Monoliths are continuous adsorbents that can easily be synthesised to possess tuneable meso-/macropores, convective fluid transport, and a plethora of chemistries for ligand immobilisation. They are grouped into three main classes: organic, inorganic...
In the last years, macroporous monolithic materials have been introduced as a new and useful generation of polymers used in different fields. These polymers may be prepared in a simple way from a homogenous mixture into a mold and contain large inter...
This research aimed to investigate a new fabrication of poly-(2-dimethyl(aminoethyl) methacrylate)-co-styrene in a porous polymer monolithic morphology. Poly-(2-dimethyl(aminoethyl) methacrylate) (PDMAEMA) is responsive to changes in pH while styrene...
Monolithic column materials offer great advantages as chromatographic media in bioseparations and as solid-supports in biocatalysis. These single-piece porous materials have an interconnected ligament structure that limits the void volume inside the...
The vast cache of methods used in polymeric monolithic column modification is presented herein, with specific attention to post-polymerization modification reactions. The modification of polymeric monolithic columns is defined and can include the mo...
Currently, organizations face the need to create scalable applications in an agile way that impacts new forms of production and business organization. The traditional monolithic architecture no longer meets the needs of scalability and rapid developm...
As for the measurement of polycyclic aromatic hydrocarbons (PAHs), ultra-performance liquid chromatography (UPLC) is used for PAH identification and densitometry. However, when a solvent containing a substance to be identified passes through a column...
In this review, we trace the evolution of liquid chromatography from the pioneering work of Tennikova and Svec to the current monolithic polymethacrylate supports for performing liquid chromatography with biological macromolecules and nanoparticles,...
Monolithic materials have become very popular because of various applications, especially within chromatography and catalysis. Large surface areas and multimodal porosities are great advantages for these applications. New sol-gel preparation methods...
Additive manufacturing (AM) can revolutionise engineering by taking advantage of unconstrained design and overcoming the limitations of traditional manufacturing capabilities. A promising application of AM is in catalyst substrate manufacturing, aime...
Monolithic columns are gaining interest as excellent substitutes to conventional particle-packed columns. These columns show higher permeability and lower flow resistance than conventional liquid chromatography columns, providing high-throughput perf...
Growing medical, engineering, biochemical, and biological interest has led to a steady pace of research and development into polymeric monolithic structures with densely interconnected pores for purifying bio compounds. Cryogels, which are generated...
A butyl methacrylate (BMA) monolithic column was polymerized in-situ with UV irradiation in an ultraviolet transparent PDMS micro-channel on a homemade micro-fluidic chip. Under the optimized conditions and using a typical polymerization mixture cons...
There is continuous effort towards developing monolithic materials as solid supports for the separation, enrichment, and digestion of glycoproteins. The intention of this review is to discuss and summarize work reported in this area during the period...
Monolithic catalysts have great industrial application prospects compared to powdered catalysts due to their low pressure drop, the high efficiency of mass and heat transfer, and recyclability. Deposition of active phases on the monolithic carriers d...
A strategy for the preparation of silica-based monolithic capillary columns (150 × 0.1 mm) with high selectivity to amino acids is presented. The zwitterionic columns were prepared by coating the silica monolith with [2-(methacryloyloxy)ethyl]-dimeth...
New monolithic multi-layered zirconia restorations are gaining popularity due to their excellent aesthetic properties. However, current knowledge of these newest multi-layer ceramics in terms of mechanical properties is scarce. Three monolithic, mult...
The purpose of this paper was to update the knowledge concerning the wear, translucency, as well as clinical performance of monolithic zirconia ceramics, aiming at highlighting their advantages and weaknesses through data presented in recent literatu...
The space integration of the lithiation of aryl halides, the borylation of aryllithiums, and Suzuki–Miyaura coupling using a Pd catalyst supported by a polymer monolith flow reactor without using an intentionally added base was achieved. To sca...
Porous LaFeO3 powders were produced by high-temperature calcination of LaFeO3 precursors obtained by hydrothermal treatment of corresponding nitrates in the presence of citric acid. Four LaFeO3 powders calcinated at different temperatures were mixed...
In the last few decades, the attention of researchers has been focused on the characterization of aerogels in order to improve the thermal performance of transparent building envelopes. Granular aerogel is already spread in the market thanks to the e...
The present systematic review aimed to evaluate the influence of different treatments and conditions on the optical properties of monolithic zirconia. An electronic search was performed using the following databases: PubMed (National Library of Medic...
Preferential oxidation of CO (CO-PROX) has tremendous significance in purifying hydrogen for fuel cells to avoid catalyst poisoning by CO molecules. Traditional powder catalysts face numerous challenges, including high pressure drop, aggregation tend...
The transition from polylithic (composed of many parts) to monolithic (one part) design in automotive components presents an opportunity for a reduction in part count, weight, processing routes, and production time without compromising performance. T...
The deposition of V-based catalysts for the oxidative dehydrogenation of propane to propene on cordierite honeycomb monoliths was optimised as a strategy to decrease the contact time in a structured reactor with respect to a conventional fixed bed on...
