study demonstrates that reservoirs in the study area can be categorized into three types: A, B, and C, exhibiting progressively declining reservoir performance. Type A reservoirs are characterized primarily by dissolution-formed large to medium pores, where macropores (radius > 5 μm) account for more than 92% of storage capacity, average coordination numbers reach 0.27~0.45, and connectivity is optimal. Type B reservoirs are influenced by siliceous cementation, featuring developed residual intergranular pores, macropore volume share declining to 88%, and coordination numbers decreasing to 0.11~0.20. Type C reservoirs experience intense compaction and illite cementation modification, where micropores (radius < 1 μm) constitute 5.6% numerically, yet macropore volume share is merely 76%, coordination numbers drop to 0.02–0.03, and connectivity is minimal. Mineralogical analysis reveals that quartz content exhibits a positive correlation with reservoir properties, as its rigid grain framework effectively resists compaction. Illite content rises with increasing burial depth, and plastic illite occupies pores and segment throats, resulting in Type C reservoir permeability reduction to 0.01~0.25 mD. Dissolution intensity (Type A > Type B > Type C) and cementation types (quartz cementation prevailing in Type B, illite cementation prevailing in Type C) represent crucial factors governing reservoir quality differentiation. This research confirms the reliability of digital core technology for tight reservoir classification and assessment, developing a discrimination model founded on “pore structure-mineral composition-diagenesis”. It provides a geological basis for sweet spot prediction and efficient development in the study area. Full article

(This article belongs to the Section Mineral Exploration Methods and Applications)

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21 pages, 9961 KB

Open AccessArticle

Geochronology and Geochemistry of Early–Middle Permian Intrusive Rocks in the Southern Greater Xing’an Range, China: Constraints on the Tectonic Evolution of the Paleo-Asian Ocean

by Haihua Zhang, Xiaoping Yang, Xin Huang, Liang Qiu, Gongjian Li, Yujin Zhang, Wei Chen and Haiwei Jiao

Minerals 2025, 15(12), 1288; https://doi.org/10.3390/min15121288 - 8 Dec 2025

Abstract

The tectonic evolution of the Paleo-Asian Ocean during the Early to Middle Permian remains a key issue in understanding the geodynamic history of the Central Asian Orogenic Belt. To address this, we conducted petrological, whole-rock geochemical, zircon U–Pb geochronological, and Hf isotopic analyses [...] Read more.

The tectonic evolution of the Paleo-Asian Ocean during the Early to Middle Permian remains a key issue in understanding the geodynamic history of the Central Asian Orogenic Belt. To address this, we conducted petrological, whole-rock geochemical, zircon U–Pb geochronological, and Hf isotopic analyses of Early Permian biotite granodiorite and Middle Permian porphyritic granite from the south-central Great Xing’an Range. Zircon U–Pb dating yields ages of 273.2 ± 1.4 Ma and 264.4 ± 1.5 Ma, indicating that these intrusions emplaced during Early and Middle Permian. Geochemical analyses show that the rocks are characterized by high SiO₂ and Al₂O₃ contents, and low MgO and CaO contents and belong to the metaluminous to weakly peraluminous series, typical of I-type granites. The rocks are enriched in light rare earth elements and large-ion lithophile elements (e.g., Rb, Ba, K), but depleted in heavy rare earth elements and high field strength elements (e.g., Nb, Ta, P, Ti), with weakly negative Eu anomalies. The Early Permian pluton exhibits low-Sr and high-Yb characteristics and thus fall in the plagioclase stability field. In contrast, Middle Permian pluton was derived from magmas generated by partial melting under high-pressure conditions and that, underwent crystal fractionation during ascent to the mid-upper crust, ultimately forming low-Sr and low-Yb type granites. All zircon ε_Hf(t) values are positive (+4.84 to +14.87), with the corresponding two-stage Hf model ages ranging from 345 Ma to 980 Ma, indicating that the magmas were predominantly derived from juvenile crustal materials accreted during the Neoproterozoic to Phanerozoic. Considering these results, we propose that the Paleo-Asian Oceanic plate continued to subduct beneath the Songliao–Xilinhot block to the north during the Early to Middle Permian, with intense subduction and crustal thickening occurring in the Middle Permian. This suggests that the south-central segment of the Great Xing’an Range was situated in an active continental marginal setting during the Early-Middle Permian. Full article

