Japan is a unique country in terms of mobility. While the popularity of bicycles as a practical and environmentally friendly means of transport is growing worldwide, particularly since the COVID crisis, bicycle use in Japan has been declining for ove...
Embedding cycles into a network topology is crucial for a network simulation. In particular, embedding Hamiltonian cycles is a major requirement for designing good interconnection networks. A graph G is called r-spanning cyclable if, for any r distin...
A liquid electrolyte lithium/sulfur (Li/S) cell is a liquid electrochemical system. In discharge, sulfur is first reduced to highly soluble Li2S8, which dissolves into the organic electrolyte and serves as the liquid cathode. In solution, lithium pol...
This paper reports a modeling methodology to predict the effect of the loss of cyclable lithium of a lithium-ion battery (LIB) cell comprised of a LiNi0.6Co0.2Mn0.2O2 cathode, natural graphite anode, and an organic electrolyte on the discharge behavi...
In this study, we present a modeling approach to estimate the combined effects of cyclable lithium loss and electrolyte depletion on the capacity and discharge power fades of lithium-ion batteries (LIBs). The LIB cell based on LiNi0.6Co0.2Mn0.2O2 (NC...
Flexible electrodes are highly desirable for next-generation wearable lithium-ion batteries. To achieve high-capacity flexible electrode materials, SnO2 with high theoretical capacity has been introduced into electrodes and shows promising capacity....
Preparation of reduced graphene oxide (RGO) from abundant and inexpensive low-grade coal is regarded as one of the most promising methods for utilizing this resource in a high-value and environmentally sustainable manner. As the main precursor for th...
One of the important issues in evaluating an interconnection network is to study the hamiltonian cycle embedding problems. A graph G is spanning k-edge-cyclable if for any k independent edges
Solid-state refrigeration based on elastocaloric materials (eCMs) requires reversibility and repeatability. However, the intrinsic intergranular brittleness of ferromagnetic shape memory alloys (FMSMAs) limits fatigue life and, thus, is the crucial b...
This paper presents a Decision Support System (DSS) designed to enhance cyclability and perceived bikeability in urban areas, with an application to the city of Milan, Italy, focusing on cycling toward the urban university campuses of Politecnico di...
As a step towards efficient and cost-effective electrocatalytic cathodes for Li–O2 batteries, highly porous hausmannite-type Mn3O4 hollow nanocages (MOHNs) of a large diameter of ~250 nm and a high surface area of 90.65 m2·g−1 were...
To improve the thermochemical energy storage (TCS) behavior of Mn2O3, several Mn–Mo oxides with varying amounts of MoO3 (0–30 wt%) were prepared by a precipitation method. The physico-chemical properties of the solids were studied by N2 a...
Potassium-ion battery, a key analog of lithium-ion battery, is attracting enormous attentions owing to the abundant reserves and low cost of potassium salts, and the electrochemically reversible insertion/extraction of the K-ion within the commercial...
Severe plastic deformation via high-ratio differential speed rolling (HRDSR) was applied to the Ni-rich Ti-50.8Ni alloy. Application of HRDSR and a short annealing time of 5 min at 873 K leads to the production of a partially recrystallized microstru...
The interest in and need for carbon-free fuels that do not rely on fossil fuels are constantly growing from both environmental and energetic perspectives. Green hydrogen production is at the core of the transition away from conventional fuels. Along...
Lithium–sulfur batteries (LSBs) are widely studied as an alternative to lithium-ion batteries, this emphasis being due to their high theoretical energy density and low cost, and to the high natural abundance of sulfur. Lithium polysulfide shutt...
Silicon is a promising anode material that can increase the theoretical capacity of lithium-ion batteries (LIBs). However, the volume expansion of silicon remains a challenge. In this study, we employed a novel combination of conductive additives to...
The revolution in lithium-ion battery (LIB) technology was partly due to the invention of graphite as a robust negative electrode material. However, equivalent negative electrode materials for complementary sodium ion battery (NIB) technologies are y...
Aqueous zinc-ion batteries (AZIBs) are considered hopeful large-scale electrochemical energy storage devices because of their simple production process, high specific capacity, intrinsic safety and low cost. However, the dendritic growth of Zn and si...
The preparation of a dextran (Dex)-hydroxyethyl cellulose (HEC) blend impregnated with ammonium bromide (NH4Br) is done via the solution cast method. The phases due to crystalline and amorphous regions were separated and used to estimate the degree o...
Cr8O21 can be used as the cathode material in all-solid-state batteries with high energy density due to its high reversible specific capacity and high potential plateau. However, the strong oxidation of Cr8O21 leads to poor compatibility with polymer...
Germanium–cobalt–indium nanostructures were synthesized via cathodic electrodeposition from aqueous complex solutions of Ge (IV) and Co (II) with drop-like indium crystallization centers. This approach features simplicity, avoids heating...
Flexible cross-linked anion exchange membranes (AEMs) based on poly (p-phenylene oxide) grafted with N-spirocyclic quaternary ammonium cations were synthesized via UV-induced free-radical polymerization by using diallylpiperidinium chloride as an ion...
Taking advantage of fact that the surface electrons of metallic nanoparticles (NPs) can be effectively released even at a low voltage bias, we demonstrate an improvement in the electrochemical performance of nanosized Prussian Blue (PB)-based seconda...
Graphite materials for commercial Li-ion batteries usually undergo special treatment to control specific parameters such as particle size, shape, and surface area to have desirable electrochemical properties. Graphite surfaces can be classified into...
