Water

A fully penetrating cut-off wall is a vertical seepage barrier that fully penetrates an aquifer and is embedded in an underlying aquitard to a certain depth. Groundwater seepage with this type of wall occurs through three paths: leakage through the body of the wall in the aquifer, leakage through the body of the wall embedded in the aquitard, and seepage under the wall. Seepage through the first path can be simply treated as one-dimensional flow. However, due to the mutual influence of seepage through the latter two paths, the seepage problem is complicated and still needs to be studied. An analytical method is proposed to solve this problem in this study. Mathematic expressions for flow rate and head value are obtained by superposition of drawdowns of two exact models, namely, the model with only leakage through the wall body and the model with only seepage under the wall, respectively. Exact solutions are quoted or derived for the exact models, but they involve Legendre’s elliptic integrals of the first and third kinds. To facilitate an engineering application, approximate models of the exact models are introduced and their solutions are applied to the analytical formulas. The accuracy and applicability of the proposed method are verified compared with the numerical method. The proposed method provides a simple but effective method for quickly estimating the quantity of seepage in the aquitard (including leakage through the wall body and seepage under the wall) when simultaneously considering the effects of wall permeability and thickness. Full article

This study assessed the spatiotemporal variability and pollution grades of heavy metals in water and sediments of Bahr El-Baqar drain, Eastern Nile Delta, Egypt, by integration of geochemical analysis, metal pollution indices, correlation, and multivariate statistical analyses. Twenty samples of water and sediments were collected during 2018 and analyzed for heavy metal concentrations using ICP-OES. Heavy metal contents in the water samples followed the order: Fe > Zn > Al > Pb > Mn > Cu > Ni. The drain sediments were highly contaminated with heavy metals that followed the order: Fe ˃ Al ˃ Mn ˃ V ˃ Zn ˃ Cu > Cr ˃ Ba > Ni ˃ Pb ˃ As. Spatiotemporally, most metals in the drain sediments showed a decreasing trend from upstream (south) to downstream sites (north). Results of principal component analysis (PCA) supported those from the Pearson correlation between investigated heavy metals. In water, Mn, Ni, Pb, Zn, Cu, and Fe showed highly significant correlations. In sediments, Ba, Ni, Zn, Fe, Al, Mn, and V showed strong positive correlations indicating that these metals were derived from similar anthropogenic sources. The calculated metal pollution indices: enrichment factor (EF), contamination factor (CF), pollution load index (PLI), degree of contamination (DC), and index of geo-accumulation (I_geo) indicated high loadings of heavy metals in the drain sediments. EFs revealed low, moderate to significant enrichment, whereas CFs showed low, moderate, and considerable contamination. PLI indicated low, baseline, and progressive contamination, while DC indicated low, moderate, and considerable degree of contamination. I_geo of all investigated metals (except for As; class 1) indicated extremely contaminated sediments (class 7). Full article

Polycyclic aromatic hydrocarbons (PAHs) distributed in air and soil are harmful because of their carcinogenicity, mutagenicity, and teratogenicity. Biodegradation is an environmentally friendly and economical approach to control these types of contaminants and has become an essential method for remediating environments contaminated with petroleum hydrocarbons. The bacteria are isolated and identified using a mineral nutrient medium containing PAHs as the sole source of carbon and energy and biochemical differential tests. Thus, this study focuses on some bacteria and fungi that degrade oil and hydrocarbons. This study provides a comprehensive, up-to-date, and efficient overview of petroleum hydrocarbon contaminant bioremediation considering hydrocarbon modification by microorganisms, emphasizing the new knowledge gained in recent years. The study shows that petroleum hydrocarbon contaminants are acceptably biodegradable by some microorganisms, and their removal by this method is cost-effective. Moreover, microbial biodegradation of petroleum hydrocarbon contaminants utilizes the enzymatic catalytic activities of microorganisms and increases the degradation of pollutants several times compared to conventional methods. Biological treatment is carried out in two ways: microbial stimulation and microbial propagation. In the first method, the growth of indigenous microorganisms in the area increases, and the pollution is eliminated. In the second method, on the other hand, there are no effective microorganisms in the area, so these microorganisms are added to the environment. Full article

