Batteries

59 pages, 11235 KB

Open AccessEditor’s ChoiceReview

A Review of EV Adoption, Charging Standards, and Charging Infrastructure Growth in Europe and Italy

by Mahwish Memon and Claudio Rossi

Batteries 2025, 11(6), 229; https://doi.org/10.3390/batteries11060229 - 12 Jun 2025

Cited by 1 | Viewed by 2929

This work analyzes the electric vehicle (EV) sales trends of plug-in hybrid electric vehicles (PHEVs) and battery electric vehicles (BEVs) and trends in the growth of Alternating Current (AC) and Direct Current (DC) charging infrastructure station scenarios in Europe and Italy. It offers [...] Read more.

This work analyzes the electric vehicle (EV) sales trends of plug-in hybrid electric vehicles (PHEVs) and battery electric vehicles (BEVs) and trends in the growth of Alternating Current (AC) and Direct Current (DC) charging infrastructure station scenarios in Europe and Italy. It offers a comprehensive view of market trends, technical developments, infrastructure development, and worldwide standardization initiatives for policymakers, researchers, and industry. A detailed classification of the charging technologies of EVs, i.e., conductive, wireless power transfer (WPT), battery swapping (BS), and different EV types, is presented. Finally, this work provides a comparative overview of charging standards and protocols, including the ones established by the Society of Automotive Engineers (SAE), International Electrotechnical Commission (IEC), and Standardization Administration of China (SAC), emphasizing interoperability and cross-border integration to accelerate the transition to clean transportation. Full article

(This article belongs to the Topic Electric Vehicles Smart Charging: Strategies, Technologies, and Challenges)

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28 pages, 5473 KB

Open AccessEditor’s ChoiceReview

Advances in the Battery Thermal Management Systems of Electric Vehicles for Thermal Runaway Prevention and Suppression

by Le Duc Tai and Moo-Yeon Lee

Batteries 2025, 11(6), 216; https://doi.org/10.3390/batteries11060216 - 1 Jun 2025

Viewed by 3619

Abstract

In response to the global imperative to reduce greenhouse gas emissions and fossil fuel dependency, electric vehicles (EVs) have emerged as a sustainable transportation alternative, primarily utilizing lithium-ion batteries (LIBs) due to their high energy density and efficiency. However, LIBs are highly sensitive [...] Read more.

In response to the global imperative to reduce greenhouse gas emissions and fossil fuel dependency, electric vehicles (EVs) have emerged as a sustainable transportation alternative, primarily utilizing lithium-ion batteries (LIBs) due to their high energy density and efficiency. However, LIBs are highly sensitive to temperature fluctuations, significantly affecting their performance, lifespan, and safety. One of the most critical threats to the safe operation of LIBs is thermal runaway (TR), an uncontrollable exothermic process that can lead to catastrophic failure under abusive conditions. Moreover, thermal runaway propagation (TRP) can rapidly spread failures across battery cells, intensifying safety threats. To address these challenges, developing advanced battery thermal management systems (BTMS) is essential to ensure optimal temperature control and suppress TR and TRP within LIB modules. This review systematically evaluates advanced cooling strategies, including indirect liquid cooling, water mist cooling, immersion cooling, phase change material (PCM) cooling, and hybrid cooling based on the latest studies published between 2020 and 2025. The review highlights their mechanisms, effectiveness, and practical considerations for preventing TR initiation and suppressing TRP in battery modules. Finally, key findings and future directions for designing next-generation BTMS are proposed, contributing valuable insights for enhancing the safety and reliability of LIB applications. Full article

(This article belongs to the Special Issue Thermal Management in Lithium-Ion Batteries: Latest Advances and Prospects)

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12 pages, 2446 KB

Open AccessEditor’s ChoiceArticle

Characterization of Industrial Black Mass from End-of-Life LiFePO₄-Graphite Batteries

by Nanna Bjerre-Christensen, Caroline Birksø Eriksen, Kristian Oluf Sylvester-Hvid and Dorthe Bomholdt Ravnsbæk

Batteries 2025, 11(6), 210; https://doi.org/10.3390/batteries11060210 - 26 May 2025

Viewed by 1267

Abstract

The use of Li-ion batteries is drastically increasing, especially due to the growing sales of electric vehicles. Simultaneously, there is a shift towards exchanging the traditional Co- and Ni-rich electrode materials with more sustainable alternatives such as LiFePO₄. This transition challenges [...] Read more.

The use of Li-ion batteries is drastically increasing, especially due to the growing sales of electric vehicles. Simultaneously, there is a shift towards exchanging the traditional Co- and Ni-rich electrode materials with more sustainable alternatives such as LiFePO₄. This transition challenges conventional recycling practices, which typically rely on shredding batteries into a substance known as black mass, which is subsequently processed via hydrometallurgical or pyrometallurgical methods to extract valuable elements. These routes may not be economically viable for future sustainable chemistries with lower contents of high-value metal. Hence, new methods for processing the black mass, allowing, e.g., for physical separation and direct recycling, are direly needed. Such developments require that the black mass is thoroughly understood. In this study, we thoroughly characterize a commercially produced Graphite/LFP black mass sample from real battery waste using a suite of analytical techniques. Our findings reveal detailed chemical, morphological, and structural insights and show that the components in the black mass have different micro-size profiles, which may enable simple size separation. Unfortunately, our analysis also reveals that the employed processing of battery waste into black mass leads to the formation of an unknown Fe-containing compound, which may hamper direct recycling routes. Full article

(This article belongs to the Special Issue 10th Anniversary of Batteries: Second-Life Applications and Recycling of Li-Ion Batteries)

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19 pages, 1500 KB

Open AccessEditor’s ChoiceArticle

Comprehensive Study of the Gas Volume and Composition Generated by 5 Ah Nickel Manganese Cobalt Oxide (NMC) Li-Ion Pouch Cells Through Different Failure Mechanisms at Varying States of Charge

by Gemma E. Howard, Katie C. Abbott, Jonathan E. H. Buston, Jason Gill, Steven L. Goddard and Daniel Howard

Batteries 2025, 11(5), 197; https://doi.org/10.3390/batteries11050197 - 17 May 2025

Cited by 1 | Viewed by 876

Abstract

Lithium-ion batteries risk failing when subjected to different abuse tests, resulting in gas and flames. In this study, 5 Ah nickel manganese cobalt oxide (NMC) pouch cells were subjected to external heating; overcharge at rates of 2.5, 5 and 10 A; and nail [...] Read more.

Lithium-ion batteries risk failing when subjected to different abuse tests, resulting in gas and flames. In this study, 5 Ah nickel manganese cobalt oxide (NMC) pouch cells were subjected to external heating; overcharge at rates of 2.5, 5 and 10 A; and nail penetration. Tests were conducted in air and N₂ atmospheres. Additional external heat tests were performed on cells at 5, 25, 50, and 75% SoC and on two, three, and four cell blocks. Gas volumes were calculated, and the gas composition was given for H₂, CO, CO₂, C₂H₄, C₂H₆, CH₄, C₃H₆, and C₃H₈. For tests under an air atmosphere at 100% SoC, the volume of gas varied between abuse methods: 3.9 L (external heat), 6.4 L (overcharge), and 8.9 L (nail penetration). The gas composition was found to predominantly contain H₂, CO₂, and CO for all abuse methods; however, higher concentrations of H₂ and CO were present in tests performed under N₂. External heat tests at different SoCs showed that the gas volume decreased with SoC. Overall, the type of abuse method can have a large effect on the gas volume and composition produced by cell failure. Full article

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18 pages, 1112 KB

Open AccessEditor’s ChoiceArticle

Domain Generalization Using Maximum Mean Discrepancy Loss for Remaining Useful Life Prediction of Lithium-Ion Batteries

by Wenbin Li, Yue Yang and Stefan Pischinger

Batteries 2025, 11(5), 194; https://doi.org/10.3390/batteries11050194 - 14 May 2025

Viewed by 812

Abstract

The capacity of Lithium-ion batteries degrades over the time, making accurate prediction of their Remaining Useful Life (RUL) crucial for maintenance and product lifespan design. However, diverse aging mechanisms, changing working conditions and cell-to-cell variation lead to the inhomogeneous cell lifespan and complicated [...] Read more.

The capacity of Lithium-ion batteries degrades over the time, making accurate prediction of their Remaining Useful Life (RUL) crucial for maintenance and product lifespan design. However, diverse aging mechanisms, changing working conditions and cell-to-cell variation lead to the inhomogeneous cell lifespan and complicated life prediction. In this work, a data-driven algorithm based on stacked Long Short Term Memory (LSTM) encoder–decoders is proposed for RUL prediction. The encoder and upstream decoder form an autoencoder framework for feature extraction. The encoder and the downstream decoder form the encoder–decoder framework for RUL prediction. To enhance generalization during training, the Maximum Mean Discrepancy (MMD) loss is included in the autoencoder framework. The similarity of aging patterns is analyzed during splitting source and target datasets through k-means and Density-Based Spatial Clustering of Applications with Noise (DBSCAN). The Euclidean metric with accumulated Equivalent Cycle Number (ECN) sequence during aging shows better performance for similarity-based data splitting than the Dynamic Time Wrapping (DTW) distance metric based on capacity fading trajectory. The experimental results indicate that the proposed algorithm can provide accurate RUL prediction using 5% fading data and shows good generalization with Coefficient of Determination (R²) score of 0.98. Full article

(This article belongs to the Special Issue Data-Driven Modeling, Degradation, Control, and Advanced Management Systems for Batteries)

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52 pages, 1276 KB

Open AccessEditor’s ChoiceReview

A Review of Battery Energy Storage Optimization in the Built Environment

by Simone Coccato, Khadija Barhmi, Ioannis Lampropoulos, Sara Golroodbari and Wilfried van Sark

Batteries 2025, 11(5), 179; https://doi.org/10.3390/batteries11050179 - 2 May 2025

Cited by 1 | Viewed by 5480

Abstract

The increasing adoption of renewable energy sources necessitates efficient energy storage solutions, with buildings emerging as critical nodes in residential energy systems. This review synthesizes state-of-the-art research on the role of batteries in residential settings, emphasizing their diverse applications, such as energy storage [...] Read more.

The increasing adoption of renewable energy sources necessitates efficient energy storage solutions, with buildings emerging as critical nodes in residential energy systems. This review synthesizes state-of-the-art research on the role of batteries in residential settings, emphasizing their diverse applications, such as energy storage for photovoltaic systems, peak shaving, load shifting, demand response, and backup power. Distinct from prior review studies, our work provides a structured framework categorizing battery applications, spanning individual use, shared systems, and energy communities, and examines modeling techniques like State of Charge estimation and degradation analysis. Highlighting the integration of batteries with renewable infrastructures, we explore multi-objective optimization strategies and hierarchical decomposition methods for effective battery utilization. The findings underscore that advanced battery management systems and technological innovations are aimed at extending battery life and enhancing efficiency. Finally, we identify critical knowledge gaps and propose directions for future research, with a focus on scaling battery applications to meet operational, economic, and environmental objectives. By bridging theoretical insights with practical applications, this review contributes to advancing the understanding and optimization of residential energy storage systems within the energy transition. Full article

(This article belongs to the Section Battery Modelling, Simulation, Management and Application)

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25 pages, 3739 KB

Open AccessEditor’s ChoiceArticle

Electrochemical–Thermal Modeling of Lithium-Ion Batteries: An Analysis of Thermal Runaway with Observation on Aging Effects

by Milad Tulabi and Roberto Bubbico

Batteries 2025, 11(5), 178; https://doi.org/10.3390/batteries11050178 - 2 May 2025

Viewed by 2985

Abstract

The increasing demand for energy storage solutions, particularly in electric vehicles and renewable energy systems, has intensified research on lithium-ion (Li-ion) battery safety and performance. A critical challenge is thermal runaway (TR), a highly exothermic sequence of reactions triggered by mechanical, electrical, or [...] Read more.