(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)

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16 pages, 2983 KB

Open AccessArticle

Preliminary Study of Geochemical, Mineralogical and Magnetic Susceptibility Properties of Flotation Tailings from the Pb-Zn-Cu-Ag Rudnik Mine, Serbia

by Stefan Petrović, Nenad Nikolić, Jovica Stojanović, Vesna Cvetkov, Vladimir Simić, Jovana Malbašić, Ljiljana Obrenović and Dragana Životić

Minerals 2025, 15(12), 1287; https://doi.org/10.3390/min15121287 - 7 Dec 2025

Abstract

Samples of flotation tailings generated during the exploitation and processing of Zn–Pb–Cu–Ag ore from the Rudnik mine (Serbia) were investigated for their mineralogical, geochemical, and magnetic susceptibility properties. The flotation tailings consist of a complex mineral assemblage, including silicates, carbonates, sulfides, phosphates, sulfates, [...] Read more.

Samples of flotation tailings generated during the exploitation and processing of Zn–Pb–Cu–Ag ore from the Rudnik mine (Serbia) were investigated for their mineralogical, geochemical, and magnetic susceptibility properties. The flotation tailings consist of a complex mineral assemblage, including silicates, carbonates, sulfides, phosphates, sulfates, oxides, hydroxides, and native elements. Quartz, calcite, and orthoclase dominate the coarse fraction (>400 µm), accompanied by epidote, Ca-garnet, and Ca-clinopyroxene. Sulfide minerals are concentrated in finer fractions (<400 µm), with pyrite and arsenopyrite being the most abundant, followed by pyrrhotite, sphalerite, galena, and chalcopyrite. These sulfides occur as dispersed grains within a silicate–carbonate matrix. Post-depositional oxidative alteration is moderately developed, with pyrite replaced by hematite, galena by cerussite, and chalcopyrite by malachite. Geochemical analyses reveal that SiO₂ (avg. 38.98 wt%), Fe₂O₃ (avg. 23.68 wt%), Al₂O₃ (avg. 8.95 wt%), CaO (avg. 9.03 wt%) and MgO (avg. 1.50 wt%) dominate the composition. Economically significant metals include Zn (avg. 0.47 wt%), Pb (avg. 0.20 wt%), Cu (avg. 0.11 wt%), Ag (max. 19 µg/g), and Bi (max. 130 µg/g). Mass magnetic susceptibility shows a strong correlation with S (r = 0.92), Co (r = 0.90), and Bi (r = 0.87); moderate correlation with Fe₂O₃, Al₂O₃, and As; and negative correlation with Mn, TiO₂, Zn, and Pb. The ferromagnetic phase most likely originates from pyrrhotite, as well as hematite formed during pyrite alteration and goethite. Full article

(This article belongs to the Special Issue Waste Valorization: Recycling and Recovery of Critical and Strategic Metals)

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19 pages, 9483 KB

Open AccessArticle

Application of Portable X-Ray Fluorescence Analysis in Mineral Exploration: A Case Study from Cimabanshuo Porphyry Copper Deposit

by Zheming Li, Naiying Wei, Miao Li, Song Wu, Hao Li and Peng Liu

Minerals 2025, 15(12), 1286; https://doi.org/10.3390/min15121286 - 7 Dec 2025

Abstract

The Cimabanshuo deposit, situated in the western Gangdese Belt, is a recently discovered porphyry Cu deposit formed in a post-collisional setting, approximately 10 km from the giant Zhunuo porphyry Cu deposit. Despite its proximity to Zhunuo, Cimabanshuo remains poorly studied, and the current [...] Read more.

