This study develops a spherical crystallization approach using a small amount of water, which avoids adding extra bridging agents. Notably, a new ternary solvate of pantoprazole sodium (PS–BuOH–H2O) was obtained, and its crystal structure...
The formulation process for some drugs can be challenging, due to their unfavorable physical and mechanical properties and poor water solubility. Powder technology has made a significant impact in regard to the modification of the particles in active...
Clopidogrel bisulfate (CLP) form-I crystals are irregular, rectangular-shaped crystals. Because of their poor compressibility, flowability and their strong surface tension, manufacturers apply spherical crystallization methods to produce CLP form-I s...
In this study, two novel spherical agglomeration processes based on membrane systems were successfully implemented to produce spherical agglomerates of benzoic acid crystals obtained via antisolvent crystallization. Two membrane configurations were c...
This research work presents the use of the Quality by Design (QbD) concept for optimization of the spherical agglomeration crystallization method in the case of the active agent, ambroxol hydrochloride (AMB HCl). AMB HCl spherical crystals were formu...
Ice crystal icing occurs in jet engine compressors, which can severely degrade jet engine performance. In this paper, two different numerical calculation methods, the Eulerian method and the Lagrangian method, were used to evaluate the dynamics, mass...
Many drugs have a propensity for agglomeration, resulting in poor flowability. Spherical crystallization can be used to improve product properties including flowability and particle size. In this work, two methods were developed and utilized to succe...
Nickel-based superalloys are widely utilized in critical hot-end components, such as aeroengine turbine blades, owing to their exceptional high-temperature strength, creep resistance, and oxidation resistance. During service, these components are fre...
Periodic excitation is a relatively simple and common active control mode. Owing to the advantages of direct access to environmental energy and controllability under periodic illumination, it enjoys broad prospects for application in soft robotics an...
Salbutamol sulfate is a selective β2-receptor agonist used to treat asthma and chronic obstructive pulmonary disease. The crystals of salbutamol sulfate usually appear as needles with a relatively large aspect ratio, showing poor powder properti...
In this experiment, a series of poly(propylene 2,5-furan dicarboxylate)-b-poly(ethylene glycol) (PPFEG) copolymers with different ratios were synthesized using melt polycondensation of dimethylfuran-2,5-dicarboxylate (DMFD), 1,3-propanediol (PDO) and...
Quasi-emulsion solvent diffusion (QESD) crystallizations can improve the micromeritic properties of drugs and excipients. A solution is dispersed in a miscible antisolvent as a transient emulsion. Using this technique, substances that normally crysta...
The sapphire crystal, the most commonly used LED substrate material, has excellent optical and chemical properties and has rapidly developed in recent years. However, the challenge of growing large–size sapphire crystals remains. This paper pre...
Motivated by a wide range of applications in various fields of physics and materials science, we consider a generalized approach to the evolution of a polydisperse ensemble of spherical particles in metastable media. An integrodifferential system of...
We study liquid crystal (LC) shells in hybrid configuration (director tangential to the inside but normal to the outside) as they slowly undergo a transition from a nematic (N) to a smectic-A (SmA) phase. Every shell has two antipodal +1 topological...
As a class of self-organized soft matter systems merging fluidic mobility with long-range molecular order, cholesteric liquid crystals (CLCs) possess immense potential for the development of high-sensitivity, visually tractable flexible sensors. Leve...
In this paper, we perform crystal plasticity finite element (CPFE) simulations of spherical nanoindentation to extract the indentation stress–strain (ISS) curve for a single-crystalline copper. The load–displacement curves on the Cu (010)...
Cholesteric liquid crystals (CLCs) exhibit selective Bragg reflections of circularly polarized (CP) light owing to their spontaneous self-assembly abilities into periodic helical structures. Photonic cross-communication patterns could be generated to...
Here, we report a facile and effective one-pot approach to prepare uniform amylose-based polymeric microparticles (PMPs) through enzymatic synthesis of short-chain amylose (SCA) followed by spontaneous self-assembly of the SCA in the presence of leci...
Identification of elastic and plastic properties of materials from indentation tests received considerable attention in the open literature. However, unambiguous and automatic determination of parameters in the case of the crystal plasticity (CP) mod...
Relying on nanoindentation technology, the room-temperature creep behavior of a LiTaO3 single crystal in the typical orientation (01
In this paper, the spherical Fe-C micro-electrolysis materials (Fe-C MEM) were prepared using iron powder, activated carbon powder, corn straw, and bentonite as the raw materials. The preparation conditions optimized by single factor test showed Fe-C...
Multicellular magnetotactic prokaryotes (MMPs) are a unique group of magnetotactic bacteria that are composed of 10–100 individual cells and show coordinated swimming along magnetic field lines. MMPs produce nanometer-sized magnetite (Fe3O4) an...
This paper presents a new production method for a spherical and monocrystalline aluminum powder. Aluminum powder of irregular particle shapes was mixed with silica nanoparticles and heated to a temperature above the melting point of aluminum. Due to...
Simple but robust growth of spherical BaTiO3 nanoparticles with uniform nanoscale sizes is of great significance for the miniaturization of BaTiO3-based electron devices. This paper reports a TiO2-seeded hydrothermal process to synthesize spherical B...
We first shortly review, in part throwing a new light on, basics of ball numbers for balls having a positively homogeneous Minkowski functional and turn over then to a new particular class of ball numbers of balls having a Minkowski functional being...
