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Batteries, Volume 9, Issue 5

2023 May - 49 articles

Cover Story: This work reviews the suitability of polymorphic Li-Nb-O-based compounds for LIB operation. Additional experimental results obtained from neutron scattering and electrochemical experiments on amorphous LiNbO3 films are the focus of the present work. Neutron reflectometry reveals a higher porosity in ion-beam sputtered amorphous LiNbO3 films (22% free volume) than in other metal oxide films such as amorphous LiAlO2 (8% free volume). The films allow long-term cycling even for fast cycling with rates of 240C possessing reversible capacities as high as 600 mAhg−1. Electrochemical impedance spectroscopy (EIS) shows that the film atomic network is stable during cycling. The results anticipate that amorphous LiNbO3 layers also contribute to the capacity of positive (LiNixMnyCozO2, NMC) and negative LIB electrode materials such as carbon and silicon. View this paper
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Articles (49)

  • Article
  • Open Access
6 Citations
2,862 Views
12 Pages

Readily Accessible M-Ferrocenyl-Phenyl Sulfonate as Novel Cathodic Electrolyte for Aqueous Organic Redox Flow Batteries

  • Dawei Fang,
  • Junzhi Zheng,
  • Xi Li,
  • Diandian Wang,
  • Yuxuan Yang,
  • Zhuling Liu,
  • Zongren Song and
  • Minghua Jing

Ferrocene derivatives are amongst the most promising electroactive organic electrolytes. The bottleneck problems of their application in aqueous redox flow batteries are their poor solubility and lower potential as well as the complexity of the modif...

  • Review
  • Open Access
19 Citations
7,204 Views
16 Pages

Recent Progress in Electrolyte Additives for Highly Reversible Zinc Anodes in Aqueous Zinc Batteries

  • Qibin Shen,
  • Yuanduo Wang,
  • Guanjie Han,
  • Xin Li,
  • Tao Yuan,
  • Hao Sun,
  • Yinyan Gong and
  • Taiqiang Chen

Aqueous zinc batteries (AZBs) are one of the most promising large-scale energy storage devices by virtue of their high specific capacity, high degree of safety, non-toxicity, and significant economic benefits. However, Zn anodes in aqueous electrolyt...

  • Article
  • Open Access
8 Citations
4,101 Views
11 Pages

Prefabrication of a Lithium Fluoride Interfacial Layer to Enable Dendrite-Free Lithium Deposition

  • Jie Ni,
  • Yike Lei,
  • Yongkang Han,
  • Yingchuan Zhang,
  • Cunman Zhang,
  • Zhen Geng and
  • Qiangfeng Xiao

Lithium metal is one of the most attractive anode materials for rechargeable batteries. However, its high reactivity with electrolytes, huge volume change, and dendrite growth upon charge or discharge lead to a low CE and the cycle instability of bat...

  • Article
  • Open Access
2,943 Views
16 Pages

A Polyacrylonitrile Shutdown Film for Prevention of Thermal Runaway in Lithium-Ion Cells

  • Jonathan Peter Charles Allen,
  • Marcin Mierzwa,
  • Denis Kramer,
  • Nuria Garcia-Araez and
  • Andrew L. Hector

The electrodeposition of a polymer (polyacrylonitrile, PAN) is used to reduce the risk of thermal runaway in lithium-ion batteries, which is the most important cause of battery accidents and fires. PAN was electrodeposited on a graphite battery elect...

  • Review
  • Open Access
16 Citations
5,563 Views
19 Pages

Integration of Flexible Supercapacitors with Triboelectric Nanogenerators: A Review

  • Yin Lu,
  • Tong Wu,
  • Zimeng Ma,
  • Yajun Mi,
  • Zequan Zhao,
  • Fei Liu,
  • Xia Cao and
  • Ning Wang

The ever-growing interest in wearable electronic devices has unleashed a strong demand for sustainable and flexible power sources that are represented by the combination of flexible energy harvesting with storage devices/technologies. Triboelectric n...

