With the aim to enhance interfacial adhesion of a hydrophobic polymer matrix and cellulosic fibers and fillers, chemical surface modifications with silane coupling agents are performed. Thermogravimetric analysis (TGA) could be used to determine the...
The cement industry contributes approximately 7% of global anthropogenic CO2 emissions, primarily through energy-intensive clinker production. This study evaluates the thermal behavior and gas emissions of seven waste materials (sawdust, pecan nutshe...
Fire-retardant intumescent coatings offer an effective means of enhancing the fire resistance of combustible substrates such as wood. These coatings have a complex chemical composition and, when exposed to temperatures above 200 °C, undergo an in...
Visible light-sensitive TiO2-based nanomaterials are widely investigated for photocatalytic applications under high power (≥300 W) UV and visible light. The formation of charge transfer complexes (CTCs) between bidentate ligands and nanocrystallin...
Thermogravimetric analysis (TGA) is a key technique for evaluating the kinetics and thermodynamics of thermal degradation, providing essential data for material assessment and system design. When coupled with Fourier-transform infrared (FT-IR) spectr...
A deoiled rapeseed press cake (RPC) was pyrolyzed by heating at a slow heating rate to 1000 °C in a fixed bed reactor, and the produced char was then gasified to obtain data for the kinetic modeling of the process. The gasification experiments we...
Microscopic and acoustic emission analysis and sound patterns recognition techniques were applied for the characterization of granular activated carbon (GAC). A new and improved methodology has been developed to characterize the exhaustion degree of...
The gasification behavior of pine wood sawdust was investigated in CO2 with different heating rates of 5, 10, 15, and 20 °C/min from room temperature to 1400 °C by thermogravimetric analysis (TGA) and mass spectrometry (MS). It was also examined unde...
Lignin is a complex biopolymer extracted from plant cell walls, playing a crucial role in structural integrity. As the second most abundant biopolymer after cellulose, lignin has significant industrial value in bioenergy, the chemical industry, and a...
In comparison to other methods, valorising food waste through pyrolysis appears to be the most promising because it is environmentally friendly, fast, and has a low infrastructure footprint. On the other hand, understanding the pyrolytic kinetic beha...
In the last decades, organic azides haven proven to be very useful precursors in organic chemistry, for example in 1,3-dipolar cycloaddition reactions (click-chemistry). Likewise, azides can be introduced into graphene oxide with an almost intact car...
This study presents the first comprehensive lipophilic chemical profile of Bovistella utriformis, integrated with a multimodal physicochemical characterization of its whole biomass collected from Chilean Patagonia, complementing recent studies that d...
Manufactured nanomaterials (MNMs) often have a surface-chemical modification in order to tailor their physicochemical properties, including also powder properties and miscibility. Surface-chemical modifications may influence the toxicological propert...
Microplastics, defined as particles up to 5 mm in size, present a significant environmental and health concern due to their ubiquity, capacity to accumulate in organisms, and potential to cause toxic effects, inflammation, and endocrine disruption. A...
Among the waste materials of wine production, grape seeds constitute an important fraction of the pomace, from which the precious edible oil is extracted. The residual mass from oil extraction, the defatted grape seeds (DGS), can be destined for comp...
Organo-modified layered materials characterization poses challenges due to their complexity and how other aspects such as contamination, preparation methods and degree of intercalation influence the properties of these materials. Consequently, a deep...
Acrylonitrile butadiene styrene (ABS) is a thermoplastic polymer widely used in several everyday life applications; moreover, it is also one of the most employed plastics in contemporary artworks and design objects. In this study, the chemical and th...
The recent proliferation of sensor technology applications in therapies for children’s disabilities to promote positive behavior among such children has produced optimistic results in developing a variety of skills and abilities in them. Dolphi...
In this study, we thoroughly investigated the stability of haloperidol using a comprehensive set of chromatographic and thermal analyses. Various stress conditions were examined, including exposure to oxidizing agents (such as hydrogen peroxide), dry...
The effect of different cooking processes such as frying and roasting on the oxidative stability of sunflower seeds was evaluated under accelerated oxidation and normal storage conditions. The fatty acid composition by GC-MS showed a higher amount of...
Background: Bioenergy attracts much attention due to the global demand for renewable and sustainable energy resources. Waste biomass feedstocks—date pits, coffee waste, and cow dung—require efficient and environmentally friendly waste-man...
Tire wear particles (TWPs), as a type of thermosetting microplastic (MP), accumulate in aquatic environments due to their wide application in road traffic globally. The increase in temperature because of friction heat may cause aging of tire material...
Graphite anodes are specified by bulk structural and textural parameters, but these converge after graphitization and say little about the surface at which the first cycle is determined. This work aimed to determine whether thermogravimetry coupled w...
With the rapid development of generative artificial intelligence (AI) technologies, large language models have been developed and used in education. In this study, we employ the Google Gemini AI tool (version 1.0) to annotate teachers’ programm...
The continuous depletion of natural resources coupled with plastics pollution, has prompted the scientific community to explore alternative biobased and/or biodegradable polymers. Poly(ethylene succinate) (PESu) is a promising substitute due to its h...
Carboxylate-functionalised polymers of intrinsic microporosity (C-PIMs) are highly desirable materials for membrane separation applications. The recently reported method to afford C-PIMs was via an extensive base hydrolysis process requiring 360 h. H...
