Skip to Content

Crystals, Volume 15, Issue 11

2025 November - 93 articles

Cover Story: Metal additive manufacturing is advancing the production of metallic components; however, understanding the quality of these parts in terms of bending fatigue is crucial for their safe use in demanding industries. This review explores the impact of AM process parameters, build orientation, post processing, and surface treatment on bending fatigue performance. By identifying current unresolved challenges, this study emphasizes the promise of miniaturized special geometries and predictive modeling techniques, establishing standardized procedures, and correlations across different fatigue tests to accelerate the testing and qualification of AM parts. By bridging current knowledge gaps and exploring future pathways, this work ensures the safer deployment of AM components in real-life bending fatigue loading applications. View this paper
  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
  • You may sign up for email alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.

Articles (93)

  • Article
  • Open Access
421 Views
19 Pages

Effect of Over-Temperature on Creep Damage of Bi-Based Brazing Filler Alloy

  • Jun Hong,
  • Tao Wang,
  • Baoyin Zhu,
  • Dongpeng Li,
  • Haitao Dong,
  • Dungui Zuo and
  • Gongye Zhang

20 November 2025

This work investigates the creep damage behavior and life prediction of Bi-based brazing alloys and their corresponding joints under intermittent over-temperature conditions, and proposes an integrated real-time monitoring and analytical framework. T...

  • Article
  • Open Access
2 Citations
815 Views
20 Pages

Influence of Y2O3 Content and Sintering Temperature on Microstructure and Mechanical Properties of YSZ Ceramics

  • Madi Abilev,
  • Dias Yerbolat,
  • Mazhyn Skakov,
  • Almira Zhilkashinova,
  • Alexandr Pavlov and
  • Igor Karpov

20 November 2025

This study investigates the influence of Y2O3 content and sintering temperature on the microstructure, phase composition, and physico-mechanical properties of zirconia-based ceramics with Al2O3 addition. It was shown that varying the stabilizer conte...

  • Article
  • Open Access
763 Views
17 Pages

20 November 2025

Halogen bonds play an important role in the targeted generation of solid-state structures, with polyhalogenated compounds enabling the simultaneous formation of various interactions. In this manuscript, we investigate the interactions of dihalogenate...

  • Article
  • Open Access
412 Views
16 Pages

20 November 2025

Alkali-activated slag grouting materials exhibited excellent mechanical properties but still faced technical challenges such as insufficient fluidity and overly rapid setting. To enhance their workability, this study introduced fly ash as a modifying...

  • Article
  • Open Access
669 Views
21 Pages

Effect of Partial Fe-Substitution by Y and/or Ce in BaFeO3-Based Oxides on Oxygen Diffusion

  • Anna Khodimchuk,
  • Irina Svishch,
  • Egor Gordeev and
  • Natalia Porotnikova

19 November 2025

The chemical diffusion coefficients of oxygen (Dδ) for the oxides BaFe0.9Ce0.1O3−δ (BFC10), BaFe0.9Y0.1O3−δ (BFY10), and BaFe0.8Ce0.1Y0.1O3−δ (BFCY1010) were determined by the oxygen pressure relaxation metho...

  • Article
  • Open Access
1 Citations
633 Views
20 Pages

18 November 2025

Electromagnetic phase reconfigurability is a critical functionality for many emerging applications in electronics, defence, and other disruptive technologies. This work addresses a significant challenge in developing nematic liquid crystal (NLC)-base...

  • Article
  • Open Access
1 Citations
690 Views
10 Pages

A Long-Wave Infrared Circularly Polarized Photodetector Based on an Array of Trapezoidal Silicon Pillars

  • Bo Cheng,
  • Yuxiao Zou,
  • Taohua Liang,
  • Ansheng Ye,
  • Kunpeng Zhai and
  • Longfeng Lv

17 November 2025

Integrating metasurface-based polarizing filters atop photodetectors enables the expansion of detection capabilities from intensity to polarization, offering significant potential for applications requiring high-precision discrimination in scientific...