The increasing demand for energy storage solutions, particularly in electric vehicles and renewable energy systems, has intensified research on lithium-ion (Li-ion) battery safety and performance. A critical challenge is thermal runaway (TR), a highly exothermic sequence of reactions triggered by mechanical, electrical, or thermal abuse, which can lead to catastrophic failures. While most TR models focus on fresh cells, aging significantly impacts battery behavior and safety. This study develops an electrochemical–thermal coupled model that incorporates aging effects to better predict thermal behavior and TR initiation in cylindrical Li-ion batteries. The model is validated against experimental data for fresh NMC and aged NCA cells, and statistical analysis is conducted to identify key factors influencing TR (p < 0.05). A full factorial design evaluates the effects of internal resistance (10, 20, 30, and 40 mΩ), capacity (1, 2, 3, and 5 Ah), and current rate (1C, 3C, 6C, and 8C) on temperature evolution. Additionally, a machine learning algorithm (logistic regression) is employed to identify an internal resistance threshold, beyond which thermal runaway (TR) becomes highly probable, and to predict TR probability based on key battery parameters. The model achieved a high prediction accuracy of 95% on the test dataset. Results indicate that aging affects thermal stability in complex ways. The increased internal resistance exacerbates heating rates, while capacity fade reduces stored energy, mitigating TR risk. These findings provide a validated framework for enhancing battery thermal management and predictive safety mechanisms, which contributed to the development of safer, more reliable Li-ion energy storage systems. Full article

(This article belongs to the Special Issue The Breakthrough of Traditional Electrochemical Energy Storage Systems)

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19 pages, 257 KB

Open AccessEditor’s ChoiceReview

Advances in Standardised Battery Testing for Enhanced Safety and Innovation in Electric Vehicles: A Comprehensive Review

by Márton Pepó, Soma Fullér, Tibor Cseke and Zoltán Weltsch

Batteries 2025, 11(4), 157; https://doi.org/10.3390/batteries11040157 - 16 Apr 2025

Cited by 3 | Viewed by 2624

Abstract

Standardised battery tests are essential for evaluating the safety, reliability, and performance of modern battery technologies, especially with the rapid emergence of innovations such as solid-state and lithium–sulphur batteries. This review reveals critical shortcomings in current international standards (e.g., IEC, IEEE, SAE), which [...] Read more.

Standardised battery tests are essential for evaluating the safety, reliability, and performance of modern battery technologies, especially with the rapid emergence of innovations such as solid-state and lithium–sulphur batteries. This review reveals critical shortcomings in current international standards (e.g., IEC, IEEE, SAE), which often do not keep pace with technological developments and are not harmonised across regions, limiting their effectiveness in real-world applications. The paper stresses the need for the continuous review of test protocols through collaboration between researchers, manufacturers, and regulators. A detailed case study of the BYD Dolphin battery demonstrates the practical importance of comprehensive testing in real-world conditions, spanning electrical, thermal, and mechanical ranges. The review concludes that up-to-date, harmonised, and scenario-specific test methods are needed to ensure accurate battery assessment, support global comparability, and enable the safe introduction of next-generation batteries for electric mobility and energy storage. Future work should prioritise operational monitoring, open access data sharing, and the development of sustainability-focused practices such as recycling and reclamation. Full article

(This article belongs to the Section Battery Performance, Ageing, Reliability and Safety)

32 pages, 1077 KB

Open AccessEditor’s ChoiceArticle

Optimizing Multi-Microgrid Operations with Battery Energy Storage and Electric Vehicle Integration: A Comparative Analysis of Strategies

by Syed Muhammad Ahsan and Petr Musilek

Batteries 2025, 11(4), 129; https://doi.org/10.3390/batteries11040129 - 27 Mar 2025

Cited by 3 | Viewed by 1405

Abstract

This study presents a comprehensive comparative analysis of the operational strategies for multi-microgrid systems that integrate battery energy storage systems and electric vehicles. The analyzed strategies include individual operation, community-based operation, a cooperative game-theoretic method, and the alternating direction method of multipliers for [...] Read more.

This study presents a comprehensive comparative analysis of the operational strategies for multi-microgrid systems that integrate battery energy storage systems and electric vehicles. The analyzed strategies include individual operation, community-based operation, a cooperative game-theoretic method, and the alternating direction method of multipliers for multi-microgrid systems. The operation of multi-microgrid systems that incorporate electric vehicles presents challenges related to coordination, privacy, and fairness. Mathematical models for each strategy are developed and evaluated using annual simulations with real-world data. Individual operation offers simplicity but incurs higher costs due to the absence of power sharing among microgrids and limited optimization of battery usage. However, individual optimization reduces the multi-microgrid system cost by 47.5% when compared to the base case with no solar PV or BESS and without optimization. Community-based operation enables power sharing, reducing the net cost of the multi-microgrid system by approximately 7%, as compared to individual operation, but requires full data transparency, raising privacy concerns. Game theory ensures fair benefit allocation, allowing some microgrids to achieve cost reductions of up to 13% through enhanced cooperation and shared use of energy storage assets. The alternating direction method of multipliers achieves a reduction in the electricity costs of each microgrid by 6–7%. It balances privacy and performance without extensive data sharing while effectively utilizing energy storage. The findings highlight the trade-offs between cost efficiency, fairness, privacy, and computational efficiency, offering insights into optimizing multi-microgrid operations that incorporate advanced energy storage solutions. Full article

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41 pages, 7831 KB

Open AccessEditor’s ChoiceReview

Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion Batteries

by Koorosh Nikgoftar, Anil Kumar Madikere Raghunatha Reddy, Mogalahalli Venkatashamy Reddy and Karim Zaghib

Batteries 2025, 11(4), 123; https://doi.org/10.3390/batteries11040123 - 25 Mar 2025

Cited by 6 | Viewed by 4563

Abstract

The increasing global population and, thus, energy demand have made research into renewable energy sources more critical. Lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) have been recognized as the most promising technologies for storing energy and effectively addressing this demand. Carbonaceous materials are [...] Read more.

The increasing global population and, thus, energy demand have made research into renewable energy sources more critical. Lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) have been recognized as the most promising technologies for storing energy and effectively addressing this demand. Carbonaceous materials are the most widespread anode material due to their fascinating features, such as high theoretical capacity, high electrical conductivity, and excellent structural stability. Additionally, these materials’ abundance, cost-effectiveness, and environmental friendliness have emphasized the need for further investigation and development. Among these carbon-based materials, graphite (both artificial and natural) stands out as the most ubiquitous anode material due to its layered crystal structure, high mechanical strength, long cycle life, and excellent safety profile, making it ideal for intercalation with lithium and sodium. In recent years, extensive research has been conducted to enhance the efficiency of anodes and, ultimately, the overall performance of batteries. In this review, the role of carbonaceous materials in anodes for lithium-ion and sodium-ion batteries was comprehensively investigated, focusing on advancements in synthesizing and optimizing artificial graphite. Furthermore, the intercalation mechanism and the factors influencing the electrochemical properties of both LIBs and SIBs were extensively discussed. This work also provides a holistic perspective on the differences between these two types of batteries, highlighting their cost, safety applications, and future potential advancement. Full article

(This article belongs to the Section Battery Materials and Interfaces: Anode, Cathode, Separators and Electrolytes or Others)

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15 pages, 1678 KB

Open AccessEditor’s ChoiceArticle

Assessment of Laser-Ablated Silicon Wafers as Lithium-Ion Battery Anodes

by Byeongcheol Min, Anustup Chakraborty, Chen Cai, Mool C. Gupta and Gary M. Koenig, Jr.

Batteries 2025, 11(4), 121; https://doi.org/10.3390/batteries11040121 - 23 Mar 2025

Cited by 1 | Viewed by 853

Abstract

Silicon materials have been widely investigated as anode materials for lithium-ion batteries. However, they are typically processed as fine powders into composite electrodes. Towards potentially repurposing silicon wafers as battery anodes, in this work, the impacts of the laser ablation of silicon wafers [...] Read more.

Silicon materials have been widely investigated as anode materials for lithium-ion batteries. However, they are typically processed as fine powders into composite electrodes. Towards potentially repurposing silicon wafers as battery anodes, in this work, the impacts of the laser ablation of silicon wafers on electrochemical cycling outcomes were investigated. Both pristine wafers and laser-ablated wafers were assessed, where the silicon anodes were paired with all-active material LiCoO₂ cathodes to assess the system as lithium-ion full cells. The laser ablation process modified the surface morphology of the silicon wafers, creating a polycrystalline silicon layer with increased surface area. Electrochemical cycling revealed that the laser-treated wafers demonstrated higher capacity retention and improved rate capability compared to untreated wafers, especially when discharged at the highest current density of 7 mA cm⁻². This work demonstrated the improvements in electrochemical outcomes with the direct use of silicon wafers as lithium-ion anodes when laser ablation surface treatment is applied. Full article

(This article belongs to the Section Battery Materials and Interfaces: Anode, Cathode, Separators and Electrolytes or Others)

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35 pages, 4055 KB

Open AccessFeature PaperEditor’s ChoiceReview

Water-in-Salt Electrolytes: Advances and Chemistry for Sustainable Aqueous Monovalent-Metal-Ion Batteries

by Rashmi Nidhi Mishra, Anil Kumar Madikere Raghunatha Reddy, Marc-Antoni Goulet and Karim Zaghib

Batteries 2025, 11(4), 120; https://doi.org/10.3390/batteries11040120 - 22 Mar 2025

Cited by 1 | Viewed by 4016

Abstract

Electrolytes play a vital role in the performance and safety of electrochemical energy storage devices, such as lithium-ion batteries (LIBs). While traditional LIBs rely on organic electrolytes, these flammable solutions pose safety risks and require expensive, moisture-sensitive manufacturing processes. Aqueous electrolytes offer a [...] Read more.

Electrolytes play a vital role in the performance and safety of electrochemical energy storage devices, such as lithium-ion batteries (LIBs). While traditional LIBs rely on organic electrolytes, these flammable solutions pose safety risks and require expensive, moisture-sensitive manufacturing processes. Aqueous electrolytes offer a safer, more cost-effective alternative, but their narrow electrochemical window, corrosivity to electrodes, and enabling of dendritic growth on metal anodes limit their practical applications. Water-in-salt electrolytes (WiSEs) have emerged as a promising solution to these challenges. By significantly reducing water activity and forming a stable solid–electrolyte interphase (SEI), WiSEs can expand the electrochemical stability window, inhibit material dissolution, and suppress dendritic growth. This unique SEI formation mechanism, which is similar to that observed in organic electrolytes, contributes to the improved performance and stability of WiSE-based batteries. Additionally, the altered solvation structure of WiSEs minimizes the presence of free water molecules, further stabilizing the SEI and reducing water activity. This review comprehensively examines the composition, mechanisms, and characterization of WiSEs and their application in monovalent-metal-ion batteries. Full article

(This article belongs to the Section Aqueous Batteries)

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15 pages, 2917 KB

Open AccessEditor’s ChoiceArticle

Plasticized Ionic Liquid Crystal Elastomer Emulsion-Based Polymer Electrolyte for Lithium-Ion Batteries

by Zakaria Siddiquee, Hyunsang Lee, Weinan Xu, Thein Kyu and Antal Jákli

Batteries 2025, 11(3), 106; https://doi.org/10.3390/batteries11030106 - 12 Mar 2025

Cited by 1 | Viewed by 1109

Abstract

The development and electrochemical characteristics of ionic liquid crystal elastomers (iLCEs) are described for use as electrolyte components in lithium-ion batteries. The unique combination of elastic and liquid crystal properties in iLCEs grants them robust mechanical attributes and structural ordering. Specifically, the macroscopic [...] Read more.