Nitrate pollution in groundwater has become a global concern for agriculture and regional ecology. However, tracing the spatiotemporal groundwater nitrate pollution sources, calculating the total nitrogen loading, and assessing contamination at the watershed scale have not been well documented. In this study, 20 groundwater samplings from 2020 to 2021 (in dry and wet seasons) on the Yiluo River watershed in middle China were collected. Tracing groundwater nitrate pollution sources, calculating total nitrogen loading, and assessing contamination using dual isotopes (18ONO3 and 15NNO3), conservation of mass, and the nitrate pollution index (NPI), respectively. The results indicated that there were three nitrate sources in groundwater: (1) manure and sewage waste input (MSWI), (2) sediment nitrogen input (SNI), and (3) agriculture chemical fertilizer input (ACFI) in the Yiluo River watershed. ACFI and SNI were the main groundwater nitrogen pollution sources. The average nitrogen loading percentages of ACFI, SNI, and MSWI in the whole watershed were 94.7%, 4.34%, and 0.96%, respectively. The total nitrogen loading in the Yiluo River watershed was 7,256,835.99 kg/year, 4,084,870.09 kg/year in downstream areas, 2,121,938.93 kg/year in midstream areas, and 1,050,026.95 kg/year in upstream areas. Sixty percent of groundwater in the Yiluo River watershed has been polluted by nitrate. Nitrate pollution in midstream areas is more severe. Nitrite pollution was more serious in the wet season than in the dry season. The results of this study can provide useful information for watershed-scale groundwater nitrogen pollution control and treatment. Full article

A monthly hydropower scheduling determines the monthly flows, storage, and power generation of each reservoir/hydropower plant over a planning horizon to maximize the total revenue or minimize the total operational cost. The problem is typically a complex and nonlinear optimization that involves equality and inequality constraints including the water balance, hydraulic coupling between cascaded hydropower plants, bounds on the reservoir storage, etc. This work applied the Zoutendijk algorithm for the first time to a medium/long-term hydropower scheduling of cascaded reservoirs, where the generating discharge capacity is handled with an iterative procedure, while the other head-related nonlinear constraints are represented with exponential functions fitting to discrete points. The procedure starts at an initial feasible solution, from which it finds a feasible improving direction, along which a better feasible solution is sought with a one-dimensional search. The results demonstrate that the Zoutendijk algorithm, when applied to six cascaded hydropower reservoirs on the Lancang River, worked very well in maximizing the hydropower production while ensuring the highest firm power output to be secured. Full article

Natural Treatment Systems for Wastewater (NTSW) show great potential for economic, socially acceptable and environmentally friendly wastewater treatment, along with the renewal of water for its safe reuse. This article presents the reduction in nitrogen and phosphorus compounds in domestic wastewater, which was achieved in a 2.5-year operation of the newly developed NTSW. The presented installation was developed by the Institute of Applied Ecology in Skórzyn (Poland) and implemented as a pilot plant serving the institute building with three permanent residents and up to five employees. The installation consisted of two parts, responsible for: wastewater treatment (septic tank and compost beds) and water renewal (denitrification beds, phosphorus beds and activated carbon beds). The mean values of nitrogen and phosphorus compound concentrations obtained in the renewed water for the entire research period were: 0.8, 49.4, 12 and 3.1 mg/L for ammonium nitrogen (NH₄), nitrates (NO₃), total nitrogen and phosphates (PO₄), respectively. Thus, average reductions of 99.6%, 90.9% and 94.4% were obtained for NH₄, total nitrogen and PO₄, respectively. Treatment of domestic sewage to such a level, similar to drinking water, enables versatile, safe water reuse, which in the situation of increasingly limited water resources will constitute increasing ecological and economic value. Full article

