Processes

Lignocellulose is a complex and abundant biomass source, and finding ways to efficiently break it down is essential for various applications, including bioenergy production and waste management. Biogas production can be significantly enhanced by adding rumen fluid to the anaerobic digestion process, which contains a variety of microorganisms with the enzyme activity necessary to breakdown complex lignocellulosic materials. This study examined the influence of rumen anaerobic bacteria inoculum on alfalfa biomass biogas yield and quality. Inoculation experiments were performed, and the higher biogas yield from organic matter was gained in experiment (A), with a rumen fluid addition of 340 ± 3.2 L/kg_VS, compared to the utilization of a digestate alone in (B), 238 ± 1.2 L/kg_VS. The results demonstrated that a pretreatment temperature of 37 °C (experiment D) yielded the highest biogas production, 381 ± 3.9 L/kg_VS, and maintained a high methane content of 63.9 ± 1.9%. Notably, pretreatment at 25 °C resulted in only a 3% increase over the raw sample and a pretreatment at 50 °C (respectively, experiments C and E) showed no significant changes, emphasizing the sensitivity of pretreatment efficiency to temperature variations. Full article

Pilot diesel ignition is an effective approach for achieving efficient and clean combustion of natural gas. In this study, a rapid compression and expansion machine (RCEM) was constructed for examining diesel-ignited premixed methane combustion. The effects of the methane equivalence ratio and pilot diesel mass on the combustion process of diesel-ignited premixed methane gas were investigated. The results show that the combustion process can be divided into two stages: diesel dominance and premixed methane combustion. An increase in the methane equivalence ratio inhibits diesel combustion, leading to delayed CA10 and OH radical generation. However, it enhances premixed methane flame propagation and improves the heat release rate, resulting in a shorter combustion duration. An increase in the pilot diesel mass contributes to a larger flame area and higher OH generation intensity in the ignition region; however, too large a diesel mass inhibits methane flame propagation towards the diesel nozzle due to an extended injection duration. In conclusion, a larger pilot diesel mass can achieve better overall combustion performance, but excessive amounts may be counterproductive. Full article

In order to study the internal flow state and wear law of a bulb cross-flow unit based on the particle non-uniform phase model in the Euler–Euler method, the solid-liquid two-phase flow condition of the hydraulic turbine under different solid-phase diameters, concentrations, and guide vane openings is calculated. The results show that (1) Under the same solid-phase physical parameters, the distribution of solid-phase concentration on the working surface of the blade is positively correlated with the opening degree of the guide vane, the concentration of the solid phase on the back of the blade is negatively correlated with the opening degree of the guide vane. (2) The addition of the solid phase changes the time-domain period of pressure pulsations at the rotor inlet and the tailpipe inlet under clear water conditions, and the tailpipe pressure pulsation coefficient decreases with increasing solid-phase concentration. The pressure pulsation coefficient increases with increasing solid-phase diameter and concentration at the inlet of the rotor. (3) Numerical simulation of the wear characteristics of cross-flow turbine by Finne’s wear model reveals that the two-phase flow condition with high concentration, large particle size and small openings has a more serious effect on turbine blade wear. Full article

In order to simulate and analyze the mechanized seeding process of sesbania seeds by using a discrete element method and improve the reliability of the discrete element simulation test, the contact parameters of sesbania seeds were calibrated in combination with the actual seed drop test and the simulated seed drop test. Through measurements, the intrinsic parameters of the sesbania seed were determined, and the discrete element simulation model of the sesbania seed was established. A measuring device that can simultaneously measure the resting angle and the stacking angle of the population was designed. The rest angle error and the stack angle error of the actual seed drop test and the simulated seed drop test were used as test indicators. The Plackett–Burman test screened out the contact parameters that had a significant effect on the test indicators. The response surface method (RSM) was used to carry out the three-factor quadratic rotation orthogonal combination test, and the mathematical regression model between the significant contact parameters and the test indexes was established. The optimal combination of contact parameters was determined using the multi-objective optimization method as follows: collision recovery coefficient between seeds of 0.463, static friction coefficient between seeds of 0.520, and rolling friction coefficient between seeds of 0.072. The discrete element model and calibration parameters of sesbania seeds were tested and verified using a fluted roller feed mechanism. The results showed that the average relative error between the measured value and the simulated value of the mass flow rate of the sesbania seeds was 2.74%, less than 5%, indicating that the discrete element simulation model of sesbania seeds and the calibration results of the contact parameters had high accuracy and reliability, which could be used for the discrete element simulation test of sesbania seeds. Full article