The development and electrochemical characteristics of ionic liquid crystal elastomers (iLCEs) are described for use as electrolyte components in lithium-ion batteries. The unique combination of elastic and liquid crystal properties in iLCEs grants them robust mechanical attributes and structural ordering. Specifically, the macroscopic alignment of phase-segregated, ordered nanostructures in iLCEs serves as an ion pathway, which can be solidified through photopolymerization to create ion-conductive solid-state polymer lithium batteries (SSPLBs) with high ionic conductivity (1.76 × 10⁻³ S cm⁻¹ at 30 °C), and a high (0.61) transference number. Additionally, the rubbery state ensures good interfacial contact with electrodes that inhibits lithium dendrite formation. Furthermore, in contrast to liquid electrolytes, the iLCE shrinks upon heating, thus preventing any overheating-related explosions. The Li/LiFePO₄ (LFP) cells fabricated using iLCE-based solid electrolytes show excellent cycling stability with a discharge capacity of ~124 mAh g⁻¹ and a coulombic efficiency close to 100%. These results are promising for the practical application of iLCE-based SSPLBs. Full article

(This article belongs to the Special Issue Recent Advances of All-Solid-State Battery)

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14 pages, 2120 KB

Open AccessEditor’s ChoiceArticle

Design and Validation of Anode-Free Sodium-Ion Pouch Cells Employing Prussian White Cathodes

by Ashley Willow, Marcin Orzech, Sajad Kiani, Nathan Reynolds, Matthew Houchell, Olutimilehin Omisore, Zari Tehrani and Serena Margadonna

Batteries 2025, 11(3), 97; https://doi.org/10.3390/batteries11030097 - 4 Mar 2025

Cited by 1 | Viewed by 1754

Abstract

This study investigated the impact of pouch cell design on energy density, both volumetric and gravimetric, through the development of accurate 3D models of small-format (<5 Ah) pouch cells. Various configurations were analysed, considering material properties and extrapolating expected electrochemical performance from studies [...] Read more.

This study investigated the impact of pouch cell design on energy density, both volumetric and gravimetric, through the development of accurate 3D models of small-format (<5 Ah) pouch cells. Various configurations were analysed, considering material properties and extrapolating expected electrochemical performance from studies on Prussian white cathodes in coin and pouch cells. This approach allowed for a rapid assessment of several performance-influencing factors, including the number of layers in the pouch cell, cathode thickness, active material percentage, and electrolyte volume. The highest calculated energy density of small-format pouch cells was shown to be 282 Wh kg⁻¹ and 454 Wh L⁻¹, achieved in a 3 Ah, 20-layer pouch cell. The calculations were validated using sodium-ion anode-free pouch cells utilising a Prussian white cathode in single- and few-layer format pouch cells (<0.1 Ah) cycled under a low external pressure (~200 kPa). Full article

(This article belongs to the Special Issue Materials Development and Optimization for Sodium/Potassium-Ion Batteries)

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13 pages, 6626 KB

Open AccessEditor’s ChoiceArticle

Exploring the Solubility of Ethylene Carbonate in Supercritical Carbon Dioxide: A Pathway for Sustainable Electrolyte Recycling from Li-Ion Batteries

by Nils Zachmann, Claude Cicconardi and Burçak Ebin

Batteries 2025, 11(3), 98; https://doi.org/10.3390/batteries11030098 - 4 Mar 2025

Cited by 1 | Viewed by 1511

Abstract

Ethylene carbonate is, among other applications, used in Li-ion batteries as an electrolyte solvent to dissociate Li-salt. Supercritical CO₂ extraction is a promising method for the recycling of electrolyte solvents from spent batteries. To design an extraction process, knowledge of the solute [...] Read more.

Ethylene carbonate is, among other applications, used in Li-ion batteries as an electrolyte solvent to dissociate Li-salt. Supercritical CO₂ extraction is a promising method for the recycling of electrolyte solvents from spent batteries. To design an extraction process, knowledge of the solute solubility is essential. In this work, the solubility of ethylene carbonate at different pressure (80–160 bar) and temperature (40 °C, and 60 °C) conditions is studied. It is shown that the solubility of ethylene carbonate increased with pressure at both temperatures, ranging from 0.24 to 8.35 g/kg CO₂. The retrieved solubility data were fitted using the Chrastil model, and the average equilibrium association number was determined to be 4.46 and 4.02 at 40 °C and 60 °C, respectively. Scanning electron microscopy, Fourier-transform infrared spectroscopy, and X-ray diffraction analysis of the collected ethylene carbonate indicated that the crystal morphology and structure remained unchanged. A proof-of-principle experiment showed that EC can be successfully extracted from Li-ion battery waste at 140 bar and 40 °C. Full article

(This article belongs to the Special Issue Recycling and Reuse of End-of-Life Lithium-Ion Batteries: Challenges and Strategies—2nd Edition)

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41 pages, 10418 KB

Open AccessEditor’s ChoiceReview

Advancements in Vibration Testing: Effects on Thermal Performance and Degradation of Modern Batteries

by Khursheed Sabeel, Maher Al-Greer and Imran Bashir

Batteries 2025, 11(2), 82; https://doi.org/10.3390/batteries11020082 - 19 Feb 2025

Cited by 2 | Viewed by 4303

Abstract

Lithium-ion cells are increasingly being used as central power storage systems for modern applications, i.e., e-bikes, electric vehicles (EVs), satellites, and spacecraft, and they face significant and constant vibrations. This review examines how these vibrations affect the batteries’ mechanical, thermal, and electrical properties. [...] Read more.

Lithium-ion cells are increasingly being used as central power storage systems for modern applications, i.e., e-bikes, electric vehicles (EVs), satellites, and spacecraft, and they face significant and constant vibrations. This review examines how these vibrations affect the batteries’ mechanical, thermal, and electrical properties. Vibrations can cause structural issues, such as the separation of electrodes and the deformation of separators. These problems raise internal resistance and lead to localized heat generation. As a result, thermal management becomes more complicated, battery aging accelerates, and safety risks arise, including short circuits and thermal runaways. To tackle these challenges, we need more realistic testing protocols that consider the combined effects of vibrations, temperature, and mechanical stress. Improving thermal management systems (TMSs) using advanced cooling techniques and materials, e.g., phase change solutions, can help to alleviate these problems. It is also essential to design batteries with vibration-resistant materials and enhanced structural integrity to boost their durability. Moreover, vibrations play a significant role in various degradation mechanisms, including dendrite formation, self-discharge, and lithium plating, all of which can reduce battery capacity and lifespan. Our current research builds on these insights using a multiscale physics-based modeling approach to investigate how vibrations interact with thermal behavior and contribute to battery degradation. By combining computational models with experimental data, we aim to develop strategies and tools to enhance lithium-ion batteries’ safety, reliability, and longevity in challenging environments. Full article

(This article belongs to the Special Issue Advances in Lithium-Ion Battery Safety and Fire)

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75 pages, 13093 KB

Open AccessEditor’s ChoiceReview

Review on Advancements in Carbon Nanotubes: Synthesis, Purification, and Multifaceted Applications

by Anil Kumar Madikere Raghunatha Reddy, Ali Darwiche, Mogalahalli Venkatashamy Reddy and Karim Zaghib

Batteries 2025, 11(2), 71; https://doi.org/10.3390/batteries11020071 - 8 Feb 2025

Cited by 9 | Viewed by 6597

Abstract

Since their discovery over two decades ago, carbon nanotubes (CNTs) have captivated researchers due to their exceptional electrical, optical, mechanical, and thermal properties, making them versatile candidates for various advanced applications. CNTs have transformed numerous scientific domains, including nanotechnology, electronics, materials science, and [...] Read more.

Since their discovery over two decades ago, carbon nanotubes (CNTs) have captivated researchers due to their exceptional electrical, optical, mechanical, and thermal properties, making them versatile candidates for various advanced applications. CNTs have transformed numerous scientific domains, including nanotechnology, electronics, materials science, and biomedical engineering. Their applications range from nanoelectronics, robust nanocomposites, and energy storage devices to innovative materials, sensors, conducting polymers, field emission sources, and Li-ion batteries. Furthermore, CNTs have found critical roles in biosensing, water purification, bone scaffolding, and targeted gene and drug delivery. The chemical reactivity and functional versatility of CNTs are profoundly influenced by their structural and physicochemical properties, such as surface area, surface charge, size distribution, surface chemistry, and purity. This review comprehensively explores the current state of CNT research, focusing on widely used synthesis, purification, and characterization techniques alongside emerging applications. By highlighting recent advancements and addressing unresolved challenges, it aims to present a novel perspective on the transformative potential of CNTs, fostering innovation across diverse scientific and technological fields. Full article

(This article belongs to the Section Battery Materials and Interfaces: Anode, Cathode, Separators and Electrolytes or Others)

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29 pages, 20118 KB

Open AccessEditor’s ChoiceReview

Heteroatom Doping Strategy of Advanced Carbon for Alkali Metal-Ion Capacitors

by Ti Yin, Yaqin Guo, Xing Huang, Xinya Yang, Leixin Qin, Tianxiang Ning, Lei Tan, Lingjun Li and Kangyu Zou

Batteries 2025, 11(2), 69; https://doi.org/10.3390/batteries11020069 - 8 Feb 2025

Cited by 5 | Viewed by 1452

Abstract

Alkali metal-ion capacitors (AMICs) combine the advantages of the high specific energy of alkali metal-ion batteries (AMIBs) and the high power output of supercapacitors (SCs), which are considered highly promising and efficient energy storage devices. It is found that carbon has been the [...] Read more.

Alkali metal-ion capacitors (AMICs) combine the advantages of the high specific energy of alkali metal-ion batteries (AMIBs) and the high power output of supercapacitors (SCs), which are considered highly promising and efficient energy storage devices. It is found that carbon has been the most widely used electrode material of AMICs due to its advantages of low cost, a large specific surface area, and excellent electrical conductivity. However, the application of carbon is limited by its low specific capacity, finite kinetic performance, and few active sites. Doping heteroatoms in carbon materials is an effective strategy to adjust their microstructures and improve their electrochemical storage performance, which effectively helps to increase the pseudo-capacitance, enhance the wettability, and increase the ionic migration rate. Moreover, an appropriate heteroatom doping strategy can purposefully guide the design of advanced AMICs. Herein, a systematic review of advanced heteroatom (N, S, P, and B)-doped carbon, which has acted as a positrode and negatrode in AMICs (M = Li, Na, and K) in recent years, has been summarized. Moreover, emphasis is placed on the mechanism of single-element doping versus two-element doping for the enhancement in the performance of carbon positrodes and negatrodes, and an introduction to the use of doped carbon in dual-carbon alkali metal-ion capacitors (DC-AMICs) is discussed. Finally, an outlook is given to solve the problems arising when using doped carbon materials in practical applications and future development directions are presented. Full article

(This article belongs to the Special Issue Advanced Studies on High-Performance Metal-Ion Capacitors: Technologies, Systems and Applications)

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30 pages, 10158 KB

Open AccessFeature PaperEditor’s ChoiceReview

A Review of Pnictogenides for Next-Generation Anode Materials for Sodium-Ion Batteries

by Sion Ha, Junhee Kim, Dong Won Kim, Jun Min Suh and Kyeong-Ho Kim

Batteries 2025, 11(2), 54; https://doi.org/10.3390/batteries11020054 - 29 Jan 2025

Viewed by 1538

Abstract

With the growing market of secondary batteries for electric vehicles (EVs) and grid-scale energy storage systems (ESS), driven by environmental challenges, the commercialization of sodium-ion batteries (SIBs) has emerged to address the high price of lithium resources used in lithium-ion batteries (LIBs). However, [...] Read more.

With the growing market of secondary batteries for electric vehicles (EVs) and grid-scale energy storage systems (ESS), driven by environmental challenges, the commercialization of sodium-ion batteries (SIBs) has emerged to address the high price of lithium resources used in lithium-ion batteries (LIBs). However, achieving competitive energy densities of SIBs to LIBs remains challenging due to the absence of high-capacity anodes in SIBs such as the group-14 elements, Si or Ge, which are highly abundant in LIBs. This review presents potential candidates in metal pnictogenides as promising anode materials for SIBs to overcome the energy density bottleneck. The sodium-ion storage mechanisms and electrochemical performance across various compositions and intrinsic physical and chemical properties of pnictogenide have been summarized. By correlating these properties, strategic frameworks for designing advanced anode materials for next-generation SIBs were suggested. The trade-off relation in pnictogenides between the high specific capacities and the failure mechanism due to large volume expansion has been considered in this paper to address the current issues. This review covers several emerging strategies focused on improving both high reversible capacity and cycle stability. Full article

(This article belongs to the Special Issue Two-Dimensional Materials for Battery Applications)

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36 pages, 6468 KB

Open AccessEditor’s ChoiceReview

Sustainable Extraction of Critical Minerals from Waste Batteries: A Green Solvent Approach in Resource Recovery

by Afzal Ahmed Dar, Zhi Chen, Gaixia Zhang, Jinguang Hu, Karim Zaghib, Sixu Deng, Xiaolei Wang, Fariborz Haghighat, Catherine N. Mulligan, Chunjiang An, Antonio Avalos Ramirez and Shuhui Sun

Batteries 2025, 11(2), 51; https://doi.org/10.3390/batteries11020051 - 28 Jan 2025

Cited by 5 | Viewed by 4695

Abstract

This strategic review examines the pivotal role of sustainable methodologies in battery recycling and the recovery of critical minerals from waste batteries, emphasizing the need to address existing technical and environmental challenges. Through a systematic analysis, it explores the application of green organic [...] Read more.

