Journal of Composites Science

In order to evaluate the capability of carbon nanotube yarn (CNTY)-based composites for self-sensing of temperature, the temperature-dependent electrical resistance of CNTY monofilament composites was investigated using two epoxy resins: one that cures at 130 $°$C (CNTY/ERHT) and one that cures at room temperature (CNTY/ERRT). The effect of the curing kinetics of these epoxy resins on the electrical response of the embedded CNTY was investigated in prior studies. It was observed that the viscosity and curing kinetics affect the level of wetting and resin infiltration, which govern the electrical response of the embedded CNTY. In this work, the cyclic thermoresistive characterization of CNTY monofilament composites was conducted under heating–cooling, incremental heating–cooling, and incremental dwell cycles in order to study the effect of the curing temperature of the epoxy matrix on the electrical response of the CNTY monofilament composites. Both monofilament composites showed nearly linear and negative temperature coefficients of resistance (TCR) of −7.07 × 10⁻⁴ °C⁻¹ for specimens cured at a high temperature and −5.93 × 10⁻⁴ °C⁻¹ for specimens cured at room temperature. The hysteresis loops upon heating–cooling cycles were slightly smaller for high-temperature cured specimens in comparison to those cured at room temperature. A combination of factors, such as resin infiltration, curing mechanisms, intrinsic thermoresistivity of CNTY, variations in tunneling and contact resistance between the nanotubes and CNT bundles, and the polymer structure, are paramount factors in the thermoresistive sensitivity of the CNTY monofilament composites. Full article

Gellan gum is one of the water-soluble anionic polysaccharides produced by the bacteria Sphingomonas elodea. In this study, we prepared gellan gum-inorganic composite films by mixing the gellan gum and a silane coupling reagent—3-glycidoxypropyltrimethoxysilane (GPTMS). These gellan gum-GPTMS composite films were stable in an aqueous solution and showed a thermal stability. In addition, these composite films indicated a mechanical strength by the formation of the three-dimensional network of siloxane. We demonstrated the accumulation of metal ions from a metal ion-containing aqueous solution by the composite film. As a result, although the composite film indicated the accumulation of heavy and rare-earth metal ions, the light metal ions, such as Mg(II) and Al(III) ions, did not interact with the composite material. Therefore, the accumulative mechanism of metal ions using a composite film was evaluated by IR measurements. As a consequence, although the accumulation of heavy and rare-earth metal ions occurred at both the −COO⁻ group and the −OH group in the gellan gum, the accumulation of light metal ions occurred only at the −OH group. Full article

Thermoplastic materials such as PA12 and PA6 have been extensively employed in Selective Laser Sintering (SLS) 3D printing applications due to their printability, processability, and crystalline structure. However, thermoplastic-based materials lack polymer inter-chain bonding, resulting in inferior mechanical and thermal properties and relatively low fatigue behavior. Therefore, 3D printing of high-performance crosslinked thermosets using SLS technology is paramount to pursue as an alternative to thermoplastics. In this work, a thermoset resin was successfully 3D printed using SLS, and its thermal stability of printed parts after a multi-step post-curing process was investigated. Dimensionally stable and high glass transition temperature (T_g: ~300 °C) thermoset parts were fabricated using SLS. The polymer crosslinking mechanism during the printing and curing process was investigated through FTIR spectra, while the mechanical stability of the SLS 3D-printed thermoset was characterized through compression tests. It is found that 100% crosslinked thermoset can be 3D printed with 900% higher compressive strength than printed green parts. Full article

Poly(ethyl methacrylate) (PEMA) is dissolved in ethanol, known to be a non-solvent for PEMA, due to the solubilizing ability of an added bile acid biosurfactant, lithocholic acid (LA). The ability to avoid traditional toxic and carcinogenic solvents is important for the fabrication of composites for biomedical applications. The formation of concentrated solutions of high molecular weight PEMA is a key factor for the film deposition using the dip coating method. PEMA films provide corrosion protection for stainless steel. Composite films are prepared, containing bioceramics, such as hydroxyapatite and silica, for biomedical applications. LA facilitates dispersion of hydroxyapatite and silica in suspensions for film deposition. Ibuprofen and tetracycline are used as model drugs for the fabrication of composite films. PEMA-nanocellulose films are successfully prepared using the dip coating method. The microstructure and composition of the films are investigated. The conceptually new approach developed in this investigation represents a versatile strategy for the fabrication of composites for biomedical and other applications, using natural biosurfactants as solubilizing and dispersing agents. Full article

