Atmosphere — Open Access Journal

PM_2.5 and PM_2.5–10 samples were simultaneously collected in Urumqi from January to December 2011, and 14 priority polycyclic aromatic hydrocarbons (PAHs) were determined. The mean concentrations of total PAHs in PM_2.5 and PM_2.5–10 were 20.90~844.22 ng m⁻³ and 19.65~176.5 ng m⁻³ respectively, with the highest in winter and the lowest in summer. Above 80% of PAHs were enriched in PM_2.5, which showed remarkable seasonal variations compared to coarse particles. High molecular weight (HMW) PAHs were predominant in PM_2.5 (46.61~85.13%), whereas the proportions of lower molecular weight (LMW) and HMW PAHs in PM_2.5–10 showed a decreasing and an increasing trend, respectively, from spring to winter. The estimated concentrations of benzo[a]pyrene equivalent carcinogenic potency (BaP_eq) in PM_2.5 (10.49~84.52 ng m⁻³) were higher than that of in PM_2.5–10 (1.15~13.33 ng m⁻³) except in summer. The estimated value of inhalation cancer risk in PM_2.5 and PM_2.5–10 were 1.63 × 10⁻⁴~7.35 × 10⁻³ and 9.94 × 10⁻⁵~1.16 × 10⁻³, respectively, far exceeding the health-based guideline level of 10⁻⁴. Diagnostic ratios and positive matrix factorization results demonstrated that PAHs in PM_2.5 and PM_2.5–10 were from similar sources, such as coal combustion, biomass burning, coking, and petroleum combustion, respectively. Coal combustion was the most important source for PAHs both in PM_2.5 and PM_2.5–10, accounting for 54.20% and 50.29%, respectively. Full article

Providing efficient ventilation in road tunnels is essential to prevent severe air pollution exposure for both drivers and pedestrians in such enclosed spaces with heavy vehicle emissions. Longitudinal ventilation methods like commercial jet fans have been widely applied and confirmed to be effective for introducing external fresh air into road tunnels that are shorter than 3 km. However, operating tunnel jet fans is energy consuming. Therefore, for small-scale (~100 m–1 km) road tunnels, mechanical ventilation methods might be highly energetically expensive and unaffordable. Many studies have found that the use of wind catchers could improve buildings’ natural ventilation, but their effect on improving natural ventilation in small-scale road tunnels has, hitherto, rarely been studied. This paper, therefore, aims to quantify the influence of style and arrangement of one-sided flat-roof wind catchers on ventilation performance in a road tunnel. The concept of intake fraction (IF) is applied for ventilation and pollutant exposure assessment in the overall tunnel and for pedestrian regions. Computational fluid dynamics (CFD) methodology with a standard k-epsilon turbulence model is used to perform a three-dimensional (3D) turbulent flow simulation, and CFD results have been validated by wind-tunnel experiments for building cross ventilation. Results show that the introduction of wind catchers would significantly enhance wind speed at pedestrian level, but a negative velocity reduction effect and a near-catcher recirculation zone can also be found. A special downstream vortex extending along the downstream tunnel is found, helping remove the accumulated pollutants away from the low-level pedestrian sides. Both wind catcher style and arrangement would significantly influence the ventilation performance in the tunnel. Compared to long-catcher designs, short-catchers would be more effective for providing fresh air to pedestrian sides due to a weaker upstream velocity reduction effect and smaller near-catcher recirculation zone. In long-catcher cases, IF increases to 1.13 ppm when the wind catcher is positioned 240 m away from the tunnel entrance, which is almost twice that in short-catcher cases. For the effects of catcher arrangements, single, short-catcher, span-wise, shifting would not help dilute pollutants effectively. Generally, a design involving a double short-catcher in a parallel arrangement is the most recommended, with the smallest IF, i.e., 61% of that in the tunnel without wind catchers (0.36 ppm). Full article

We examine the 2002 Yakutsk wildfire event and simulate the impacts of smoke aerosols on local radiative energy budget, using the WRF-Chem-SMOKE model. When comparing satellite retrievals (the Surface Radiation Budget (SRB) dataset) with model simulations, we found that the agreement is generally good, except for the regions where the model predicts too few clouds or SRB misclassifies strong smoke plumes as clouds. We also found that the smoke-induced changes in upward shortwave fluxes at top of atmosphere (TOA) vary under different burning and meteorological conditions. In the first period of the fire season (9–12 August), smoke particles cause a warming effect around 3 W/m², mainly through functioning as ice nuclei, which deplete the cloud water amount in the frontal system. At the beginning of the second period of the fire season (19–20 August), large amounts of pre-existing smoke particles cause a strong cooling effect of −8 W/m². This is offset by the warming effect caused by relatively small amounts of cloud condensation nuclei increases, which promotes the rain formation and depletes the cloud water amount. After the cloud decks are well mixed with smoke plumes (21–22 August), the first indirect and direct effects of smoke together lead to a cooling of −10 W/m². These results highlight the importance of meso-scale modeling efforts in estimating the smoke-induced changes in the radiative energy budget over high latitudes. Full article