This strategic review examines the pivotal role of sustainable methodologies in battery recycling and the recovery of critical minerals from waste batteries, emphasizing the need to address existing technical and environmental challenges. Through a systematic analysis, it explores the application of green organic solvents in mineral processing, advocating for establishing eco-friendly techniques aimed at clipping waste and boosting resource utilization. The escalating demand for and shortage of essential minerals including copper, cobalt, lithium, and nickel are comprehensively analyzed and forecasted for 2023, 2030, and 2040. Traditional extraction techniques, including hydrometallurgical, pyrometallurgical, and bio-metallurgical processes, are efficient but pose substantial environmental hazards and contribute to resource scarcity. The concept of green extraction arises as a crucial step towards ecological conservation, integrating sustainable practices to lessen the environmental footprint of mineral extraction. The advancement of green organic solvents, notably ionic liquids and deep eutectic solvents, is examined, highlighting their attributes of minimal toxicity, biodegradability, and superior efficacy, thus presenting great potential in transforming the sector. The emergence of organic solvents such as palm oil, 1-octanol, and Span 80 is recognized, with advantageous low solubility and adaptability to varying temperatures. Kinetic (mainly temperature) data of different deep eutectic solvents are extracted from previous studies and computed with machine learning techniques. The coefficient of determination and mean squared error reveal the accuracy of experimental and computed data. In essence, this study seeks to inspire ongoing efforts to navigate impediments, embrace technological advancements including artificial intelligence, and foster an ethos of environmental stewardship in the sustainable extraction and recycling of critical metals from waste batteries. Full article

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26 pages, 4828 KB

Open AccessFeature PaperEditor’s ChoiceArticle

Temperature-Dependent FTIRS Study of Manganese Oxide Spinel Obtained by Solution Combustion Synthesis (SCS) for Supercapacitor Applications

by Taylan Karakoç, Sécou Sall and Sergey N. Pronkin

Batteries 2025, 11(2), 39; https://doi.org/10.3390/batteries11020039 - 21 Jan 2025

Cited by 2 | Viewed by 1305

Abstract

Solution combustion synthesis (SCS) is often utilized to prepare crystalline nanoparticles of transition metal oxides, in particular Mn oxides. The structure and composition of the final product depend on the conditions of the synthesis, in particular on the composition of metal precursors, its [...] Read more.

Solution combustion synthesis (SCS) is often utilized to prepare crystalline nanoparticles of transition metal oxides, in particular Mn oxides. The structure and composition of the final product depend on the conditions of the synthesis, in particular on the composition of metal precursors, its molar ratio to the fuel component, and the mode of heating. In the present work, the study of chemical phenomena that may occur in the SCS process has been studied for the conventional nitrate–glycine synthesis of Mn oxide, as well as for nitrate–citrate–glycine and nitrate–citrate–urea synthesis. In the case of nitrate–glycine synthesis at a 1:1 fuel-to-salt ratio, the formation of a weak complex of Mn(II) and glycine provides the conditions for an instantaneous SCS reaction upon heating, resulting in slight sintering of final oxide nanoparticles. Partial hydrolysis of the Mn precursor during slow solvent evaporation results in the formation of a mixture of oxides, namely MnO and Mn₃O₄. Formation of MnO is completely suppressed when ammonium citrate is added into the initial mixture. Pure Mn₂O₃ oxide is obtained from nitrate–citrate synthesis, while the pure Mn₃O₄ phase is obtained in the case of nitrate–citrate–glycine and nitrate–citrate–urea synthesis, due to the higher temperature generated in the presence of additional fuel. In the presence of citrate, the SCS reaction is slower, resulting in stronger sintering of the nanoparticles. The study of the electrochemical properties of synthesized oxides demonstrates that SCS with the nitrate–citrate–urea mixture provides the highest charge capacitance in 1 M NaOH: 130 F/g at 2 A/g. The impedance characterization of materials allows us to propose a tentative mechanism of degradation of electrode materials during galvanostatic cycling. Full article

(This article belongs to the Special Issue High Energy Density Supercapacitors: Acquisition, Characterization, and Application)

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15 pages, 3713 KB

Open AccessEditor’s ChoiceArticle

Analysis of Aging and Degradation in Lithium Batteries Using Distribution of Relaxation Time

by Muhammad Sohaib, Abdul Shakoor Akram and Woojin Choi

Batteries 2025, 11(1), 34; https://doi.org/10.3390/batteries11010034 - 19 Jan 2025

Cited by 2 | Viewed by 3650

Abstract

In this paper, the deconvolution of Electrochemical Impedance Spectroscopy (EIS) data into the Distribution of Relaxation Times (DRTs) is employed to provide a detailed examination of degradation mechanisms in lithium-ion batteries. Using an nth RC model with Gaussian functions, this study achieves enhanced [...] Read more.

In this paper, the deconvolution of Electrochemical Impedance Spectroscopy (EIS) data into the Distribution of Relaxation Times (DRTs) is employed to provide a detailed examination of degradation mechanisms in lithium-ion batteries. Using an nth RC model with Gaussian functions, this study achieves enhanced separation of overlapping electrochemical processes where Gaussian functions yield smoother transitions and clearer peak identification than conventional piecewise linear functions. The advantages of employing Tikhonov Regularization (TR) with Gaussian functions over Maximum Entropy (ME) and FFT methods are highlighted as this approach provides superior noise resilience, unbiased analysis, and enhanced resolution of critical features. This approach is applied to LIB cell data to identify characteristic peaks of the DRT plot and evaluate their correlation with battery degradation. By observing how these peaks evolve through cycles of battery aging, insights into specific aging mechanisms and performance decline are obtained. This study combines experimental measurements with DRT peak analysis to characterize the impedance distribution within LIBs which enables accelerated detection of degradation pathways and enhances the predictive accuracy for battery life and reliability. This analysis contributes to a refined understanding of LIB degradation behavior, supporting the development of advanced battery management systems designed to improve safety, optimize battery performance, and extend the operational lifespan of LIBs for various applications. Full article

(This article belongs to the Special Issue Battery Management in Electric Vehicles: Current Status and Future Trends: 2nd Edition)

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20 pages, 6706 KB

Open AccessEditor’s ChoiceArticle

On the Performance of Portable NiMH Batteries of General Use

by Diego F. Quintero Pulido, Catalin Felix Covrig and Matthias Bruchhausen

Batteries 2025, 11(1), 30; https://doi.org/10.3390/batteries11010030 - 16 Jan 2025

Cited by 2 | Viewed by 2804

Abstract

NiMH batteries are the most used technology of rechargeable batteries sold directly to consumers. Herein, we study the performance of the most common sizes of portable NiMH batteries (AA, AAA, D, C, and 9V). The performance and durability parameters—capacity, charge retention, charge recovery, [...] Read more.

NiMH batteries are the most used technology of rechargeable batteries sold directly to consumers. Herein, we study the performance of the most common sizes of portable NiMH batteries (AA, AAA, D, C, and 9V). The performance and durability parameters—capacity, charge retention, charge recovery, and endurance in cycles—are measured for these types of batteries, according to the standard IEC 61951-2:2017 NiMH batteries. The purpose of this study is to create a basis for setting minimum performance requirements for the parameters in the European Regulation concerning batteries and waste batteries, EU 2023/1542, Annex III, Part B. Results show that the charging time of 16 h could be reduced to 8 h for verifying the rated capacity. The performance of commercial batteries with regard to charge retention, charge recovery, and endurance in cycles is often found to be 25–30% better than required in the relevant IEC standard. Furthermore, we present a short comparative analysis of an application test (IEC 60086-2:2021 “toy”) for portable NiMH batteries with primary batteries. Such data allow comparing the performance of portable NiMH batteries compared to primary batteries in the application test “toy”. Full article

(This article belongs to the Section Battery Performance, Ageing, Reliability and Safety)

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15 pages, 4641 KB

Open AccessEditor’s ChoiceArticle

Investigation of the Suitability of the DTV Method for the Online SoH Estimation of NMC Lithium-Ion Cells in Battery Management Systems

by Jan Neunzling, Philipp Hainke, Hanno Winter, David Henriques, Matthias Fleckenstein and Torsten Markus

Batteries 2025, 11(1), 25; https://doi.org/10.3390/batteries11010025 - 13 Jan 2025

Cited by 2 | Viewed by 1372

Abstract

Investigating the temperature behavior of lithium-ion battery cells has become an important part of today’s research and development. The main reason for this is that the temperature profile of a battery cell changes during aging. By using Differential Thermal Voltammetry (DTV), new possibilities [...] Read more.

Investigating the temperature behavior of lithium-ion battery cells has become an important part of today’s research and development. The main reason for this is that the temperature profile of a battery cell changes during aging. By using Differential Thermal Voltammetry (DTV), new possibilities are opened up, especially since this diagnostic method is designed to work in operando by only requiring voltage and temperature readings. In this study, a batch of NMC-21700 cells were aged in calendar and cyclic manners. After a specified aging cycle was complete, a check-up measurement was performed. During this time, the cycler collected the electrical measuring values, while a negative temperature coefficient thermistor, which was located on the cell, was used to record the temperature fluctuations. The data were then evaluated by using the DTV analysis technique. By comparing the characteristic points of DTV, correlations between the changing curve characteristics and the capacity loss, and therefore the aging of the respective cell, were established. Based on these results, a simple model suitable for online State of Health (SoH) is derived and validated, showing an estimation accuracy of

1.1

%. Full article

(This article belongs to the Section Battery Performance, Ageing, Reliability and Safety)

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23 pages, 10391 KB

Open AccessEditor’s ChoiceArticle

Research on the Thermal Runaway Behavior and Flammability Limits of Sodium-Ion and Lithium-Ion Batteries

by Changbao Qi, Hewu Wang, Minghai Li, Cheng Li, Yalun Li, Chao Shi, Ningning Wei, Yan Wang and Huipeng Zhang

Batteries 2025, 11(1), 24; https://doi.org/10.3390/batteries11010024 - 12 Jan 2025

Cited by 7 | Viewed by 4753

Abstract

Batteries are widely used in energy storage systems (ESS), and thermal runaway in different types of batteries presents varying safety risks. Therefore, comparative research on the thermal runaway behaviors of various batteries is essential. This study investigates the thermal runaway characteristics of sodium-ion [...] Read more.