Energy dissipators, such as stilling basins, are usually required at the toe of stepped chutes to achieve adequate and safe operation of the spillway. Stepped chute hydraulics has been extensively studied in last several decades, however, only limited knowledge is available on the stilling basin performance below stepped chutes. In particular, the effect of the chute slope remains unknown, despite being a central design issue. Therefore, an experimental campaign was performed using a 30° or 50° inclined smooth or stepped chute with an adjacent conventional plain stilling basin. The experimental results indicated that, within the stilling basin, the surface characteristics and the roller as well as hydraulic jump lengths are practically independent of the chute slope. This further strengthens the previous findings that stepped chutes require 17% longer dimensionless jump lengths and consequently stilling basin lengths. The experimental results also confirmed that stepped chutes generated increased extreme and fluctuating bottom pressure characteristics at the stilling basin entrance area. With increasing chute slope, the latter were found to significantly magnify. However, such increased magnitudes were not expected to provoke cavitation damage as stepped chute inflows induced bottom aeration at the basin entrance, irrespective of the chute slope. Full article

Hydroponics is a soilless cultivation technique in which plants are grown in a nutrient solution typically made from mineral fertilizers. This alternative to soil farming can be advantageous in terms of nutrient and water use efficiency, plant pest management, and space use. However, developing methods to produce nutrient solutions based on local organic materials is crucial to include hydroponics within a perspective of sustainability. They would also allow hydroponics to be developed in any context, even in remote areas or regions that do not have access to commercial fertilizers. This emerging organic form of hydroponics, which can be qualified as “bioponics”, typically recycles organic waste into a nutrient-rich solution that can be used for plant growth. Many methods have been developed and tested in the past three decades, leading to greatly heterogenous results in terms of plant yield and quality. This review describes the main organic materials used to produce nutrient solutions and characterizes and categorizes the different types of methods. Four main categories emerged: a “tea”-type method, an aerobic microbial degradation method, an anaerobic digestion method, and a combined anaerobic-aerobic degradation method. The advantages and drawbacks of each technique are discussed, as well as potential lines of improvement. This aims at better understanding the links between agronomic results and the main biochemical processes involved during the production, as well as discussing the most suitable method for certain plants and/or contexts. Full article

The typical lime precipitation method is used to treat high-concentration fluorine-containing wastewater. In this way, the fluorine in the wastewater can be removed in the form of CaF₂. Thus, this method has a good fluoride removal effect. In this study, calcium hydroxide was used to adjust the pH and achieve a significant fluoride removal effect at the same time. The removal rate of fluoride ion decreases gradually with the increase in the concentration of sulphate in the raw water. When the synergistic defluorination cannot meet the requirements of water production, adding a step of aluminium salt flocculation and precipitation can further reduce the fluoride ion concentration. According to the feasibility of the actual project, this study improves the lime coagulation precipitation defluorination process on this basis, and the combined process is synchronised. In the process optimisation, barium chloride is added to remove the influence of sulphate radicals in the water, and then, the pH is adjusted to 5–6. The fluoride ion concentration in high-salt wastewater can be reduced from 446.6 mg/L to 35.4 mg/L by defluorination after pre-treatment whose removal rate was 92.1%. The combined process synchronously removes fluorine and purifies the water quality to a certain extent. Indicators such as COD, total phosphorus, ammonia nitrogen, and chloride ions in wastewater are reduced, and the removal rate is increased by 35.5% under the same conditions. This scheme improves the wastewater treatment effect without increasing the existing treatment equipment. Thus, it achieves a better defluorination effect and reduces the dosage of chemicals as much as possible, which is conducive to lowering the discharge of sludge after treatment. Full article

Numerical optimization is gradually finding its way into drinking water practice. For successful introduction of optimization into the sector, it is important that researchers and utility experts work together on the problem formulation with the water utility experts. Water utilities heed the solutions provided by optimization techniques only when the underlying approach and performance criteria match their specific goals. In this contribution, we demonstrate the application of numerical optimization on a real-life problem. The Belgian utility De Watergroep is looking to not only reinforce its distribution networks but to also structurally modify the network’s topology to enhance the quality of water delivered in the future. To help the utility explore the possibilities of these far-reaching changes in the most flexible way possible, an optimization problem was formulated to optimize topology and pipe sizing simultaneously for the distribution network of a Belgian city. The objective of the problem is to minimize the volume of the looped network and thereby work towards a situation where most of the customers are fed by branched extremities of the network. This objective is constrained by pressure and fire flow requirements and thresholds on the number of customers on the branched sections. The requirements for continuity of supply under failure scenarios are guaranteed by these constraints, as verified in the final solution. The results of the optimization process show that it is possible to design a network which is 18.5% cheaper than the currently existing network. Moreover, it turns out the—previously completely meshed—topology can be restructured so that 67% of the network length is turned into branched clusters, with a meshed superstructure of 33% of the length remaining. Full article