High temperatures have large impacts on premature mortality risks across the world, and there is concern that warming temperatures associated with climate change, and in particular larger-than-expected increases in the proportion of days with extremely high temperatures, may lead to increasing mortality risks. Comparisons of heat-related mortality exposure-response functions across different cities show that the effects of heat on mortality risk vary by latitude, with more pronounced heat effects in more northerly climates. Evidence has also emerged in recent years of trends over time in heat-related mortality, suggesting that in many locations, the risk per unit increase in temperature has been declining. Here, I review the emerging literature on these trends, and draw conclusions for studies that seek to project future impacts of heat on mortality. I also make reference to the more general heat-mortality literature, including studies comparing effects across locations. I conclude that climate change projection studies will need to take into account trends over time (and possibly space) in the exposure response function for heat-related mortality. Several potential methods are discussed. Full article

Iran has faced many water shortage crises in the past. Iran’s moisture sources for precipitation were identified by Lagrangian approach using the FLEXible PARTicle dispersion model (FLEXPART) v9.0 model. The results demonstrate that Iran receives its moisture from both continental and oceanic sources. During the wet season, moisture uptake from the Arabian Sea, the Persian Gulf, and the Mediterranean Sea is dominant, while during the dry season, the role of the Red Sea, the Caspian Sea, and the Persian Gulf is intensified. Studying drought conditions by comparing 1-month, 6-month, and 12-month standardized precipitation index (SPI) with (E-P) values of oceanic and continental moisture sources (E stands for the evaporation and P the precipitation) using multiregression model demonstrates that among oceanic sources the Arabian Sea, the Persian Gulf, the Mediterranean Sea, and the Indian Ocean affect SPI values and among continental sources, moisture from bare grounds and cultivated lands influences SPI values during wet season. However, no correlation exists between oceanic and continental (E-P) and SPI values during the dry season. The results obtained by this study can be used by meteorologists and hydrology scientists for future water management programmes in Iran. Full article

European groundwater reservoirs are frequently subject to reactive nitrogen pollution (N_r) owing to the intensive use of nitrogen (N) fertilizer and animal manure in agriculture. Besides its risk on human health, groundwater N_r loading also affects the carbon (C) and N cycle of associated ecosystems. For a temperate grassland in Germany, the long-term (12 years) annual average exports of N_r in form of harvest exceeded N_r inputs via fertilization and deposition by more than 50 kgN ha⁻¹. We hypothesize that the resulting deficit in the N budget of the plant-soil system could be closed by N_r input via the groundwater. To test this hypothesis, the ecosystem model LandscapeDNDC was used to simulate the C and N cycle of the respective grassland under different model setups, i.e., with and without additional N_r inputs via groundwater transport. Simulated plant nitrate uptake compensated the measured N deficit for 2 of 3 plots and lead to substantial improvements regarding the match between simulated and observed plant biomass and CO₂ emission. This suggests that the C and N cycle of the investigated grassland were influenced by N_r inputs via groundwater transport. We also found that inputs of nitrate-rich groundwater increased the modelled nitrous oxide (N₂O) emissions, while soil water content was not affected. Full article

Using ERA-interim Reanalysis data and observational data, the intraseasonal oscillation of the winter rainfall in southern China is studied. The mean square deviation of daily precipitation is used to express precipitation variability, and winter precipitation variability over southern China is determined to be highly correlated with sea surface temperature (SST) in central and eastern tropical Pacific; the dominant period of the precipitation is 10–30 days, which reflects quasi-biweekly oscillation. Examination of 1000 hPa geopotential height suggests that key low-pressure systems affecting the intraseasonal precipitation come from Lake Baikal, but with different travel paths. In El Niño years, key low-pressure systems converge with other low-pressure systems and move southeastward until reaching South China, while in La Niña years, only one low-pressure system can reach southern China. Meanwhile, the explosive development of the low-pressure system is mainly caused by the joint effects of thermal advection and vorticity advection in El Niño, and only vorticity advection accounted for the dominant status in La Niña. Multiscale analysis shows that the meridional distribution of intraseasonal circulation plays an important role on the thermal transmission and brings strong warm advection from low latitudes to high latitudes in El Niño. Full article