Batteries are widely used in energy storage systems (ESS), and thermal runaway in different types of batteries presents varying safety risks. Therefore, comparative research on the thermal runaway behaviors of various batteries is essential. This study investigates the thermal runaway characteristics of sodium-ion batteries (NIBs), lithium iron phosphate batteries (LFP), and lithium-ion batteries with NCM523 and NCM622 cathodes. The experiments were conducted in a nitrogen-filled constant-volume sealed chamber. The results show that the critical surface temperatures at the time of thermal runaway are as follows: LFP (346 °C) > NIBs (292 °C) > NCM523 (290 °C) > NCM622 (281 °C), with LFP batteries exhibiting the highest thermal runaway critical temperature. NIBs have the lowest thermal runaway triggering energy (158 kJ), while LFP has the highest (592.8 kJ). During the thermal runaway of all four battery types, the primary gases produced include carbon dioxide, hydrogen, carbon monoxide, methane, ethylene, propylene, and ethane. For NCM622 and NCM523, carbon monoxide is the dominant combustible gas, with volume fractions of 35% and 29%, respectively. In contrast, hydrogen is the main flammable gas for LFP and NIBs, with volume fractions of 44% and 30%, respectively. Among these, NIBs have the lowest lower flammability limit (LFL), indicating the highest explosion risk. The thermal runaway characteristics of 50 Ah batteries provide valuable insights for battery selection and design in energy storage applications. Full article

(This article belongs to the Special Issue Thermal Safety of Lithium Ion Batteries—2nd Edition)

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16 pages, 5055 KB

Open AccessEditor’s ChoiceArticle

A Millimeter-Resolution Operando Thermal Image of Prismatic Li-Ion Batteries Using a Distributed Optical Fiber Sensor

by Zhen Guo, Mina Abedi Varnosfaderani, Calum Briggs, Erdogan Guk and James Marco

Batteries 2025, 11(1), 19; https://doi.org/10.3390/batteries11010019 - 8 Jan 2025

Cited by 1 | Viewed by 1597

Abstract

With the demand for energy gravimetric and volumetric density in electrical vehicles, lithium-ion batteries are undergoing a trend toward larger formats, along with maximized cell-to-pack efficiency. Current battery thermal management systems and battery modeling, relying on point measurement (thermocouples/thermistors), face challenges in providing [...] Read more.

With the demand for energy gravimetric and volumetric density in electrical vehicles, lithium-ion batteries are undergoing a trend toward larger formats, along with maximized cell-to-pack efficiency. Current battery thermal management systems and battery modeling, relying on point measurement (thermocouples/thermistors), face challenges in providing comprehensive characterization for larger batteries and extensive monitoring across the pack. Here, we proposed a novel Rayleigh-scattering-based distributed optical fiber sensor to deliver thermal images of a large prismatic cell. Using an optical fiber of 1 mm diameter wrapped around the cell, the optical sensor delivered over 400 unique measurement locations at 3 mm spatial resolution. During a 1.0 C charge, the optical-measured maximum temperature difference was 8.2 °C, while point-like thermocouples, located at the cell front surface and rear surface center, only had a 0.8 °C maximum temperature difference. Moreover, the all-surface-covered optical sensor identified hotspot generation around the vicinity of the tabs, highlighting the essential role of tabs. The maximum temperature on the negative current tab reached 113.9 °C during a 1.5 C discharge, while the hottest spot on the cell surface was only 52.1 °C. This was further validated by the operando thermal image in both the time domain and the spatial domain, facilitating a detailed analysis of the thermal-behavior-like heat generation on the current tabs, transmission through the surface, and dissipation to the cell bottom. Full article

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11 pages, 2117 KB

Open AccessFeature PaperEditor’s ChoiceReview

Recycling of Lithium-Ion Batteries via Electrochemical Recovery: A Mini-Review

by Lu Yu, Yaocai Bai and Ilias Belharouak

Batteries 2024, 10(10), 337; https://doi.org/10.3390/batteries10100337 - 24 Sep 2024

Cited by 12 | Viewed by 7272

Abstract

With the rising demand for lithium-ion batteries (LIBs), it is crucial to develop recycling methods that minimize environmental impacts and ensure resource sustainability. The focus of this short review is on the electrochemical techniques used in LIB recycling, particularly electrochemical leaching and electrodeposition. [...] Read more.

With the rising demand for lithium-ion batteries (LIBs), it is crucial to develop recycling methods that minimize environmental impacts and ensure resource sustainability. The focus of this short review is on the electrochemical techniques used in LIB recycling, particularly electrochemical leaching and electrodeposition. Our summary covers the latest research, highlighting the principles, progress, and challenges tied to these methods. By examining the current state of electrochemical recovery, this review intends to provide guidance for future advancements and enhance LIB recycling efficiency. Full article

(This article belongs to the Special Issue Lithium-Ion Battery Recycling)

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17 pages, 4493 KB

Open AccessEditor’s ChoiceArticle

Improving Lithium-Ion Battery Performance: Nano Al₂O₃ Coatings on High-Mass Loading LiFePO₄ Cathodes via Atomic Layer Deposition

by Pejman Salimi, Gloria Gottardi, William G. Morais, Ruben Bartali, Nadhira Laidani and Edoardo Gino Macchi

Batteries 2024, 10(9), 304; https://doi.org/10.3390/batteries10090304 - 28 Aug 2024

Cited by 8 | Viewed by 4893

Abstract

Lithium iron phosphate (LiFePO₄ or LFP) is a promising cathode material for lithium-ion batteries (LIBs), but side reactions between the electrolyte and the LFP electrode can degrade battery performance. This study introduces an innovative coating strategy, using atomic layer deposition (ALD) to [...] Read more.

Lithium iron phosphate (LiFePO₄ or LFP) is a promising cathode material for lithium-ion batteries (LIBs), but side reactions between the electrolyte and the LFP electrode can degrade battery performance. This study introduces an innovative coating strategy, using atomic layer deposition (ALD) to apply a thin (5 nm and 10 nm) Al₂O₃ layer onto high-mass loading LFP electrodes. Galvanostatic charge–discharge cycling and electrochemical impedance spectroscopy (EIS) were used to assess the electrochemical performance of coated and uncoated LFP electrodes. The results show that Al₂O₃ coatings enhance the cycling performance at room temperature (RT) and 40 °C by suppressing side reactions and stabilizing the cathode–electrolyte interface (CEI). The coated LFP retained 67% of its capacity after 100 cycles at 1C and RT, compared to 57% for the uncoated sample. Post-mortem analyses, including scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), were conducted to investigate the mechanisms behind the improved performance. These analyses reveal that Al₂O₃ coatings are highly effective in reducing LFP electrode degradation during cycling, demonstrating the potential of ALD Al₂O₃ coatings to enhance the durability and performance of LFP electrodes in LIBs. Full article

(This article belongs to the Special Issue Processes and Advances in Electrode Materials for Lithium-Ion Batteries)

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15 pages, 4783 KB

Open AccessEditor’s ChoiceArticle

Anion Intercalation/De-Intercalation Mechanism Enabling High Energy and Power Densities of Lithium-Ion Capacitors

by Yang Zhang, Junquan Lao and Ping Xiao

Batteries 2024, 10(9), 296; https://doi.org/10.3390/batteries10090296 - 23 Aug 2024

Cited by 1 | Viewed by 2096

Abstract

The growing demands for electrochemical energy storage systems is driving the exploration of novel devices, with lithium-ion capacitors (LICs) emerging as a promising strategy to achieve both high energy density and fast charge capability. However, the low capacitance of commercial activated carbon (AC) [...] Read more.

The growing demands for electrochemical energy storage systems is driving the exploration of novel devices, with lithium-ion capacitors (LICs) emerging as a promising strategy to achieve both high energy density and fast charge capability. However, the low capacitance of commercial activated carbon (AC) cathode based on anion absorption/desorption limits LIC applications. Herein, commercial graphite is proposed as the cathode to construct an innovative AC (−)//graphite (+) system. The graphite cathode functions as anion hosting, allowing reversible intercalation/de-intercalation of anions into/from its interlayers. The as-designed AC (−)//graphite (+) full cell achieves stable cycling with 90.6% capacity retention after 200 cycles at 0.1 A g⁻¹ and a prolonged lifespan with 87.5% capacity retention after 5000 cycles at 0.5 A g⁻¹ with the upper cut-off voltage of 5.0 V, yielding a high average Coulombic efficiency (CE) of 99.3%. Moreover, the full cell exhibits a high energy density (>200 Wh kg⁻¹) and power density of 7.7 kW kg⁻¹ (calculated based on active mass in both electrodes). These performances exceed most LICs based on anions absorption/desorption on the surface of AC cathodes. This work explores an effective electrode revolution with the assistance of anion intercalation/de-intercalation chemistry for developing novel LICs with high energy and power densities. Full article

(This article belongs to the Special Issue Advanced Studies on High-Performance Metal-Ion Capacitors: Technologies, Systems and Applications)

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18 pages, 18755 KB

Open AccessEditor’s ChoiceArticle

Experimental Study on Thermal Runaway Characteristics of High-Nickel Ternary Lithium-Ion Batteries under Normal and Low Pressures

by Ye Jin, Di Meng, Chen-Xi Zhao, Jia-Ling Yu, Xue-Hui Wang and Jian Wang

Batteries 2024, 10(8), 287; https://doi.org/10.3390/batteries10080287 - 12 Aug 2024

Cited by 4 | Viewed by 2768

Abstract

High-nickel (Ni) ternary lithium-ion batteries (LIBs) are widely used in low-pressure environments such as in the aviation industry, but their attribute of high energy density poses significant fire hazards, especially under low pressure where thermal runaway behavior is complex, thus requiring relevant experiments. [...] Read more.

High-nickel (Ni) ternary lithium-ion batteries (LIBs) are widely used in low-pressure environments such as in the aviation industry, but their attribute of high energy density poses significant fire hazards, especially under low pressure where thermal runaway behavior is complex, thus requiring relevant experiments. This study investigates the thermal runaway characteristics of LiNi_0.8Mn_0.1Co_0.1O₂ (NCM811) 18650 LIBs at different states of charge (SOCs) (75%, 100%) under various ambient pressures (101 kPa, 80 kPa, 60 kPa, 40 kPa). The results show that, as the pressure is decreased from 101 kPa to 40 kPa, the onset time of thermal runaway is extended by 28.2 s for 75% SOC and by 40.8 s for 100% SOC; accordingly, the onset temperature of thermal runaway increases by 19.3 °C for 75% SOC and by 33.5 °C for 100% SOC; the maximum surface temperature decreases by 70.8 °C for 75% SOC and by 68.2 °C for 100% SOC. The cell mass loss and loss rate slightly decrease with reduced pressure. However, ambient pressure has little impact on the time and temperature of venting as well as the voltage drop time. SEM/EDS analysis verifies that electrolyte evaporates faster under low pressure. Furthermore, the oxygen concentration is lower under low pressure, which consequently leads to a delay in thermal runaway. This study contributes to understanding thermal runaway characteristics of high-Ni ternary LIBs and provides guidance for their safe application in low-pressure aviation environments. Full article

(This article belongs to the Special Issue Advances in Lithium-Ion Battery Safety and Fire)

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21 pages, 5171 KB

Open AccessEditor’s ChoiceArticle

Sustainable Battery Lifecycle: Non-Destructive Separation of Batteries and Potential Second Life Applications

by Gernot Schlögl, Stefan Grollitsch, Christian Ellersdorfer, Florian Feist, Christoph Kirschner, Josef Ecker and Franz Haas

Batteries 2024, 10(8), 280; https://doi.org/10.3390/batteries10080280 - 5 Aug 2024

Cited by 4 | Viewed by 3587

Abstract

Large quantities of battery systems will be discarded from electric vehicles in the future. Non-destructive separation of used electric vehicle (EV) traction batteries enables a second life of battery components, extraction of high value secondary materials, and reduces the environmental footprint of recycling [...] Read more.

Large quantities of battery systems will be discarded from electric vehicles in the future. Non-destructive separation of used electric vehicle (EV) traction batteries enables a second life of battery components, extraction of high value secondary materials, and reduces the environmental footprint of recycling and separation processes. In this study, the key performance indicators (KPIs) for the second life application of spent EV batteries are identified. Three battery packs are analyzed in terms of the joining techniques used—and possible separation techniques—considering only direct recycling methods. The components that can be recovered from these batteries are evaluated against the KPIs. This study shows that all the batteries analyzed allow a second life in stationary and semi-stationary electrical storage systems and marine applications when used at the pack and module levels. Two packs can be reused in electric vehicles such as forklifts. However, the feasibility of re-use in micro-mobility and consumer electronics is very limited. This study shows that technically feasible separation methods are dictated and constrained by the joining techniques used. As welding and adhesive bonding pose challenges to separation processes, future efforts should prioritize ‘design for disassembly’ to ensure sustainable battery life cycle management. Full article

(This article belongs to the Special Issue Sustainable Materials and Recycling Processes for Battery Production)

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38 pages, 9849 KB

Open AccessEditor’s ChoiceReview

Binders for Li-Ion Battery Technologies and Beyond: A Comprehensive Review

by Muskan Srivastava, Anil Kumar M. R. and Karim Zaghib

Batteries 2024, 10(8), 268; https://doi.org/10.3390/batteries10080268 - 26 Jul 2024

Cited by 19 | Viewed by 18476

Abstract

The effects of global warming highlight the urgent need for effective solutions to this problem. The electrification of society, which occurs through the widespread adoption of electric vehicles (EVs), is a critical strategy to combat climate change. Lithium-ion batteries (LIBs) are vital components [...] Read more.

