Recycling

The expected rapid growth in electric vehicle deployment will inevitably be followed by a corresponding rise in the supply of end-of-life vehicles and their lithium-ion batteries (LIBs). The batteries may be reused, but will eventually be spent and provide a potential domestic resource that can help supply materials for future battery production. However, commercial recycling processes depend on profits from recovery of cobalt, use of which is being reduced in new cathode chemistries. The U.S. Department of Energy, therefore, established the ReCell Center in early 2019 to develop robust LIB recycling technology that would be economical even for batteries that contain no cobalt. The central feature of the technology is recovery of the cathode material with its unique crystalline cathode morphology intact in order to retain its value and functionality. Other materials are recovered as well in order to maximize revenues and minimize waste-handling costs. Analysis and modeling serve to evaluate and compare process options so that we can identify those that will be most economical while still minimizing energy use and environmental impacts. This paper provides background and describes highlights of the center’s first 2 years of operation. Full article

Mobile phone consumers have been motivated by the rapid growth of technology and encouraged to update their devices regularly to keep up with new innovations, architectures, and capabilities. Consequently, mobile/cell phone waste has risen significantly in the last decade. Due to their small size, it is convenient for users to keep outdated or unused mobile phones at home or the office, rather than recycling them appropriately. A reverse supply chain (RSC) is one possible method of mitigating the questionable e-waste activity present in the ecosystem. RSC has been significant for the mobile phone industry, user states, analysts, and scholars. This paper reviews the available literature in the RSC management (RSCM) domain, along with its processes and strategies. The paper reviews 223 published scholarly papers in the domain of mobile phone waste recycling and investigates 22 papers related to factors influencing consumers’ intention with regard to electronic recycling, focusing on mobile devices, which contribute significantly to electronic waste management practices. Full article

The recycling target for plastics is expected to increase Europe-wide from 22.5% to 55% by 2025, hence the relevance of incentive schemes and the need to reach conclusions about how to encourage families to recycle more. Following this objective, a pilot project was implemented and a virtual reward token called RECICLOS created to encourage recycling among families, using incentives and awards to improve recycling behaviour and a webapp prototype to register the recycled plastic. By the end of the 6-week pilot project, 1053 families were registered on the scheme, representing 10% of the targeted population in the pilot area of the county of Pla de l’Estany, Catalonia, Spain. The novelties were the introduction of a token, the gamification of incentives through raffles and lotteries, webapp-based direct communication with citizens, and feedback after collecting and registering the recycled material. The multidimensional aspects of recycling activities, their strong relation with human behavioural patterns, and the high demand for communication and interaction mean that mobile technologies find significant application in this field. The results show that people can be influenced and their recycling habits changed by means of varied, effective, and innovative incentive schemes. Full article

The use of residual biomass of forest and/or agricultural origin is an increasingly common issue regarding the incorporation of materials that, until recently, were out of the typical raw material supply chains for the production of biomass pellets, mainly due to the quality constraints that some of these materials present. The need to control the quality of biomass-derived fuels led to the development of standards, such as ENplus^®, to define the permitted limits for a set of parameters, such as the ash or alkali metal content. In the present study, samples of vine pruning, and ENplus^®-certified pellets were collected and characterized, and the results obtained were compared with the limits presented in the standard. The values presented from vine pruning approximated the values presented by Pinus pinaster wood, the main raw material used in the production of certified pellets in Portugal, except for the values of ash, copper (Cu), and nitrogen (N) contents, with vine pruning being out of the qualifying limits for certification. However, it was found that the incorporation of up to 10% of biomass from vine pruning allowed the fulfillment of the requirements presented in the ENplus^® standard, indicating a path for the implementation of circular economy processes in the wine industry. Full article