We present a theoretical model of a cylindrical tunable liquid crystal lens based on the modulation of anchoring energy. The latter can be easily obtained using photoalignment techniques. The liquid crystal cell we propose exhibits strong anchoring a...
Microbial communities found in arid environments often exhibit unique genetic and metabolic adaptations that enable them to synthesize potent bioactive compounds. Bacillus thuringiensis (Bt) is widely recognized for its biocontrol potential against v...
Fillers are essential in the encapsulation molding compound. For three fillers of crystal, spherical, and fused silica, the effects of their size, type, and shape on the viscosity, flow spiral length, thermal conductivity, and coefficient of thermal...
In salt lake KCl cold decomposition–direct flotation for K-Na separation, octadecylamine hydrochloride (ODA-H) acts as a collector, reducing product purity and limiting high-end applications of salt lake KCl. To study KCl purification mechanism...
We investigated pore formation in aluminum foams by controlling primary crystal morphology using three master alloys. The first one was a direct chill cast A2024 (Al-Cu-Mg) alloy (DC-cast alloy). The others were A2024 alloys prepared to possess fine...
The growth of MnSn2 phase during the solidification process of Sn-Mn alloy was crystallographically investigated. The results show that the non-faced spherical caps of the MnSn2 crystals follow the continuous growth mechanism to grow rapidly along th...
Structural coloration based on nanostructures is one of the alternatives that can prevent environmental pollution compared to the use of chemically synthesized materials. This technique has attracted considerable attention for various applications, i...
In this study, the recrystallization and production of spherical submicron particles of sulfasalazine, an active pharmaceutical ingredient (API), were performed using the supercritical antisolvent (SAS) process, a nonconventional crystallization tech...
We successfully prepared Au nanoparticles using the modified polyol methods and design of experiments. The desirable crystal structure and particle size of Au nanoparticles with various kinds of polyhedral and spherical shapes as well as various kind...
In situ aircraft measurements of the sizes and concentrations of liquid cloud droplets and ice crystals with maximum dimensions (Dmax) less than ~50 μm have been measured mainly using forward scattering probes over the past half century. The opera...
Ti48Zr27Cu6Nb5Be14 amorphous composites were prepared by copper mold suction casting to obtain as-cast specimens. Subsequently, the as-cast specimens were held at 900 °C for different durations (5, 10, 20, 30, and 40 min) and then water quenched...
Using formaldehyde and urea as raw materials, a stable urea–formaldehyde resin (UF) is synthesized by the “alkali-acid-alkali” method. Unlike most thermosetting resins, UF often shows the appearance of crystal domains. In order to understand the rela...
Five liquid crystal epoxy resins and composites containing flat boron nitride (f-BN) and spherical boron nitride (s-BN) were successfully synthesized. The chemical structures, crystal diffraction, and thermal conductivity of the liquid crystal (LC) e...
CaCO3 spherulites were found in the myostracum layer of common limpet shells collected from East Sands, St Andrews, Scotland. Their microstructures were revealed by using powder X-ray diffraction, scanning electron microscopy, high-resolution transmi...
A novel strategy is proposed to design an exclusive nanostructured mullite spherical feedstock for environmental barrier coatings (EBCs) via atmosphere plasma spraying (APS). The nanostructured mullite spherical feedstocks are successfully obtained b...
Zeolite microspheres have been successfully applied in commercial-scale separators such as oxygen concentrators. However, further enhancement of their applications is hampered by the post-synthetic shaping process that formulates the zeolite powder i...
The crystal habit of pentaerythritol (PE) crystals is usually rod-shaped, which may lead to low bulk density and bad flowability compared with low aspect ratio crystals. In this study, dipentaerythritol (DPE), methylcellulose (MC), and hydroxypropyl...
The one-dimensional (1D) polyethylene (PE) nanocrystals were generated in epoxy thermosets via crystallization-driven self-assembly. Toward this end, an ABA triblock copolymer composed of PE midblock and poly(ε-caprolactone) (PCL) endblocks w...
In this research work, we reported the synthesis of a spherical-shaped bismuth vanadate (BiVO4) photocatalyst using a cost-effective, simple, chemical hydrothermal method and studied the effect of deposition temperatures on the structural, morphologi...
Silver powders chemically synthesized by reduction with hydrazine and those produced by electrolysis from the basic (nitrate) and complex (ammonium) electrolytes were examined by X-ray diffraction (XRD) and scanning electron microscopic (SEM) analysi...
We present a novel concept and first experimental results of a new type of 3D display, which is based on the synthesis of spherical waves. The setup comprises a lens array (LA) with apertures in the millimeter range and a liquid crystal display (LCD)...
We studied the evaporation-driven crystallization in the droplets of sodium acetate anhydrous (CH3COONa) aqueous solution, which were deposited on superhydrophobic substrates. The results reveal distinct crystallization behaviors between saturated an...
A novel phthalonitrile-terminated polyaryl ether nitrile (PEN-Ph) was synthesized and characterized. The crystallization behavior coexisting with the crosslinking behavior in the PEN-Ph system was confirmed by rheological measurements. DSC was applie...
Levitation of single trapped particles enables the exploration of fundamental physicochemical aerosol properties never previously achieved. Experimental measurements showed that (NH4)2SO4’s particle shape deviated from sphericity during the crystalli...
of 13