  • Article
  • Open Access
16 Citations
4,154 Views
15 Pages

Lithium-ion (Li-ion) batteries are considered to be one of the ideal energy sources for automotive and electronic products due to their size, high levels of charge, higher energy density, and low maintenance. When Li-ion batteries are used in harsh e...

  • Article
  • Open Access
16 Citations
4,637 Views
12 Pages

Mediating Lithium Plating/Stripping by Constructing 3D Au@Cu Pentagonal Pyramid Array

  • Yaohua Liang,
  • Wei Ding,
  • Bin Yao,
  • Fan Zheng,
  • Alevtina Smirnova and
  • Zhengrong Gu

Lithium (Li) metal is perceived as the “holy grail” of anodes for secondary batteries due to its innate merits. Regrettably, the commercial application of Li metal anodes (LMAs) has been hampered by problems derived from the uncontrollabl...

  • Article
  • Open Access
2 Citations
3,376 Views
17 Pages

Model-Based Analysis and Optimization of Acidic Tin–Iron Flow Batteries

  • Fuyu Chen,
  • Ying Wang,
  • Ying Shi,
  • Hui Chen,
  • Xinzhi Ma and
  • Qinfang Zhang

Acidic tin–iron flow batteries (TIFBs) employing Sn/Sn2+ and Fe2+/Fe3+ as active materials are regarded as promising energy storage devices due to their superior low capital cost, long lifecycle, and high system reliability. In this paper, the...

  • Article
  • Open Access
2 Citations
3,652 Views
16 Pages

Silicon has gained considerable attention as an anode material in lithium-ion batteries due to its high theoretical capacity. However, the significant volume changes that occur during lithiation/delithiation processes often result in poor cycling sta...

  • Article
  • Open Access
2 Citations
2,162 Views
15 Pages

Calorimetric Studies on Chemically Delithiated LiNi0.4Mn0.4Co0.2O2: Investigation of Phase Transition, Gas Evolution and Enthalpy of Formation

  • Wenjiao Zhao,
  • Julian Gebauer,
  • Thomas Bergfeldt,
  • Magnus Rohde,
  • Carlos Ziebert,
  • Yong Du and
  • Hans J. Seifert

Li1.11(Ni0.4Mn0.4Co0.2)O2 powders were chemically delithiated by (NH4)2S2O8 oxidizer to obtain Lix(Ni0.4Mn0.4Co0.2)O2 powders. The thermal behavior of two delithiated specimens, Li0.76Ni0.41Mn0.42Co0.17O2.10 and Li0.48Ni0.38Mn0.46Co0.16O2.07, was stu...

  • Article
  • Open Access
12 Citations
7,834 Views
26 Pages

This study investigates the influence of the considered Electric Equivalent Circuit Model (ECM) parameter dependencies and architectures on the predicted heat generation rate by using the Bernardi equation. For this purpose, the whole workflow, from...

  • Article
  • Open Access
3 Citations
2,832 Views
17 Pages

Controlling the cation to anion (Mn2+/MnO4) molar ratios of the precursors was used to obtain a highly performance capacitive properties of nanostructural MnO2 hybridized carbon-based materials on nickel foam (NF) through successive ionic laye...

  • Article
  • Open Access
2 Citations
2,969 Views
14 Pages

Control-Oriented Electrochemical Model and Parameter Estimation for an All-Copper Redox Flow Battery

  • Wouter Badenhorst,
  • Christian M. Jensen,
  • Uffe Jakobsen,
  • Zahra Esfahani and
  • Lasse Murtomäki

Redox flow batteries are an emergent technology in the field of energy storage for power grids with high renewable generator penetration. The copper redox flow battery (CuRFB) could play a significant role in the future of electrochemical energy stor...