Considering economics and environmental sustainability, recycling of critical metals from end-of-life devices should be a priority. In this work the hydrometallurgical treatment of a spent automotive catalytic converter (SACC) using HCl with CaCl₂ as a leaching medium, and solvent extraction (SX) with a thiodiglycolamide derivative, is reported. The aim was to develop a leaching scheme allowing high Pt recoveries and minimizing Al dissolution, facilitating the application of SX. The replacement of part of HCl by CaCl₂ in the leaching step is viable, without compromising Pt recovery (in the range 75–85%), as found for the mixture 2 M CaCl₂ + 8 M HCl when compared to 11.6 M HCl. All leaching media showed good potential to recover Ce, particularly for higher reaction times and temperatures. Regarding SX, results achieved with a model solution were promising, but SX for Pt separation from the real SACC solution did not work as expected. For the adopted experimental conditions, the tested thiodiglycolamide derivative in toluene revealed a very good loading performance for both Pt and Fe, but Fe removal and Pt stripping from the organic phases after contact with the SACC solution were not successfully accomplished. Hence, the reutilization of the organic solvent needs improvement. Full article

Laminated glass is ever more frequently used nowadays. This applies to the automobile industry and the construction industry. In cars, this refers mostly to the front and rear windows, whereas in construction, technical safety glass is used for railings and window glass. The task of this type of glass is to provide sufficient resistance against mechanical impact and unpleasant weather conditions. At the same time, if it is damaged, it has to break into the smallest possible pieces, or, wherever possible, the glass should remain intact on the interlayer film to prevent shards from injuring people and animals in the immediate vicinity. The paper deals with the recycling of laminated glass, especially with the effective separation of glass (in the form of cullet) from the polyvinyl butyral (PVB) interlayer film. The experimental research is focused on the mechanical separation of glass from the interlayer film by vibration, and also on the chemical cleaning of PVB film in order to allow subsequent recycling of both materials. The results quantify the efficiency of mechanical separation in the form of weight loss of the sample of laminated glass and define the particle size distribution of glass cullet, which is an important parameter in the possibility of glass recycling. The research leads to a methodology proposal for the separation of glass and PVB film and the design of equipment for this method. Full article

(1) Phosphorus (P) is an essential plant nutrient, and P deficiency negatively affects plant growth and development. Furthermore, P is a finite and nonrenewable resource, and there is an urgent need to recover P from some of the important waste streams in society. Newly engineered calcareous materials (sol–gel coated cat litter (CATSAN^®)) can bind P from wastewater in decentralized treatment systems and potentially enable P recycling into agricultural production by direct addition of the P saturated material. (2) The effects of the addition of two P-enriched calcareous materials as fertilizers for maize (Zea mays L.) growth were investigated in a mesocosm experiment. We compared fertilization with the P-enriched materials at rates of 6, 12, 25, 50, 100 kg P ha⁻¹ yr⁻¹ with fertilization with commercial NPK fertilizer. (3) The P fertilization by the P-enriched materials had a significant positive effect on plant height, biomass, maximum light-saturated photosynthetic rate, respiration rate, and total P content in biomass. However, plants fertilized by the commercial NPK fertilizer performed significantly better in the majority of measured parameters at identical fertilization rates. (4) The bioavailability of the P bound to the calcareous material was very low. However, the studied material has the potential to be used as part of a decentralized treatment solution to remove and subsequently recover and recycle P from wastewater. Full article

While the total amount of municipal solid waste (MSW) in Dammam city was about 13 million tons in 2013, it is expected to reach about 18.4 million tons in 2025. Although the main problem in Dammam city is an increase in solid waste production without any formal treatment except landfilling, the lack of waste segregation greatly affects the residents’ handling practices of solid waste due to incorrect disposing practices. The objective of this study explored the possibility of Dammam residents’ participation in sorting and recycling to improve MSW handling and to measure the influence of psychological factors which affecting residents’ willingness to participate in waste handling regarding socioeconomic levels and moderating effects. This study also examined various respondents’ perspectives on sorting and recycling sustainable waste and the handling of waste generation. This study covered most Dammam communities, with a gender distribution of 56% males and 44% females and the monthly income ranging from SR700 to SR12,000. The descriptive analysis showed that of the 450 participants, 170 (37.8%) were in the middle-income levels, 199 (44.2%) were in the high-income levels and 81 (18%) were in the low-income levels. The moderating effect of income was observed between attitude and willingness to sort and recycle waste in the low-income levels and high-income levels groups. Additionally, an association was found between market incentives and willingness to sort and recycle waste in the low-income levels and high-income levels groups. The gender status of the participants had a moderating effect on the relationship between market incentives and willingness to sort and recycle waste in males and females. Additionally, the moderating effect of social influence on households’ willingness to sort and recycle waste was moderated by gender in males and females. Full article