In the fragile mining areas of western China, the contradiction between coal mining and water resource protection coexists prominently. Facing this issue, it is necessary to understand the dynamic relationship between mining-induced shear stress and groundwater seepage, as well as the fracture morphology of the overlying strata. In this study, the seepage characteristics of rough fractures within the rock mass are thoroughly investigated, with an emphasis on studying the effects of shear stress and seepage erosion. This research is carried out through seepage experiments and 3D fracture morphology scanning, and the research results are mainly as follows: (a) Rocks with higher shear strengths show less fluctuation in changes in fracture morphology and seepage velocity. (b) The permeability of sandstone and concrete fractures is inversely proportional to the shear stress. The layering of coal greatly limits seepage through the fractures and the permeability of coal is about one-tenth of the permeability of sandstone and concrete under the same conditions. (c) The mechanism of erosion damage to the rock by water-force coupling is the result of the shear and extrusion generated by rock fractures and the transport of rock particles. Changes in fracture erosion and seepage characteristics brought about by the damage will mutually promote and intensify the erosive effect of water force. (d) The degree of change in fracture morphology (fracture damage) under the same conditions is coal > concrete > sandstone. There are differences in the response of different types of rock to the shear stress–seepage erosion, but all show obvious changes in fracture damage and seepage characteristics. Full article

Wastewater treatment results in large amounts of sewage sludge in the wastewater treatment plant (WWTP) which imposes on its reuse. The most promising application is as a fertilizer in agriculture which is regulated by national and European legislation. Along with the mandatory determination of potentially toxic elements (PTEs), in order to assess not only the risks, but also the beneficial properties, the determination of the total chemical composition is desirable. Inductively coupled plasma mass spectrometry (ICP-MS) is the most promising technique for multielement characterization which can be applied both for quantitative and semiquantitative analysis. A significant difference between the approaches is that the semiquantitative analysis is performed after a calibration with one standard solution containing at least three elements, but, at the same time, the accuracy is worse. In the present work, the accuracy of semiquantitative analysis with a different number of calibration elements using both water standard solutions and certified reference material (CRM) for calibration was investigated for the determination of 69 elements in sewage sludge CRMs and samples. It has been found that the accuracy can vary within a wide range, depending on the concentration of the elements, the number of calibration elements, and/or the presence of neighboring masses. In order to obtain an accuracy of up to 30%, it is recommended to shorten the mass intervals and perform the calibration with at least 18 elements, mainly microelements. The method was applied for fast panoramic analysis of sewage sludge samples from WWTPs and the concentrations were close to the data from quantitative analysis. Full article

Due to the presence of diverse phenolic classes in wild strawberry (Fragaria vesca L.) leaves, there is an ever-growing effort to find new, efficient methods for their recovery and detailed characterization. Microwave-assisted extraction (MAE) and accelerated solvent extraction (ASE) were evaluated to understand the impact of the extraction temperature, extraction time, and solvent-to-sample ratio (SSR) on the quantitative and qualitative properties of the obtained extracts. The highest total phenolic content (8027 mg GA/100 g DW), as well as the highest DPPH^• antiradical activity (903 μmol TE/g DW), was obtained with ASE at 150 °C with a static time of 5 min and an SSR of 40:1, while the highest ABTS^•+ antiradical activity (681 μmol TE/g DW) and FRAP (2389 μmol TE/g DW) were obtained with MAE after 5 min at 80 °C and an SSR of 40:1. A total of 54 different phenolics were identified by UPLC/MS-MS, some for the first time. The MAE extract had a higher content of phenolic acids (40%; esp. p-hydroxybenzoic acid, gallic acid) and myricetin, while the ASE extract was richer in proanthocyanidins (88%; esp. procyanidin B1, procyanidin trimer), flavonols (29%; esp. quercetin, quercetin-3-glucuronide, rutin), flavan-3-ols (50%; esp. epicatechin), and flavones (39%; esp. luteolin). The results indicated that for optimal extraction conditions, the target phenolics and the desired antioxidant properties of the obtained extracts should be considered. Full article

