Fibers — Open Access Journal

Since their inception, about 20 years ago, hollow-core photonic crystal fiber and its gas-filled form are now establishing themselves both as a platform in advancing our knowledge on how light is confined and guided in microstructured dielectric optical waveguides, and a remarkable enabler in a large and diverse range of fields. The latter spans from nonlinear and coherent optics, atom optics and laser metrology, quantum information to high optical field physics and plasma physics. Here, we give a historical account of the major seminal works, we review the physics principles underlying the different optical guidance mechanisms that have emerged and how they have been used as design tools to set the current state-of-the-art in the transmission performance of such fibers. In a second part of this review, we give a nonexhaustive, yet representative, list of the different applications where gas-filled hollow-core photonic crystal fiber played a transformative role, and how the achieved results are leading to the emergence of a new field, which could be coined “Gas photonics”. We particularly stress on the synergetic interplay between glass, gas, and light in founding this new fiber science and technology. Full article

Fluorescence microscopy was applied to understand adhesion interfaces developed within laminated composite sandwiches formed between poly(lactic acid) (PLA) and wood veneers. Composites formed with maple veneer had greater tensile bond strength when manufactured at 200 °C (10.4 N/mm²) compared to formation at 140 °C (8.7 N/mm²), while significantly lower bond strength was achieved using spruce veneers, at 5.2 and 3.5 N/mm², respectively. Qualitative and quantitative confocal microscopy assessments revealed differing bondline thicknesses and PLA ingress within the wood ultrastructure. Forming maple veneer composites at 200 °C promoted greater PLA mobility away from the bondline to reinforce the wood–PLA interface and deliver associated greater composite bond strength. The addition of 25% wood fibre to PLA led to fibre alignment and overlap within bondlines contributing to relatively thicker, heterogeneous bondlines. Study outcomes show that the composite processing temperature impacts the adhesion interface and composite performance and will have broad application over veneer overlays, laminates and wood plastic composites (WPCs) using wood, particles or fibres with PLA. Full article

Mechanical properties of parts produced with polymer deposition additive manufacturing (AM) depend on the print bead direction, particularly when short carbon-fiber reinforcement is added to the polymer feedstock. This offers a unique opportunity in the design of these structures since the AM print path can potentially be defined in a direction that takes advantage of the enhanced stiffness gained in the bead and, therefore, fiber direction. This paper presents a topology optimization approach for continuous fiber angle optimization (CFAO), which computes the best layout and orientation of fiber reinforcement for AM structures. Statically loaded structures are designed for minimum compliance where the adjoint variable method is used to compute design derivatives, and a sensitivity filter is employed to reduce the checkerboard effect. The nature of the layer-by-layer approach in AM is given special consideration in the algorithm presented. Examples are provided to demonstrate the applicability of the method in both two and three dimensions. The solution to our two dimensional problem is then printed with a fused filament fabrication (FFF) desktop printer using the material distribution results and a simple infill method which approximates the optimal fiber angle results using a contour-parallel deposition strategy. Mechanical stiffness testing of the printed parts shows improved results as compared to structures designed without accounting for the direction of the composite structure. Results show that the mechanical properties of the final FFF carbon fiber/polymer composite printed parts are greatly influenced by the print direction, and optimized material orientation tends to align with the imposed force direction to minimize the compliance. Full article

The use of high strength-to-weight ratio-laminated fiber-reinforced composites is emerging in engineering sectors such as aerospace, marine and automotive to improve productivity. Nevertheless, delamination between the layers is a limiting factor for the wider application of laminated composites, as it reduces the stiffness and strengths of the structure. Previous studies have proven that ply interface nanofibrous fiber reinforcement has an effective influence on delamination resistance of laminated composite materials. This paper aims to investigate the effect of nanofiber ply interface reinforcement on mode I properties and failure responses when being subjected to static and fatigue loadings. For this purpose, virgin and nanomodified woven laminates were subjected to Double Cantilever Beam (DCB) experiments. Static and fatigue tests were performed in accordance with standards and the Acoustic Emissions (AE) were acquired during these tests. The results showed not only a 130% increase of delamination toughness for nanomodified specimens in the case of static loads, but also a relevant crack growth resistance in the case of fatigue loads. In addition, the AE permitted to relate these improvements to the different failure mechanisms occurring. Full article