The assessment of direct radiative forcing due to atmospheric aerosols (ADRF) in the Indo Gangetic Plain (IGP), which is a food basket of south Asia, is important for measuring the effect of atmospheric aerosols on the terrestrial ecosystem and for assessing the effect of aerosols on crop production in the region. Existing comprehensive analytical models to estimate ADRF require a large number of input parameters and high processing time. In this context, here, we develop a simple model to estimate daily ADRF at any location on the surface of the IGP through multiple regressions of AErosol RObotic NETwork (AERONET) aerosol optical depth (AOD) and atmospheric water vapour using data from 2002 to 2015 at 10 stations in the IGP. The goodness of fit of the model is indicated by an adjusted R² value of 0.834. The Jackknife method of deleting one group (station data) was employed to cross validate and study the stability of the regression model. It was found to be robust with an adjusted R² fluctuating between 0.813 and 0.842. In order to use the year-round ADRF model for locations beyond the AERONET stations in the IGP, AOD, and atmospheric water vapour products from MODIS Aqua and Terra were compared against AERONET station data and they were found to be similar. Using MODIS Aqua and Terra products as input, the year-round ADRF regression was evaluated at the IGP AERONET stations and found to perform well with Pearson correlation coefficients of 0.66 and 0.65, respectively. Using ADRF regression model with MODIS inputs allows for the estimation of ADRF across the IGP for assessing the aerosol impact on ecosystem and crop production. Full article

This paper describes the methodology used to incorporate two numerical plume rise algorithms, one by Janicke and Janicke and another by Webster and Thomson, into the Lagrangian particle model LAPMOD. LAPMOD is fully interfaced with the diagnostic meteorological model CALMET, which is part of the widely used CALPUFF modeling system. LAPMOD can also use the meteorological input files produced with the AERMET meteorological processor of the US-EPA recommended model AERMOD. This paper outlines the theory behind the two plume rise algorithms and the details of their implementation in LAPMOD. The paper also provides the results of the evaluation of LAPMOD and its included plume rise algorithms against the well-known Indianapolis and Kincaid SF₆ and SO₂ field studies and tracer experiments. The performance of LAPMOD is successfully evaluated with the Model Evaluation Kit and compared with that of other air quality models. Full article

We present a study of upper tropospheric westward transport of air masses coming from the Indian monsoon zone over the period 1998–2008. The objective is to characterize upper tropospheric transport of water vapor from the Indian to Sahelian regions, and to improve the understanding of the dynamical mechanisms that govern water vapor variations in West Africa and the interconnections between India and the Sahel, focusing on the direct role of the Indian monsoon region on Sahel tropospheric water vapor and precipitation. The calculations of forward trajectories with LACYTRAJ (LACY TRAJectory code) and humidity fluxes show that a substantial part (40 to 70% at 300 hPa) of trajectories coming from the upper troposphere of the monsoon region crossed the Sahelian region in a few days (3–14 days), and water vapor fluxes connecting these two regions are established when the Indian monsoon begins at latitudes higher than 15° N in its south–north migration. The intensity and orientation of water vapor fluxes are related to the tropical easterly jet, but they are from the east above the high convection zones. Between 1998 and 2008, these fluxes between the 500–300 hPa pressure levels are associated with precipitation in Sahel only if they are from the east and with an intensity exceeding 8 kg·(m·s)⁻¹. Full article

The street thermal environment is important for thermal comfort, urban climate and pollutant dispersion. A 24-h vehicle traverse study was conducted over the Kowloon Peninsula of Hong Kong in summer, with each measurement period consisting of 2–3 full days. The data covered a total of 158 loops in 198 h along the route on sunny days. The measured data were averaged by three methods (direct average, FFT filter and interpolated by the piecewise cubic Hermite interpolation). The average street air temperatures were found to be 1–3 °C higher than those recorded at nearby fixed weather stations. The street warming phenomenon observed in the study has substantial implications as usually urban heat island (UHI) intensity is estimated from measurement at fixed weather stations, and therefore the UHI intensity in the built areas of the city may have been underestimated. This significant difference is of interest for studies on outdoor air temperature, thermal comfort, urban environment and pollutant dispersion. The differences were simulated by an improved one-dimensional temperature model (ZERO-CAT) using different urban morphology parameters. The model can correct the underestimation of street air temperature. Further sensitivity studies show that the building arrangement in the daytime and nighttime plays different roles for air temperature in the street. City designers can choose different parameters based on their purpose. Full article