The corrosion of metallic devices and degradation of plastic materials are a cause of great concern for companies and countries’ economies; it is necessary to contrast these phenomena by studying innovative methodologies and techniques. A simple solution lies in the realization of materials that can resist corrosive environments and be used as coatings to prevent, or at least delay, deterioration. The purpose of this work was to study the behavior of an epoxy resin, in thin film form, exposed to corrosive chemicals. In particular, the samples were subjected to aging of 31 days in dilute sulfuric acid (H₂SO₄) and in an aqueous solution of potassium chloride (KCl). Subsequently, thin films of Epoxy/graphene nanoplatelets (GNP) composite material have been subjected to the same conditions: it was investigated how these samples respond to the corrosive environment. We found that the addition of carbonaceous nanofillers prolongs in time the ability of the material to resist the attack of chemical agents. Full article

The effect of fibre length distribution on the fatigue behaviour of an injection-moulded PA66 carbon fibre composite is investigated. Two materials, short carbon fibre with a mean length of 100 microns, and long carbon fibre with a mean length of 580 microns, are subjected to fully reversed fatigue loading at room temperature and three stress ratios at 120 °C. The fatigue results are compared, and fracture surfaces are analyzed to determine the differing failure modes between the materials and loading conditions. At 120 °C, the fibre length has a significant effect on the fatigue behaviour with order of magnitudes of different fatigue life for a given stress amplitude during tensile fatigue loading. Under tensile loading, fatigue failure initates as fibre matrix debonding with pits present due to end effects in the short carbon fibre material. Under compression–compression loading, the fatigue life is matrix-dominated and should be treated as a maximum stress failure. Under this loading, a smooth crack propagates across the sample with buckling as the final failure mode. Full article

It is always challenging to provide appropriate material properties for a composite progressive failure model. The nonstandard percentage reduction method that is commonly used to degrade the material constants with micro-scale defects generates tremendous uncertainty in failure prediction. The constitutive matrix is composed of multiple material constants. It is not necessary that all constants degrade either equally or linearly due to a certain state of material defects. With this very concern in mind, this article presents a guideline for using a quantified perturbation for each coefficient appropriately. It also presents distribution of effective material properties (EMPs) in unidirectional composite materials with different states of defects such as voids. Irrespective of resin transfer molding (RTM) or chemical vapor infiltration (CVI) processes, manufacturers’ defects such as voids of different shapes and sizes are the most common that occur in composite materials. Hence, it is important to quantify the ‘effects of defects’ void content herein on each material coefficient and EMP. In this article, stochastically distributed void parameters such as the void content by percent, size, shape, and location are considered. Void diameters and shapes were extracted from scanning acoustic microscope (SAM) images of 300,000 cycles of a fatigued composite. The EMPs were calculated by considering unit cells, homogenization techniques, and micromechanical concepts. The periodic boundary conditions were applied to unit cells to calculate the EMPs. The result showed that EMPs were degraded even when there was a small percentage of the void content. More importantly, the constitutive coefficients did not degrade equally but had a definitive pattern. Full article

A novel approach of a gas pressure infiltration technique is presented for the synthesis of Co-Continuous Ceramic Composite (C4). SiC foams of varying pore sizes were infiltrated with aluminium AA5083. Optical examination revealed that the SiC foams contained open cells with a network of triangular voids. The number of pores-per-inch (PPI) in the foams was found to depend on the strut thickness and pore diameter. The compressive strengths of two foam configurations, 10 and 20 PPI, were estimated to lie between 1–2 MPa. After infiltration, the compressive yield strength of the resulting C4 was observed to increase to 126 MPa and 120 MPa, respectively, for the 10 and 20 PPI C4. Additionally, the infiltration of ceramic foam with the AA5083 alloy resulted in an increase in strength of 58–100 times when compared with plain ceramic foam. The failure modes of the composites in compression were analyzed by crack propagation and determining the type of failure. The study revealed that shear failure and vertical splitting were the predominant mechanisms of compression failure, and that the fabricated C4 is advantageous in mechanical properties compared to the plain ceramic foam. This study, therefore, suggests the use of C4 composites in armour applications. Full article