With the deep development of tight reservoir in Mahu Sag, the trend of rising water cut during flowback concerns engineers, and its control mechanism is not yet clear. For this purpose, the integrated numerical model of horizontal well pattern from fracturing to production was established, and its applicability has been demonstrated. Then the flowback performance from child wells to parent wells and single well to well pattern was simulated, and the optimization method of reasonable flowback strategy was discussed. The results show that the formation pressure coefficient decreases as well patterns were put into production year by year, so that the seepage driving force of the matrix is weakened. The pressure-sensitive reservoir is also accompanied by the decrease of permeability, resulting in the increase of seepage resistance, which is the key factor causing the prolongation of flowback period. With the synchronous fracturing mode of well patterns, the stimulated reservoir volume (SRV) is greatly increased compared with that of single well, which improves the reservoir recovery. However, when the well spacing is less than 200 m, well interference is easy to occur, resulting in the rapid entry and outflow of fracturing fluid, and the increased water cut during flowback. Additionally, the well patterns in target reservoir should adopt a drawdown management after fracturing, with an aggressive flowback in the early stage and a slow flowback in the middle and late stage. With pressure depletion in different development stages, the pressure drop rate should be further slowed down to ensure stable liquid supply from matrix. This research can provide a theoretical guidance for optimizing the flowback strategy of tight oil wells in Mahu sag. Full article

The grinding process via friction at the micro-scale in a mill with stones is considered a variable combination of contacts, with two-body (the asperities of lower millstone in direct contact with the asperities of upper millstone) and three-body (micro-particles of ground seeds trapped between the asperities of lower and upper stones of the mill) contacts. Three elements are described: (1) the mechanical contact of the asperities of the lower and upper millstones to predict pressures on asperities by modeling; (2) tests on a millstone sample covered with grinding particles; and (3) tests on a wafer sample formed by the millstones with the grinding particles between them. This paper highlights the combined effects of the micro-scale friction via individual measurements, using an analytical model to sum these effects and validating the model by performing several experiments. An efficiency grind by friction assumes the grain’s movement and interaction between the seeds and solid surfaces, and is highlighted through theoretical and experimental studies. Topography analysis of the surface of the millstones reveals the model of microscopic frictional force. Endpoint measurements (the traces of the surface topography evolution) enable model verification in the grinding process. Thus, the results obtained in the grinding process in the stone mills via friction have practical utility through research benefits. Therefore, they allow for the improvement of quality, reliability, flexible grinding, quality control of the flours, and uniformity degree (fineness/shredding). Full article

One of the operational challenges regarding the use of bentonite pellets as sealing materials in the abandonment of offshore fields consists of their placement inside the well. This study aimed to analyze the interaction of fluid media, consisting of saline solutions (NaCl, CaCl₂ and KCl) and organic compounds (diesel, glycerin and olefin), with bentonite pellets, for their applications as displacement fluids in offshore oil well abandonment operations. The physical integrity of the bentonite pellets in contact with the fluids was verified through visual inspections and dispersibility tests. Linear swelling tests were also performed to evaluate the swelling potentials of the pellets in deionized water after their contact with the fluid media. The results indicated that the NaCl, CaCl₂ and KCl solutions completely compromised the physical integrity of the pellets, while diesel and olefin showed the best responses regarding the structural preservation. Furthermore, the linear swelling tests showed that, even after the contact with diesel and olefin for 1 h, the bentonite pellets reached a total swelling of 78% in water after 24 h. In this way, diesel and olefin proved to be highly promising alternatives to be used as displacement fluids for bentonite pellets in wells that will be abandoned in a submarine environment. Full article

In order to mitigate time-varying, lag, and nonlinearity impacts on fertilization systems and achieve precise control of liquid conductivity, we propose a novel hybrid-optimized fractional-order proportional-integral-derivative (PID) algorithm. This algorithm utilizes a fuzzy algorithm to tune the five parameters of the fractional-order PID algorithm, employs the Smith predictor for structural optimization, and utilizes Wild Horse Optimizer, improved by genetic algorithms, to optimize fuzzy rules. We conducted MATLAB simulations, precision experiments, and stability tests on this controller. MATLAB simulation results, along with precision experiment results, indicate that compared to PID controllers, Smith predictor-optimized PID controllers, and fuzzy-tuned fractional-order PID controllers, the proposed controller has the narrowest steady-state conductivity range, the shortest settling time, and the lowest overshoot, showcasing excellent overall dynamic performance. Stability test results demonstrate that the controller maintains stable operation under different pressure conditions. Therefore, this control system from our study achieves superior control effectiveness, providing a viable approach for the control of nonlinear time-delay systems. Full article