Biochar can potentially increase soil fertility and sequester carbon by incorporating nutrients and stable black carbon into the soil; however its effect on soil nitrogen (N) and carbon (C) processes is not well understood. A defined methodology to c...
This study investigates how O2 concentration affects the combustion performance and kinetic response of Changji and Fushun oil shales under CO2-based oxy-fuel atmospheres. Coupled TGA–DSC–MS analysis was performed to characterize thermal...
The exponential growth of waste plastic accumulation has had an irreversible and lasting impact on the world. An imminent threat to marine and terrestrial ecosystems of massive proportions, plastic waste accumulation is a global problem that will not...
Two catalysts are prepared by tethering ionic liquid cation components (1-(propyl-3-sulfonate)-3-(3-trimethoxysilylpropyl) imidazolium) with either chloride or sulphate anions, to the surface of a mesoporous SiO2 material through a condensation react...
The reactivity of a heterogeneous rhodium(III) and ruthenium(II) complex-functionalized TiO2 nanoparticle (NP) system is reported. The ruthenium and rhodium metal complexes work in tandem on the TiO2 NPs surface to generate H2 through water reduction...
In this work, the influence of degassing temperature and urea functionalization were investigated as ways to improve the CO2 adsorption performance of CPO-27-Mg. Through post-synthesis modification treatments, four samples with different degrees of u...
Poly(p-phenylene benzobisoxazole) (PBO) fiber shows fascinating properties including excellent mechanical performance, high crystallinity, and fairly good heat resistance as a kind of polymer fiber. Its properties make it a possible candidate as a pr...
The synthesis of diazonium tetrachloroaurate(III) complexes [R-4-C6H4N≡N]AuCl4 involves protonation of anilines CN-4-C6H4NH2, C8F17-4-C6H4NH2, and C6H13-4-C6H4NH2 with tetrachloroauric acid H[AuCl4] 3H2O in acetonitrile followed by one-electron oxid...
SrTiO3 and BaTiO3 nanoparticles (NPs) were activated using H2O2 or aqueous HNO3, and pristine and activated NPs were functionalized with a 2,2′-bipyridine phosphonic acid anchoring ligand (1), followed by reaction with RuCl3.3H2O and bpy, RhCl3...
In this study, two nitrogen-doping strategies for magnesium oxide—an in situ method and a post-synthesis modification—were developed, and their visible-light photocatalytic activity was evaluated using methylene blue (MB) as a model organ...
Radioactive I2 (iodine) produced as a by-product of nuclear fission poses a risk to public health if released into the environment, and it is thus vital to develop materials that can capture I2 vapour. Materials designed for the capture and storage o...
Co3O4 particles were supported on a series of activated carbons (G60, CNR, RX3, and RB3). Incipient wetness method was used to prepare these catalysts. The effect of the structural and surface properties of the carbonaceous supports during oxidation...
In this work, the hybrids based on nanocrystalline SnO2 or In2O3 semiconductor matrixes and heterocyclic Ru(II) complex are studied as materials for gas sensors operating at room temperature under photoactivation with visible light. Nanocrystalline s...
Mixed metal oxides are promising heterogeneous catalysts for biofuel production from lipids via alcoholysis, however, the impact of solid acidity and/or basicity on reactivity is comparatively poorly understood. Two systematically related families of...
Hydrotalcites (HTCs) are promising solid base catalysts to produce advanced biofuels by aldol condensation. Their main potential lies in the tunability of their acid-base properties by varying their composition. However, the relationship between the...
New insight was gained into the acidity-reactivity relationships of sulfated zirconia (SZ) catalysts prepared via (NH4)2SO4 impregnation of Zr(OH)4 for propanoic acid esterification with methanol. A family of systematically related SZs was characteri...
The torrefaction process represents a thermal conversion technique conducted at relatively low temperatures ranging between 200 to 300 °C. Its objective is to produce fuel with a higher energy density by decomposing the reactive portion of hemice...
With the continuous promotion of electric vehicles, the pressure to scrap vehicle batteries is increasing, especially in China, where nickel cobalt manganese lithium (NCM) batteries have gradually come to occupy a dominant position in the battery mar...
Plastics usage is rising daily because of increased population, modernization, and industrialization, which produces a lot of plastic garbage. Due to their various chemical structures, long chain polymeric compositions, and thermal/decomposition beha...
In order to maximally reduce the toxicity of fullerenol (the first derivative of C60, FD-C60), and increase its biomedical efficiency, the second derivative SD-C60 (3HFWC, Hyper-Harmonized Hydroxylated Fullerene Water Complex) was created. Several di...
Bioenergy production from hydrochar via catalytic thermal conversion is of increasing importance to easing the energy shortage. The catalytic pyrolysis characteristics of hydrochar derived from sawdust (HSD) with calcined eggshell (CES) were investig...
Recently, catalysts with hydrotalcites and hydrotalcite-derived compounds have attracted particular interest due to their specific properties, mostly well-developed texture, high thermal stability, and favorable acid–base properties. In this wo...
Nitric oxide (NO) is one of the main environmental pollutants and one of the biomarkers noninvasive diagnosis of respiratory diseases. Organic-inorganic hybrids based on heterocyclic Ru (II) complex and nanocrystalline semiconductor oxides SnO2 and I...
The effect of different nitrogen-doped carbon additives (carbon coating from polyaniline, N-doped carbon nanotubes, and N-doped carbon nanoparticles) on electrochemical performance of nanocomposites based on the olivine-type LiFePO4 was investigated....
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