Electronic yarns (E-yarns) contain electronics fully incorporated into the yarn’s structure prior to textile or garment production. They consist of a conductive core made from a flexible, multi-strand copper wire onto which semiconductor dies or MEMS (microelectromechanical systems) are soldered. The device and solder joints are then encapsulated within a resin micro-pod, which is subsequently surrounded by a textile sheath, which also covers the copper wires. The encapsulation of semiconductor dies or MEMS devices within the resin polymer micro-pod is a critical component of the fabrication process, as the micro-pod protects the dies from mechanical and chemical stresses, and hermetically seals the device, which makes the E-yarn washable. The process of manufacturing E-yarns requires automation to increase production speeds and to ensure consistency of the micro-pod structure. The design and development of a semi-automated encapsulation unit used to fabricate the micro-pods is presented here. The micro-pods were made from a ultra-violet (UV) curable polymer resin. This work details the choice of machinery and methods to create a semi-automated encapsulation system in which incoming dies were detected then covered in resin micro-pods. The system detected incoming 0402 metric package dies with an accuracy of 87 to 98%. Full article

Fiber-reinforced polymer (FRP) is an important material used for strengthening and retrofitting of reinforced concrete structures. Commonly used fibers are glass, carbon, and aramid fibers. The durability of structures can be extended by selecting an appropriate method of strengthening. FRP wrapping is one of the easiest methods for repair, retrofit, and maintenance of structural elements. Deterioration of structures may be due to moisture content, salt water, or contact with alkali solutions. Using FRP, additional strength can be gained by structural elements. This paper investigates the durability of aramid-fiber-wrapped concrete cube specimens subjected to acid attack and temperature rise. The study focuses on the durability of aramid-fiber-wrapped concrete by considering the compressive strength parameter of the concrete cube. Concrete cubes are prepared as specimens with a double wrapping of aramid fibers. Diluted hydrochloric acid solution is used for immersion of specimens for curing periods of 7, 30, and 70 days. The aramid-fiber wrapping reduces weight loss by 40% and improves compressive strength by 140%. In a fire resistance test, the specimens were kept in a hot air oven at a temperature of 200 °C at different time intervals. Even after fire attack, weight loss in specimens reduced by 60%, with about 150% enhancement in compressive strength due to aramid fiber. Full article

Nowadays, asbestos waste still remains a serious problem. Due to the carcinogenic properties of asbestos, which are related to its fibrous structure, the exposure to asbestos mineral and asbestos-containing materials (ACM) causes dangerous health effects. This problem can be solved by recycling techniques, which allow the re-use of neutralized asbestos waste, instead of disposing it in special landfills. The article presents the results of research aimed at investigating the possibility of obtaining aggregates from asbestos waste by the fusion process in the electric arc-resistance process. A mixture of ACM with selected fluxes was were melted and then cast to form a grain of aggregates. The chemical composition of the material was determined before and after the melting process. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to evaluate the effects of the fusion process. The main properties of the obtained aggregate were also measured. The results confirmed that the fibrous structure of asbestos was destroyed in the obtained material, which can be successfully used for the production of artificial aggregates. Full article