The extraction of silica particles from rice husks has been extensively studied. This review aims to present the most efficient approach to harnessing rice husk biomass and converting silica into high-value-added materials for direct applications to address current challenges like water purification. Rice husks, as a residue from agriculture, had been largely used as a source of power through direct incineration in major rice-producing countries. However, rice husks present an intriguing opportunity as a renewable source of SiO₂, offering a low-cost adsorbent with a high surface area and ease of functionalization that can be transformed into diverse mesoporous silica structures or composites, enabling applications in catalysis, drug delivery, water treatment, etc. This dual potential of rice husks can be harnessed by combining bio-oil and syngas production through pyrolysis with the efficient extraction of SiO₂, ensuring the comprehensive utilization of the biomass. This review not only highlights the immense potential of silica nanoparticles but also serves as a roadmap for future investigations, with the ultimate aim of harnessing the full capabilities of this renewable and sustainable resource, contributing to the circular economy by yielding valuable by-products. Full article

The effect of hollow glass beads on poly(ε-caprolactone) (PCL) oxidative degradation has been evaluated by the non-isothermal chemiluminescence (CL) method and thermogravimetry analysis (TGA). The main goal of the research and this publication was to reduce the production costs associated with the materials for 3D printing, which would also have a low mass, excellent biocompatibility and suitable thermal properties. Experiments have clearly shown the dual effect of a filler and its extent in terms of poly(ε-caprolactone). The chosen methods demonstrate the superposition of both the pro-degradation and stabilization effects of hollow glass beads on the polymer. The former was evident above the load of 10 wt.% of filler. The non-isothermal TGA records were analyzed as being composed of three temperature-dependent processes of the first-order kinetics. A massive compensation effect between the so-called activation energy and the logarithm of pre-exponential factors for heating rates of 2.5, 5 and 10 °C/min has been shown to be typical for similar non-isothermal thermogravimetry evaluation. Full article

Ice formation on structures like wind turbine blade airfoils significantly reduces their aerodynamic efficiency. The presence of ice on airfoils causes deformation in their geometry and an increase in their surface roughness, enhancing turbulence, particularly on the suction side of the airfoil at high angles of attack. An approach for understanding this phenomenon and assessing its impact on wind turbine operation is modeling and simulation. In this contribution, a computational fluid dynamics (CFD) study is conducted using FENSAP-ICE 2022 R1 software available in the ANSYS package. The objective was to evaluate the influence of surface roughness modeling (Shin et al. and beading models) in combination with different turbulence models (Spalart–Allmaras and k-ω shear stress transport) on the estimation of the aerodynamic performance losses of wind turbine airfoils not only under rime ice conditions but also considering the less studied case of glaze ice. Moreover, the behavior of the commonly less explored pressure and skin friction coefficients is examined in the clean and iced airfoil scenarios. As a result, the iced profile experiences higher drag and lower lift than in the no-ice conditions, which is explained by modifying skin friction and pressure coefficients by ice. Overall, the outcomes of both turbulence models are similar, showing maximum differences not higher than 10% in the simulations for both ice regimes. However, it is demonstrated that the influence of blade roughness was critical and cannot be disregarded in ice accretion simulations on wind turbine blades. In this context, the beading model has demonstrated an excellent ability to manage changes in roughness throughout the ice accretion process. On the other hand, the widely used roughness model of Shin et al. could underestimate the lift and overestimate the drag coefficients of the wind turbine airfoil in icy conditions. Full article

Agrivoltaics, a system combining the production of agricultural crops and solar energy on the same land area, offers a potential solution to land use competition between different sectors. However, concerns have been raised regarding the impact of shade on plant growth under Agrivoltaic Systems (AVSs). Numerous studies have explored the effects of AVSs shading on agricultural crops. However, most of these studies focused on shade-tolerant crops, leaving a gap in the understanding of how these systems affect shade-intolerant crops. To this end, this study was conducted in Bari, southern Italy, using two types of AVSs: conventional (Con) and semi-transparent (ST) panels. The objective was to assess the impacts of the different levels of shading on the tomato yield and fruit quality. Tomato cultivation occurred between May and August under various conditions: Con panels, ST panels, and Open Field. The results revealed that soil temperature decreased under both AVSs compared to in the open field conditions. However, the significant reduction in photosynthetically active radiation (PAR), up to 43% in ST and 67% in Con, led to yield reductions ranging between 28% and 58% in ST and Con, respectively. Nonetheless, AVSs demonstrated their potential to reduce irrigation water demand by over 15% in ST and more than 20% in Con. Interestingly, the AVSs reduced fruit size but improved certain fruit quality attributes, such as titratable acidity, which is closely correlated with fruit flavour. These findings highlight the challenges of cultivating shade-intolerant crops under AVSs in a Mediterranean climate, while temperate, dry conditions may offer more favourable prospects for agricultural production. Full article