Recycled concrete aggregate (RCA) collected from the demolition of old reinforced concrete structures can be reused to prepare structural and non-structural concrete, thereby protecting the environment by preserving natural resources. This study explores RCA’s use, collected from the crushed concrete of different building projects in Riyadh, to manufacture fresh self-compacting concrete (SCC) and investigate its properties in the fresh and hardened state. Four SCC mixes were prepared by replacing natural aggregate (NA) with RCA at 0%, 25%, 50%, and 75% replacement levels. The water-cement (w/c) ratio was maintained constant at 0.38 for all the mixes. Slump Flow, J-ring, and V-funnel tests were performed on the SCC mixes in the fresh state, and the compressive strength of hardened concrete was determined after seven, 14, and 28 days. Water absorption and split tensile tests were also carried out for all the mixes. The findings revealed that it is possible to reach compressive strengths higher than 40 MPa at 28 days for RCA replacement level of 75% by using a superplasticizer and low w/c ratio. The decrease in compressive strength concerning the SCC-NA mix was 25% for 75% replacement level. The highest split tensile strength at 28 days was around 3.3 MPa for a 50% replacement level. The lowest water absorption was 3.2% for SCC-NA, which was gradually increased and was highest at 5.6% for 75% replacement level. Full article

The volume of discarded solid wastes, especially plastic, which accumulates in large quantities in different environments, has substantially increased. Population growth and the consumption pattern of societies associated with unsustainable production routes have caused the pollution level to increase. Therefore, the development of materials that help mitigate the impacts of plastics is fundamental. However, bioplastics can result in a misunderstanding about their properties and environmental impacts, as well as incorrect management of their final disposition, from misidentifications and classifications. This chapter addresses the aspects and factors surrounding the biodegradation of bioplastics from natural (plant biomass (starch, lignin, cellulose, hemicellulose, and starch) and bacterial polyester polymers. Therefore, the biodegradation of bioplastics is a factor that must be studied, because due to the increase in the production of different bioplastics, they may present differences in the decomposition rates. Full article

The use of biomass as an energy source presents itself as a viable alternative, especially at a time when the mitigation of climate change requires that all possibilities of replacing fossil fuels be used and implemented. The use of residual biomass also appears as a way to include in the renewable energy production system products that came out of it, while allowing the resolution of environmental problems, such as large volumes available, which are not used, but also by the elimination of fuel load that only contributes to the increased risk of rural fires occurrence. Invasive species contribute to a significant part of this fuel load, and its control and eradication require strong investments, so the valorization of these materials can allow the sustainability of the control and eradication processes. However, the chemical composition of some of these species, namely Acacia dealbata, Acacia melanoxylon, Eucalyptus globulus, Robinia pseudoacacia and Hakea sericea, presents some problems, mainly due to the nitrogen, chlorine and ash contents found, which preclude exclusive use for the production of certified wood pellets. In the case of Eucalyptus globulus, the values obtained in the characterization allow the use in mixtures with Pinus pinaster, but for the other species, this mixture is not possible. From a perspective of local valorization, the use of materials for domestic applications remains a possibility, creating a circular economy process that guarantees the sustainability of operations to control and eradicate invasive species. Full article

Aseptic beverage cartons are multilayer polymer-coated paperboards with a layer of aluminum foil. Due to their multilayer structure it is commonly assumed that they cannot be recycled. This is not the case and this review details the multifarious processes that are used to recycle aseptic beverage cartons. Hydrapulping to recover the paper fibers that constitute 75% of the carton is the most widespread process, followed by the manufacture of construction materials such as boards and tiles which utilize the complete carton. A range of mechanical, chemical and thermal processes are used to separate the PolyAl (polyethylene and aluminum) residual that remains after the paper fibers have been recovered. The simplest process involves agglutination followed by extrusion to obtain pellets that can then be used in industrial and consumer products or combined with other materials such as lignocellulosic wastes. Chemical approaches involve the solubilization of polyethylene and the removal of aluminum. Various thermal processes have also been investigated and a novel microwave-induced pyrolysis process appears the most commercially viable. It is concluded that the focus in future years is likely to be on recycling cartons into construction materials where there is a theoretical yield of 100% compared with 75% for hydrapulping. Full article