Rate coefficients at ambient temperature and atmospheric pressure for the reaction of ozone with 2-methoxypropene (2-MPE) and 2-ethoxypropene (2-EPE) were determined in an evacuable 100 L Teflon reaction chamber using absolute and relative rate methods. The product experiments were carried out using a 50 L Teflon reaction chamber in conjunction with FTIR as the detection technique. The rate coefficients (k in units of cm³ molecule⁻¹ s⁻¹) obtained are 1.18 ± 0.13 × 10⁻¹⁷ and 1.89 ± 0.23 × 10⁻¹⁷ for reactions with 2-MPE and 2-EPE, respectively. The effects of the alkoxy group on the gas-phase reactivity of alkyl vinyl ethers toward ozone are compared and discussed. The major ozonolysis products are methyl acetate, formaldehyde and CO₂ for 2-MPE, and ethyl acetate, formaldehyde and CO₂ for 2-EPE. Possible mechanisms for the two vinyl ethers are proposed based on the observed reaction products. Additionally, atmospheric lifetimes of 32 h and 21 h for 2-MPE and 2-EPE were estimated based on the measured rate constants and the ambient tropospheric concentration of ozone, respectively. The obtained values of the lifetimes indicate that the reaction with ozone is an important loss process for these vinyl ethers in the atmosphere, especially in polluted areas. Full article

Evapotranspiration (ET) is a typical biological environmental process to influence leaf temperature, crop water requirement, and greenhouse microclimate. Affecting factors of ET include air temperature, air relative humidity, wind speed, solar radiation, longwave radiation, soil moisture, CO₂ concentration, and crop state. In this study, two ET models of indoor cultivation commonly adopted in literature were selected to evaluate the effect of the performance of sensors on the model uncertainty. The method of the International Organization for Standardization, Guides to the expression of Uncertainty in Measurement (ISO GUM) was adopted. The result indicated that the performance of leaf area index (LAI) and solar radiation (Is) sensors were primary sources of uncertainty. The uncertainty of ET models due to sensor performance needs to be considered. To ensure the predictive ability for applying the ET model for crops irrigation management and greenhouse environmental control, the improvements in the measurement of environmental variables for calculating ET would be of particular importance. The method of this study can be used for evaluating the uncertainty of ET models that calculate ET based on environmental variables measured by meteorological sensors or the remote sensing technique. Full article

Using a high resolution model of Large Eddies Simulation (LES), named PALM from PArallel LES Model, a set of simulations were performed to understand how turbulence and convection behave in a pasture and forest sites in Amazonia during the dry and rainy seasons. Related to seasonality, dry period presented higher differences of values (40 W m⁻²) and patterns over the sites, while in the wet period have more similar characteristics (difference of −10 W m⁻²). The pasture site had more convection than the forest, with effective mixing and a deeper boundary layer (2600 m). The vertical decrease of sensible heat flux with altitude fed convection and also influenced the convective boundary layer (CBL) height. Regarding the components of turbulent kinetic energy equation, the thermal production was the most important component and the dissipation rate responded with higher growth, especially in cases of greatest mechanical production at the forest surface reaching values up to −20.0. Full article

The Gamo Highlands in Ethiopia are characterized by complex topography and lakes. These modulate the mesoscale and synoptic scale weather systems. In this study, we analyzed the temporal and spatial variations in weather as function of topography and season and their impact on potato crop growth. To determine how crop growth varies with elevation, we installed a network of six automatic weather stations along two transects. It covers a 30-km radius and 1800-m elevation difference. We conducted a potato field experiment near the weather stations. We used the weather observations as input for a crop model, GECROS. Data analysis showed large differences between weather in February and May. February is more dominated by mesoscale circulations. The averaged February diurnal patter shows a strong east to southeast lake breezes and, at night, weak localized flows driven by mountain density flows. In contrast, in May, the synoptic flow dominates, interacting with the mesoscale flows. The GECROS model satisfactorily predicted the elevational gradient in crop yield. Model sensitivity experiments showed that belg-averaged precipitation distribution gave the highest yield, followed by exchanging May weather observations with April. Full article

