This study fabricated a composite ePTFE-backed proton-exchange membrane by filling the pores on the ePTFE backing with sulfonated polyarylene ethers through an externally supplied electric field. The morphology changes were observed under an SEM. The...
Corrosion resistance and electrical conductivity of stainless steel bipolar plate remains a big challenge while it has been regarded as the most promising candidate for proton exchange membrane fuel cell. The purpose of this paper is to study the eff...
The effect of Sr-nonstoichiometry on phase composition, microstructure, defect chemistry and electrical conductivity of SrxZrO3−δ and SrxZr0.95Y0.05O3−δ ceramics (SZx and SZYx, respectively; x = 0.94–1.02) was investigat...
Based on the previous work conducted by Fujii et al., NdBaInO4 compounds present modest oxide-ion conductivities. Therefore, it has been an attractive system of significant interest. In this study, we attempted to partially substitute Ca for Nd and t...
The dielectric spectra and conductivity properties of neat poly(epichlorohydrin-co-ethylene oxide)(PECH-co-EO) copolymer and two modified copolymers with a 20% or 40% of dendron 3,4,5-tris[4-(n-dodecan-1-yloxy)benzyloxy] benzoate units were analysed....
Understanding the impact of sintering temperature on the physical and chemical properties of Ni-BaCe0.54Zr0.36Y0.1O3-δ (Ni-BCZY) composite anode is worthy of being investigated as this anode is the potential for protonic ceramic fuel cell (PCFC...
This paper presents the results of a comparative study of methods to prevent the loss of barium during the formation of thin-film proton-conducting electrolyte BaCe0.89Gd0.1Cu0.01O3−δ (BCGCuO) on La2NiO4+δ-based (LNO) cathode substr...
This study introduces a novel nanocomposite coating composed of PANI/CeO2 nanocomposite films, aimed at addressing corrosion protection needs. Analysis through FTIR spectra and XRD patterns confirms the successful formation of the nanocomposite films...
It is well known that a proton conductor is needed as an electrolyte of hydrogen fuel cells, which are attracting attention as an environmentally friendly next-generation device. In particular, anhydrous proton-conducting electrolytes are highly desi...
Proton conductors are ceramic materials with a crystalline or amorphous structure, which allow the passage of an electrical current through them exclusively by the movement of protons: H+. Recent developments in proton-conducting ceramics present con...
In this article, the effects of high-energy proton irradiation on top-gate graphene field-effect transistors (GFETs) were investigated by using 20 MeV protons. The basic electrical parameters of the top-gate GFETs were measured before and after proto...
The development of innovative proton-conducting materials for low-temperature fuel cells (FCs) is, today, a central topic among the scientific community. Polyantimonic acid (PAA) is characterized by high conductivity and sufficient thermal stability;...
One of the urgent tasks of applied materials science is the creation of novel high-effective materials with target properties. In the area of energy systems, there is a problem in the conversion of chemical energy to electricity without mechanical wo...
Proton-conducting solid oxide fuel cells (P-SOFCs) are widely studied for their lower working temperatures than oxygen-ion-conducting SOFCs (O-SOFCs). Due to the elevated preparation and operation temperatures varying from 500 °C to 1500 °C,...
This work focused on the novel electrochemical energy material with significantly improved electrical properties. The novel complex oxide Ba1.1La0.9In0.5Y0.5O3.95 with layered perovskite structure was obtained for the first time. It was proven that t...
Intense electric fields applied on H-bonded systems are able to induce molecular dissociations, proton transfers, and complex chemical reactions. Nevertheless, the effects induced in heterogeneous molecular systems such as methanol-water mixtures are...
Proton-conducting ceramic membranes show high hydrogen ion conductivity in the temperature range of 300–700 °C. They are attracting significant attention due to their relevant characteristics compared to both higher-temperature oxygen ion-c...
In this work, hydration kinetics related to the incorporation of water into proton-conducting Ba0.9La0.1Zr0.25Sn0.25In0.5O3−a perovskite-type oxide are presented, with a recorded transition on temperature from a single-fold to a two-fold behavior. Th...
Hydrogen energy is converted to electricity through fuel cells, aided by nanostructured materials. Fuel cell technology is a promising method for utilizing energy sources, ensuring sustainability, and protecting the environment. However, it still fac...
Large Co-MOF-74 crystals of a few hundred micrometers were prepared by solvothermal synthesis, and their structure and morphology were characterized by scanning electron microscopy (SEM), IR, and Raman spectroscopy. The hydrothermal stability of the...
Polymer blend electrolytes based on poly(vinyl alcohol):chitosan (PVA:CS) incorporated with various quantities of ammonium iodide were prepared and characterized using a range of electrochemical, structural and microscopic techniques. In the structur...
The development of solid oxide fuel cells operating at medium temperatures (500–700 °C and even lower) requires the search for proton conductors based on complex oxides that would have a wide range of required properties. This task stimulat...
Protonic ceramic fuel cells (PCFCs) offer a convenient means of converting chemical energy into electricity with high performance and efficiency at low- and intermediate-temperature ranges. However, in order to ensure good life-time stability of PCFC...
Polymer electrolyte membrane fuel cell (PEMFC) is an eco-friendly energy conversion device that can convert chemical energy into electrical energy without emission of harmful oxidants such as nitrogen oxides (NOx) and/or sulfur oxides (SOx) during op...
Bioelectrochemical systems (BESs) are technologies capable of converting chemical energy into electrical energy or producing value-added compounds. These systems typically employ Nafion membranes as proton exchange separators; however, Nafion is cost...