Increasing globalization in the last two decades has transformed the environment; hence, the demand for sustainable remediation approaches has also recorded an increasing trend. The varied sources of soil pollution include the application of chemical fertilizers and pesticides, industrial discharge, and transformed products of these accumulated chemical residues. These processes may hamper the composition and soil ecosystem. Different types of methodologies ranging from physical, chemical, and biological approaches have been exploited to tackle of this challenge. The last decade has observed a significant application of nanotechnology for the treatment and removal of contaminants. Nanomaterial (NMs) research has contributed to a new dimension for the remediation of polluted soils. The use of engineered NMs has not only carried out the remediation of contaminated sites but also has proven useful in combatting the release of soil pollutants. They have paved the way for eco-friendly approaches for the detection of pollutants along with the restoration of polluted sites to their nascent stages, which will also help in increasing soil fertility. Nano-enabled remediation mechanisms require extensive field and target-specific research to deliver the required output. This review focused on recent trends, emphasized the areas for further improvement, and intended to understand the requirement of an interdisciplinary approach to utilize nanotechnology for multitasking remediation approaches comprising different contaminants. Full article

The compatibility of sediments in terms of grain size, composition and colour among beaches and strategic sediment deposits (SSD) along Western Sardinia (Western Mediterranean Sea) were assessed to explore management strategy in the protection and adaptation to counteract the beach erosion and the effect of sea level rise along sandy shores. Twelve beaches, mainly conditioned by geological control, due to the presence of extensive rocky outcrops in the sea, enclosed in seven sedimentary cells (defined by the continuity of sediment transport pathways and by identification of boundaries where there are discontinuities), were characterised in terms of sediment composition and grain size. One hundred ninety-three beach sediments and one hundred sediments from SSDs were collected and analysed for sediment grain size, carbonate content and sediment colour. The beach sediments are composed by gravel to fine sands (D₅₀: from 81 µm to 4986 µm) with siliciclastic and biogenic carbonate sediments mixed in different proportions (0–100% in CaCO₃). The SSDs sediments are gravels to medium-fine sand (D₅₀: from 96 µm to 1769 µm) composed by biogenic carbonate sands mixed with siliciclastic grains (0–100% in CaCO₃). To be able to evaluate the compatibility between the beaches and SSDs, a multivariate statistical procedure was applied to grain size dataset. Our results show that 8 beaches have strategic deposits of compatible grain size and composition, whereas only 2 beaches have compatible strategic deposits of both grain size and colour. This may be related to the different sediment sources and depositional processes of sediment along the coastal cells and the continental shelf. Full article

The stationarity test and systematic prediction of hydrometeorological parameters are becoming increasingly important in water resources management. Based on the Ensemble Kalman Filter (EnKF) and wavelet analysis, this study selects precipitation, evaporation, temperature, and runoff as model variables, builds a model, tests and analyzes the stationarity of the hydrometeorological parameters of the Manas River, and forecasts the selected parameters for two years. The results of the study show that during the 2000–2020 study period, precipitation in the Manas River Basin on the northern slope of the Tianshan Mountains shows a significant downward trend from 2016 to 2020, with an annual average decline rate of 23.30 mm/a over five years. The proportion of runoff during the flood season also increases, with the statistical probability of an extremely low value of runoff increasing by 37.62% on average. After using wavelet decomposition to provide input to EnKF, the NSE of the model for the prediction of precipitation, evaporation, temperature, and runoff reached 0.86, 0.89, 0.96, and 0.9 respectively. At the same time, the K-S value increases from 0.28 to 0.40, which means that the wavelet analysis technique has great potential as a preprocessing of the Ensemble Kalman filter. Full article

