A serial of Cu2O/activated carbon (AC) and Cu0/AC catalysts were prepared in situ and evaluated in methanol oxidative carbonylation to clarify the mechanistic differences between Cu2O and Cu0 active species. It was found that both species are catalyt...
In the context of global efforts to pursue carbon neutrality, the research on the application technology of methanol fuel in internal combustion engines has ushered in a new peak. In order to provide a theoretical basis for the development of direct...
In a methanol-reforming system, because the mixture of methanol and water must be evaporated before reaching the reforming reaction zone, having an appropriate evaporator design is a fundamental requirement for completing the reforming reaction. This...
Direct-methanol fuel cell (DMFC) systems are comparatively simple, sometimes just requiring a fuel cartridge and a fuel cell stack with appropriate control devices. The key challenge in these systems is the accurate determination and control of the f...
Direct methanol fuel cells (DMFCs) typically operate in passive mode, where methanol is distributed across the membrane electrode assembly through natural diffusion. Usual methanol concentrations range from 1% to 5% by weight (wt.%), although this ca...
Methanol crossover through a polymer electrolyte membrane has numerous negative effects on direct methanol fuel cells (DMFCs) because it decreases the cell voltage due to a mixed potential (occurrence of both oxygen reduction and methanol oxidation r...
Methanol is a promising feedstock for metabolically competent yeast strains-based biorefineries. However, methanol toxicity can limit the productivity of these bioprocesses. Therefore, the identification of genes whose expression is required for maxi...
An alternative Nafion composite membrane was prepared by incorporating various loadings of CeO2 nanoparticles into the Nafion matrix and evaluated its potential application in direct methanol fuel cells (DMFCs). The effects of CeO2 in the Nafion matr...
This study presents an integrated Life Cycle Sustainability Assessment (LCSA) of the Natural gas-to-methanol (NGTM) and methanol-to-gasoline (MTG) pathways using Aspen HYSYS process modeling, Environmental Life Cycle Assessment (LCA), Social Life Cyc...
Methanol is the simplest C1 oxygenated compound possessing the highest hydrogen-to-carbon ratio and can therefore be used as an effective hydrogen carrier. Furthermore, it can be easily transported by land and sea because it is liquid at room tempera...
Mature methanol vehicle technology with low exhaust emissions and economic benefits are a viable way to mitigate oil dependency and reduce greenhouse gas emissions. As a result, pilot projects for methanol vehicles have been carried out in 10 differe...
Lignin is considered a renewable source for the production of valuable aromatic chemicals and liquid fuel. Solvent depolymerization of lignin is a fruitful strategy for the valorization of lignin. However, Kraft lignin is highly prone to produce char...
Methanol crossover (MCO) significantly affects the performance of a direct methanol fuel cell (DMFC). In order to reduce its effect, this study presents in-house carbon nanofiber webs (CNWs) used as a porous methanol barrier for MCO control in a pass...
The combustion process of traditional diesel engines is mainly determined by the injection timing of diesel. There is a trade-off relationship between the soot and NOx (nitrogen oxides) during this combustion process, making it difficult to reduce th...
Pt-Pd catalyst supported on nitrogen-doped carbon nanofiber (N-CNF) was prepared and evaluated as a cathode electrode of the direct methanol fuel cell (DMFC). The N-CNF, which was directly synthesized by the catalytic chemical vapor deposition from a...
Given the increasing concern around greenhouse gas emissions and the decline in the availability of fossil fuels, there is increasing global demand to develop alternate fuels for maritime transportation that are sustainable and which have lower green...
Methanol, naturally present in small quantities in the distillation of alcoholic beverages, can lead to serious health problems. When it exceeds a certain concentration, it causes blindness, organ failure, and even death if not recognized in time. An...
Sulfonic acid-functionalized polymer electrolyte membranes alternative to Nafion® were developed. These were hydrocarbon systems, such as blend sulfonated polyetheretherketone (s-PEEK), new generation perfluorosulfonic acid (PFSA) systems, and compo...
This article presents the concept of renewable methanol production in the gas turbine cycle. As part of the work, an analysis was performed, including the impact of changing the parameters in the methanol reactor on the obtained values of power, yiel...
The separation of liquid mixture components is relevant to many applications—ranging from water purification to biofuel production—and is a growing concern related to the UN Sustainable Development Goals (SDGs), such as “Clean water...
In the present work, the combustion process of a retrofitted high-speed marine Diesel Methanol Dual Fuel (DMDF) engine is numerically evaluated. This study examines the effects of two important operational parameters, the methanol energy substitution...
A hyper-branched sulfonated polyimide (s-PI) was synthesized successfully and composited with polyvinylidene fluoride (PVDF) to achieve ultra-high methanol-permeation resistive for direct methanol fuel cell application. The optimized s-PI-PVDF compos...
Direct methanol fuel cells (DMFCs) are emerging technologies for the electrochemical conversion of the chemical energy of a fuel (methanol) directly into electrical energy, with a low environmental impact and high efficiency. Yet, before this technol...
This study conducts a detailed analysis of the mixed combustion of dissociated methanol gas (DMG) and methanol in a marine medium-speed methanol engine through numerical simulation methods. The research focuses on the impact of partially replacing me...