  • Article
  • Open Access
1 Citations
661 Views
17 Pages

Electrolytic-Plasma Nitriding of Austenitic Stainless Steels After Mechanical Surface Treatment

  • Bauyrzhan Rakhadilov,
  • Zarina Satbayeva,
  • Almasbek Maulit,
  • Nurlat Kadyrbolat and
  • Anuar Rustemov

17 November 2025

In this work, the effect of preliminary mechanical surface treatment on the kinetics of formation, phase composition, and functional properties of the nitrided layer during electrolytic-plasma nitriding (EPN) of austenitic stainless steel 12Kh18N10T...

  • Article
  • Open Access
873 Views
10 Pages

Persistent PbI2-Passivated Microdomains in As-Prepared MAPbI3 Perovskite Thin Film Revealed by Spatially Resolved Photoluminescence and Raman Maps

  • Bong-Geun Kim,
  • Jiwon Choi,
  • Taeji Seo,
  • Hyun Sung Kim,
  • Minseok Kwak,
  • Joonkyung Jang,
  • Songyi Lee and
  • Myeongkee Park

17 November 2025

Methylammonium lead iodide (MAPbI3) perovskite has been widely studied for its optoelectronic properties, but its polycrystalline thin films inevitably contain grain boundaries and defects that degrade performance and stability. PbI2 is often conside...

  • Article
  • Open Access
4 Citations
656 Views
20 Pages

16 November 2025

In this work, density functional theory (DFT)-based first-principles investigations are performed by Generalized Gradient Approximation (GGA) with the Perdew–Burke–Ernzerhof (PBE) functional in the CASTEP code. These simulations provide t...

  • Article
  • Open Access
659 Views
13 Pages

Novel 2D Porous Metal–Organic Frameworks: Synthesis, X-Ray Structure, Thermal, and Hirshfeld Surface Analyses

  • Rupam Sen,
  • Mahananda Roy,
  • Sriparna Sanyal,
  • Arpan Dolui,
  • Paula Brandão and
  • Zhi Lin

15 November 2025

In the present study, we have developed a series of compounds [M(tcm)2(bix)4]n [where M = Co (1), Ni (2), and Cu (3)] using tricyanomethanide (tcm) and 1,4-bis(imidazol-1-ylmethyl)benzene (bix) ligands. The compounds were characterized by elemental a...

  • Article
  • Open Access
1 Citations
646 Views
19 Pages

15 November 2025

In serpentinite-related green nephrite, light-colored nephrite commonly occurs as veins or interlayers at nearly every nephrite locality. However, its characteristics have been poorly understood. In this study, samples containing both green and light...

  • Article
  • Open Access
581 Views
16 Pages

15 November 2025

This paper presents a compact and high-performance 2-to-4 optical decoder based on a plasmonic well structure incorporating suspended graphene nanoribbons. By exploiting the tunable graphene’s chemical potential, the propagation and confinement...

  • Article
  • Open Access
553 Views
16 Pages

Crystal Structure and Optical Behavior of Diamino-Substituted 1,4-Benzoquinones

  • Anastasija Gaile,
  • Sergey Belyakov,
  • Svetlana Zhizhkun and
  • Nelli Batenko

15 November 2025

Reactions of benzoquinone with amines can potentially lead to the formation of coupled merocyanine or merocyanine/polymethine systems. In this study, several diamino-substituted 1,4-benzoquinones were synthesized. The crystal structures for three der...

  • Article
  • Open Access
792 Views
17 Pages

Plasmon Dispersion in Two-Dimensional Systems with Non-Coulomb Interaction

  • Levente Máthé,
  • Ilinca Lianu,
  • Adrian Calborean and
  • Ioan Grosu

15 November 2025

We theoretically study plasmon dispersion within the random-phase approximation in two-dimensional systems, including undoped and doped monolayer graphene at zero and finite temperatures, and hole- and electron-doped monolayer XSe (X=In,Ga) and disor...

  • Article
  • Open Access
1 Citations
613 Views
14 Pages

14 November 2025

The Ohon Continuous Casting is the main method for preparing single crystal copper wire, and it is also the research hotspot at present, but it is difficult to directly cast ultrafine single crystal copper wire (diameter < 0.05 mm). The copper wir...

