The development of high-performance solid-polymer electrolytes (SPEs) is a key to the practical application of lithium metal batteries (LMBs). The use of two-dimensional (2D) inorganic nanofiller is an efficient way to build poly(ethylene oxide) (PEO...
Hybrid solid-state batteries using a bilayer of ceramic and solid polymer electrolytes may offer advantages over using a single type of solid electrolyte alone. However, the impedance to Li+ transport across interfaces between different electrolytes...
Conventional carbonate-based liquid electrolytes have safety issues related to their high flammability and easy leakage. Therefore, it is essential to develop alternative electrolytes for lithium-ion batteries (LIBs). As a potential candidate, solid-...
The low ionic conductivity, narrow electrochemical window, poor interfacial stability with lithium metal, and non-degradability of raw materials are the main problems of solid polymer electrolytes, restricting the development of lithium solid-state b...
All-solid-state polymer lithium batteries have good safety, stability, and high energy densities and are employed in wireless sensors. However, the solid contact between the polymer electrolyte and the cathode leads to high interface resistance, limi...
The solid oxide electrolyte Li1.5Al0.5Ge1.5(PO4)3 (LAGP) with a NASICON structure has a high bulk ionic conductivity of 10−4 S cm−1 at room temperature and good stability in the air because of the strong P5+-O2− covalence bonding. H...
Traditional liquid electrolyte batteries face safety concerns such as leakage and flammability, while further optimization has reached a bottleneck. Solid electrolytes are therefore considered a promising solution. Here, a PEO–LiTFSI–LATP...
Lithium metal batteries (LMBs) are a dazzling star in electrochemical energy storage thanks to their high energy density and low redox potential. However, LMBs have a deadly lithium dendrite problem. Among the various methods for inhibiting lithium d...
An electrochemical amperometric ethylene sensor with solid polymer electrolyte (SPE) and semi-planar three electrode topology involving a working, pseudoreference, and counter electrode is presented. The polymer electrolyte is based on the ionic liqu...
Solid polymer electrolytes show their potential to partially replace conventional electrolytes in electrochemical devices. The solvent evaporation rate represents one of many options for modifying the electrode–electrolyte interface by affectin...
Solid-state batteries (SSBs) are gaining attention as they promise to provide better safety and a higher energy density than conventional liquid electrolyte batteries. Solid polymer electrolytes (SPEs) are promising candidates due to their flexibilit...
Solid polymer electrolytes (SPEs) for symmetrical supercapacitors are proposed herein with activated carbon as electrodes and optimized solid polymer electrolyte membranes, which serve as the separators and electrolytes. We propose the design of a lo...
Thermal treatment conditions of solid polymer polymer electrolyte (SPE) were studied with respect to their impact on the surface morphology, phase composition and chemical composition of an imidazolium ionic-liquid-based SPE, namely PVDF/NMP/[EMIM][T...
Solid polymer electrolytes (SPEs) are gaining attention as viable alternatives to traditional aqueous electrolytes in zinc–air batteries (ZABs), owing to their enhanced performance and stability. In this study, anion-exchange solid polymer elec...
Natural bamboo charcoal (BC) powder has been developed as a novel filler in order to further improve performances of the polyvinyl alcohol (PVA)-based alkaline solid polymer electrolyte (ASPE) by solution casting method. X-ray diffraction patterns of...
Lithium metal anodes have been pursued for decades as a way to significantly increase the energy density of lithium-ion batteries. However, safety risks caused by flammable liquid electrolytes and short circuits due to lithium dendrite formation duri...
Polyurethane acrylate (PUA) from vegetable oil has been synthesized and prepared for solid polymer electrolyte. Polyol has been end-capped with Toluene 2,4-Diisocyanate (TDI) followed by hydroxylethylmethylacrylate (HEMA) in a urethanation process to...
In this work, solid-state polymer supercapacitor (SSC) was assembled using poly(3,4-ethylenedioxythiophene/carbon paper (PEDOT/CP) as an electrode and ionic liquid (1-butyl-3-methylimidazole tetrafluoroborate)/polyvinyl alcohol/sulfuric acid (IL/PVA/...
Developing a solid polymer electrolyte with superior flame retardancy and lithium-ion transportation properties is still a challenge. Herein, an intrinsic silicon/phosphorus co-flame retardant polymer solid electrolyte was prepared by using polyethyl...
A polymer/ionic liquid thermoplastic solid electrolyte based on poly(ethylene oxide) (PEO), modified sepiolite (TPGS-S), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), and 1-Butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR14T...
The effect of the composition of liquid electrolytes in the bulk and at the interface with the LiFePO4 cathode on the operation of a solid-state lithium battery with a nanocomposite polymer gel electrolyte based on polyethylene glycol diacrylate and...
The growing popularity of quasi-solid-state supercapacitors inevitably leads to the unrestricted consumption of commonly used petroleum-derived polymer electrolytes, causing excessive carbon emissions and resulting in global warming. Also, the porosi...
To optimize the preparation process of polymer electrolytes by in situ UV curing and improve the performance of polymer electrolytes, we investigated the effect of carrier film phase conversion time on the properties of polymer electrolyte properties...
Solid-state batteries (SSBs) have attracted considerable attention for high-energy-density and high-safety energy storage devices. Many efforts have focused on the thin solid-state-electrolyte (SSE) films with high room-temperature ionic conductivity...
Supercapacitors are a very active research topic. However, liquid electrolytes present several drawbacks on security and packaging. Herein, a gel polymer electrolyte was prepared based on crosslinked renewable and environmentally friendly soybean pro...