The naturally occurring one-carbon assimilation pathways for the production of acetyl-CoA and its derivatives often have low product yields because of carbon loss as CO2. We constructed a methanol assimilation pathway to produce poly-3-hydroxybutyrat...
The development of sustainable and environmentally benign N-methylation methodologies is essential for enhancing sustainable synthetic practice in pharmaceutical manufacturing. In this study, we demonstrate that microwave heating (MWH) markedly enhan...
Photonic crystals (PCs) show reflectance spectra depending on the geometrical structure of the crystal, the refractive index (neff), and the light incident angle, according to the Bragg-Snell law. Three-dimensional photonic crystals (3D-PCs) composed...
Methyl formate is a key component for both defossilized industry and mobility. The current industrial production via carbonylation of methanol has various disadvantages such as high requirements on reactant purity and low methanol conversion rates. I...
The paper describes the conversion of carbon dioxide into methanol in a chemical reactor under standard operating conditions. Electro-analytical techniques, cyclic voltammetry, and chrono-amperometry characterize the process. The electrochemical redo...
Persimmon wine has various nutritional elements and high commercial potential. However, the high content of methanol, which is derived from the fruit’s pectin, always hinders persimmon wine production. To reduce the methanol level in the wine,...
High-efficiency utilization of CO2 facilitates the reduction of CO2 concentration in the global atmosphere and hence the alleviation of the greenhouse effect. The catalytic hydrogenation of CO2 to produce value-added chemicals exhibits attractive pro...
This review presents methanol as a potential renewable alternative to fossil fuels in the fight against climate change. It explores the renewable ways of obtaining methanol and its use in efficient energy systems for a net zero-emission carbon cycle,...
Methanol steam reforming (MSR) is a promising technology for on-board hydrogen production in fuel cell applications. Although traditional Cu-based catalysts demonstrate high catalytic activity and selectivity towards CO2 relative to CO, which is prod...
Hydrogen production through methanol reforming processes has been stimulated over the years due to increasing interest in fuel cell technology and clean energy production. Among different types of methanol reforming, the steam reforming of methanol h...
Biofuels are the most essential types of alternative fuels, which currently have significant potential to reduce CO2 emissions compared to fossil fuels. Methanol is a more efficient fuel than petrol due to its physicochemical properties, such as a hi...
Power-to-X technologies play a crucial role in accelerating the energy and material transition. A key opportunity lies in integrating these systems with existing bio-based infrastructures such as anaerobic digesters, providing a reliable source of bi...
Herein, graphene oxide nanosheets (GO) were synthesized and employed as an additive at various proportions to fabricate a novel cation exchange membrane based on grafted cellulose acetate with sodium 4-styrenesulfonate (GCA) via a solution casting me...
Methane is one of the promising alternatives to non-renewable petroleum resources since it can be transformed into added-value hydrocarbon feedstocks through suitable reactions. The conversion of methane to methanol with a higher chemical value has r...
The purpose of this study is to identify the steps involved in fabricating silica/chitosan composite membranes and their suitability for fuel cell applications. It also intends to identify the physical characteristics of chitosan composite membranes,...
Methanol adsorption over both supported NiSn Nps and analogous NiSn catalyst prepared by impregnation was studied by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) to gain insights into the basis of hydrogen production f...
Methanol synthesis from CO2 is a key strategy for carbon capture and utilization, offering a viable solution to mitigate climate change. The direct synthesis of methanol not only reduces greenhouse gases but also produces valuable chemicals for indus...
Approximately 25% of global carbon emissions come from food production. Renewable fuels are crucial for curbing greenhouse gas (GHG) emissions from vehicles, non-road machines, and agricultural machinery. Tractors, key to modern farming, are central...
Methanol fuel engines can effectively reduce emissions of carbon monoxide and particulate matter, but they cause a substantial increase in emissions of unregulated pollutants like methanol and formaldehyde. In this study, Ag/CeO2 catalysts were prepa...
In industry, one of the main catalysts typically employed for the selective oxidation of methanol to formaldehyde is a multi-component oxide containing both bulk Fe2(MoO4)3 and excess MoO3. It is thought that the excess MoO3 primarily acts to replace...
Methanol is a widely used industrial and household alcohol that poses significant health risks upon exposure. Despite its extensive use, methanol poisoning remains a critical public health concern globally, often resulting from accidental or intentio...
The molecular dynamics method was used to study the structure and properties of dendrigrafts of the first and second generations in methanol–water mixtures with various volume fractions of methanol. At a small volume fraction of methanol, the s...
In this research, an ANOVA analysis and a response surface methodology are applied to analyze the equilibrium of methanol reaction from pure carbon dioxide and hydrogen. In the ANOVA analysis, carbon monoxide composition in the feed, reaction tempera...
Several Cu and Ni-based catalysts were synthetized over Ce-based supports, either pure or mixed with different amounts of alumina (1:2 and 1:3 mol/mol). Different metal loadings (10–40 wt%) and preparation methods (wet impregnation, co-precipit...
Recrystallization of polyoxymethylene (POM) in solvent is an effective post-treatment method for manufacturing a better POM product. Herein, the crystallization process of POM in methanol was investigated with the use of a series of equipment. The re...
The kinetics of methanol synthesis remains debatable for various reasons, such as the lack of scientifically conclusive agreement about reaction mechanisms. The focus of this paper is on the evaluation of the intrinsic kinetics of the methanol synthe...
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