In the present study, graphite scrap powder from machining of commercial graphite blocks for electrical discharge machining (EDM) applications was recycled as a filler material for manufacturing graphite blocks, and its suitability for use as EDM electrodes was thoroughly assessed. The effects of process parameters applied in EDM electrode manufacturing, including the number of impregnations and graphitization temperatures, on the physical properties of the resulting graphite blocks, were examined. Additionally, EDM performance was evaluated with respect to the above process parameters. In blocks subjected to three impregnation treatments, followed by graphitization at 2200 °C, surface protrusions formed during the EDM process, indicating that the EDM process did not proceed smoothly. On the other hand, in blocks that underwent three impregnation treatments, followed by graphitization at 2800 °C, no surface protrusions were observed, indicating successful EDM operation. This observation further confirms the suitability of these recycled materials for use in EDM electrodes. The graphite block electrodes fabricated using recycled graphite scrap exhibited inferior cyclic stability, with an electrode wear rate of 0.82%, higher than that of a commercial graphite block electrode (0.04%). Nevertheless, using recycled graphite scrap contributes to reducing product costs and CO₂ emissions, making the developed graphite electrodes a favorable choice. Full article

Endless rolling urgently requires an increase in the casting speed of continuous casting. For the continuous casting process of a high-casting-speed billet, the heat flux of the mold would be much higher, requiring a stronger cooling performance and longer mold life to match the high-speed casting. Mold material, thickness, and slot structure have a great influence on the casting speed. To design a more efficient billet casting mold, a three-dimensional thermal-stress-coupled analysis model of a 150 mm × 150 mm mold was established in this research to analyze the thermal state of a mold with high casting speed; in addition, the material, thickness, and water slot structure, which pertain to the mold cooling performance, were also studied. The results show that the billet mold of Cu-Ag with a thinner thickness and right-corner water slot is better in terms of casting speed. Regarding the material, the Cu-Ag mold has a higher thermal conductivity efficiency; its hot surface temperature is 4.89 °C lower, its equivalent stress is 7 MPa lower, and its longitudinal deformation is 0.0023% lower compared with the deoxidized phosphorus copper mold. Regarding the thickness, the thinner mold has a 60.76 °C lower hot surface temperature, its equivalent stress is 340 MPa lower, and its longitudinal deformation is 0.0443% lower compared with the thicker mold. For the water slot structure, the mold with the right-angled water slot has a 2.895 °C lower hot surface temperature, its equivalent stress is 37 MPa lower, and its longitudinal deformation is 0.0039% lower compared with the mold with a rounded-corner water slot. Full article

The nanoscale pores in shale oil and gas are often filled with external nanomaterials to enhance wellbore stability and improve energy production. And there has been considerable research on discrete element blocking models and simulations related to nanoparticles. In this paper, the pressure transmission experimental platform is used to systematically study the influence law of different water activity salt solutions on shale permeability and borehole stability. In addition, the force model of the particles in the pore space is reconstructed to study the blocking law of the particle parameters and fluid physical properties on the shale pore space based on the discrete element hydrodynamic model. However, the migration and sealing patterns of nanomaterials in shale pores are unknown, as are the effects of changes in particle parameters on nanoscale sealing. The results show that: (1) The salt solution adopts a formate system, and the salt solution is most capable of blocking the pressure transmission in the shale pores when the water activity is 0.092. The drilling fluid does not easily penetrate into the shale pore space, and it is more capable of maintaining the stability of the shale wellbore. (2) For the physical blocking numerical simulation, the nanoparticle concentration is the most critical factor affecting the shale pore blocking efficiency. Particle size has a large impact on the blocking efficiency of shale pores. The particle diameter increases by 30% and the pore-blocking efficiency increases by 13% when the maximum particle size is smaller than the pore exit. (3) Particle density has a small effect on the final sealing effect of pore space. The pore-plugging efficiency is only increased by 4% as the particle density is increased by 60%. (4) Fluid viscosity has a significant effect on shale pore plugging. The increase in viscosity at a nanoparticle concentration of 1 wt% significantly improves the sealing effectiveness, specifically, the sealing efficiency of the 5 mPa-s nanoparticle solution is 16% higher than that of the 1 mPa-s nanoparticle solution. Finally, we present a technical basis for the selection of a water-based drilling fluid system for long horizontal shale gas drilling. Full article