The substitution of mineral aggregates with crumb rubber (CR) from waste end-of-life tires (ELTs) in the asphalt concretes, has been considered a sustainable paving industry approach. The rubber has been used to construct pavements with proven enhanced resilience and improved durability. However, some issues related to the rubber’s surface adhesion or swelling may arise with these practices and generate complications (binder consumption, temperatures, mixing times). One possible solution to overcome the materials’ compatibility problems is to pre-treat the CR’s surface before its incorporation into the asphalt mixes to allow a surface functionalization that can enhance coverage and cohesion inside the mixes. The physical treatments using radiations-based beam are already exploited in the plastic recycling industries avoiding the use of chemicals in considerable amounts. Such treatments permit the recovering of large quantities of polymer-based materials and the enhancement of interfacial properties. This article provides an overview of existing surface treatments of polymers and especially rubber, including gamma ray, UV-ozone, microwaves, and plasma. Several studies have shown an overall improvement of the rubber surface’s reactive properties due to contaminant removal or roughness enhancement attributed to cross-linking or scission reactions occurring on the rubber’s surface layer. With those properties, the asphalt mixes’ phase stability properties are increased when the pre-treated rubber is incorporated. The treatments would permit to increase the CR quantities, yet reduce the layer stiffness, and improve the durability and the sustainability of future advanced road pavements. Full article

This study examined HDPE (high-density polyethylene) plastic waste as an added material for concrete mixtures. The selection of HDPE was based on its increased strength, hardness, and resistance to high temperatures compared with other plastics. It focused on how HDPE plastic can be used as an additive in concrete to increase its tensile strength and compressive strength. 156 specimens were used to identify the effect of adding different percentages and sizes of HDPE lamellar particles to lower, medium, and higher strength concrete for non-structural applications. HDPE 0.5 mm thick lamellar particles with sizes of 10 × 10 mm, 5 × 20 mm, and 2.5 × 40 mm were added at 2.5%, 5%, 10%, and 20% by weight of cement. The results showed that the medium concrete class (with compressive strength equal to 10 MPa) had the best response to the addition of HDPE. The 5% HDPE addition represented the optimal mix for all concrete types, while the 5 × 20 mm size was best. Full article

The need to satisfy the increasing demand for building materials and the challenge of reusing plastic to help improve the critical environmental crisis has led to the recycling of plastic waste, which is further exploited and transformed into new and creative materials for the construction industry. This study looked into the use of low-density recycled polyethylene (LDPE) to produce non-conventional plastic sand cobbles. LDPE waste was melted in order to obtain enough fluid consistency which was then mixed with sand in a 25/75 plastic-sand ratio respectively, such a mixture helped producing cobbles of 10 cm × 20 cm × 4 cm. Water absorption, weight, and density measurements were performed on both commercial and non-conventional plastic sand cobbles. Moreover, compression, bending, and wear resistance were also conducted as part of their mechanical characterization. Plastic sand cobbles showed lower water absorption and density values than commercial cobbles. The mechanical properties evaluated showed that plastic sand cobbles have a higher modulus of rupture and wear resistance than commercial cobbles. In addition, plastic sand cobbles meet the Colombian Technical Standard in lightweight traffic for pedestrians and vehicle, officially known as Norma Técnica Colombiana (NTC), with 25.5 MPa, 16.3 MPa, and 12 mm compression resistance, modulus of rupture and footprint length in wear resistance respectively. Finally, a market study was conducted to establish a factory to produce this type of cobbles in Ibague, Colombia. Not only the study showed positive financial indicators, which means that it is feasible running a factory to manufacture plastic sand cobbles in the city of Ibague, but it also concluded that nonconventional plastic sand cobbles could be explored to provide a comprehensive alternative to LDPE waste. Full article