  • Article
  • Open Access
1,123 Views
17 Pages

14 November 2025

Maw-sit-sit jade resembles kosmochlor-jadeitite in appearance and is spatially associated with it in the Myanmar Jade Belt. However, the mineral composition, microstructure, and petrogenesis of this type of jade remain unclear. To address this gap, t...

  • Article
  • Open Access
966 Views
17 Pages

14 November 2025

Sensing represents one of the most rapidly developing areas of modern life sciences, spreading from the detection of pathogenic microorganisms in living systems, food, and beverages to hazardous substances in liquid and gaseous environments. However,...

  • Article
  • Open Access
2 Citations
923 Views
18 Pages

14 November 2025

Kaolin from the Donigazza deposit (NW Sardinia, Italy) was used to investigate the mechanisms of zeolite crystallization under alkaline hydrothermal conditions. The starting material, composed mainly of kaolinite and opal-CT with minor quartz and low...

  • Article
  • Open Access
821 Views
13 Pages

14 November 2025

Although low-silicon Al-Si alloys have been extensively studied, further improvement in their mechanical performance remains a critical challenge. This study examines the synergistic effects of scandium (Sc) and zirconium (Zr) additions on the solidi...

  • Article
  • Open Access
1 Citations
936 Views
19 Pages

14 November 2025

A comprehensive numerical investigation of Fatigue Crack Growth (FCG) under negative stress ratios (R < 0) was conducted using the Finite Element Method (FEM) and the ANSYS Benchmark 19.2 SMART crack growth module on modified Compact Tension (CT)...

  • Article
  • Open Access
981 Views
21 Pages

13 November 2025

We investigate the stability of higher-order skyrmion crystals with large topological charges in the presence of crystal-dependent magnetic anisotropies. Focusing on the competition between two types of bond-dependent anisotropy allowed by D3d crysta...

  • Article
  • Open Access
635 Views
16 Pages

Resulted Mechanical and Microstructural Properties of Ballistic Protection Materials for Bulletproof Vest Applications Using Plasma Jet Thermal Spray Coatings

  • Adrian Ioan Ropotoae,
  • Corneliu Munteanu,
  • Fabian Cezar Lupu,
  • Bogdan Istrate,
  • Marcelin Benchea,
  • Adrian Nicolae Rotariu and
  • Andrei Spoiala

13 November 2025

This paper addresses ballistic protection, which is an important element in the performance of any military equipment. Improving ballistic properties is a necessity for individual protection through the use of protective vests. In this study, plasma...

  • Article
  • Open Access
586 Views
15 Pages

Spectroscopic Study of Electrolytic-Plasma Discharge During Hardening of 20GL Steel and Its Effect on Microstructure and Mechanical Properties

  • Bauyrzhan Rakhadilov,
  • Rinat Kurmangaliyev,
  • Nurlat Kadyrbolat,
  • Rinat Kussainov,
  • Zarina Satbayeva,
  • Almasbek Maulit and
  • Yerzhan Shayakhmetov

13 November 2025

This study investigated the electrolytic-plasma hardening (EPH) of cast 20GL steel, used for railway spring beams. The main objective was to analyze the spectral characteristics of the cathodic discharge and establish correlations between the plasma...

  • Article
  • Open Access
650 Views
29 Pages

Reactions of the Uranyl Ion and a Bulky Tetradentate, “Salen-Type” Schiff Base: Synthesis and Study of Two Mononuclear Complexes

  • Sotiris G. Skiadas,
  • Ioanna Th. Papageorgiou,
  • Zoi G. Lada,
  • Catherine P. Raptopoulou,
  • Vlasoula Bekiari,
  • Vassilis Psycharis,
  • Sokratis T. Tsantis and
  • Spyros P. Perlepes

12 November 2025

The reactions of UO2(NO3)2·6H2O or UO2(O2CMe)2·2H2O and 2,2′-{(1,2-ethanediyl)bis[nitrilo(phenyl)methylidene]}bisphenol (H2L) in MeOH and DMF have provided access to complexes [UO2(L)(MeOH)] (1) and [UO2(L)(DMF)]·DMF (2&mid...