The inland aquatic ecosystems play a significant role in the global carbon cycle, owing to the metabolism of terrestrially derived organic matter as it moves through fluvial networks along the water continuum. During this transport, dissolved organic matter (DOM) is microbial processed and released into the atmosphere, but the degree and intensity of this processing vary greatly both spatially and temporally. The Western Siberian Lowlands is of particular interest for a quantitative assessment of DOM biodegradation potential because the global areal-scale effects of DOM biodegradation in abundant surface organic-rich waters might be the highest in this region. To this end, we collected water samples along a typical aquatic continuum of the Bakchar Bog (the north-eastern part of the Great Vasyugan Mire) and, following standardized protocol, conducted an experimental study aimed at characterizing the seasonal and spatial variability of dissolved organic carbon (DOC) biodegradability. The biodegradable DOC fraction (BDOC) over the exposure incubation period ranged from 2% to 25%. The natural aquatic continuum “mire–forest–stream–river” demonstrated the systematic evolution of biodegradable DOC among the sites and across the seasons. The highest biodegradation rates were measured during spring flood in May and decreased along the continuum. The maximum possible CO₂ production from DOM yielded the maximum possible flux in the range of 0.1 and 0.2 g C-CO₂ m⁻² day⁻¹ d, which is an order of magnitude lower than the actual net CO₂ emissions from the inland waters of the WSL. This study suggests that although the biodegradation of the humic waters of the WSL can sizably modify the concentration and nature of the DOM along the aquatic continuum, it plays only a subordinary role in overall C emissions from the lakes and rivers of the region. Full article

Microplastics’ dangers and the absence of effective regulation technologies have risen to prominence as a worldwide issue in recent years. South Asian countries, such as Bangladesh, are among the most threatened nations to face the drastic consequence of releasing microplastics into the aquatic environment. The research on managing and degrading microplastics is ongoing, however, sustainable techniques have not yet been found. To create a green and efficient microplastic management plan, we have compiled all the information on the existing removal and degradation techniques for microplastics and provided an overview of all the noteworthy methods that can be implemented in Bangladesh. In the portrayed biotic and abiotic techniques, coagulation and photocatalysis were found to be most efficient in removing microplastics (as high as 99%) in different studies. The concept of microplastic is new to the researchers of Bangladesh, therefore, the characteristics, occurrence, fate, and threats are briefly discussed in this paper. Sampling, extraction, and identification methods of microplastic in freshwater and sediment samples are also thoroughly specified. The sources of microplastic pollution in Bangladesh and possible strategies that can be implemented to minimize additional microplastic discharge into aquatic environments are discussed. Although Bangladesh was the very first country to ban polythene, the failure of the implementation of rules and regulations and a lack of management strategy made Bangladesh the 10th worst country in managing plastic waste. This work is a wake-up call for other researchers to conduct an in-depth investigation to improve microplastic degrading technologies and develop a sustainable strategy to end microplastic pollution in Bangladesh. Full article

Climate change increasingly is affecting every aspect of human life on the earth. Many regional climate models (RCMs) have so far been developed to carefully assess this important phenomenon on specific regions. In this study, ten RCMs captured from the European Coordinated Downscaling Experiment (EURO CORDEX) platform are evaluated on the river Chiese catchment located in the northeast of Italy. The models’ ensembles are assessed in terms of the uncertainty and error calculated through different statistical and error indices. The uncertainties are investigated in terms of signal (increase, decrease, or neutral changes in the variables) and value uncertainties. Together with the spatial analysis of the data over the catchment, the weighted averaged values are used for the models’ evaluations and data projections. Using weighted catchment variables, climate change impacts are assessed on 10 different hydro-climatological variables showing the changes in the temperature, precipitation, rainfall events’ features, and the hydrological variables of the Chiese catchment between historical (1991–2000) and future (2071–2080) decades under RCP (Representative Concentration Path for increasing greenhouse gas emissions) scenario 4.5. The results show that, even though the multi-model ensemble mean (MMEM) could cover the outputs’ uncertainty of the models, it increases the error of the outputs. On the other hand, the RCM with the least error could cause high signal and value uncertainties for the results. Hence, different multi-model subsets of ensembles (MMEM-s) of 10 RCMs are obtained through a proposed algorithm for different impact models’ calculations and projections, making tradeoffs between two important shortcomings of model outputs, which are error and uncertainty. The single model (SM) and multi-model (MM) outputs imply that catchment warming is obvious in all cases and, therefore, evapotranspiration will be intensified in the future where there are about 1.28% and 6% value uncertainties for monthly temperature increase and the decadal relative balance of evapotranspiration, respectively. While rainfall events feature higher intensity and shorter duration in the SM, there are no significant differences for the mentioned features in the MM, showing high signal uncertainties in this regard. The unchanged catchment rainfall events’ depth can be observed in two SM and MM approaches, implying good signal certainty for the depth feature trend; there is still high uncertainty about the depth values. As a result of climate change, the percolation component change is negligible, with low signal and value uncertainties, while decadal evapotranspiration and discharge uncertainties show the same signal and value. While extreme events and their anomalous outcomes direct the uncertainties in rainfall events’ features’ values towards zero, they remain critical for yearly maximum catchment discharge in 2071–2080 as the highest value uncertainty is observed for this variable. Full article