  • Article
  • Open Access
4 Citations
3,066 Views
19 Pages

Design of Sodium Titanate Nanowires as Anodes for Dual Li,Na Ion Batteries

  • Silva Stanchovska,
  • Mariya Kalapsazova,
  • Sonya Harizanova,
  • Violeta Koleva and
  • Radostina Stoyanova

The bottleneck in the implementation of hybrid lithium-sodium-ion batteries is the lack of anode materials with a desired rate capability. Herein, we provide an in-depth examination of the Li-storage performance of sodium titanate nanowires as negati...

  • Article
  • Open Access
10 Citations
2,591 Views
14 Pages

Gel polymer-ceramic hybrid electrolytes (GHEs) have emerged as desirable candidates for preparing high energy density and excellent practicability gel batteries. However, the agglomeration of ceramic particles in polymer matrix leads to a decrease in...

  • Review
  • Open Access
7 Citations
6,064 Views
20 Pages

In this paper, the methods used to enhance the conductivity of LiBH4, a potential electrolyte for the construction of solid-state batteries, are summarized. Since this electrolyte becomes conductive at temperatures above 380 K due to a phase change,...

  • Article
  • Open Access
7 Citations
7,478 Views
17 Pages

Several effective methods have been developed recently to demonstrate simultaneous high energy and high power density in Lithium - carbon fluoride (Li-CFx) batteries. These methods can achieve as high as a 1000 Wh/kg energy density at a 60–70 k...

  • Article
  • Open Access
9 Citations
3,403 Views
14 Pages

Nickel phosphide (Ni2P), as an anode material for both lithium- and sodium-ion batteries, offers high theoretical specific and volumetric capacities. However, considerable challenges include its limited rate capability and low cycle stability arising...

  • Article
  • Open Access
11 Citations
3,042 Views
25 Pages

The state of charge (SOC) of a battery is a key parameter of electrical vehicles (EVs). However, limited by the lack of computing resources, the SOC estimation strategy used in vehicle-mounted battery management systems (V-BMS) is usually simplified....

  • Article
  • Open Access
2 Citations
4,219 Views
13 Pages

Synthesis and Performance of NaTi2(PO4)3/VGCF@C Anode Composite Material for Aqueous Sodium-Ion Batteries

  • Bo Ding,
  • Mingzhu Li,
  • Fuzhou Zheng,
  • Yangzhou Ma,
  • Guangsheng Song,
  • Xiulong Guan,
  • Yi Cao and
  • Cuie Wen

This study combines self-prepared NaTi2(PO4)3 (NTP) with commercial vapor-grown carbon fiber (VGCF) using a solid state calcination, then coats it with carbon to synthesize the composite anode material NaTi2(PO4)3/VGCF@C (NTP/VGCF@C). The microstruct...

  • Article
  • Open Access
13 Citations
5,971 Views
23 Pages

Variations across cells, modules, packs, and vehicles can cause significant errors in the state estimation of LIBs using machine learning algorithms, especially when trained with small datasets. Training with large datasets that account for all varia...

  • Article
  • Open Access
1 Citations
3,161 Views
20 Pages

The goal of this work was to predict the dynamic charge acceptance (DCA) for cells using different additives on the negative electrode from the evaluation of small-signal measurements by electrochemical impedance spectroscopy (EIS). Thereby, various...

  • Article
  • Open Access
5 Citations
3,288 Views
15 Pages

A Self-Growing 3D Porous Sn Protective Layer Enhanced Zn Anode

  • Dezhi Kong,
  • Qingwei Zhang,
  • Lin Li,
  • Huimin Zhao,
  • Ruixin Liu,
  • Ziyang Guo and
  • Lei Wang

Aqueous zinc-ion batteries (ZIBs) have received much attention because of their high safety, low pollution, and satisfactory energy density (840 mAh g−1), which is important for the research of new energy storage devices. However, problems such...

  • Article
  • Open Access
61 Citations
19,351 Views
23 Pages

Lithium-ion (Li-ion) batteries have become the preferred power source for electric vehicles (EVs) due to their high energy density, low self-discharge rate, and long cycle life. Over the past decade, technological enhancements accompanied by massive...