The microstructure-based finite element modeling (MB-FEM) of material representative volume element (RVE) is a widely used tool in the characterization and design of various composites. However, the MB-FEM has a number of deficiencies, e.g., time-consuming in the generation of a workable geometric model, challenge in achieving high volume-fractions of inclusions, and poor quality of finite element mesh. In this paper, we first demonstrate that for particulate composites the particle inclusions have homogeneous distribution and random orientation, and if the ratio of particle characteristic length to RVE size is adequately small, elastic properties characterized from the RVE are independent of particle shape and size. Based on this fact, we propose a microstructure-free finite element modeling (MF-FEM) approach to eliminate the deficiencies of the MB-FEM. The MF-FEM first generates a uniform mesh of brick elements for the RVE, and then a number of the elements, with their total volume determined by the desired volume fraction of inclusions, is randomly selected and assigned with the material properties of the inclusions; the rest of the elements are set to have the material properties of the matrix. Numerical comparison showed that the MF-FEM has a similar accuracy as the MB-FEM in the predicted properties. The MF-FEM was validated against experimental data reported in the literature and compared with the widely used micromechanical models. The results show that for a composite with small contrast of phase properties, the MF-FEM has excellent agreement with both the experimental data and the micromechanical models. However, for a composite that has large contrast of phase properties and high volume-fraction of inclusions, there exist significant differences between the MF-FEM and the micromechanical models. The proposed MF-FEM may become a more effective tool than the MB-FEM for material engineers to design novel composites. Full article

This work introduces a finite element model of a steel cable-reinforced conveyor belt to accurately compute stresses in the splice. In the modelled test rig, the belt runs on two drums and is loaded with a cyclic longitudinal force. An explicit solver is used to efficiently handle the high number of elements and contact conditions. This, however, introduces some issues of dynamics in the model, which are subsequently solved: (a) the longitudinal load is applied with a smooth curve and damping is introduced in the beginning of the simulation, (b) residual stresses are applied in regions of the belt that are initially bent around the drums, and (c) supporting drums are introduced at the start of the simulation to hinder oscillations of the belt at low applied forces. To accurately capture the tensile and bending stiffness of the cables, they are modelled by a combination of solid and beam elements. The results show that numerical artefacts can be reduced to an acceptable extent. In the region of highest stresses, the displacements are additionally mapped onto a submodel with a smaller mesh size. The results show that, for the investigated belt, the local maximum principal stresses significantly increase when this region of highest stresses comes into contact with, and is bent by, the drum. Therefore, it is essential to also consider the belt’s bending to predict failure in such applications. Full article

Flexural testing provides a rapid and straightforward assessment of fiber-reinforced composites’ performance. In many high-strength composites, flexural strength is higher than compressive strength. A finite-element model was developed to better understand this improvement in load-bearing capability and to predict the flexural strength of three different carbon-fiber-reinforced polymer composite systems. The model is validated against publicly available experimental data and verified using theory. Different failure criteria are evaluated with respect to their ability to predict the strength of composites under flexural loading. The Tsai–Wu criterion best explains the experimental data. An expansion in compressive stress limit for all three systems was observed and is explained by the compression from the loading roller and Poisson’s effects. Full article

The growing demands for electrical energy, especially renewable, is boosting the development of wind turbines equipped with longer composite blades. To reduce the maintenance cost of such huge composite parts, the structural health monitoring (SHM) is an approach to anticipate and/or follow the structural behaviour along time. Apart from the development of traditional non-destructive testing methods, in order to reduce the use of intrusive instrumentation there is a growing interest for the development of “self-sensing materials”. An interesting route to achieve this, can be to introduce carbon nanofillers such as nanotubes (CNT) in the composite structures, which enables to create systems that are sensitive to both strain and damage. This review aims at updating the state of the art of this topic so far. A first overview of the existing SHM techniques for thermoset based wind turbine blades composites is presented. Then, the use of self-sensing materials for strain and damage sensing is presented. Different strategies are overviewed and discussed, from the design of conductive composites such as carbon fibres reinforced polymers, to the elaboration of conductive nano-reinforced polymer composites. The origins of sensing mechanisms along with the percolation theory applied to nanofillers dispersed in polymer matrices are also detailed. Full article

