The main objective of the manuscript is to investigate mild hydrotreatment upgrading of hydrothermal liquefaction biocrude to improve its stability and energy content. To that end, biocrude hydrotreatment was performed, exploring three different oper...
Catalytic hydrotreatment (HT) is one of the most important refining steps in the actual petroleum-based refineries for the production of fuels and chemicals, and it will play also a crucial role for the development of biomass-based refineries. In fac...
Repolymerization is a huge problem in the storage and processing of biomass pyrolysis liquid (PL). Herein, to solve the problem of repolymerization, mild catalytic hydrotreatment of PL was conducted to convert unstable PL model compounds (hydroxyacet...
The mild hydrotreatment of a model mixture of tar-type compounds (i.e., naphthalene, 1-methylnaphthalene, acenaphthylene, and phenanthrene) to produce partially hydrogenated products in the range of C9–C15 was studied over Pd supported on TiO2 posses...
Due to the world’s rising energy demand and reliance on fossil fuels, exploring cleaner energy sources is urgent. Green diesel from renewable resources, such as waste vegetable oil, is promising because it is compatible with petroleum diesel fr...
The high-energy potential of wastewater sewage sludge (SS) produced in large amounts around the world makes it an attractive feedstock for fuels and energy sectors. Thermochemical valorization relying on pyrolysis of SS followed by hydrotreatment of...
The catalytic hydrotreatment of humins, the solid byproduct produced from the conversion of C6 sugars (glucose, fructose) to 5-hydroxymethylfurfural (HMF), using supported Pd@zeolite (Beta, Y, and USY) catalysts with different amounts of Pd (i.e., 0....
Hydrotreatment is vital for producing high-quality liquid fuels in petroleum refining and its air coolers are critical components prone to severe corrosion under high-temperature and high-pressure conditions. Ammonium salts from NH3-HCl and NH3-H2S r...
Catalytic hydrotreatment is recognized as an efficient method to improve the properties of pyrolysis liquids (PO) to allow co-feeding with fossil fuels in conventional refinery units. The promising catalyst recipes identified so far are catalysts wit...
Waste cooking oil with a high-acid-value (28.7 mg-KOH/g-oil) was converted to bio-hydrogenated diesel by a hydrotreatment process over supported Ru catalysts. The standard reaction temperature, H2 pressure, liquid hourly space velocity (LHSV), and H2...
This study investigates the hydrothermal liquefaction (HTL) of sewage sludge across a temperature range of 250–375 °C, combined with selective solvent extraction and catalytic hydrotreatment to produce high-quality biocrude. Four solvents i...
In this study, conditions were determined to obtain a solid wax with a waxy ester content of more than 25% from the hydrotreating of palm oil. The experiments were conducted in a pilot-scale fixed-bed reactor. The influence of temperature, liquid hou...
Effects of the recycle solvent hydrotreatment on oil yield of direct coal liquefaction were carried out in the 0.18 t/day direct coal liquefaction bench support unit of National Engineering Laboratory for Direct Coal Liquefaction (China). Results sho...
At the moment, there are no available data or studies exploring the production of naphtha boiling range hydrocarbons via hydroprocessing of pretreated residual lipids. To that aim, this study targets the production of naphtha, jet and diesel boiling...
The removal of nitrogen from coal tar pitch (CTP) through the hydrodenitrogenation (HDN) of CTP and its molecular behavior were evaluated in the presence of NiMo/γ-alumina and CoMo/γ-alumina catalysts. Fourier transform ion cyclotron reso...
The significance and challenges of hydrotreatment processes for vegetable oils have recently become apparent, encompassing various reactions like decarbonylation, decarboxylation, and hydrogenation. Heterogeneous noble or transition metal catalysts p...
Hydrothermal liquefaction of solid waste has been gaining more and more attention over the last few years. However, the properties of the HTL product, i.e., biocrude, are limiting its direct utilization. As a result, HTL biocrude upgrading is essenti...
To lower the sulphur content below 500 ppm and to increase the quality of bitumen derived heavy oil, a combination of hydrotreating followed by oxidative desulfurization (ODS) and oxidative denitrogenation (ODN) is proposed in this work. NiMo/γ...
Triacylglycerides (TAGs) produced via the syngas fermentation of biogenic residues and wastes were evaluated as a potential feedstock for advanced road transportation, aviation, and maritime drop-in fuels via hydroprocessing technology. Due to the li...
To obtain drop-in fuel properties from 3rd generation biomass, we herein report the catalytic hydrotreatment of microalgae biocrude, produced from hydrothermal liquefaction (HTL) of Spirulina. Our contribution focuses on the effect of temperature, in...
Acoustic emission (AE) testing is traditionally carried out on non-operating objects. Such requirement is associated both with the Kaiser effect, leading to the necessity for exceeding the test load above the working one and with a high level of nois...
The catalytic activity of high-loaded Ni-based catalysts for beech wood fast-pyrolysis bio-oil hydrotreatment is compared to Ru/C. The influence of promoter, temperature, reaction time, and consecutive upgrading is investigated. The catalytic activit...
Nickel-based catalysts promoted by Mo-oxo species have been proven to be quite promising for transformation of triglycerides into green diesel. The selection of the support for such catalysts is crucial. In the present study, pyrolyzed rice husk subj...
This study examined engine combustion characteristics of the plastic diesel produced through pyrolysis of waste plastics as an eco-friendly source of engine fuel. We extensively measured and compared the key fuel properties based on various diesel fu...