  • Article
  • Open Access
606 Views
30 Pages

12 November 2025

Aluminum nitride (AlN), diamond, and β-phase gallium oxide (β-Ga2O3) belong to the family of ultra-wide bandgap (UWBG) semiconductors and exhibit remarkable properties for future power and optoelectronic applications. Compared to convention...

  • Article
  • Open Access
588 Views
23 Pages

Microstructure and Mechanical Properties of Hybrid Pure Al/B4C/Microsilica Composites Produced by Ultrasonically Assisted Stir Casting

  • Maxat Abishkenov,
  • Ilgar Tavshanov,
  • Kairosh Nogayev,
  • Zoja Gelmanova,
  • Saule Kamarova and
  • Almas Yerzhanov

12 November 2025

This study explores the fabrication and characterization of hybrid aluminum matrix composites reinforced with boron carbide (B4C) and microsilica, produced via ultrasonically assisted stir casting followed by T6 heat treatment. Pure aluminum was sele...

  • Article
  • Open Access
791 Views
22 Pages

Effect of Tungsten Content on the Microstructure, Mechanical and Tribological Properties of AlCoCrFeNi High-Entropy Alloys

  • Ersin Bahceci,
  • Ali Oktay Gul,
  • Oykum Basgoz Orhan,
  • Levent Cenk Kumruoglu and
  • Omer Guler

12 November 2025

High-entropy alloys (HEAs) have recently attracted considerable attention due to their unique combination of high strength, hardness, and corrosion and wear resistance, making them promising candidates for advanced structural and functional applicati...

  • Article
  • Open Access
470 Views
16 Pages

Tribological Behavior of SPS-Prepared Al-Matrix–ZrO2-Nanofiber Composites with Graphene Nanoplatelets Solid-Lubricating Surface Films

  • Viktor Puchý,
  • Richard Sedlák,
  • Marek Vojtko,
  • Mária Podobová,
  • Ondrej Petruš,
  • Lucia Čiripová and
  • Ladislav Falat

12 November 2025

In this study, the tribological compatibility of ZrO2-nanofiber-strengthened Al-matrix composites with graphene nanoplatelets (GNPs)-derived surface film acting as a solid lubricant was investigated. The substrate materials prepared by Spark Plasma S...

  • Article
  • Open Access
3 Citations
683 Views
11 Pages

Characterization of Cobalt-Based Composite Multilayer Laser-Cladded Coatings

  • Iasmina-Mădălina Anghel,
  • Alexandru Pascu,
  • Iosif Hulka,
  • Dino Horst Woelk,
  • Ion-Dragoș Uțu and
  • Gabriela Mărginean

11 November 2025

Laser cladding is an essential method for strengthening and restoring component surfaces. To increase its efficacy and provide a reliable surface treatment technique, it is necessary to optimize process parameters, enhance material adhesion, and guar...

  • Article
  • Open Access
521 Views
23 Pages

11 November 2025

The Mapeng pluton in the central Taihang Mountains hosts significant gold mineralization; however, the magmatic processes controlling its emplacement, crystallization, and potential role in ore genesis remain debated. Previous petrological and geoche...

  • Article
  • Open Access
1,114 Views
14 Pages

Microstructural and Magnetic Evolution of α″-Fe16N2 Bulk Magnets Consolidated by Spark Plasma Sintering

  • Marian Grigoras,
  • Mihaela Lostun,
  • Marieta Porcescu,
  • George Stoian and
  • Nicoleta Lupu

11 November 2025

The development of rare-earth-free permanent magnets represents a strategic direction in advanced magnetic materials research. Among the most promising candidates, the metastable α″-Fe16N2 phase stands out due to its exceptionally high sa...

  • Article
  • Open Access
753 Views
17 Pages

Zinc(II) Iodide Complexes with Redox-Active α-Diimine Ligands: Synthesis, Structure, Spectroscopic and Electrochemical Properties

  • Dmitriy S. Yambulatov,
  • Natalia V. Gogoleva,
  • Ivan V. Smolyaninov,
  • Vladimir A. Bushuev,
  • Anna A. Tychinina,
  • Alexandra S. Samulionis,
  • Julia K. Voronina,
  • Ivan V. Skabitsky,
  • Sergey S. Shapovalov and
  • Mikhail A. Kiskin
  • + 1 author

10 November 2025

Reactions of anhydrous Zn(II) iodides with redox-active 1,4-diaza-1,3-butadiene (DAD) and its bis(imino)acenaphtene (BIAN) derivatives in absolute acetonitrile yielded a series of new complexes: [(Mes-DAD)ZnI2] (1), [(dpp-DAD)ZnI2] (2), and [(dpp-BIA...