Due to the emerging requirements of miniaturization and multifunctionality, monolithic devices with both functions of lighting and detection are essential for next-generation optoelectronic devices. In this work, based on freestanding (In,Ga)N films,...
Polymer composite materials with hierarchical porous structure have been advancing in many different application fields due to excellent physico-chemical properties. However, their synthesis continues to be a highly energy-demanding and environmental...
The aim of this work is to present an overview about the combination of the Reduced Basis Method (RBM) with two different approaches for Fluid–Structure Interaction (FSI) problems, namely a monolithic and a partitioned approach. We provide the detail...
With the advent of ultrafast lasers, new manufacturing techniques have come into existence. In micromachining, the use of femtosecond lasers not only offers the possibility for three-dimensional monolithic fabrication inside a single optically transp...
Metasurfaces with a high engineering degree of freedom are promising building blocks for applications in metalenses, beam deflectors, metaholograms, sensing, and many others. Though the fundamental and technological challenges, proposing tunable meta...
A monolithic rod of polyurethane foam–[4-(2-pyridylazo) resorcinol] (PUF–PAR) as a simple chemical sensor for lead assays with smartphone detection and image processing was developed. With readily available simple apparatus such as a plastic cup and...
Coenzyme Q10 (CoQ10) is a vital substance found throughout body. It helps convert food into energy and is eaten small amounts in foods. CoQ10 has gained great interest in recent years as a potential candidate for the treatment of various diseases. Th...
Over the past decade, many software enterprises have migrated from monolithic to microservice architectures to enhance scalability, maintainability, and performance. However, this transition presents significant challenges, requiring considerable dev...
Monolithic zirconia and hybrid ceramic restorations have been widely used in the last decade for both anterior and posterior dental restorations. However, their use lacks sufficient scientific evidence in most cases, as the expeditious manufacturing...
Machining distortion is a recurring problem in the machining of monolithic aircraft parts. This paper aims to study the machining distortion minimization of monolithic aircraft parts. Firstly, the energy principle of machining distortion was analyzed...
One of the main difficulties for a global implantation of the Internet of Things (IoT) is the energy dependence of the nodes, limited by the battery’s lifetime. Energy harvesting seems to be a promising solution to provide energy autonomy to IoT node...
Background: The aim of this systematic review and meta-analysis was to determine the wear sustained in the natural antagonist tooth in cases of full-coverage fixed-base prosthetic restorations or monolithic zirconia tooth-supported crowns, as well as...
To enhance the mechanical properties and damage resistance of prefabricated monolithic composite beams, this study introduces HPFRCC precast mold shells as a replacement for ordinary concrete in the construction of prefabricated monolithic composite...
This study evaluated the effects of different simulated chairside grinding and polishing protocols on the physical and mechanical properties of surface roughness, hardness, and flexural strength of monolithic zirconia. Sintered monolithic zirconia sp...
To develop materials suitable for aerospace applications, silicon nitride/boron nitride (Si
Purpose: The objective of this study was to assess the quality of posterior teeth prepared for monolithic zirconia crowns. Materials and Methods: A total of 392 STL-files of posterior preparations for monolithic zirconia crowns were evaluated in this...
This paper presents a fully integrated linear Hall sensor by means of 0.8 μm high voltage complementary metal-oxide semiconductor (CMOS) technology. This monolithic Hall sensor chip features a highly sensitive horizontal switched Hall plate and an ef...
In this work, ceramic monolithic catalyst carriers based on zirconium dioxide (ZrO2) were produced using fused filament fabrication (FFF). The active catalyst components were deposited on the resulting carriers using the wet impregnation method. The...
We have simulated a monolithic three-dimensional inverter (M3DINV) structure by considering the interfacial trap charges generated thermally during the monolithic three-dimensional integration process. We extracted the SPICE model parameters from M3D...
Zirconia has generated tremendous interest in the esthetic materials used for dental restorations. However, using conventional zirconia has some limitations especially in highly esthetically demanding situations, as it lacks the translucency that oth...
In miniaturized affinity chromatography, the development of hydrophilic organic monoliths with reduced non-specific interactions and high-protein grafting capacity remains a hot topic. In this work, we propose the one-step synthesis of a diol organic...
With the aim of developing efficient flow-through microreactors for high-throughput organic synthesis, in this work, microreactors were fabricated by chemically immobilizing palladium-, nickel-, iron-, and copper-based catalysts onto ligand-modified...
The performance of monolithic silica microreactors activated with sulphonic acid groups and a packed bed reactor with Amberlyst 15 resin were compared in the esterification of acetic acid with n-butanol. The monolithic microreactors were made of sing...
Purpose Maintaining the surface quality of ceramic restorations after clinical adjustments is critical for both aesthetic outcomes and long-term oral health, yet the optimal approach to restoring gloss and smoothness remains unclear. The purpose of t...
Monolithic fillings used in chromatography are of great interest among scientists since the first reports of their synthesis and use were published. In the 20 years since silica-based monolithic columns were introduced into the commercial market, num...
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