Addition of steel fibres to concrete is known to have a significant positive influence on the mechanical properties of concrete. Micro polypropylene (PP) fibres are added to concrete to improve its performance under thermal loads such as in case of fire by preventing the phenomena of explosive spalling. An optimum mixture of steel and micro PP fibres added to concrete may be utilized to enhance both the mechanical and thermal behaviour of concrete. In this work, systematic investigations were carried out to study the influence of elevated temperature on the mechanical properties and physical properties of high strength concrete without and with fibres. Three different mixtures for high strength concrete were used, namely normal concrete without fibres, Steel fibre reinforced concrete and Hybrid fibre reinforced concrete having a blend of hooked end steel fibres and micro PP fibres. The specimens were tested in ambient conditions as well as after exposure to a pre-defined elevated temperature and cooling down to room temperature. For all investigated concrete mixtures the thermal degradation of following properties were investigated: compressive strength, tensile splitting strength, bending strength, fracture energy and static modulus of elasticity. This paper summarizes the findings of the tests performed. Full article

This paper deals with the behavior of concrete’s self-compatibility in a fresh state and its compressive and flexural strength in a hardened state with the addition of polyolefin macro fibers. Four different amounts (3 kg/m³, 4.5 kg/m³, 6 kg/m³, and 9 kg/m³) of polyolefin macro fibers were mixed into the concrete mixture to observe the differences in workability and strength properties between the concrete specimens. As a partial replacement of cement, class C type of fly ash was added to make up 25% of the total cement mass. The water-binder ratio (W/B) of the concrete mix was 0.36. Superplasticizer was added to the concrete mixture to achieve self-compacting properties. The slump test was carried out in the fresh state for determining the flowability. On the 7th and 28th days of the curing process, compression strength tests were performed, and on the 28th day, flexural strength tests and crack mouth opening displacement (CMOD) analyses were carried out to determine the strength properties and post-cracking behavior of the concrete samples. Bending strength and post-cracking behavior of the samples were improved by the addition of fibers. The fiber concentration in the concrete mixture greatly influenced the slump flow and self-compaction properties. Full article

A number of analytical techniques were applied to investigate changes to the surface of unsized boron-free E-glass fibres after thermal conditioning at temperatures up to 700 °C. Novel systematic studies were carried out to investigate the fundamental strength loss from thermal conditioning. Surface chemical changes studied using X-ray photoelectron spectroscopy (XPS) showed a consistent increase in the surface concentration of calcium with increasing conditioning temperature, although this did not correlate well with a loss of fibre strength. Scanning electron microscopy fractography confirmed the difficulty of analysing failure-inducing flaws on individual fibre fracture surfaces. Analysis by atomic force microscopy (AFM) did not reveal any likely surface cracks or flaws of significant dimensions to cause failure: the observation of cracks before fibre fracture may not be possible when using this technique. Fibre surface roughness increased over the whole range of the conditioning temperatures investigated. Although surface roughness did not correlate precisely with fibre strength, there was a clear inverse relationship at temperatures exceeding 400 °C. The interpretation of the surface topography that formed between 400–700 °C produced evidence that the initial stage of phase separation by spinodal decomposition may have occurred at the fibre surface. Full article

An ideal hernia mesh is one that absorbs drugs and withstands muscle forces after mesh implantation. Polypropylene (PP) mesh devices have been accepted as a standard material to repair abdominal hernia, but the hydrophobicity of PP fibers makes them unsuitable to carry drugs during the pre-implantation of PP meshes. In this study, for the first time, one-step functionalization of PP mesh surfaces was performed to incorporate bio-inspired polydopamine (PDA) onto PP surfaces. All PP mesh samples were dipped in the same concentration of dopamine solution. The surface functionalization of PP meshes was performed for 24 h at 37 °C and 80 rpm. It was proved by scanning electron microscopic (SEM) images and Fourier Transform Infrared Spectroscopy (FTIR) results that a thin layer of PDA was connected with PP surfaces. Moreover, water contact angle results proved that surface functionalized PP meshes were highly hydrophilic (73.1°) in comparison to untreated PP mesh surfaces (138.5°). Thus, hydrophilic PP meshes with bio-inspired poly-dopamine functionalization could be a good choice for hernia mesh implantation. Full article