Several CoMoS/carbons were successfully synthetized using hydrothermal-type approaches and a subsequent surface reaction for the promotion step with Co. The effect of the microstructure of carbons used as a matrix for CoMoS-based catalysts was studie...
Phonolite material has shown to be promising catalyst support for the deoxygenation of triglycerides. In this work, we continue with our previous research by synthesising and testing three acid-treated phonolite-supported Co-Mo, Ni-Mo and Ni-W cataly...
One-pot deoxygenation of kraft lignin to aromatics and hydrocarbons of fuel-range quality is a promising way to improve its added value. Since most of the commercially resourced kraft lignins are impure (Na, S, K, Ca, etc., present as impurities), th...
C4 and C5 fractions are significant by-products in the ethylene industry, with considerable research and economic potential when processed through hydrogenation technology to enhance their value. This study explored the development of hydrotreating c...
In the present work, we compared the chemical profile of the organic compounds produced in non-catalytic pyrolysis of sugarcane bagasse at 500 °C with those obtained by the in-line catalytic upgrading of the vapor phase at 350 °C. The influen...
Bio-oils derived from the thermochemical processing of lignocellulosic biomass are recognized as a promising platform for sustainable biofuels and chemicals. While significant advances have been achieved with regard to the production of bio-oils by h...
Currently, Euro 5 (no more than 10 ppm sulfur content) and Euro 6 (less than 10 ppm sulfur content) diesel motor fuels are produced worldwide. High-quality diesel fuels are produced by removing sulfur compounds using a hydrodesulfurization process. T...
Co-Mo/γ-Al2O3 catalysts with different pore shapes were synthesized for the ex situ upgrading of extra heavy oils by hydrodesulfurization (HDS), hydrodemetallization (HDM), and hydrodeasphaltization (HDA). The catalysts were synthesized using a...
The hydrogenation of polyaromatic compounds (PACs) present in mineral oils is of great importance when it comes to the desired product properties and the minimization of health hazards; however, the presence of organonitrogen inhibits the conversion...
This study validates green hydrogen (
In this study, we investigate the catalytic degradation of polystyrene (PS) in water at low temperature (90–110 °C, 1 atm) using a multiphase carbide–alloy catalyst obtained by mechanosynthesis. X-ray diffraction and scanning electron...
The transformation of sunflower oil (SO) and waste cooking oil (WCO) into green diesel over co-precipitated nickel–zirconia catalysts was studied. Two series of catalysts were prepared. The first series included catalysts with various Ni loadin...
Mesityl oxide is standardly used to produce methyl iso butyl ketone but it can be also used to produce other useful compounds. Three catalysts were used for the reaction of the mesityl oxide reduction. They were NiW, NiMo, and CoMo supported on phono...
The main goal of this research is the production of e-fuels in gasoline- and diesel-range hydrocarbons via the hydrocracking of wax from Fischer–Tropsch (FT-wax) synthesis. The hydrogen for the hydrocracking process originated from solar energy via w...
The upgrading of waste plastic pyrolysis oil (WPPO) through hydrotreating (HDT) is crucial for transforming plastic waste into chemical feedstock. The catalytic role of HDT is of paramount importance for this conversion procedure. In this study, bime...
The ReFuelEU Aviation Regulation introduces mandatory targets for sustainable aviation fuels (SAF) from 2025 to 2050. However, hydrotreated esters and fatty acids (HEFA) technology based on waste oils alone is insufficient to meet targets beyond 2030...
The vacuum residue hydrocracker naphtha (VRHN) is a chemically unstable product that during storage changes its colour and forms sediments after two weeks. It cannot be directly exported from the refinery without improving its chemical stability. In...
Hydrotreatment is an efficient method for pyrolytic oil upgrading; however, the trade-off between the operational cost on hydrogen consumption and process profit remains the major challenge for the process designs. In this study, an integrated proces...
Risk analysis and prediction is a primary monitoring strategy to identify abnormal events occurring in chemical processes. The accidental release of toxic gases may result in severe problems for people and the environment. Risk analysis of hazardous...
Hydrotreatment of mucic acid (also known as galactaric acid, an glucaric acid enantiomer), one of the most promising bio-based platform chemicals, was systematically investigated in aqueous media over alumina, silica, or carbon-supported transition (...
Four nickel-based catalysts are synthesized by wet impregnation and evaluated for the hydrotreatment/hydrodeoxygenation of beech wood fast-pyrolysis bio-oil. Parameters such as elemental analysis, pH value, and water content, as well as the heating v...
Flaring is necessary to prevent pressure buildup in the unit. Due to hydrotreatment processes at the refinery, flare gas can contain significant amounts of hydrogen sulfide. Combusting this gas can result in environmental and health issues. One metho...
This article discusses the problems of exhaust gas emissions in the context of the possibility of their reduction through the use of fuels with hydrogen as an additive or hydrotreatment. These fuels, thanks to their properties, may be a suitable resp...
The long term ambition of energy security and solidarity, coupled with the environmental concerns of problematic waste accumulation, is addressed via the proposed waste-to-fuel technology. Plastic waste is converted into automotive diesel fuel via a...
Utilization of magnetic nanoparticle-mediated conversion of electromagnetic energy into heat is gaining attention in catalysis as a source of heat needed for a substrate’s chemical reaction (electrification of chemical conversions). We demonstr...
During the pre-hydrotreatment process, the hydrogen sulfide and ammonia present in the reaction atmosphere affect the conversion rate of bicyclic aromatics and the retention rate of monocyclic aromatic hydrocarbons (RRMA). In this study, 1-Methylnaph...
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