Zn(II) Curcuminate Complexes with 2,2′-bipyridine and Carboxylates
Abstract
:1. Introduction
2. Results and Discussion
2.1. Crystallographic Study
2.2. Synthesis
2.3. Solubility and Stability
2.4. Spectroscopic Studies
3. Materials and Methods
3.1. General
3.2. Measurements
3.3. Syntheses
3.3.1. Synthesis of [Zn(PhCOO)2]
3.3.2. Synthesis of [Zn(CH3COO)(cur)(bpy)](1)·CH3OH·2H2O
3.3.3. Synthesis of [Zn(PhCOO)(cur)(bpy)](2) CH3OH
3.4. X-Ray Structure Determinations
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample Availability: Samples of the compounds are not available from the authors. |
1 | 2 | ||
---|---|---|---|
Zn(1)–O(7) | 1.973(1) | Zn(1)–O(7) | 1.987(3) |
Zn(1)–O(1) | 2.016(1) | Zn(1)–O(1) | 2.007(3) |
Zn(1)–O(2) | 2.001(1) | Zn(1)–O(2) | 2.051(3) |
Zn(1)–N(1) | 2.162(2) | Zn(1)–N(1) | 2.121(4) |
Zn(1)–N(2) | 2.123(1) | Zn(1)–N(2) | 2.112(4) |
Zn(1)–O(8) | 3.303(2) | Zn(1)–O(8) | 3.127(3) |
C(8)–O(7) | 1.263(2) | C(31)–O(7) | 1.266(5) |
C(8)–O(8) | 1.243(2) | C(31)–O(8) | 1.242(5) |
O(7)–Zn(1)–O(1) | 100.79(6) | N(1)–Zn(1)–O(2) | 162.9(1) |
O(7)–Zn(1)–O(2) | 101.48(6) | N(1)–Zn(1)–N(2) | 77.0(2) |
O(7)–Zn(1)–N(1) | 99.73(6) | N(1)–Zn(1)–O(1) | 90.5(1) |
O(7)–Zn(1)–N(2) | 123.32(6) | N(1)–Zn(1)–O(7) | 98.6(1) |
O(1)–Zn(1)–N(1) | 158.86(6) | O(1)–Zn(1)–O(7) | 127.3(1) |
O(2)–Zn(1)–N(2) | 134.18(6) | O(7)–Zn(1)–N(2) | 94.8(1) |
O(1)–Zn(1)–O(2) | 92.22(5) | N(2)–Zn(1)–O(1) | 124.8(1) |
O(2)–Zn(1)–N(1) | 88.61(5) | O(2)–Zn(1)–O(1) | 89.75(1) |
N(1)–Zn(1)–N(2) | 75.82(6) | O(2)–Zn(1)–O(7) | 94.8(1) |
N(2)–Zn(1)–O(1) | 88.66(5) | O(2)–Zn(1)–N(2) | 88.9(1) |
Groups Engaged in Interaction (b) | Donor Atom Acceptor (c) | Length (Å) |
---|---|---|
OH·CH3OH | O(6)···O(9) i | 2.715(5) |
OH···O(cur−) | O(4)···O(1) ii | 2.788(4) |
CH3OH···COO− | O(9)···O(8) | 2.709(5) |
Groups Engaged in Interaction (b) | Donor Atom Acceptor (c) | Length (Å) |
---|---|---|
OH···COO− | O(6)···O(8) i | 2.653(2) |
OH···H2O | O(4)···O(12) ii | 2.729(2) |
OH···H2O | O(6)···O(12) iii | 3.012(2) |
CH3OH···COO− | O(10)···O(8) i | 2.787(3) |
CH3OH···H2O | O(10)···O(11) iv | 2.702(3) |
H2O···OCH3 | O(12)···O(3) ii | 3.026(2) |
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Grabner, S.; Modec, B. Zn(II) Curcuminate Complexes with 2,2′-bipyridine and Carboxylates. Molecules 2019, 24, 2540. https://doi.org/10.3390/molecules24142540
Grabner S, Modec B. Zn(II) Curcuminate Complexes with 2,2′-bipyridine and Carboxylates. Molecules. 2019; 24(14):2540. https://doi.org/10.3390/molecules24142540
Chicago/Turabian StyleGrabner, Sabina, and Barbara Modec. 2019. "Zn(II) Curcuminate Complexes with 2,2′-bipyridine and Carboxylates" Molecules 24, no. 14: 2540. https://doi.org/10.3390/molecules24142540