The recovery rate of construction materials is only 5% in China, which will lead to environmental and economic problems. Researchers from other countries have recognized the potential of building information modelling (BIM) in optimizing construction material recycling. However, previous research did not take the whole life cycle into consideration and was not practical enough. In this research, a questionnaire was conducted to find out how construction waste is disposed of in construction projects. Then, the existing research results were analyzed to find out how to apply BIM in the whole-life-cycle disposal of construction materials. According to the results of the questionnaire, landfill is the most common way to dispose of construction materials in China; besides this, almost no construction projects use BIM in material recycling. Hence, a BIM-based dynamic recycling model is proposed. Information management of materials, demolition planning, and BIM were all combined in this model for the purpose of optimizing the application of BIM, thus developing a waste material disposal system to achieve higher recovery rates and sustainability. More positive measures should be taken to deal with the problem of construction waste; if not, more environmental and economic problems will follow. Full article

The estimated production of world electronic waste until 2017 is approximately 6 Gt. Despite this enormous problem, there are no clear regulations regarding the orientation for disposal or treatment of this type of residuals in many countries. There is a federal public policy in Brazil that supports a network of Computer Reconditioning Centers—CRCs. These CRCs train young people and recover or recycle electronic equipment. Through this work, CRCs produce interlocking plastic pavers for application on pavements from recycled electronic industry waste. This article presents the characterization of these interlocking paver’s mechanical properties when applied on the pavement. This characterization is a necessary step to show the effectiveness of this product. We show that the plastic pavers behave similarly to the artifacts manufactured in concrete, thus creating commercial opportunities for this initiative, and contributing to the Brazilian Solid Waste Policy. Full article

Next-generation vehicles (NGVs), which mainly refers to hybrid vehicles (HVs), plug-in hybrid vehicles (PHVs), electric vehicles (EVs), fuel-cell vehicles (FCVs), and clean diesel vehicles (CDVs), are becoming more and more popular as the potential answer to decreasing fossil fuel consumption and CO₂ emission from traffic sectors. Although the research on NGVs started in the 1990s, a systematic observation or summarization of the research on NGVs has not been performed yet. Thus, the current status, characteristics, latest trends, and issues of the research on NGVs have not been clarified yet. This research analyzed the research on NGVs recorded in the Web of Science published between 1990 to 2020 using CiteSpace, from a macro perspective. The results show that HVs and EVs are the crucial research objects in comparison with FCVs and CDVs. The research on NGVs was mainly performed by countries that own large vehicle makers or markets. However, it is noticeable that many developing countries have also started to study NGVs, which proves that NGVs have become popular globally. On the other hand, the research topics and categories of NGV study have always had a strong bias in favor of their function and technology development. Since NGVs have been sold for years in many countries already, there will be a considerable number of waste NGVs generated in the future, and so, future research should focus on recycling policies and/or recycling technology for NGVs to guarantee their sustainable development. Full article

Each year, more than 5 million Waste Mobile Phones (WMP) is generated in Japan. Since WMPs contain many rare metals and precious metals, it is essential to collect and recycle high-value metal resources from them effectively. Although multiple stakeholders have already developed WMP collection routes, these WMP collection routes’ current status is unclear. Furthermore, some WMP collection routes can only collect a small number of WMP, and so, their resource efficiency is low. This research aims to clarify each WMP collection route’s characteristics and evaluate their resource efficiency by conducting interview research on related stakeholders and the WMP dismantle experiment. The result shows that local government, authorized recyclers, and telecom carriers are the major stakeholders in collecting WMPs in Japan. To improve the WMP collection rate in cities with high population densities, using the local government’s collection route and installing an authorized recycler’s collection station is considered to be more effective. In cities with low population densities, the collection stations built by authorized recyclers are sufficient. The collection stations can also improve recycling behavior by offering points. Furthermore, the telecom carriers are encouraged to participate in the WMP collection business, but they should figure out a way to monitor the flow route of secondhand phones they exported and prompt the proper recycling of exported phones. Full article