In this paper, we report the preparation of bio-based polyurethane (PU) from renewable vegetable oil. The PU was synthesized through the reaction between jatropha oil-based polyol and isocyanate in a one-shot method. Then, lithium perchlorate (LiClO4...
The prediction of electrochemical performance is the basis for long-term service of all-solid-state-battery (ASSB) regarding the time-aging of solid polymer electrolytes. To get insight into the influence mechanism of electrolyte aging on cell fading...
In the current paper, ion transport parameters in poly (vinyl alcohol) (PVA) based solid polymer electrolyte were examined using Trukhan model successfully. The desired amount of lithium trifluoromethanesulfonate (LiCF3SO3) was dissolved in PVA host...
Solid-state lithium metal batteries (LMBs) have been extensively investigated owing to their safer and higher energy density. In this work, we prepared a novel elastic solid-state polymer electrolyte based on an in situ-formed elastomer polymer matri...
The synthesize of solid polymer electrolyte (SPE) based on polyethylene oxide (PEO), NaClO4 and nano-SiO2 was carried out by solution cast technique. Nano-SiO2 was synthesized from sugarcane bagasse using sol-gel method. FTIR analysis was carried out...
This study presents the synthesis of a transparent, flexible gel polymer electrolyte (GPE) based on the protic ionic liquid BMImHSO4 and on polyvinyl alcohol (PVA) through solution casting and electrochemical evaluation in a 2.5 V symmetrical C/C ele...
Solid polymer electrolytes (SPEs) hold great potential in high-safety energy storage but face two key bottlenecks: low room-temperature ionic conductivity and insufficient mechanical strength. This study proposes a synergistic optimization strategy o...
The development of solid-state polymer electrolytes is an effective way to overcome the notorious shuttle effect of polysulfides in traditional liquid lithium sulfur batteries. In this paper, cationic cyclopropenium based cross-linked polymer was fir...
Li-ion batteries (LIBs) represent the most sophisticated electrochemical energy storage technology. Nevertheless, they still suffer from safety issues and practical drawbacks related to the use of toxic and flammable liquid electrolytes. Thus, polyme...
This study evaluated the memristive switching characteristics of a biomaterial solid polymer electrolyte (SPE) chitosan-based memristor and confirmed its artificial synaptic behavior with analog switching. Despite the potential advantages of organic...
Solid polymer electrolytes (SPE) based on ionic liquid, poly-(vinylidene fluoride) and solvent N-methyl-pyrrolidone represent an effective component in electrochemical sensors. The advantage lies in their composition, which offers an opportunity to p...
The safety concern arising from flammable liquid electrolytes used in batteries and supercapacitors drives technological advances in solid polymer electrolytes (SPEs) in which flammable organic solvents are absent. However, there is always a trade-of...
Considering the safety problem that is caused by liquid electrolytes and Li dendrites for lithium batteries, a new quasi-solid-state polymer electrolyte technology is presented in this work. A layer of 1,4-phenylene bridged polysilsesquioxane (PSiO)...
A solid-state polymer electrolyte membrane is formed by blending poly(vinylidene fluoride-co-hexafluoropropylene) with the synthesized copolymer of poly(methyl methacrylate-co-1-vinyl-3-butyl-imidazolium bis(trifluoromethanesulfonyl)imide, in which l...
The attention to a stable and ionic conductive electrolyte is driven by the limitations of liquid electrolytes, particularly evaporation and leakage, which restrain their widespread use for electrochemical device applications. Solid polymer electroly...
A facile oxygen (O2) atmospheric plasma treatment is applied to a polyvinyl alcohol (PVA) matrix to enhance its wettability and hydrophilicity. The optimal plasma treatment conditions are determined by varying the applied plasma power and plasma trea...
Metal anodes promise improvements in energy density and cost; however, their performance is determined within the first several nanometers at the interface. This review reports on how polymer-based artificial solid electrolyte interphases (SEIs) are...
Solid polymer electrolytes (SPEs) have emerged as a promising avenue for developing flexible lithium-ion batteries. However, the low ionic conductivity of polymers remains a primary challenge that has been the subject of intensive research efforts in...
PEO-LiCF3SO3-halloysite nanotube (HNT) composites were fabricated by solution casting together with hot compression to form a solid polymer electrolyte (SPE) membrane. Different ultrasonic exposure times were used to disperse HNT nanoparticles in the...
We report the analysis of comb-like polymers by solid-state NMR. The polymers were previously evaluated as solid-polymer-electrolytes (SPE) for lithium-polymer-metal batteries that have suitable ionic conductivity at 60 °C. We propose to develop a co...
Here, the time dependence of the interfacial resistance for Li/polyethylene oxide (PEO)-Li(CF3SO2)2N (LiTFSI)-LiPF6/LiCoO2 cells was measured to investigate the stabilization effect of LiPF6 on the interface between a solid polymer electrolyte (SPE)...
Polyethylene oxide (PEO)-based composite polymer electrolytes (CPEs) containing in situ SiO2 fillers are prepared using an electrostatic spinning method at room temperature. Through the in situ hydrolysis of tetraethyl silicate (TEOS), the generated...
This study presents a structurally tunable Au-based solid polymer electrolyte (SPE) membrane electrode with significantly enhanced performance in organic hydrogenation reactions. Compared to a Pt-based counterpart, the Au-based electrode achieved a 2...
Electrolytes are key components in electrochemical storage systems, which provide an ion-transport mechanism between the cathode and anode of a cell. As battery technologies are in continuous development, there has been growing demand for more effici...
All-solid-state lithium batteries (ASSLBs) have gained enormous interest due to their potential high energy density, high performance, and inherent safety characteristics for advanced energy storage systems. Although solid-state ceramic (inorganic) e...
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