Proton exchange membrane fuel cells are devices that directly convert chemical energy to electricity. A hydrogen oxidation reaction takes place on the anode side, generating protons and electrons. In the cathode, oxygen reduction reaction involving o...
A comprehensive study of proton irradiation reliability on a bilayer dielectrics SiNx/Al2O3 MIS-HEMT, the common Schottky gate HEMT, and a single dielectric layer MIS-HEMT with SiNx and with Al2O3 for comparison is conducted in this paper. Combining...
Taking advantage of the high functionalization capacity of poly(vinyl alcohol) (PVA), bead-free homogeneous nanofibrous mats were produced. The addition of functional groups by means of grafting strategies such as the sulfonation and the addition of...
Advanced functionalities textiles embedding electronic fibers, yarns and fabrics are a demand for innovative smart cloths. Conductive electrospun membranes and yarns based on polyaniline/polyvinylpyrrolidone (PANI/PVP) were investigated using the che...
The introduction of nanoparticles into the polymer matrix is a useful technique for creating highly functional composite membranes. Our research focuses on the development of nanoparticle-filled proton exchange membranes (PEMs). PEMs play a crucial r...
This paper proposes molecular and supramolecular concepts for potential application in perovskite solar cells. New air-stable symmetrical imine, with thiadiazole moieties PPL2: (5E,6E)-N2,N5-bis(4-(diphenylamino)benzylidene)-1,3,4-thiadiazole-2,5-dia...
A proton-conductive solid oxide fuel cell (H-SOFC) has the advantage of operating at higher temperatures than a PEM fuel cell, but at lower temperatures than a SOFC. This study proposes a mathematical model for an H-SOFC in order to simulate the perf...
The electrical characterization of catalysts composed of layered manganese oxide in the form of birnessite supported on γ-Al2O3, which have been successfully used in the combustion of soot, is presented. The results indicate that the electrical...
The quantum statistical properties of the proton subsystem in hydrogen-bonded crystals (HBC) are investigated. Based on the non-stationary Liouville operator equation (taking into account a number of assumptions established in the experiment), a quan...
SrZrO3-based perovskites are promising proton-conducting membranes for use in fuel and electrolysis cells, sensors, hydrogen separators, etc., because they combine good proton conductivity with excellent chemical stability. In the present research, t...
The main insulation of converter transformers consists of transformer oil and oil-impregnated pressboard. Under operating conditions, the valve-side winding of the converter transformer is subject to DC voltage components. Therefore, studies on the c...
Hydrogen production through electrolysis using renewable resources is highly promising for reducing greenhouse gas emissions. While significant efforts have focused on developing more efficient and cost-effective catalysts to lower hydrogen productio...
The unique physicochemical, electrical, mechanical, and thermal properties of micas make them suitable for a wide range of industrial applications, and thus, the interest for these kind of hydrous aluminosilicate minerals is still persistent, not onl...
Fuel cells using biomaterials have the potential for environmentally friendly clean energy and have attracted a lot of interest. Moreover, biomaterials are expected to develop into in vivo electrical devices such as pacemakers with no side effects. I...
The present study investigates the real-time estimation of CO2 absorption capacity (CAC) based on the electrical conductivity (EC) of low-concentration di-methyl-ethanolamine (DMEA) solutions (0.1–0.5 M). CO2 absorption experiments are conducte...
A systematic study was carried out on Nafion® 112 membranes to evaluate the effects of different electric field strengths on the structural and electrical properties of the membranes. The membranes were subjected to different electric field stren...
17 March 2023
In conventional chemical and electrochemical oxidation methods, it is very difficult to control the active centers, and the average prepared polymers are short and wide. The use of an electric field creates the most stable intermediate form of active...
To improve the conductivity and flexural strength of bipolar plates for proton-exchange membrane fuel cells, multi-filler-reinforced composites were prepared using graphite, multiwalled carbon nanotubes (MWCNTs), chopped carbon fibers (CCFs), and phe...
A series of glass-ceramics were prepared by heat-treatments of 40Na2O-30MoO3-30P2O5 (in mol%) glass in a temperature range from 380 (Tg) to 490 °C (Tc) and for 1–24 h. The prepared glass-ceramics contain from 2 to 25 wt.% of crystalline NaM...
Hydrogen is expected to have an important role in future energy systems; however, further research is required to ensure the commercial viability of hydrogen generation. Proton exchange membrane steam electrolysis above 100 °C has attracted signi...
BaZr0.9Y0.1O3-δ (BZY10), a promising proton conducting material, exhibits p-type conduction under oxidative conditions. Holes in BZY10 are of the small polaron type. However, there is no clear understanding at which places in the lattice they a...
Research has been conducted on solid oxide fuel cells (SOFCs) for their fuel flexibility, modularity, high efficiency, and power density. However, the high working temperature leads to the deterioration of materials and increased operating costs. Con...
This paper is focused on the determination of the physicochemical properties of a composite inorganic–organic modified membrane. The electrical conductivity of a family of glassy protonic electrolytes defined by the general formula (P2O5)x(SiO2...
The inherently variable nature of renewable energy sources makes them storage-dependent when providing a reliable and continuous energy supply. One feasible energy-storage option that could meet this challenge is storing surplus renewable energy in t...
The effect of Sr-deficiency on microstructure, phase composition and electrical conductivity of SrxZr0.95Yb0.05O3-δ (x = 0.94–1.00) was investigated via X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy...
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