In industrial applications where contact behavior of materials is characterized, fretting-associated fatigue plays a vital role as a failure agitator. While considering connection, it encounters friction. Biomaterials like polytetrafluoroethylene (PTFE) and ultra-high-molecular-weight polyethylene (UHMWPE) are renowned for their low coefficient of friction and are utilized in sophisticated functions like the hip joint cup and other biomedical implants. In addition to the axial stresses, some degree of dynamic bending stress is also developed occasionally in those fretting contacts. This research investigated the fracture behavior of a polymer PTFE under bending fretting fatigue. Finite element analysis justified the experimental results. A mathematical model is proposed by developing an empirical equation for fracture characterization in polymers like PTFE. It was found that the bending stiffness exists below the loading point ratio (LPR) 3.0, near the collar section of the specimen. Along with fretting, the bending load forces the specimen to crack in a brittle-ductile mode near the sharp-edged collar where the maximum strain rate, as well as stress, builds up. For a loading point ratio of above 3, a fracture takes place near the fretting pads in a tensile-brittle mode. Strain proportionality factor, k was found as a life optimization parameter under conditional loading. The microscopic analysis revealed that the fracture striation initiates perpendicularly to the fretting load. The fretting fatigue damage characteristic of PTFE may have a new era for the biomedical application of polymer-based composite materials. Full article

The current review paper studies the most noteworthy points in the fabrication of inorganic, eco-benign geopolymer mortar stressing the valorisation of Waste of Glasses (WG) about its properties and applications. Only a few studies are so far accessible on the topic, and therefore, more advanced studies in this respect will be valuable to construction industries and the research scientist, too. Mostly, the centre of attention on its valorisation with WG points a finger to its attitude to embrace the “conversion of wastes into best” strategy. Up until now, their character is neither well understood nor as embraced as OPC mortars. That is why this article reviews its confined literature with an aim to comprehend the valorisation of WG incorporation with geopolymer mortar, and it also reviews studies on its properties and applications, establishing it as a forthcoming constructive, productive, cost-effective, and sustainable large-scale construction material. The recommendations of this paper will be helpful for potential researchers on the topic. However, there are some challenges, such as curing impediments, occasionally practical antagonises of use, a restrained chain of supply, and a precondition for a sharp-eyed command of mixing design for preparing it for use in roadways to replace OPC counterparts in industry. When fabricated by employing abundantly available precursors, activators, and WG up to the standard superior control of varied properties, chiefly strength, durability, and the low-carbon footprints of alkali activators, GP mortars supplemented with WG are ground-breaking approaches to part of the prospect toolbox of sustainable and reasonably inexpensive construction materials. Finally, the paper identifies research work challenges, endorsement of utilisation, and most essentially the features of its properties and pertinent discussions for this promising new kind of valorised construction material. Full article

To answer the question “How does lanthanide doping in iron oxide affect cure kinetics of epoxy-based nanocomposites?”, we synthesized samarium (Sm)-doped Fe₃O₄ nanoparticles electrochemically and characterized it using Fourier-transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy dispersive X-Ray analysis (EDX), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy analyses (XPS). The magnetic particles were uniformly dispersed in epoxy resin to increase the curability of the epoxy/amine system. The effect of the lanthanide dopant on the curing reaction of epoxy with amine was explored by analyzing differential scanning calorimetry (DSC) experimental data based on a model-free methodology. It was found that Sm³⁺ in the structure of Fe₃O₄ crystal participates in cross-linking epoxy by catalyzing the reaction between epoxide rings and amine groups of curing agents. In addition, the etherification reaction of active OH groups on the surface of nanoparticles reacts with epoxy rings, which prolong the reaction time at the late stage of reaction where diffusion is the dominant mechanism. Full article