Olefin/paraffin separation is an important technological process. A promising alternative to conventional energy-consuming methods is employment of gas-liquid membrane contactors. In the present work, the membranes used were polysulfone (PSf) asymmetrical porous hollow fibers fabricated via the NIPS (non-solvent induced phase separation) technique in the free spinning mode. The surface of the fine-pored selective layer from the lumen side of the fibers was modified by layer-by-layer deposition of perfluorinated acrylic copolymer Protect Guard^® in order to hydrophobized the surface and to avoid penetration of the liquid absorbent in the porous structure of the membranes. The absorbents studied were silver salts (AgNO₃ and AgBF₄) solutions in five ionic liquids (ILs) based on imidazolium and phosphonium cations. The membranes were analyzed through gas permeance measurement, SEM and dispersive X-ray (EDXS). Contact angle values of both unmodified and modified membranes were determined for water, ethylene glycol, ILs and silver salts solutions in ILs. It was shown that the preferable properties for employment in membrane contactor refer to the PSf hollow fiber membranes modified by two layers of Protect Guard^®, and to the absorbent based on 1 M AgNO₃ solution in 1-ethyl-3-methylimidazolium dicyanamide. Using the membrane contactor designed, ethylene/ethane mixture (80/20) separation was carried out. The fluxes of both components as well as their overall mass transport coefficients (MTC) were calculated. It was shown that the membrane absorption system developed provides absorption of approx. 37% of the initial ethylene volume in the mixture. The overall MTC value for ethylene was 4.7 GPU (gas permeance unit). Full article

Animal protein-based fibers used in textiles often are assumed to have uniform properties independent of source, and yet are different when considering texture, structure, and color. Differences between fibers from animal species have been studied in regard to general flammability behavior, but differences between fibers from breeds of the same species have not been studied. Fibers from two sheep breeds (Jacob, CVM/Romeldale) and two camelids (Alpaca, Llama) were studied for flammability effects on fabrics hand knit from yarns made from these different fibers. A total of five different yarns were studied: 100% Jacob, 100% CVM/Romeldale, 100% Alpaca, 50% Llama/Merino wool, and 50% Alpaca/Merino wool. Flammability was studied with cone calorimeter, microcombustion calorimeter, and vertical flame spread techniques. The results from this limited study demonstrate that there are differences between fibers from different breeds and differences between species, but the differences cannot be easily explained on the basis of inherent heat release or chemistry of the fiber. Sometimes yarn density and the tightness of the knit have more of an effect on self-extinguishment in vertical flame spread tests than does fiber heat release/chemistry. Pure Alpaca fiber, however, displays self-extinguishing behavior and low heat release when subjected to combustion conditions. This may be related to the amount of sulfur in its chemical structure, and its ability to be spun into a yarn which yields a tighter hand-knit density. Full article

A facile, solvent-minimized approach to functionalize commercial raw fabrics is described. Reactive vapor deposition of conjugated polymers followed by post-deposition functionalization transforms common, off-the-shelf textiles into distinctly hydrophobic or superhydrophilic materials. The fabric coatings created by reactive vapor deposition are especially resistant to mechanical and solvent washing, as compared to coatings applied by conventional, solution-phase silane chemistries. Janus fabrics with dissimilar wettability on each face are also easily created using a simple, three-step vapor coating process, which cannot be replicated using conventional solution phase functionalization strategies. Hydrophobic fabrics created using reactive vapor deposition and post-deposition functionalization are effective, reusable, large-volume oil–water separators, either under gravity filtration or as immersible absorbants. Full article

Only nonwetted porous membranes can be used in membrane distillation. The possibility of application in this process the capillary polypropylene membranes manufactured by thermally-induced phase separation was studied. The performance of a few types of membranes available commercially was presented. The resistance of the membranes to wetting was tested in the continuous process of water desalination. These studies were carried out for 1000 h without module cleaning. The presence of scaling layer on the membranes surface was confirmed by Scanning Electron Microscope observations. Both the permeate flux and distillate conductivity were almost not varied after the studied period of time, what indicates that the used membranes maintained their nonwettability, and the negative influence of scaling was limited. The role of surface porosity on the pore wetting and influence of membrane wettability on the quality of the distillate obtained were discussed. Full article