The Cimabanshuo deposit, situated in the western Gangdese Belt, is a recently discovered porphyry Cu deposit formed in a post-collisional setting, approximately 10 km from the giant Zhunuo porphyry Cu deposit. Despite its proximity to Zhunuo, Cimabanshuo remains poorly studied, and the current exploration depth of 600 m leaves the potential for deeper resources uncertain. In this study, 840 samples from four drill holes along the NW-SE section (A-A′) were analyzed using portable X-ray fluorescence (pXRF). Based on the geochemical characteristics of primary halos, the deep mineralization potential of Cimabanshuo was evaluated. The results show that Co, Pb, and Ag are near-ore indicator elements; Zn, Cs, Hg, Sb, As, and Ba represent the frontal elements; and Te, Sn, and Bi occur as tail elements. Based on these distributions, a 14-element zoning sequence is defined along the A-A′ profile according to Gregorian’s zoning index, showing Mo-Co-Cu-Pb-Bi-Ag-Sn-Te-Sb-Hg-Cs-Zn-Ba-As from shallow to deep. This sequence shows a distinct reverse zonation pattern, in which tail elements occur in the middle and frontal elements appear at depth, suggesting the existence of a concealed ore body in the lower part of the deposit. Horizontally, the geochemical ratios Ag/Mo and Ag/Cu decrease from northwest to southeast along the profile, implying hydrothermal flow from southeast to northwest. Vertically, the ratios As/Bi, (As × Cs)/(Bi × Te), (As × Ba)/(Bi × Sn), and (As × Ba × Cs)/(Bi × Sn × Te) display a downward-decreasing then upward-increasing trend, further indicating hidden mineralization at depth. This inference is supported by the predominance of propylitic alteration and the deep polarization anomaly revealed by audio-magnetotelluric imaging. pXRF analysis provides a fast, efficient, and environmentally friendly approach, showing strong potential for rapid geochemical evaluation in porphyry Cu exploration. Full article

(This article belongs to the Section Mineral Exploration Methods and Applications)

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27 pages, 20165 KB

Open AccessArticle

Genetic and Sealing Mechanisms of Calcareous Sandstones in the Paleogene Zhuhai–Enping Formations, Panyu A Sag, Pearl River Mouth Basin

by Yong Zhou, Guangrong Peng, Wenchi Zhang, Xinwei Qiu, Zhensheng Li, Ke Wang, Xiaoming Que and Peimeng Jia

Minerals 2025, 15(12), 1285; https://doi.org/10.3390/min15121285 - 7 Dec 2025

Abstract

Calcareous sandstones, acting as sealing layers, play a crucial role in hydrocarbon accumulation of formations with high sand content (sand content > 80%). However, the genetic mechanisms, sealing mechanisms, and effectiveness of calcareous sandstones remain unclear. This study takes the Zhuhai–Enping formations in [...] Read more.

Calcareous sandstones, acting as sealing layers, play a crucial role in hydrocarbon accumulation of formations with high sand content (sand content > 80%). However, the genetic mechanisms, sealing mechanisms, and effectiveness of calcareous sandstones remain unclear. This study takes the Zhuhai–Enping formations in the Panyu A Sag as an example. By comprehensively analyzing data from well logs, cores, cast thin sections, elemental geochemical analysis and carbon–oxygen isotopes, the genetic mechanisms, development patterns, and controlling effects on hydrocarbon accumulation of calcareous cement layers are investigated. The main findings are as follows: (1) The calcareous sandstone cements are mainly composed of dolomite, ankerite, and anhydrite. With increasing burial depth, dolomite transitions from micritic dolomite to silt-sized and fine-crystalline dolomite, and finally to coarse-crystalline dolomite. (2) The local transgression provided ions such as Ca²⁺ and Mg²⁺, forming the material basis for early dolomite formation. As burial depth increased, the diagenetic environment shifted from acidic to alkaline, leading to the dolomitization of early-formed calcite and the formation of ankerite. (3) The high source-reservoir displacement pressure difference effectively seals hydrocarbon accumulation. Vertically interbedded tight calcareous sandstones and thin marine transgressive mud-stones collectively control efficient hydrocarbon preservation and enrichment. This research addresses the current limits in the study of “self-sealing sandstone layers,” and provides new geological insights and predictive models for hydrocarbon exploration in sand-rich settings. Full article

(This article belongs to the Special Issue Mineralogy, Geochemistry, and Sedimentary Geology of Lacustrine Basins, 2nd Edition)

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