This paper deals with preparing a functional composite carbon fiber with a large surface area for spilled oil cleaning. The composite fiber consisted of photosensitive oxide particles and polymer-derived carbon. It was made by co-spinning the polymer and metallic compounds. After heat treatment at high temperatures, an activated carbon fiber containing oxide particles was obtained. The particles were found distributed in the fiber and at the surface of the fiber. The composite fiber was found sensitive to sunlight. Fiber mats made of the composite fiber possessed a high surface area for oil absorption and removal. Cobalt(II) titanate particles were obtained from the reaction of titanium dioxide and cobalt oxide. The reaction happened in situ through the hydrolysis of metallic compounds in the spun fiber. The titanium dioxide and cobalt(II) titanate particle-containing fibers demonstrated the photoactivity in the visible light spectrum. It was concluded that particle-containing composite carbon fiber mats can be prepared successfully by co-electrospinning. Due to the oleophilic property and the high active surface area, the composites are suitable for spilled oil cleaning through fast absorption. Full article

In thermoplastic composites, the polymeric matrix upon exposure to heat may melt, decompose and deform prior to burning, as opposed to the char-forming matrices of thermoset composites, which retain their shape until reaching a temperature at which decomposition and ignition occur. In this work, a theoretical and numerical heat transfer model to simulate temperature variations during the melting, decomposition and early stages of burning of commonly used thermoplastic matrices is proposed. The scenario includes exposing polymeric slabs to one-sided radiant heat in a cone calorimeter with heat fluxes ranging from 15 to 35 kW/m². A one-dimensional finite difference method based on the Stefan approach involving phase-changing and moving boundary conditions was developed by considering convective and radiative heat transfer at the exposed side of the polymer samples. The polymers chosen to experimentally validate the simulated results included polypropylene (PP), polyester (PET), and polyamide 6 (PA6). The predicted results match well with the experimental results. Full article

Dispersion of carbon nanotubes (CNT) in solvents and/or polymers is essential to reach the full potential of the CNTs in nanocomposite materials. Dispersion of CNTs is especially challenging due to the van-der-Waals attraction forces between the CNTs, which let them tend to re-bundle and/or re-aggregate. This paper presents a brief analysis of the quality and stability of functionalized multiwalled carbon nanotubes (fMWCNT) dispersion on polar solvents. A comparative study of functionalized CNT dispersion in water, methyl, and alcohol-based organic solvents has been carried out and the dispersion has been characterized by UV-VIS spectroscopy, electrochemical characterization such as cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Visual analysis of the dispersion has been investigated for up to 14 days to assess the dispersion’s stability. Based on the material characterization, it was observed that the degree of affinity fMWCNT with -COOH group highly depends on the polarity of the solvent, where the higher the polarity, the better the interaction of fMWCNT with solvents. Full article

The thermoelectric behavior of polypropylene (PP) based nanocomposites containing single walled carbon nanotubes (SWCNTs) and five kinds of ionic liquids (Ils) dependent on composite composition and electron beam irradiation (EB) was studied. Therefore, several samples were melt-mixed in a micro compounder, while five Ils with sufficiently different anions and/or cations were incorporated into the PP/SWCNT composites followed by an EB treatment for selected composites. Extensive investigations were carried out considering the electrical, thermal, mechanical, rheological, morphological and, most significantly, thermoelectric properties. It was found that it is possible to prepare n-type melt-mixed polymer composites from p-type commercial SWCNTs with relatively high Seebeck coefficients when adding four of the selected Ils. The highest Seebeck coefficients achieved in this study were +49.3 µV/K (PP/2 wt.% SWCNT) for p-type composites and −27.6 µV/K (PP/2 wt.% SWCNT/4 wt.% IL type AMIM Cl) for n-type composites. Generally, the type of IL is decisive whether p- or n-type thermoelectric behavior is achieved. After IL addition higher volume conductivity could be reached. Electron beam treatment of PP/SWCNT leads to increased values of the Seebeck coefficient, whereas the EB treated sample with IL (AMIM Cl) shows a less negative Seebeck coefficient value. Full article