This article presents experimental research focusing on the structural failure of the central core of a rockfill dam using sand-bentonite mixtures. It comprised an extensive geotechnical characterization of soil materials and mixtures, including compaction and strength tests, as well as the construction of 1 m high and 1.5 m wide physical models. The displacements of the cohesive cores were recorded using a tailored measuring system, based on a laser pointer and a mirror, designed to amplify the real displacements. The cohesive cores were extremely sensitive to small oscillations and behaved as rigid bodies, similar to concrete slabs with three fixed sides and another free. The shape and dimensions of the breach formed on the cohesive cores had roughly the same shape and dimensions as the unprotected area. This experimental research has the potential to be used as validation tool for several models available in the literature to predict the failure of embankment dams. Full article

Because of population growth, rapid urbanization, and climate change, many water supply utilities globally struggle to provide water that is safe to drink. A particular problem is the aging of the water supply facilities, which is exacerbated by their inefficient operation and maintenance (O&M). For this reason, many water utilities have recently been actively adopting intelligent and integrated water supply O&M solutions that utilize information and communication technology, the Internet of Things, big data, and artificial intelligence to solve water supply system problems. In this study, smart water solutions (GSWaterS) were implemented to enhance the efficiency of the water supply system in the city of Aracatuba, Brazil. They were used to monitor and analyze the operating conditions of the water supply system in real time, thus allowing for the effective management of water supply assets. GSWaterS also supports the design and optimization of district metered areas, the reduction and management of water losses, real-time water network analysis, and big data analysis using artificial intelligence. Economic analysis revealed that GSWaterS produces various direct and indirect benefits for the water supply system. Full article

TiO₂ has been hampered by drawbacks such as rapid photoelectron and hole recombination and a wide energy band gap of 3.2 eV. In this study, MIL-101(Cr)@TiO₂ was synthesised without any mineraliser (HF) as part of material modification approach to overcome those pitfalls. The composite was well characterized by XRD, FT-IR, TEM, XPS, BET, TGA, and Raman spectroscopy. Under optimal synthesis conditions, the 9.17% MIL-101(Cr)@TiO₂ composite exhibited 99.9% CBZ degradation after 60 min under UV-A irradiation. This can be attributed to the delayed recombination of photo-generated h⁺ and e⁻ and a reduced band gap energy of 2.9 eV. A Type II heterojunction structure was proposed for the composite using the Mulligan function of electronegativity with the calculated E_cb and E_vb. Besides, trapping experiments and ESR spectroscopy confirmed O₂^•− as the main ROS for CBZ degradation. The effects of the operating parameters such as pH, UV intensity, composite dosage, and initial pollutant concentration were also evaluated. The scavenging effects of inorganic and organic constituents of pharmaceutical wastewater on the process were also evaluated, with HCO₃⁻, CO₃²⁻, and THF having more significant inhibition on the overall CBZ degradation. The degradation pathways of CBZ were also proposed based on detected intermediates with the aid of LC/MS/MS. The composite illustrated reusability and stability without considerable loss in the degradation performance after repeated runs. This work builds on the development of more effective photocatalysts and provides a glimpse into applications for similar MOF heterojunction photocatalysts. Full article