  • Article
  • Open Access
10 Citations
3,555 Views
14 Pages

Modification of Single-Walled Carbon Nanotube Networks Anodes for Application in Aqueous Lithium-Ion Batteries

  • Yelyzaveta Rublova,
  • Raimonds Meija,
  • Vitalijs Lazarenko,
  • Jana Andzane,
  • Janis Svirksts and
  • Donats Erts

The changes in global energy trends and the high demand for secondary power sources, have led to a renewed interest in aqueous lithium-ion batteries. The selection of a suitable anode for aqueous media is a difficult task because many anode materials...

  • Review
  • Open Access
19 Citations
5,889 Views
42 Pages

Recent Advances and Prospects of FeOOH-Based Electrode Materials for Supercapacitors

  • Youness El Issmaeli,
  • Amina Lahrichi,
  • Shankara S. Kalanur,
  • Sadesh Kumar Natarajan and
  • Bruno G. Pollet

Supercapacitors (SCs) offer a potential replacement for traditional lithium-based batteries in energy-storage devices thanks to the increased power density and stable charge–discharge cycles, as well as negligible environmental impact. Given th...

  • Article
  • Open Access
1 Citations
2,600 Views
17 Pages

Sustainable Approach for the Development of TiO2-Based 3D Electrodes for Microsupercapacitors

  • Nathalie Poirot,
  • Marie Gabard,
  • Mohamed Boufnichel,
  • Rachelle Omnée and
  • Encarnacion Raymundo-Piñero

This study reports a sustainable approach for developing electrodes for microsupercapacitors. This approach includes the synthesis of TiO2 nanoparticles via a green sol–gel method and the deposition of thin films of that electrochemically activ...

  • Article
  • Open Access
11 Citations
7,215 Views
14 Pages

Solid polymer electrolytes (SPEs) are seen as the key component in the development of solid-state lithium batteries (SSLBs) by virtue of their good processability and flexibility. However, poor mechanical strength, low room-temperature lithium-ion (L...

  • Article
  • Open Access
3 Citations
4,429 Views
11 Pages

Battery Test Profile Generation Framework for Electric Vehicles

  • Dongxu Guo,
  • Hailong Ren,
  • Xuning Feng,
  • Xuebing Han,
  • Languang Lu and
  • Minggao Ouyang

This paper proposes a framework for generating a battery test profile that accounts for the complex operating conditions of electric vehicles, which is essential for ensuring the durability and safety of the battery system used in these vehicles. Add...

  • Article
  • Open Access
3,310 Views
13 Pages

In Situ Solidification by γ−ray Irradiation Process for Integrated Solid−State Lithium Battery

  • Zhiqiang Chen,
  • Xueying Yang,
  • Nanbiao Pei,
  • Ruiyang Li,
  • Yuejin Zeng,
  • Peng Zhang and
  • Jinbao Zhao

The safety concerns associated with power batteries have prompted significant interest in all−solid−state lithium batteries (ASSBs). However, the advancement of ASSBs has been significantly impeded due to their unsatisfactory electrochemi...

  • Article
  • Open Access
12 Citations
2,345 Views
16 Pages

The nature of renewable energy resources (RERs), such as wind energy, makes them highly unstable, unpredictable, and intermittent. As a result, they must be optimized to reduce costs and emissions, increase reliability, and also to find the optimal s...

  • Article
  • Open Access
12 Citations
4,577 Views
28 Pages

In this work, a two-dimensional mathematical model is applied to develop a new mass transport correlation for an SGL GFD4.6A carbon felt applied in a 100 cm2 single cell vanadium redox-flow battery under realistic flow conditions. Already published m...

  • Article
  • Open Access
11 Citations
4,972 Views
13 Pages

Revealing Silicon’s Delithiation Behaviour through Empirical Analysis of Galvanostatic Charge–Discharge Curves

  • Frederik T. Huld,
  • Jan Petter Mæhlen,
  • Caroline Keller,
  • Samson Y. Lai,
  • Obinna E. Eleri,
  • Alexey Y. Koposov,
  • Zhixin Yu and
  • Fengliu Lou

The galvanostatic charge–discharge (GCD) behaviour of silicon (Si) is known to depend strongly on morphology, cycling conditions and electrochemical environment. One common method for analysing GCD curves is through differential capacity, but t...