The semi-enclosed Mediterranean basin, surrounded by high mountains, is placed in a favorable location for cyclonic storms development. Most of these are extratropical cyclones of baroclinic and orographic origin, but occasionally, some low pressure systems may develop to assume features characteristic of tropical cyclones. Medicanes (MEDIterranean hurriCANES) are infrequent and small-sized tropical-like cyclones. They originate and develop over sea, and are associated with strong winds and heavy precipitations. Proper definitions and classifications for Medicanes are still partially lacking, and systematic climatic studies have appeared only in recent years. In this work, we provide climatologies of Medicanes in the Western Mediterranean basin based on multidecadal runs performed with the Weather Research and Forecasting regional model with different resolutions and setups. The detection of Medicanes is based on a cyclone tracking algorithm and on the methodology of Hart cyclone phase space diagrams. We compare the statistics of Medicanes in the historical period 1979–1998 between runs at a resolution of 11 km with different convective parameterizations and microphysics schemes and one run at a resolution of 4 km with explicitly resolved convection. We show how different convective parameterization schemes lead to different statistics of Medicanes, while the use of different microphysical schemes impacts the length of the cyclone trajectories. Full article

The knowledge of the water structure at the interface with the air in acidic pH conditions is of utmost importance for chemistry in the atmosphere. We shed light on the acidic air-water (AW) interfacial structure by DFT-MD simulations of the interface containing one hydronium ion coupled with theoretical SFG (Sum Frequency Generation) spectroscopy. The interpretation of SFG spectra at charged interfaces requires a deconvolution of the signal into BIL (Binding Interfacial Layer) and DL (Diffuse Layer) SFG contributions, which is achieved here, and hence reveals that even though H${}_3$O${}^{+}$ has a chaotropic effect on the BIL water structure (by weakening the 2D-HBond-Network observed at the neat air-water interface) it has no direct probing in SFG spectroscopy. The changes observed experimentally in the SFG of the acidic AW interface from the SFG at the neat AW are shown here to be solely due to the DL-SFG contribution to the spectroscopy. Such BIL-SFG and DL-SFG deconvolution rationalizes the experimental SFG data in the literature, while the hydronium chaotropic effect on the water 2D-HBond-Network in the BIL can be put in perspective of the decrease in surface tension at acidic AW interfaces. Full article

This study examines the decadal change in the relationship between two major Indian Ocean (IO) sea surface temperature patterns, namely the Indian Ocean dipole (IOD) and northern IO and the East Asia summer monsoon (EASM) in the early 2000s. In 1991–1999, the former epoch, the interannual variability of EASM was associated with the IOD-like pattern in the original paper and its relationship weakened in 2000–2016. There are two possible causes for this decadal change; stronger land-sea thermal contrast as a local forcing in latter epoch, which may result in the weakening of the relationship between the IO and the EASM. In addition, the influence of El Niño-southern Oscillation (ENSO) on the western North Pacific subtropical high (WNPSH) could be changed depending on the frequency of ENSO. In the 2000s, the intensity of the low frequency (LF)-type ENSO (42–86 months period) events was weaker compared to the former epoch but that of quasi-biennial (QB)-type ENSO (16–36 months period) remained persistent. This could explain that the QB-type ENSO is remote forcing that modulates the change in the relationship between the tropical IO patterns and EASM in the 2000s. Full article

As the global climate has changed, studies on the relationship between vegetation and climate have become crucial. We analyzed the long-term vegetation dynamics and diverse responses to extreme climate changes in Inner Mongolia, based on long-term Global Inventory Monitoring and Modelling Studies (GIMMS) NDVI3g datasets, as well as the eight extreme precipitation indices and six extreme temperature indices that are highly correlated with the occurrence of droughts or floods, heat or cold temperature disasters, and vegetation growth in Inner Mongolia. These datasets were analyzed using linear regression analysis, the Hurst exponent index, residual analysis, and the Pearson correlation analysis. The results showed the following: (1) The vegetation dynamical changes exhibited trends of improvement during 1982 to 2015, and 68% of the vegetation growth changes in Inner Mongolia can be explained by climate changes. (2) The extreme precipitation indices exhibited a slight change, except for the annual total wet–day precipitation (PRCPTOT). The occurrence of extreme cold temperatures showed a significant decline, while the occurrence of extreme warm temperatures showed an upward trend in Inner Mongolia. (3) The typical steppe, desert steppe, and forest steppe regions are more sensitive to extreme large precipitation, and the forest regions are more sensitive to extreme warm temperatures. (4) Extreme precipitation exhibits a one-month lagged effect on vegetation that is larger than the same-month effects on the grassland system. Extreme temperature exhibits same-month effects on vegetation, which are larger than the one-month lagged effects on the forest system. Therefore, studies of the relationship between extreme climate indices and vegetation are important for performing risk assessments of droughts, floods, and other related natural disasters. Full article