713 Results Found

Complexation of alkaline earth metal cations with fluorescent tertiary-amide lower-rim calix[4]arene derivative bearing two phenanthridine moieties was studied experimentally (UV spectrophotometry, fluorimetry, isothermal microcalorimetry, NMR spectr...

The intrinsic effects of metal cation (La) and non-metallic anion (N) doping of CeO2 nanoparticles (NPs) for regenerative scavenging of reactive oxygen radicals were studied. La-doped CeO2 NPs were prepared by the conventional impregnation method at...

The hierarchical process of guanosine (G) self-assembly, leading in aqueous solution and in the presence of metal cations to the formation of G-quadruplexes, represents an intriguing topic both for the biological correlation with telomerase activity...

Membrane capacitive deionization (MCDI) is an electrochemical ion separation process that combines ion-exchange membranes (IEMs) with porous carbon electrodes to enhance desalination efficiency and address the limitations of conventional capacitive d...

Octylphenol (OP) and bisphenol A (BPA) are known as endocrine-disrupting chemicals (EDCs). During pregnancy, the expression of steroid hormone receptors is controlled by maternal and fetal nutrition. To evaluate the impact of EDCs during pregnancy, e...

To clarify the contribution of the bridging effect from three metal cations (K+, Mn2+, and Fe3+) on the humification of lignin-rich Tilia wood shavings and further enrich the theory of lignin humification, an indoor incubation method with constant te...

First-principles electronic band calculations were used to investigate the effects of alkali metals and organic cations added to Cu-based perovskite solar cells. The copper d-orbital band was slightly above the valence-band maximum and functioned as...

The natural nacre has a regular ordered layered structure of calcium carbonate tablets and ion crosslinking proteins stacked alternately, showing outstanding mechanical properties. Inspired by nacre, we fabricated different divalent metal cation-cros...

A metal-ion-free method was developed to prepare κ-carrageenan/cellulose hydrogel beads for efficient cationic dye removal. The beads were fabricated using a mixture of 1-ethyl-3-methylimidazolium acetate and N,N-dimethylformamide as the solven...

The bonding situation in mercury-alkali diatomics HgA (2Σ+) (A = Li, Na, K, Rb) has been investigated employing the relativistic all-electron method Normalized Elimination of the Small Component (NESC), CCSD(T), and augmented VTZ basis sets. Although...

This work reports the application of an electromembrane process, Donnan dialysis (DD), for the purification of so-called wet-process phosphoric acid (WPA). Nitric acid is used as the stripping solution to remove metallic cations (mostly Fe3+, Al3+, a...

Eugenol-based azo dyes illustrate how bio-sourced compounds like eugenol can be transformed through synthetic processes into functional and colorful compounds. The main purpose of the present work was to develop new responsive colorimetric sensors fo...

Natural zeolites are highly effective adsorbents that can remove various metal cations which would otherwise contaminate the environment. However, different metal cations (Cu, Zn, and Ag) within their lattice or quaternary long-chain surfactant catio...

Sulfate groups on cellulose particles such as cellulose nanocrystals (CNCs) provide colloidal stability credit to electrostatic repulsion between the like-charged particles. The introduction of sodium counter cations on the sulfate groups enables dry...

Diclofenac is one of the most common, commercially available, non-steroidal anti-inflammatory drugs (NSAIDs) in the world, with thousands of tons produced and consumed per year, which creates issues related to its presence in water bodies and the nee...

The effect of the silicon to aluminum ratio (SAR) and alkali metal cations on adsorption and diffusion properties of ZSM-5 and silicate-1 zeolites was investigated using n-hexane as the model probe via giant canonical Monte Carlo (GCMC) and molecular...

Metal cations are often used to regulate montmorillonite, but the mechanism is still unclear. In this paper, the regulation of different cations in montmorillonite was studied, and it was found that the regulation of different cations had significant...

The polyfunctional nature of chitosan enables its application as a polymer ligand not only for the recovery, separation, and concentration of metal ions, but for the fabrication of a wide spectrum of functional materials. Although unmodified chitosan...

This study investigates novel ferrocene-based electrochemical sensors for metal cation detection via the design, synthesis and characterisation of ferrocene derivatives. Specifically, this research determines the redox potentials of ferrocene versus...

Many crop plants are exposed to heavy metals and other metals that may intoxicate the crop plants themselves or consumers of the plants. The rhizotoxicity of heavy metals is influenced strongly by the root cell plasma membrane (PM) surface’s electric...

Biotic ligand models (BLMs) predict the toxicity of metals in aquatic environments by accounting for metal interactions with cell surface receptors (biotic ligands) in organisms, including water chemistry (metal speciation) and competing cations. Met...

Cation⊗3π interactions play a special role in the behaviors of biological molecules and carbon-based materials in aqueous solutions, yet the effects of solvation on these interactions remain poorly understood. This study examines the sequen...

Metal cations are associated with many biological processes. The effects of these cations on nucleic acids and chromatin were extensively studied in the early stages of nucleic acid and chromatin research. The results revealed that some monovalent an...

Carboxymethyl starch (CMS) and carboxymethyl cellulose (CMC) loaded by highly dispersed metal subnanoparticles (MSNPs) showed antibacterial activity against E. coli and B. subtilis strains. Copper and silver were found to act in both cationic and zer...

As anion-exchange materials, layered double hydroxides (LDHs) have attracted increasing attention in the fields of selective adsorption and separation, controlled drug release, and environmental remediation. The metal cation composition of the lamina...