  • Article
  • Open Access
16 Citations
3,609 Views
11 Pages

The NASICON-type (Sodium Super Ionic Conductor) Na3Zr2Si2PO12 solid electrolyte is one of the most promising electrolytes for solid-state sodium metal batteries. When preparing Na3Zr2Si2PO12 ceramic using a traditional high-temperature solid-state re...

  • Article
  • Open Access
6 Citations
3,632 Views
21 Pages

Design and Evaluation Framework for Modular Hybrid Battery Energy Storage Systems in Full-Electric Marine Applications

  • Zhenmin Tao,
  • Rene Barrera-Cardenas,
  • Mohsen Akbarzadeh,
  • Olve Mo,
  • Jasper De Smet and
  • Jeroen Stuyts

In the context of the maritime transportation sector electrification, battery hybridization has been identified as a promising manner of meeting the critical requirements on energy and power density, as well as lifetime and safety. Today, multiple pr...

  • Article
  • Open Access
25 Citations
9,273 Views
22 Pages

On the Relations between Lithium-Ion Battery Reaction Entropy, Surface Temperatures and Degradation

  • Lena Spitthoff,
  • Markus Solberg Wahl,
  • Jacob Joseph Lamb,
  • Paul Robert Shearing,
  • Preben J. S. Vie and
  • Odne Stokke Burheim

Understanding and mitigating the degradation of batteries is important for financial as well as environmental reasons. Many studies look at cell degradation in terms of capacity losses and the mechanisms causing them. However, in this study, we take...

  • Article
  • Open Access
19 Citations
11,956 Views
19 Pages

Silicon-containing materials are still the most promising alternatives to graphite as the negative electrodes of lithium-ion batteries. However, the different Li+ storage mechanism combined with the high capacity result in new requirements for the pa...

  • Article
  • Open Access
2 Citations
3,391 Views
12 Pages

Advanced Metal-Organic Frameworks Based on Anthraquinone-2,3-Dicarboxylate Ligands as Cathode for Lithium-Ion Batteries

  • Minjie Lai,
  • Dongying Zhang,
  • Fenghua Chen,
  • Xiaoying Lin,
  • Ankun Qiu,
  • Chenxi Lei,
  • Jiaying Liang,
  • Junfeng Liang,
  • Jianhui Li and
  • Ronghua Zeng
  • + 1 author

Quinone organic materials are promising electrodes for the next lithium-ion batteries (LIBs) owing to their versatile molecular designs, high theoretical capacity, flexibility, sustainability, and environmental friendliness. However, quinone organic...

  • Review
  • Open Access
26 Citations
7,064 Views
23 Pages

Low-Cost Mn-Based Cathode Materials for Lithium-Ion Batteries

  • Hongming Yi,
  • Ying Liang,
  • Yunlong Qian,
  • Yuchuan Feng,
  • Zheng Li and
  • Xue Zhang

Due to a high energy density and satisfactory longevity, lithium-ion batteries (LIBs) have been widely applied in the fields of consumer electronics and electric vehicles. Cathodes, an essential part of LIBs, greatly determine the energy density and...

  • Article
  • Open Access
9 Citations
5,350 Views
21 Pages

The Role of Protective Surface Coatings on the Thermal Stability of Delithiated Ni-Rich Layered Oxide Cathode Materials

  • Friederike Reissig,
  • Joaquin Ramirez-Rico,
  • Tobias Johannes Placke,
  • Martin Winter,
  • Richard Schmuch and
  • Aurora Gomez-Martin

To achieve a broader public acceptance for electric vehicles based on lithium-ion battery (LIB) technology, long driving ranges, low cost, and high safety are needed. A promising pathway to address these key parameters lies in the further improvement...

