Special Issue "Earth-Abundant Metal Chemistry and Catalysis"
Deadline for manuscript submissions: 30 April 2022.
Interests: design of new catalysts with terpyridine ligands; earth-abundant metal catalysis; organometallic chemistry and small molecule activation; coordination polymers for catalytic applications; metallic anticancer drug design and synthesis
As the new MDPI flagship journal Chemistry (ISSN 2624-8549) is formally launched, we are excited to open this Special issue with a theme of Earth-Abundant Metal Chemistry and Catalysis. Currently, there is an explosively increasing amount of interest in sustainable chemistry and molecular catalysis with earth-abundant metals within the synthesis and catalysis communities. A themed issue on this topic is necessary and anticipated to attract significant contributions.
It is currently of urgency to replace noble metal catalysts with earth-abundant, inexpensive alternatives in many aspects, including valuable organic transformations, small molecule activation, and energy conversion. Rational design of molecular catalysts is the key to enabling the reactivity and hence catalytic activity. In this issue, we welcome submissions of work related to the synthesis, structure, and reactivity of molecular complexes involving earth-abundant metals as well as their catalytic applications in both traditional and new organic reactions, small molecule (CO2, CO, N2, etc.) activation, and biomass conversion. Experimental and theoretical studies leading to mechanistic understanding are particularly encouraged. In addition, submissions from a broader area of catalysis such as electrocatalysis, photocatalysis, and nanocatalysis that involve the use of earth-abundant metals are also welcomed.
Dr. Guoqi Zhang
Manuscript Submission Information
Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All papers will be peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.
Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Chemistry is an international peer-reviewed open access quarterly journal published by MDPI.
Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 1200 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.
- Catalyst design
- Well-defined molecular catalysts
- Earth-abundant metal catalysis
- Sustainable chemistry
- Green catalysis
- Biomass conversion
- Small molecule activation
The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.
Title: One-pot synthesis of Na3Fe(CN)5(CO)∙3H2O and its zero-order reaction kinetics
Authors: Jianfeng Jiang
Affiliation: Department of Chemistry, Yeshiva University, New York, NY 10033, USA
Abstract: The reaction between carbon monoxide (CO) and sodium nitroprusside (Na2Fe(CN)5(NO)∙2H2O) in basic solution leads to the quantitative formation of Na3Fe(CN)5(CO). An improved preparation of Na3Fe(CN)5(CO)·3H2O with shorter reaction time, higher yield and better purity based on the above reaction was developed. This substitution reaction at various temperatures was studied by quantitative infrared measurement. The formation of [Fe(CN)5(CO)]3- in solution follows zero-order kinetics. [Fe(CN)5(NO2)]4- was generated upon the mixing of [Fe(CN)5(NO)]2- with hydroxide and nitrite (NO2-) was subsequently substituted by CO. The zero order kinetics is due to the saturation of dissolved CO in basic solution.