The effects of global warming highlight the urgent need for effective solutions to this problem. The electrification of society, which occurs through the widespread adoption of electric vehicles (EVs), is a critical strategy to combat climate change. Lithium-ion batteries (LIBs) are vital components of the global energy-storage market for EVs, and sodium-ion batteries (SIBs) have gained renewed interest owing to their potential for rapid growth. Improved safety and stability have also put solid-state batteries (SSBs) on the chart of top batteries in the world. This review examines three critical battery technologies: LIBs, SIBs, and SSBs. Although research has historically concentrated on heavier battery components, such as electrodes, to achieve high gravimetric density, binders, which comprise less than 5% of the battery weight, have demonstrated great promise for meeting the increasing need for energy storage. This review thoroughly examines various binders, focusing on their solubilities in water and organic solvents. Understanding binder mechanisms is crucial for developing binders that maintain strong adhesion to electrodes, even during volume fluctuations caused by lithiation and delithiation. Therefore, we investigated the different mechanisms associated with binders. This review also discusses failure mechanisms and innovative design strategies to improve the performance of binders, such as composite, conductive, and self-healing binders. By investigating these fields, we hope to develop energy storage technologies that are more dependable and efficient while also helping to satisfy future energy needs. Full article

(This article belongs to the Section Battery Materials and Interfaces: Anode, Cathode, Separators and Electrolytes or Others)

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36 pages, 3484 KB

Open AccessEditor’s ChoiceReview

Environmental Aspects and Recycling of Solid-State Batteries: A Comprehensive Review

by Abniel Machín, María C. Cotto, Francisco Díaz, José Duconge, Carmen Morant and Francisco Márquez

Batteries 2024, 10(7), 255; https://doi.org/10.3390/batteries10070255 - 17 Jul 2024

Cited by 15 | Viewed by 11827

Abstract

Solid-state batteries (SSBs) have emerged as a promising alternative to conventional lithium-ion batteries, with notable advantages in safety, energy density, and longevity, yet the environmental implications of their life cycle, from manufacturing to disposal, remain a critical concern. This review examines the environmental [...] Read more.

Solid-state batteries (SSBs) have emerged as a promising alternative to conventional lithium-ion batteries, with notable advantages in safety, energy density, and longevity, yet the environmental implications of their life cycle, from manufacturing to disposal, remain a critical concern. This review examines the environmental impacts associated with the production, use, and end-of-life management of SSBs, starting with the extraction and processing of raw materials, and highlights significant natural resource consumption, energy use, and emissions. A comparative analysis with traditional battery manufacturing underscores the environmental hazards of novel materials specific to SSBs. The review also assesses the operational environmental impact of SSBs by evaluating their energy efficiency and carbon footprint in comparison to conventional batteries, followed by an exploration of end-of-life challenges, including disposal risks, regulatory frameworks, and the shortcomings of existing waste management practices. A significant focus is placed on recycling and reuse strategies, reviewing current methodologies like mechanical, pyrometallurgical, and hydrometallurgical processes, along with emerging technologies that aim to overcome recycling barriers, while also analyzing the economic and technological challenges of these processes. Additionally, real-world case studies are presented, serving as benchmarks for best practices and highlighting lessons learned in the field. In conclusion, the paper identifies research gaps and future directions for reducing the environmental footprint of SSBs, underscoring the need for interdisciplinary collaboration to advance sustainable SSB technologies and contribute to balancing technological advancements with environmental stewardship, thereby supporting the transition to a more sustainable energy future. Full article

(This article belongs to the Section Battery Processing, Manufacturing and Recycling)

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14 pages, 4677 KB

Open AccessEditor’s ChoiceArticle

Development of Printed Pouch Film and Flexible Battery

by Gyeongseok Oh, Snigdha Paramita Mantry, Jae Ho Sim, Hyeon Woo Cho, Mijin Won, Hwamok Park, Jiyoung Park, Juhwan Lee and Dong Soo Kim

Batteries 2024, 10(7), 244; https://doi.org/10.3390/batteries10070244 - 8 Jul 2024

Viewed by 2574

Abstract

This study investigates the properties of various adhesives and assesses the effects of the coating and drying conditions of aluminum surface treatment agents on adhesion strength and chemical resistance. The adhesion between aluminum and the polymer film is improved through the application of [...] Read more.

This study investigates the properties of various adhesives and assesses the effects of the coating and drying conditions of aluminum surface treatment agents on adhesion strength and chemical resistance. The adhesion between aluminum and the polymer film is improved through the application of a surface treatment agent to the aluminum surface. This study examines the initial adhesive strength of a manufactured pouch film with respect to the drying temperature and time and evaluates its adhesive strength in the presence of moisture. The results indicate that the residual moisture on the aluminum surface weakens the adhesive strength and significantly affects electrolyte resistance. A noticeable reduction in strength was observed after water spraying, when the drying temperature and time were relatively low during the initial strength measurement. Among the adhesives used for aluminum and CPP lamination, olefin adhesives exhibit less susceptibility to electrolyte effects and have higher adhesive strengths compared to urethane and ester adhesives. Leveraging these characteristics, flexible pouch cells were manufactured and their stability was evaluated. The results confirm that the flexible cells demonstrate excellent stability, exhibiting potential for application in wearable devices. Full article

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16 pages, 3731 KB

Open AccessFeature PaperEditor’s ChoiceArticle

Experimental Investigation on Thermal Runaway of Lithium-Ion Batteries under Low Pressure and Low Temperature

by Di Meng, Jingwen Weng and Jian Wang

Batteries 2024, 10(7), 243; https://doi.org/10.3390/batteries10070243 - 6 Jul 2024

Cited by 9 | Viewed by 4424

Abstract

Understanding the thermal runaway mechanism of lithium-ion batteries under low pressure and low temperature is paramount for their application and transportation in the aviation industry. This work investigated the coupling effects of ambient pressure (100 kPa, 70 kPa, 40 kPa) and ambient temperature [...] Read more.

Understanding the thermal runaway mechanism of lithium-ion batteries under low pressure and low temperature is paramount for their application and transportation in the aviation industry. This work investigated the coupling effects of ambient pressure (100 kPa, 70 kPa, 40 kPa) and ambient temperature (−15 °C, 0 °C, 25 °C) on thermal behaviors in an altitude temperature chamber. The experimental results indicate that lowering ambient pressure and temperature could attenuate the thermal runaway intensity, which is mainly attributable to the reduction in oxygen concentration and the increase in heat loss. Such a dual effect leads to the maximum temperature decreasing from 811.9 °C to 667.5 °C, and the maximum temperature rate declines up to 2.6 times. Correspondingly, the whole thermal runaway process is deferred, the total time increases from 370 s to 503 s, and the time interval, Δt, from safety venting gains by 32.3% as the ambient pressure and temperature decrease. This work delivers an in-depth understanding of the thermal characteristics under low pressure and low temperature and provides meritorious guidance for the safety of cell transportation in aviation. Full article

(This article belongs to the Section Battery Performance, Ageing, Reliability and Safety)

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12 pages, 4328 KB

Open AccessFeature PaperEditor’s ChoiceArticle

A Novel Reaction Rate Parametrization Method for Lithium-Ion Battery Electrochemical Modelling

by Alain Goussian, Loïc Assaud, Issam Baghdadi, Cédric Nouillant and Sylvain Franger

Batteries 2024, 10(6), 205; https://doi.org/10.3390/batteries10060205 - 14 Jun 2024

Cited by 3 | Viewed by 2430

Abstract

To meet the ever-growing worldwide electric vehicle demand, the development of advanced generations of lithium-ion batteries is required. To this end, modelling is one of the pillars for the innovation process. However, modelling batteries containing a large number of different mechanisms occurring at [...] Read more.

To meet the ever-growing worldwide electric vehicle demand, the development of advanced generations of lithium-ion batteries is required. To this end, modelling is one of the pillars for the innovation process. However, modelling batteries containing a large number of different mechanisms occurring at different scales remains a field of research that does not provide consensus for each particular model or approach. Parametrization as part of the modelling process appears to be one of the issues when it comes to building a high-fidelity model of a target cell. In this paper, a particular parameter identification is therefore discussed. Indeed, even if Butler–Volmer is a well-known equation in the electrochemistry field, identification of its reaction rate constant or exchange current density parameters is lacking in the literature. Thus, we discuss the process described in the literature and propose a new protocol that expects to overcome certain difficulties whereas the hypothesis of calculation and measurement maintains high sensitivity. Full article

(This article belongs to the Special Issue Modeling, Reliability and Health Management of Lithium-Ion Batteries)

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13 pages, 6231 KB

Open AccessEditor’s ChoiceArticle

Quantitative Analysis of Lithium-Ion Battery Eruption Behavior in Thermal Runaway

by Yu Xing, Ningning Wei and Minghai Li

Batteries 2024, 10(6), 182; https://doi.org/10.3390/batteries10060182 - 26 May 2024

Viewed by 2361

Abstract

With the widespread adoption of battery technology in electric vehicles, there has been significant attention drawn to the increasing frequency of battery fire incidents. However, the jetting behavior and expansion force during the thermal runaway (TR) of batteries represent highly dynamic phenomena, which [...] Read more.

With the widespread adoption of battery technology in electric vehicles, there has been significant attention drawn to the increasing frequency of battery fire incidents. However, the jetting behavior and expansion force during the thermal runaway (TR) of batteries represent highly dynamic phenomena, which lack comprehensive quantitative description. This study addresses this gap by employing an enhanced experimental setup that synchronizes the video timing of cameras with a signal acquisition system, enabling the multidimensional quantification of signals, such as images, temperature, voltage, and pressure. It also provides a detailed description of the jetting behavior and expansion force characteristics over time for Li(Ni_0.8Co_0.1Mn_0.1)O₂ batteries undergoing thermal runaway in an open environment. The results from three experiments effectively identify key temporal features, including the timing of the initial jetting spark, maximum jetting velocity, jetting duration, explosion duration, and patterns of flame volume variation. This quantitative analytical approach proves effective across various battery types and conditions. The findings could offer scientific foundations and experimental strategies for parameter identification in fire prevention and thermal runaway model development. Full article

(This article belongs to the Special Issue Battery Thermal Performance and Management: Advances and Challenges)

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21 pages, 2358 KB

Open AccessFeature PaperEditor’s ChoiceReview

Useful Quantities and Diagram Types for Diagnosis and Monitoring of Electrochemical Energy Converters Using Impedance Spectroscopy: State of the Art, Review and Outlook

by Peter Kurzweil, Wolfgang Scheuerpflug, Christian Schell and Josef Schottenbauer

Batteries 2024, 10(6), 177; https://doi.org/10.3390/batteries10060177 - 24 May 2024

Cited by 4 | Viewed by 1911

Abstract

The concept of pseudocapacitance is explored as a rapid and universal method for the state of health (SOH) determination of batteries and supercapacitors. In contrast to this, the state of the art considers the degradation of a series of full charge/discharge cycles. Lithium-ion [...] Read more.

