Condensed Matter

Graphene holds significant promise as an ideal reinforcing phase. However, its tendency to irreversibly aggregate and its unclear impact on electrodeposition mechanisms have hindered the full exploitation of its advantages for enhancing material mechanical properties. In this study, we produced a graphene/Ni composite reinforced with reduced graphene oxide (rGO) via a simple, scalable, and cost-effective electrodeposition approach. The incorporation of graphene not only raised the cathodic polarization potential but also enhanced the transport of ions. As a result, the presence of rGO significantly influenced the grain size, grain distribution, and the proportion of growth twins-3(111). Compared with Ni, the graphene/Ni composite exhibited improvements of 14.8% in strength and 16.8% in fracture elongation. Additionally, first-principles calculations confirmed that superior electronic conductivity and all elastic moduli along with Poisson’s ratio were found to be higher in the composite. Our findings offer fundamental insights into the role of rGO in governing the structural evolution of graphene/metal composites.

The studied Ce_0.5Y_0.5−XTb_XF₃ (X = 0, 0.001, 0.002, 0.005, 0.01, and 0.05) nanoparticles were synthesized via the water-based co-precipitation method. All the samples demonstrated diameters in the 17–20 nm range and a hexagonal phase corresponding to the phase of CeF₃. Under 266 nm excitation (4f–5d absorption band of Ce³⁺), the luminescence spectrum shape was notably dependent on temperature. The integrated luminescence intensity ratio (LIR) of Ce³⁺ and Tb³⁺ (⁵D₄–⁷F₃) peaks was chosen as a temperature-dependent parameter. It was shown that the LIR functions linearly decay. The rate of decay decreases with the increase in Tb³⁺ concentration. This was explained by the fact that in the case of low Tb³⁺ concentrations, the spectral temperature dependence is mostly based on effective thermal quenching of Ce³⁺ luminescence. At higher Tb³⁺ concentrations, there is a higher probability of Ce³⁺ to Tb³⁺ energy transfer. Here, the efficiency of the temperature dependence of this process is lower, and the rate of LIR decay is lower as well.

We investigate the influence of Landau Levels (LLs) and Zeeman energy, induced by an applied magnetic field $\mathbf{B}$, on the critical temperature $T_c$ for two-dimensional (2D) ultraclean superconductors using a fully quantum mechanical approach within the Bardeen–Cooper–Schrieffer (BCS) theory. In contrast to standard BCS theory, it allows for Cooper pair formation between electrons with opposite spins and momenta along the $\mathbf{B}$ direction, both on the same or on neighboring LLs. Our quantum mechanical treatment of LLs reveals that the critical temperature $T_c$ for electrons paired on the same LL exhibits oscillations around the BCS critical temperature at low magnetic fields. The Zeeman energy leads to a decrease in $T_c(\mathbf{B})$ with increasing $\mathbf{B}$ for electrons paired both on the same and on neighboring LLs. Notably, as the g-factor increases, $T_c(\mathbf{B})$ decreases faster as the magnetic field increases for a larger g-factor than for a smaller one.