  • Review
  • Open Access
26 Citations
9,532 Views
36 Pages

Lithium Niobate for Fast Cycling in Li-ion Batteries: Review and New Experimental Results

  • Erwin Hüger,
  • Lukas Riedel,
  • Jing Zhu,
  • Jochen Stahn,
  • Paul Heitjans and
  • Harald Schmidt

Li-Nb-O-based insertion layers between electrodes and electrolytes of Li-ion batteries (LIBs) are known to protect the electrodes and electrolytes from unwanted reactions and to enhance Li transport across interfaces. An improved operation of LIBs, i...

  • Article
  • Open Access
6 Citations
3,412 Views
12 Pages

Lithium–oxygen (Li-O2) batteries have captured worldwide attention owing to their highest theoretical specific energy density. However, this promising system still suffers from huge discharge/charge overpotentials and poor cycling stability, wh...

  • Article
  • Open Access
17 Citations
8,430 Views
16 Pages

Impedance Investigation of Silicon/Graphite Anode during Cycling

  • Xiuwu Wang,
  • Jiangong Zhu,
  • Haifeng Dai,
  • Chao Yu and
  • Xuezhe Wei

Silicon/graphite material is one of the most promising anodes for high-performance lithium-ion batteries. However, the considerable deformation occurring during the charge/discharge process leading to its degradation hinders its application. Research...

  • Feature Paper
  • Article
  • Open Access
5 Citations
2,179 Views
12 Pages

A Superior Lithium-Ion Capacitor Based on Ultrafine MnO/Dual N-Doped Carbon Anode and Porous Carbon Cathode

  • Da Lei,
  • Yuyang Gao,
  • Zhidong Hou,
  • Lingbo Ren,
  • Mingwei Jiang,
  • Yunjing Cao,
  • Yu Zhang and
  • Jian-Gan Wang

Owing to the unique virtues of specific energy/power densities, lithium-ion capacitors (LICs) have been increasingly attracting research attention. However, the LICs are greatly restrained by the slow Li+-reaction kinetics of battery-type anodes, whi...

  • Article
  • Open Access
3 Citations
2,622 Views
15 Pages

Capacitive deionization (CDI) based on LSC-957 resin/carbon composite electrodes was used to remove Fe impurity ions from a spent vanadium electrolyte, which enabled simple and efficient regeneration of the electrolyte. The experiments conducted in t...

  • Article
  • Open Access
16 Citations
6,169 Views
12 Pages

Online High-Resolution EIS of Lithium-Ion Batteries by Means of Compact and Low Power ASIC

  • Andrea Ria,
  • Giuseppe Manfredini,
  • Francesco Gagliardi,
  • Michele Vitelli,
  • Paolo Bruschi and
  • Massimo Piotto

A compact electronic circuit capable of performing Electrochemical Impedance Spectroscopy (EIS) on either single Lithium-ion cells or modules formed by the series of two cells is presented. The proposed device, named Double Cell Management Unit (DCMU...

  • Article
  • Open Access
5 Citations
2,798 Views
15 Pages

Hollow CuSbSy Coated by Nitrogen-Doped Carbon as Anode Electrode for High-Performance Potassium-Ion Storage

  • Ping Hu,
  • Yulian Dong,
  • Guowei Yang,
  • Xin Chao,
  • Shijiang He,
  • Huaping Zhao,
  • Qun Fu and
  • Yong Lei

As a potential anode material for potassium-ion batteries (PIBs), bimetallic sulfides are favored by researchers for their high specific capacity, low cost, and long cycle life. However, the non-ideal diffusion rate and poor cycle stability pose sign...

  • Article
  • Open Access
76 Citations
20,470 Views
31 Pages

In this experimental investigation, we studied the safety and thermal runaway behavior of commercial lithium-ion batteries of type 21700. The different cathode materials NMC, NCA and LFP were compared, as well as high power and high energy cells. Aft...

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Batteries - ISSN 2313-0105