The concept of pseudocapacitance is explored as a rapid and universal method for the state of health (SOH) determination of batteries and supercapacitors. In contrast to this, the state of the art considers the degradation of a series of full charge/discharge cycles. Lithium-ion batteries, sodium-ion batteries and supercapacitors of different cell chemistries are studied by impedance spectroscopy during lifetime testing. Faradaic and capacitive charge storage are distinguished by the relationship between the stored electric charge and capacitance. Batteries with a flat voltage–charge curve are best suited for impedance spectroscopy. There is a slight loss in the linear correlation between the pseudocapacitance and Ah capacity in regions of overcharge and deep discharge. The correct calculation of quantities related to complex impedance and differential capacitance is outlined, which may also be useful as an introductory text and tutorial for newcomers to the field. Novel diagram types are proposed for the purpose of the instant performance and failure diagnosis of batteries and supercapacitors. Full article

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51 pages, 24057 KB

Open AccessEditor’s ChoiceArticle

Biomass-Derived Carbon Materials for Advanced Metal-Ion Hybrid Supercapacitors: A Step Towards More Sustainable Energy

by Syed Shaheen Shah

Batteries 2024, 10(5), 168; https://doi.org/10.3390/batteries10050168 - 20 May 2024

Cited by 25 | Viewed by 5967

Abstract

Modern research has made the search for high-performance, sustainable, and efficient energy storage technologies a main focus, especially in light of the growing environmental and energy-demanding issues. This review paper focuses on the pivotal role of biomass-derived carbon (BDC) materials in the development [...] Read more.

Modern research has made the search for high-performance, sustainable, and efficient energy storage technologies a main focus, especially in light of the growing environmental and energy-demanding issues. This review paper focuses on the pivotal role of biomass-derived carbon (BDC) materials in the development of high-performance metal-ion hybrid supercapacitors (MIHSCs), specifically targeting sodium (Na)-, potassium (K)-, aluminium (Al)-, and zinc (Zn)-ion-based systems. Due to their widespread availability, renewable nature, and exceptional physicochemical properties, BDC materials are ideal for supercapacitor electrodes, which perfectly balance environmental sustainability and technological advancement. This paper delves into the synthesis, functionalization, and structural engineering of advanced biomass-based carbon materials, highlighting the strategies to enhance their electrochemical performance. It elaborates on the unique characteristics of these carbons, such as high specific surface area, tuneable porosity, and heteroatom doping, which are pivotal in achieving superior capacitance, energy density, and cycling stability in Na-, K-, Al-, and Zn-ion hybrid supercapacitors. Furthermore, the compatibility of BDCs with metal-ion electrolytes and their role in facilitating ion transport and charge storage mechanisms are critically analysed. Novelty arises from a comprehensive comparison of these carbon materials across metal-ion systems, unveiling the synergistic effects of BDCs’ structural attributes on the performance of each supercapacitor type. This review also casts light on the current challenges, such as scalability, cost-effectiveness, and performance consistency, offering insightful perspectives for future research. This review underscores the transformative potential of BDC materials in MIHSCs and paves the way for next-generation energy storage technologies that are both high-performing and ecologically friendly. It calls for continued innovation and interdisciplinary collaboration to explore these sustainable materials, thereby contributing to advancing green energy technologies. Full article

(This article belongs to the Special Issue Advanced Studies on High-Performance Metal-Ion Capacitors: Technologies, Systems and Applications)

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39 pages, 9443 KB

Open AccessEditor’s ChoiceReview

Empowering Electric Vehicles Batteries: A Comprehensive Look at the Application and Challenges of Second-Life Batteries

by Seyedreza Azizighalehsari, Prasanth Venugopal, Deepak Pratap Singh, Thiago Batista Soeiro and Gert Rietveld

Batteries 2024, 10(5), 161; https://doi.org/10.3390/batteries10050161 - 14 May 2024

Cited by 14 | Viewed by 8560

Abstract

The surge in electric vehicle adoption has resulted in a significant rise in end-of-life batteries, which are unsuitable for demanding EV applications. Repurposing these batteries for secondary applications presents a promising avenue to tackle environmental and economic challenges associated with their disposal. The [...] Read more.

The surge in electric vehicle adoption has resulted in a significant rise in end-of-life batteries, which are unsuitable for demanding EV applications. Repurposing these batteries for secondary applications presents a promising avenue to tackle environmental and economic challenges associated with their disposal. The second-life battery (SLB) approach emerges as a mechanism to manage this massive amount of retired EV batteries. However, this approach poses significant challenges in determining and monitoring battery degradation and performance. After evaluating different scenarios for reusing or recycling retired EV batteries, this paper examines the main challenges associated with SLBs, including techno-economic aspects, uncertainty from first life, safety, characterization and screening, battery-management systems, and secondary applications. A comprehensive review of current state-of-the-art SLB research and implementations is provided, particularly emphasizing battery characterization and the requisite evaluation processes for SLB eligibility. This paper explores diverse measurement techniques for assessing SLB performance, evaluating them based on accuracy, complexity, and time consumption, which are essential for achieving cost-effective SLB applications. The overarching objective is to thoroughly understand the principal challenges associated with repurposing EV batteries and delineate the research imperatives necessary for their successful implementation and prolonged lifespan. Full article

(This article belongs to the Special Issue Recycling and Reuse of End-of-Life Lithium-Ion Batteries: Challenges and Strategies)

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26 pages, 2299 KB

Open AccessEditor’s ChoiceReview

A Comparative Review of Models for All-Solid-State Li-Ion Batteries

by Erkin Yildiz, Mattia Serpelloni, Alberto Salvadori and Luigi Cabras

Batteries 2024, 10(5), 150; https://doi.org/10.3390/batteries10050150 - 29 Apr 2024

Cited by 5 | Viewed by 5352

Abstract

In recent times, there has been significant enthusiasm for the development of all-solid-state Li-ion batteries. This interest stems from a dual focus on safety—addressing concerns related to toxic and flammable organic liquid electrolytes—and the pursuit of high energy density. While liquid electrolyte batteries [...] Read more.

In recent times, there has been significant enthusiasm for the development of all-solid-state Li-ion batteries. This interest stems from a dual focus on safety—addressing concerns related to toxic and flammable organic liquid electrolytes—and the pursuit of high energy density. While liquid electrolyte batteries currently constitute the vast majority of commercial cells, solid electrolyte batteries show great promise. In parallel with experimental research, computational models clarify several fundamental physics that take place throughout battery operations. Giving up on reviewing a broad screening of the existing literature, we set out to select here a few highly relevant models, emphasizing some fundamental conceptual advancements and offering an in-depth and critical insight into the current state of the art. The papers we selected aim at providing the reader with a tangible and quantitative understanding of how all-solid-state Li-ion batteries operate, including the different mechanisms at play and the mathematical tools required to model the pertinent physics and mechanics. Full article

(This article belongs to the Section Battery Modelling, Simulation, Management and Application)

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20 pages, 2268 KB

Open AccessEditor’s ChoiceArticle

Mechanical Measurement Approach to Characterize Venting Behavior during Thermal Runaway of 18650 Format Lithium-Ion Batteries

by Elisabeth Irene Gillich, Marco Steinhardt, Yaroslava Fedoryshyna and Andreas Jossen

Batteries 2024, 10(4), 142; https://doi.org/10.3390/batteries10040142 - 22 Apr 2024

Cited by 3 | Viewed by 4208

Abstract

The propagation of thermal runaway in a battery system is safety-critical in almost every application, such as electric vehicles or home storage. Abuse models can help to undestand propagation mechanisms and assist in designing safe battery systems, but need to be well-parametrized. Most [...] Read more.

The propagation of thermal runaway in a battery system is safety-critical in almost every application, such as electric vehicles or home storage. Abuse models can help to undestand propagation mechanisms and assist in designing safe battery systems, but need to be well-parametrized. Most of the heat during thermal runaway is released by venting that is why the characteristic of the vent flow plays an important part in the safety assessment. During venting, the cell generates a recoil force like a rocket, which depends on the flow speed and flow rate of the gas. This principle is used in this work to measure the velocity and mass flow rate of the vent gas. High-power and high-energy 18650 format lithium-ion batteries were overheated and the recoil and weight forces were measured to determine the venting parameter during thermal runaway. Our results show, that the linearized gas flow rate for the high-power and high-energy cell is

22.15 {gs}^{- 1}

and

27.92 {gs}^{- 1}

, respectively. The progress of the gas velocity differs between the two cell types and in case of the high-energy cell, it follows a single peak asymmetrical pattern with a peak of

398.5 {ms}^{- 1}

, while the high-power cell shows a bumpy pattern with a maximum gas velocity of

260.9 {ms}^{- 1}

. The developed test bench and gained results can contribute insights in the venting behavior, characterize venting, support safety assessments, simulations and pack design studies. Full article

(This article belongs to the Section Battery Performance, Ageing, Reliability and Safety)

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15 pages, 9500 KB

Open AccessEditor’s ChoiceArticle

Postmortem Analysis of 18650 Graphite/LFP Cells in a Long-Term Aging Study for Second-Life Applications

by William Wheeler, Yann Bultel, Pascal Venet, Ali Sari and Elie Riviere

Batteries 2024, 10(4), 119; https://doi.org/10.3390/batteries10040119 - 2 Apr 2024

Cited by 4 | Viewed by 3850

Abstract

Second-life applications for lithium-ion batteries offer industry opportunities to defer recycling costs, enhance economic value, and reduce environmental impacts. However, cells are affected by numerous aging phenomena which can lead to an acceleration in capacity loss. This paper uses postmortem techniques to compare [...] Read more.

Second-life applications for lithium-ion batteries offer industry opportunities to defer recycling costs, enhance economic value, and reduce environmental impacts. However, cells are affected by numerous aging phenomena which can lead to an acceleration in capacity loss. This paper uses postmortem techniques to compare aging phenomenon in 1.1 Ah 18650 graphite/LFP cells, examining the differences between a pristine cell and three cells aged to 40~30% of state of health (SoH). Macroscopic and microscopic techniques are used to identify aging phenomenon occurring in the cell on both positive and negative electrodes. Energy-dispersive X-ray spectroscopy (EDXS) and scanning electron microscopes (SEMs) with back-scattered electron (BSE) detector are used to analyze each electrode. These methods are used to analyze the morphology and the material on each electrode. The results show a stable positive LFP electrode whereas numerous deposits and cracking occurred on the negative electrode. A discussion of the appearance of those aging phenomenon is presented. Impacts for industrial cells in second-life applications are finally discussed. Full article

(This article belongs to the Section Battery Materials and Interfaces: Anode, Cathode, Separators and Electrolytes or Others)

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15 pages, 4255 KB

Open AccessFeature PaperEditor’s ChoiceArticle

Diphenylphosphoryl Azide as a Multifunctional Flame Retardant Electrolyte Additive for Lithium-Ion Batteries

by Zhirui Li, Longfei Han, Yongchun Kan, Can Liao and Yuan Hu

Batteries 2024, 10(4), 117; https://doi.org/10.3390/batteries10040117 - 30 Mar 2024

Cited by 1 | Viewed by 2557

Abstract

Graphite anode materials and carbonate electrolyte have been the top choices for commercial lithium-ion batteries (LIBS) for a long time. However, the uneven deposition and stripping of lithium cause irreversible damage to the graphite structure, and the low flash point and high flammability [...] Read more.

Graphite anode materials and carbonate electrolyte have been the top choices for commercial lithium-ion batteries (LIBS) for a long time. However, the uneven deposition and stripping of lithium cause irreversible damage to the graphite structure, and the low flash point and high flammability of the carbonate electrolyte pose a significant fire safety risk. Here, we proposed a multifunctional electrolyte additive diphenylphosphoryl azide (DPPA), which can construct a solid electrolyte interphase (SEI) with high ionic conductivity lithium nitride (Li₃N) to ensure efficient transport of Li⁺. This not only protects the artificial graphite (AG) electrode but also inhibits lithium dendrites to achieve excellent electrochemical performance. Meanwhile, the LIBS with DPPA offers satisfactory flame retardancy performance. The AG//Li half cells with DPPA-0.5M can still maintain a specific capacity of about 350 mAh/g after 200 cycles at 0.2 C. Its cycle performance and rate performance were better than commercial electrolyte (EC/DMC). After cycling, the microstructure surface of the AG electrode was complete and flat, and the surface of the lithium metal electrode had fewer lithium dendrites. Importantly, we found that the pouch cell with DPPA-0.5M had low peak heat release rate. When exposed to external conditions of continuous heating, DPPA significantly improved the fire safety of the LIBS. The research of DPPA in lithium electrolyte is a step towards the development of safe and efficient lithium batteries. Full article

(This article belongs to the Special Issue Advanced Materials and Technologies in All-Solid-State Lithium Batteries)

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14 pages, 12337 KB

Open AccessEditor’s ChoiceArticle

Fast Impedance Spectrum Construction for Lithium-Ion Batteries Using a Multi-Density Clustering Algorithm

by Ling Zhu, Jichang Peng, Jinhao Meng, Chenghao Sun, Lei Cai and Zhizhu Qu

Batteries 2024, 10(3), 112; https://doi.org/10.3390/batteries10030112 - 20 Mar 2024

Cited by 3 | Viewed by 2801

Abstract

Effectively extracting a lithium-ion battery’s impedance is of great importance for various onboard applications, which requires consideration of both the time consumption and accuracy of the measurement process. Although the pseudorandom binary sequence (PRBS) excitation signal can inject the superposition frequencies with high [...] Read more.