  • Feature Paper
  • Review
  • Open Access
1,756 Views
19 Pages

The Crystallography of Enzymes: A Retrospective and Beyond

  • Tianyi Huang,
  • Jannat Khan,
  • Sheryar Lakhani,
  • Albert Li,
  • Aditya Vyas,
  • Julia Hunt,
  • Sara Andrea Espinosa Garcia and
  • Bo Liang

8 November 2025

Crystallography plays a crucial role in understanding the functions of macromolecules by determining their three-dimensional structures at the atomic level. This review outlines the history of crystallization, explains the principles of crystallizati...

  • Article
  • Open Access
837 Views
7 Pages

MOCVD Growth of Relaxed, Crack-Free AlGaN on Tiled GaN Substrates

  • Nirupam Hatui,
  • Henry Collins,
  • Emmanuel Kayede,
  • Feng Wu,
  • Stacia Keller and
  • Umesh K. Mishra

8 November 2025

AlxGa1-xN layers with up to 53% Al composition and 1.3 µm total thicknesses were grown utilizing step-graded layers on dense arrays of 10 × 10 µm2 GaN tiles. While the layers were fully relaxed and crack-free, the higher Al composit...

  • Article
  • Open Access
2,576 Views
19 Pages

High-Magnesium Olivines (Fo 90–100): Determination of Fo Content by Raman Spectroscopy

  • Tianqi Wang,
  • Mingyue He,
  • Bijie Peng,
  • Jingxuan Wang,
  • Mei Yang and
  • Ning Wang

7 November 2025

Olivine is a dominant constituent of the Earth’s upper mantle, and its forsterite content (Fo = 100 × Mg/(Mg + Fetotal) in molar basis) holds significant implications for indicating petrogenesis. The characteristic Raman doublet near ~820...

  • Article
  • Open Access
1,026 Views
15 Pages

Low Coefficient of Thermal Expansion (CTE) Ceramic–Thermoplastic Composite for Fused Deposition Modelling of RF and Microwave Devices

  • Vishvajitsinh Kosamiya,
  • Liguan Li,
  • Ioannis N. Gkikas,
  • Juan D. Castro,
  • Julia Oppenheimer,
  • Ioannis Spanopoulos and
  • Jing Wang

7 November 2025

Additive manufacturing (AM) has significant potential for rapid prototyping of intricate 3-dimensional geometries, yet its adoption in RF and microwave applications remains limited. Key barriers include inadequate material characterization, high diel...

  • Article
  • Open Access
1 Citations
489 Views
14 Pages

7 November 2025

The soliton spectral tunneling effect in photonic crystal fibers with three zero-dispersion wavelengths is an effective way to realize pulse wavelength conversion. However, due to the limitation of the soliton splitting mechanism, forming a tunneling...

  • Article
  • Open Access
883 Views
17 Pages

7 November 2025

Tin bronze/steel bimetallic is a widely utilized industrial material in the field of sliding bearing applications. Arc cladding technology represents an emerging method for fabricating tin bronze/steel bimetallic materials; however, research on their...

  • Article
  • Open Access
517 Views
13 Pages

A Novel Energetic Nitroform Salt Derived from Bis-(Triazolyl)-Furoxan

  • Fawei Wang,
  • Jiapeng Wang,
  • Zihu Wang,
  • Jianhua Wang and
  • Yucun Liu

6 November 2025

This study presents the synthesis and comprehensive characterization of a novel nitroform salt, bis(2-methyl-3-amino-1,2,4-triazolyl)furoxan trinitromethanide (compound 2), derived from the molecular scaffold of bis-(2-methyl-3-amino-1,2,4-triazolyl)...