A NASICON-based Na3V2(PO4)2F3 (NVPF) cathode material is reported herein as a potential symmetric cell electrode material. The symmetric cell was active from 0 to 3.5 V and showed a capacity of 85 mAh/g at 0.1 C. With cycling, the NVPF symmetric cell...
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Sodium–ion battery capacitors (SIBatCs) synergistically combine battery–type and capacitor–type components in an inter–parallel configuration, simultaneously delivering high energy and power densities. We pioneer the developme...
Synergism between the alloy materials and the carbon support matrix, in conjunction with the binder and electrolyte additives, is of utmost importance when developing sodium-ion batteries as viable replacements for lithium-ion batteries. In this stud...
Na5V12O32 is an attractive cathode candidate for aqueous zinc-ion batteries (AZIBs) by virtue of its low-cost and high specific capacity (>300 mAh g−1). However, its intrinsically inferior electronic conductivity and structural instability r...
Improving the efficiency and longevity of energy storage systems based on Li- and Na-ion rechargeable batteries presents a major challenge. The main problems are essentially capacity loss and limited cyclability. These effects are due to a hierarchy...
Proton exchange membrane fuel cells (PEMFCs) are an attractive green technology for energy generation. The poor stability and performances under working conditions of the current electrolytes are their major drawbacks. Metal-Organic Frameworks (MOFs)...
A series of Li(Ni1/3Mn1/3Co1/3)1−xMxO2 (M = Al, Mg, Zn, and Fe, x = 0.06) was prepared via sol-gel method assisted by ethylene diamine tetra acetic acid as a chelating agent. A typical hexagonal α-NaFeO2 structure (R-3m space group) was o...
The creation of effective supercapacitor materials is still a priority in the quest to improve energy storage technology. Herein, we present a novel nanocomposite composed of carbon nanoparticles (CNPs) and colloidal SnO2 quantum dots (c-SQDs) or col...
Recently, rechargeable zinc-ion batteries (ZIBs) have gained a considerable amount of attention due to their high safety, low toxicity, abundance, and low cost. Traditionally, a composite manganese oxide (MnO2) and a conductive carbon having a polyme...
The solid–electrolyte interphase (SEI), the passivation layer formed on anode particles during the initial cycles, affects the performance of lithium-ion batteries (LIBs) in terms of capacity, power output, and cycle life. SEI features are dependent...
In the pursuit of high energy density batteries beyond lithium, room-temperature (RT) sodium–sulfur (Na-S) batteries are studied, combining sulfur, as a high energy density active cathode material and a sodium anode considered to offer high ene...
Supercapacitors have attracted significant interest as increased energy storage devices due to their high power density, rapid charge/discharge performance, and long cyclability. In this study, NiO, Co3O4, NCO, and NCO/rGO composite electrodes were p...
Bismuth chalcogenide (Bi2X3; X = sulfur (S), selenium (Se), and tellurium (Te)) materials are considered as promising materials for diverse applications due to their unique properties. Their narrow bandgap, good thermal conductivity, and environmenta...
Polymer electrolyte based on Nafion-117 membranes in the Li+ form with intercalated 1,3-dioxolane-dimethoxyethane solvent mixtures (DOL-DME) has been obtained. The obtained electrolyte Nafion-Li+-DOL-DME has been characterized by DSC analysis, IR- an...
Natrium superionic conductor (NASICON) compounds have emerged as a rising star in the field of sodium-ion batteries (SIBs) owing to their stable framework structure and high Na+ ionic conductivity. The NASICON-structured Na2VTi(PO4)3 manifests signif...
Three-dimensional interconnected mesoporous nanoflakes of amorphous Ni-Mo-Co trimetallic hydroxides were successfully deposited on a Ni foam (NF) using a facile, environmentally friendly, and scalable electrochemical deposition method. The elemental...
Vanadium pentoxide (V2O5)-anchored single-walled carbon nanotube (SWCNT) composites have been developed through a simple sol–gel process, followed by hydrothermal treatment. The resulting material is suitable for use in flexible ultra-high capa...
The development of cobalt-free P2-Na2/3Ni1/3Mn2/3O2 cathodes is hampered by poor electrochemical performance, resulting from structural instability during high-voltage cycling. Herein, Li+ and F− ions are introduced simultaneously via a simple...
The development of novel anode materials for high energy density is required. Alloying Si with other metals is a promising approach to utilize the high capacity of Si. In this work, we optimized the composition of a Si–Ti–Al ternary alloy to achieve...
We present a simple method of fabricating a hierarchically nanostructured CuO–Cu current collector by using laser ablation and metal mold imprinting to maximize the surface area. The laser ablation of the Cu current collector created the CuO na...
Electrochemical energy storage and conversion systems such as electrochemical capacitors, batteries and fuel cells are considered as the most important technologies proposing environmentally friendly and sustainable solutions to address rapidly growi...
This paper proposes a new model that predicts the cell voltage dynamics and capacity degradation induced by lithium plating and stripping. The proposed model uses a single equilibrium reaction to describe the deposition and dissolution of metallic li...
The capture of radioactive iodine (129I or 131I) is of significant importance for the production of nuclear power and the treatment of nuclear waste. In recent years, crystallized porous materials have been extensively investigated to achieve highly...
Lithium-ion batteries for electric vehicles (EV) require high energy capacity, reduced weight, extended lifetime and low cost. EV manufacturers are focused on Ni-rich layered oxides because of their promising attributes, which include the ability to...
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