Effectively extracting a lithium-ion battery’s impedance is of great importance for various onboard applications, which requires consideration of both the time consumption and accuracy of the measurement process. Although the pseudorandom binary sequence (PRBS) excitation signal can inject the superposition frequencies with high time efficiency and an easily implementable device, processing the data of the battery’s impedance measurement is still a challenge at present. This study proposes a fast impedance spectrum construction method for lithium-ion batteries, where a multi-density clustering algorithm was designed to effectively extract the useful impedance after PRBS injection. According to the distribution properties of the measurement points by PRBS, a density-based spatial clustering of applications with noise (DBSCAN) was used for processing the data of the lithium-ion battery’s impedance. The two key parameters of the DBSCAN were adjusted by a delicate workflow according to the frequency range. The validation of the proposed method was proved on a 3 Ah lithium-ion battery under nine different test conditions, considering both the SOC and temperature variations. Full article

(This article belongs to the Special Issue Artificial Intelligence-Based State-of-Health Estimation of Lithium-Ion Batteries—2nd Edition)

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29 pages, 2341 KB

Open AccessFeature PaperEditor’s ChoiceReview

Safety Analysis of Lithium-Ion Cylindrical Batteries Using Design and Process Failure Mode and Effect Analysis

by Sahithi Maddipatla, Lingxi Kong and Michael Pecht

Batteries 2024, 10(3), 76; https://doi.org/10.3390/batteries10030076 - 23 Feb 2024

Cited by 14 | Viewed by 10231

Abstract

Cylindrical lithium-ion batteries are widely used in consumer electronics, electric vehicles, and energy storage applications. However, safety risks due to thermal runaway-induced fire and explosions have prompted the need for safety analysis methodologies. Though cylindrical batteries often incorporate safety devices, the safety of [...] Read more.

Cylindrical lithium-ion batteries are widely used in consumer electronics, electric vehicles, and energy storage applications. However, safety risks due to thermal runaway-induced fire and explosions have prompted the need for safety analysis methodologies. Though cylindrical batteries often incorporate safety devices, the safety of the battery also depends on its design and manufacturing processes. This study conducts a design and process failure mode and effect analysis (DFMEA and PFMEA) for the design and manufacturing of cylindrical lithium-ion batteries, with a focus on battery safety. Full article

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14 pages, 6593 KB

Open AccessEditor’s ChoiceArticle

Influence of Pressure, Temperature and Discharge Rate on the Electrical Performances of a Commercial Pouch Li-Ion Battery

by Luigi Aiello, Peter Ruchti, Simon Vitzthum and Federico Coren

Batteries 2024, 10(3), 72; https://doi.org/10.3390/batteries10030072 - 21 Feb 2024

Cited by 12 | Viewed by 7164

Abstract

In this study, the performances of a pouch Li-ion battery (LIB) with respect to temperature, pressure and discharge-rate variation are measured. A sensitivity study has been conducted with three temperatures (5 °C, 25 °C, 45 °C), four pressures (0.2 MPa, 0.5 MPa, 0.8 [...] Read more.

In this study, the performances of a pouch Li-ion battery (LIB) with respect to temperature, pressure and discharge-rate variation are measured. A sensitivity study has been conducted with three temperatures (5 °C, 25 °C, 45 °C), four pressures (0.2 MPa, 0.5 MPa, 0.8 MPa, 1.2 MPa) and three electrical discharge rates (0.5 C, 1.5 C, 3.0 C). Electrochemical processes and overall efficiency are significantly affected by temperature and pressure, influencing capacity and charge–discharge rates. In previous studies, temperature and pressure were not controlled simultaneously due to technological limitations. A novel test bench was developed to investigate these influences by controlling the surface temperature and mechanical pressure on a pouch LIB during electrical charging and discharging. This test rig permits an accurate assessment of mechanical, thermal and electrical parameters, while decoupling thermal and mechanical influences during electrical operation. The results of the study confirm what has been found in the literature: an increase in pressure leads to a decrease in performance, while an increase in temperature leads to an increase in performance. However, the extent to which the pressure impacts performance is determined by the temperature and the applied electrical discharge rate. At 5 °C and 0.5 C, an increase in pressure from 0.2 MPa to 1.2 MPa results in a 5.84% decrease in discharged capacity. At 45 °C the discharge capacity decreases by 2.17%. Regarding the impact of the temperature, at discharge rate of 0.5 C, with an applied pressure of 0.2 MPa, an increase in temperature from 25 °C to 45 °C results in an increase of 4.27% in discharged capacity. The impact on performance varies significantly at different C-rates. Under the same pressure (0.2 MPa) and temperature variation (from 25 °C to 45 °C), increasing the electrical discharge rate to 1.5 C results in a 43.04% increase in discharged capacity. The interplay between temperature, pressure and C-rate has a significant, non-linear impact on performance. This suggests that the characterisation of an LIB would require the active control of both temperature and pressure during electrical operation. Full article

(This article belongs to the Special Issue Recent Advances in Battery Measurement and Management Systems)

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18 pages, 3439 KB

Open AccessFeature PaperEditor’s ChoiceArticle

Heterogeneity of Lithium Distribution in the Graphite Anode of 21700-Type Cylindrical Li-Ion Cells during Degradation

by Dominik Petz, Volodymyr Baran, Juyeon Park, Alexander Schökel, Armin Kriele, Joana Rebelo Kornmeier, Carsten Paulmann, Max Koch, Tom Nilges, Peter Müller-Buschbaum and Anatoliy Senyshyn

Batteries 2024, 10(3), 68; https://doi.org/10.3390/batteries10030068 - 20 Feb 2024

Cited by 9 | Viewed by 4678

Abstract

Structural and spatial aspects of cell degradation are studied using a combination of diffraction-and imaging-based tools applying laboratory X-rays, neutron scattering and synchrotron radiation with electrochemical and thermal characterization. Experimental characterization is carried out on cylindrical cells of 21700-type, where four regimes of [...] Read more.

Structural and spatial aspects of cell degradation are studied using a combination of diffraction-and imaging-based tools applying laboratory X-rays, neutron scattering and synchrotron radiation with electrochemical and thermal characterization. Experimental characterization is carried out on cylindrical cells of 21700-type, where four regimes of cell degradation are identified, which are supplemented by an increased cell resistance and surface temperature during cell operation. The amount of intercalated lithium in the fully charged anodes in the fresh and aged states is determined by ex situ X-ray diffraction radiography and in situ X-ray diffraction computed tomography. The qualitatively similar character of the results revealed a loss of active lithium along with the development of a complex heterogeneous distribution over the electrode stripe. Full article

(This article belongs to the Section Battery Materials and Interfaces: Anode, Cathode, Separators and Electrolytes or Others)

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31 pages, 9263 KB

Open AccessEditor’s ChoiceArticle

Bubble Wrap-like Carbon-Coated Rattle-Type silica@silicon Nanoparticles as Hybrid Anode Materials for Lithium-Ion Batteries via Surface-Protected Etching

by Angelica Martino, Jiyun Jeon, Hyun-Ho Park, Hochun Lee and Chang-Seop Lee

Batteries 2024, 10(2), 53; https://doi.org/10.3390/batteries10020053 - 1 Feb 2024

Cited by 2 | Viewed by 4409

Abstract

Severe volumetric expansion (~400%) limits practical application of silicon nanoparticles as anode materials for next-generation lithium-ion batteries (LIBs). Here, we describe the fabrication and characterization of a conformal polydopamine carbon shell encapsulating rattle-type silica@silicon nanoparticles (PDA–PEI@PVP–SiO₂@Si) with a tunable void structure [...] Read more.

Severe volumetric expansion (~400%) limits practical application of silicon nanoparticles as anode materials for next-generation lithium-ion batteries (LIBs). Here, we describe the fabrication and characterization of a conformal polydopamine carbon shell encapsulating rattle-type silica@silicon nanoparticles (PDA–PEI@PVP–SiO₂@Si) with a tunable void structure using a dual template strategy with TEOS and (3-aminopropyl)triethoxysilane (APTES) pretreated with polyvinylpyrrolidone (PVP K30) as SiO₂ sacrificial template via a modified Stöber process. Polyethylene imine (PEI) crosslinking facilitated the construction of an interconnected three-dimensional bubble wrap-like carbon matrix structure through hydrothermal treatment, pyrolysis, and subsequent surface-protected etching. The composite anode material delivered satisfactory capacities of 539 mAh g⁻¹ after 100 cycles at 0.1 A g⁻¹, 512.76 mAh g⁻¹ after 200 cycles at 1 A g⁻¹, and 453 mAh g⁻¹ rate performance at 5 A g⁻¹, respectively. The electrochemical performance of PDA–PEI@PVP–SiO₂@Si was attributed to the rattle-type structure providing void space for Si volume expansion, PVP K30-pretreated APTES/TEOS SiO₂ seeds via catalyst-free, hydrothermal-assisted Stöber protecting Si/C spheres upon etching, carbon coating strategy increasing Si conductivity while stabilizing the solid electrolyte interface (SEI), and PEI carbon crosslinks providing continuous conductive pathways across the electrode structure. The present work describes a promising strategy to synthesize tunable yolk shell C@void@Si composite anode materials for high power/energy-density LIBs applications. Full article

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18 pages, 4251 KB

Open AccessEditor’s ChoiceArticle

Spherical Graphite Anodes: Influence of Particle Size Distribution and Multilayer Structuring in Lithium-Ion Battery Cells

by Laura Gottschalk, Jannes Müller, Alexander Schoo, Ernesto Baasch and Arno Kwade

Batteries 2024, 10(2), 40; https://doi.org/10.3390/batteries10020040 - 23 Jan 2024

Cited by 9 | Viewed by 9829

Abstract

Current research focuses on lithium-ion battery cells with a high energy density and efficient fast-charging capabilities. However, transport limitations, and, therefore, the uniform diffusion of lithium-ions across the electrode layers, remain a challenge and could lead to reduced cell performance. One approach to [...] Read more.

Current research focuses on lithium-ion battery cells with a high energy density and efficient fast-charging capabilities. However, transport limitations, and, therefore, the uniform diffusion of lithium-ions across the electrode layers, remain a challenge and could lead to reduced cell performance. One approach to overcome these transport challenges is the use of subsequently produced two-layer anodes with the particle size variation of spherical graphite (x₅₀ = 18 µm; x₅₀ = 11 µm). Thereby, a defined pore network is created, which reduces the ionic resistance and ensuring improved fast charging capabilities. The analysis focuses on the evaluation of electrode properties and the electrochemical performance. By examining the pore size distribution of the anodes, it has been found that during the manufacturing of the two-layer anodes, carbon black and binder particles are transported into the existing microstructure of the lower layer, resulting in localized densification between the anode layers. This could also be supported by color measurements. This effect also extends to electrochemical investigations, with electrochemical impedance spectroscopy showing significantly lower ionic resistances in all two-layer anodes. Reduced ionic resistance and tortuosity near the separator due to absorption effects enhance the ion diffusion and have a direct impact on anode performance. Cell ageing analysis showed a significant capacity decrease of almost 15 mAh g ⁻¹ in the single-layer references only, in contrast to the stability of the two-layer anodes. This could also be attributed to the reduced ionic resistance and active counteraction of binder migration. In conclusion, this study highlights how subsequently produced two-layer anodes significantly shape the electrode properties and cell performance of lithium-ion batteries. Full article

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