  • Article
  • Open Access
720 Views
23 Pages

Crystalline Nanoparticles and Their Impact on Electromagnetic Radiation Absorption in Advanced Clay Building Materials

  • Jelena Brdarić Kosanović,
  • Berislav Marković,
  • Ivana Miličević,
  • Anamarija Stanković and
  • Dalibor Tatar

6 November 2025

Given the increasing human exposure to electromagnetic radiation of various frequen-cies, mostly in the microwave range, awareness of potential health problems caused by this radiation has begun to grow. New building materials are being developed and...

  • Article
  • Open Access
1,195 Views
16 Pages

5 November 2025

In salt lake KCl cold decomposition–direct flotation for K-Na separation, octadecylamine hydrochloride (ODA-H) acts as a collector, reducing product purity and limiting high-end applications of salt lake KCl. To study KCl purification mechanism...

  • Article
  • Open Access
443 Views
13 Pages

5 November 2025

Spinodoid nanocubes, inspired by spinodal decomposition, feature bicontinuous dual-phase architectures with high interfacial area, offering a promising platform for tuning nanoscale mechanics. In the present study, classical molecular dynamics simula...

  • Article
  • Open Access
655 Views
18 Pages

Influence of Nanocrystallite Size on Magnetic Properties of Iron Nitride γ’-Fe4N

  • Kamila Klimza,
  • Grzegorz Leniec,
  • Karol Synoradzki,
  • Rafał Pelka,
  • Urszula Nowosielecka,
  • Izabela Moszyńska,
  • Aleksander Guskos,
  • Grzegorz Żołnierkiewicz and
  • Nikos Guskos

5 November 2025

In this paper, samples of nanocrystalline iron nitride γ’-Fe4N, doped with small amounts of hardly reducible promoter oxides (Al2O3, CaO, and K2O), were subjected to electron magnetic resonance (EMR) measurements. The samples differed in...

  • Article
  • Open Access
548 Views
12 Pages

Raman Spectral Analysis of Sputtered and Sulfurized Nanostructured WS2 Films

  • Magdaléna Kadlečíková,
  • Ivan Hotový,
  • Naman Kumar,
  • Ivan Kostič,
  • Michaela Sojková,
  • Vlastimil Řeháček and
  • Dagmar Gregušová

5 November 2025

This study presents the Raman spectral characteristics and selected electrical parameter measurements of WS2 films deposited by magnetron sputtering on sapphire and subsequently sulfurized. The analysis of the Raman spectra focuses on the positions a...

  • Article
  • Open Access
608 Views
15 Pages

Femtosecond Laser-Processed, Copper-Coated Stainless Steel Implants Promoting In Situ Calcium Phosphate Crystallization for Orthopedic Application

  • Albena Daskalova,
  • Maja Dutour Sikirić,
  • Liliya Angelova,
  • Tihomir Car,
  • Ana-Marija Milisav,
  • Stuart Neil and
  • Abeer Shaalan

5 November 2025

Today, the engineering of load-bearing bone tissue after severe trauma still relies on metal-based (Ti, CoCrMo alloys or stainless steel) permanent implants. Such artificial scaffolds are typically applied in the body and come into direct contact wit...

  • Article
  • Open Access
850 Views
15 Pages

Seed-Layer-Assisted Liquid-Phase Epitaxial Growth of YIG Films on Single-Crystal Yttrium Aluminum Garnet Substrates: Evidence for Enhancement in Strain-Induced Anisotropy

  • Chaitrali Kshirsagar,
  • Rao Bidthanapally,
  • Ying Liu,
  • Peng Zhou,
  • Sahana Mukund,
  • Aruna Bidthanapally,
  • Hongwei Qu,
  • Deepa Xavier,
  • Subhabrat Samantaray and
  • Gopalan Srinivasan
  • + 2 authors

4 November 2025

Epitaxial thick films of yttrium iron garnet (YIG) are ideal for use in microwave devices due to their low losses at high frequencies. This report is on the growth of strain-engineered YIG films by liquid-phase epitaxy (LPE) on yttrium aluminum garne...

of 2

XFacebookLinkedIn
Crystals - ISSN 2073-4352