Cyclopentadienyl (Cp)-coordinated cationic Si(II) (1) and Ge(II) compounds (2) are a new class of catalysts for various transformations in organosilicon chemistry. This review demonstrates that these compounds effectively catalyze technically importa...

Both inorganic and organic complexation of metal cations in clouds or rainwater is essential to describe the global biogeochemical cycles of metals, because complexation can increase metal solubility and stabilize some of their oxidation states. With...

Vinyl chloride, the monomer of polyvinyl chloride, is produced primarily via acetylene hydrochlorination catalyzed by environmentally toxic carbon-supported HgCl2. Recently, nitrogen-doped carbon materials have been explored as metal-free catalysts t...

Adsorbents derived from bamboo, such as biochar, charcoal, activated carbon, and chemically modified bamboo, are recognized for their efficiency and cost-effectiveness in removing heavy metals from water. Despite this, there remains a gap in applying...

As potential precursors for the synthesis of fluoroperovskites, a family of heavy alkali metal (MI = K, Cs) fluorinated β-diketonates were prepared and characterized by elemental analysis, IR, and powder-XRD. The crystal structures of the new si...

The interaction between polyelectrolytes and metal ions is governed by different types of interactions, leading to the formation of different phases, from liquid state to weak gels, through an appropriate choice of metal ion/polyelectrolyte molar rat...

The extraction and complexing properties of a series of p-tert-butylcalix[4]arene derivatives containing N-methoxycarbonylmonoaza-12-crown-4 as the substituents were evaluated using liquid–liquid extraction and spectrophotometric titration meth...

This review presents the synergistic effect in the catalytic system of ionic liquids (ILs) for the synthesis of cyclic carbonate from carbon dioxide and epoxide. The emphasis of this review is on three aspects: the catalytic system of metal-based ion...

Dihydrogen activation by metallogermylenes was investigated experimentally and theoretically. A neutral NHC-coordinated chlorometallogermylene was synthesized and converted to a cationic base-free metallogermylene of molybdenum via chloride abstracti...

Competition for the migration of interfering cations limits the scale-up and implementation of the Donnan dialysis process for the recovery of ammonia nitrogen (NH4+-N) from wastewater in practice. Highly efficient selective permeation of NH4+ throug...

KOH-based electrolytes with different salt additives were investigated to reduce their corrosive nature toward Mg/Ni metal hydride alloys used as negative electrodes in nickel metal hydride (Ni/MH) batteries. Alkaline metal halide salts and oxyacid s...

The issue of heavy metal pollution of industrial wastewaters is a major environmental concern nowadays. The aim of this study was to investigate the effectiveness of heavy metals removal from aqueous solutions by natural glauconite, in batch and dyna...

Divalent metal cations are of vital importance in biochemistry and materials science, and their structural and thermodynamic properties in aqueous solution have often been used as targets for the development of ion models. This study presented a stra...

A series of ruthenium(II) complexes with N-heterocyclic carbene (NHC) ligands of the general type (arene)(NHC)Ru(II)X2 (where X = halide) was prepared, characterized, and evaluated as antibacterial agents in comparison to the respective metal free be...

Heavy metals are non-biodegradable and carcinogenic pollutants with great bio-accumulation potential. Their ubiquitous occurrence in water and soils has caused serious environmental concerns. Effective strategies that can eliminate the heavy metal po...

Amid global energy challenges, the hydrogen evolution reaction (HER) is gaining traction for green hydrogen production. While catalyst research is ongoing, recognizing electrolyte effects remains crucial for sustainable hydrogen production via renewa...

In the present study, oyster shells, a cause of environmental pollution, were employed effectively to synthesize hydroxyapatite (HAP) by facile oxidation and phosphorylation. The ability of HAP to adsorb various metal cations and inhibit bacterial gr...

We examined the effectiveness of metal-exchanged phosphomolybdic acid salts in converting levulinic acid, derived from biomass, into valuable products (alkyl levulinate). We prepared salts of phosphomolybdic acid using different metals (Fe3+, Al3+, Z...

The analysis of cationic surfactants with high selectivity is a source of great research interest. In this study, the absorption spectra of tetra-sulphonated metal phthalocyanine (coordinated by iron, zinc, cobalt, and nickel) in the presence of cati...

The presence of intrinsic ion migration in metal halide perovskites (MHPs) is one of the main reasons that perovskite solar cells (PSCs) are not stable under operation. In this work, we quantify the ion migration of PSCs and MHP thin films in terms o...

Double-PHD fingers 3 (DPF3) is a BAF-associated human epigenetic regulator, which is increasingly recognised as a major contributor to various pathological contexts, such as cardiac defects, cancer, and neurodegenerative diseases. Recently, we unveil...

In this paper, various metal ions were utilized for the demulsification of spent metalworking fluids discharged from an automobile parts workshop. Five types of metal ions, i.e., Fe3+, Al3+, Fe2+, Ca2+ and Mg2+, combined with coagulant were systemati...

Nucleoside radicals are key intermediates in the process of DNA damage, and alkali metal ions are a common group of ions in living organisms. However, so far, there has been a significant lack of research on the structural effects of alkali metal ion...

Quadruplexes (GQs), peculiar DNA/RNA motifs concentrated in specific genomic regions, play a vital role in biological processes including telomere stability and, hence, represent promising targets for anticancer therapy. GQs are formed by folding gua...

Conversion coatings are one of the primary types of galvanic coatings used to protect steel structures against corrosion. They are created through chemical reactions between the metal surface and the environment of the phosphating. This paper investi...