Next Article in Journal / Special Issue
The NMR2 Method to Determine Rapidly the Structure of the Binding Pocket of a Protein–Ligand Complex with High Accuracy
Previous Article in Journal / Special Issue
Nuclear Magnetic Resonance, a Powerful Tool in Cultural Heritage
Article Menu
Issue 1 (March) cover image

Export Article

Open AccessArticle
Magnetochemistry 2018, 4(1), 13; https://doi.org/10.3390/magnetochemistry4010013

Solid-State NMR Study of New Copolymers as Solid Polymer Electrolytes

1
Center of Excellence in Transportation Electrification and Energy Storage (CETEES), Hydro-Québec, 1806, Lionel-Boulet blvd., Varennes, QC J3X 1S1, Canada
2
Department of Chemistry, Université du Québec à Montréal (UQAM), Succ. Centre-Ville—C.P. 8888, Montréal, QC H3C 3P8, Canada
*
Author to whom correspondence should be addressed.
Received: 4 December 2017 / Revised: 8 January 2018 / Accepted: 11 January 2018 / Published: 18 January 2018
(This article belongs to the Special Issue Nuclear Magnetic Resonance Spectroscopy)
Full-Text   |   PDF [1191 KB, uploaded 18 January 2018]   |  

Abstract

We report the analysis of comb-like polymers by solid-state NMR. The polymers were previously evaluated as solid-polymer-electrolytes (SPE) for lithium-polymer-metal batteries that have suitable ionic conductivity at 60 °C. We propose to develop a correlation between 13C solid-state NMR measurements and phase segregation. 13C solid-state NMR is a perfect tool for differentiating polymer phases with fast or slow motions. 7Li was used to monitor the motion of lithium ions in the polymer, and activation energies were calculated. View Full-Text
Keywords: solid-state NMR; comb-like copolymer; solid polymer electrolyte; lithium-polymer-metal battery solid-state NMR; comb-like copolymer; solid polymer electrolyte; lithium-polymer-metal battery
Figures

Figure 1

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
SciFeed
Printed Edition Available!
A printed edition of this Special Issue is available here.

Share & Cite This Article

MDPI and ACS Style

Daigle, J.-C.; Arnold, A.A.; Vijh, A.; Zaghib, K. Solid-State NMR Study of New Copolymers as Solid Polymer Electrolytes. Magnetochemistry 2018, 4, 13.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Magnetochemistry EISSN 2312-7481 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top