Innovative reinforcement as fiber-reinforced polymer (FRP) bars has been proposed as alternative for the substitution of the traditional steel bars in reinforced concrete (RC) structures. Although the advantages of this polymer reinforcement have long been recognised, the predominantly elastic response, the reduced bond capacity under repeated load and the low ductility of RC members with FRP bars restricted its wide application in construction so far. In this work, the behavior of seven slender concrete beams reinforced with carbon-FRP bars under increasing static loading is experimentally investigated. Load capacities, deflections, pre-cracking and after-cracking stiffness, sudden local drops of strength, failure modes, and cracking propagation have been presented and commented. Special attention has been given in the bond conditions of the anchorage lengths of the tensile carbon-FRP bars. The application of local confinement conditions along the anchorage lengths of the carbon-FRP bars in some specimens seems to influence their cracking behavior. Nevertheless, more research is required in this direction. Comparisons of experimental results for carbon-FRP beams with beams reinforced with glass-FRP bars extracted from recent literature are also presented and commented. Comparisons of the experimental results with the predictions according to ACI 440.1R-15 and to CSA S806-12 are also included herein. Full article

Fully biodegradable flax/polylactic acid (PLA) thermoplastic composites were fabricated by using random (nonwoven mat) and aligned (unidirectional yarn) flax fiber as reinforcements (39% flax by volume) and Polylactic acid (PLA) as matrix. Results revealed that the aligned flax fibers have a greater reinforcing effect due to the uniform distribution of load axially along the fiber length in the composite. The aligned flax/PLA and random flax/PLA showed the tensile strength of (83.0 ± 5.0) and (151.0 ± 7.0) MPa respectively and flexural strength of (130.0 ± 5.0) and (215.0 ± 7.2) MPa respectively. Young’s modulus of (9.3 ± 1.5) and (18.5 ± 2.0) GPa and flexural modulus of (9.9 ± 1.0) and (18.8 ± 1.0) GPa was attained for the random and unidirectional fiber composites, respectively. It was also found that both composite constituents, fiber and matrix, were degradable if buried in compost soil (ready soil after composting process), which is a distinctive advantage of the new composite structures. Remarkably, the biodegradation property of aligned flax fiber composites was significantly lower than random mat composites, possibly due to the less water swelling behavior of the aligned fiber composites. After 120 days burial test, the aligned flax/PLA composite displayed the reduction of 19% mass, residual flexural strength and modulus decreased by 57 and 50% respectively, while the random mat composites exhibited the loss of 27% mass, residual flexural strength and modulus declined by 80% at the same period. Full article

This study shows that chitosan (CS) could be highly useful as a coupling agent in phosphate glass fibre/polycaprolactone (PGF/PCL) composites, as it improved the interfacial shear strength by up to 78%. PGFs of the composition 45P₂O₅–5B₂O₃–5Na₂O–24CaO–10MgO–11Fe₂O₃ were dip-coated with CS (with a degree of deacetylation >80%) dissolved in acetic acid solution (2% v/v). Different CS concentrations (3–9 g L⁻¹) and coating processes were investigated. Tensile and fragmentation tests were conducted to obtain the mechanical properties of the single fibres and interfacial properties of the PGF/PCL composites, respectively. It was observed that post-cleaning, the treated fibres had their tensile strength reduced by around 20%; however, the CS-coated fibres experienced strength increases of up to 1.1–11.5%. TGA and SEM analyses were used to confirm the presence of CS on the fibre surface. FTIR, Raman, and X-ray photoelectron spectroscopy (XPS) analyses further confirmed the presence of CS and indicated the protonation of CS amine groups. Moreover, the nitrogen spectrum of XPS demonstrated a minimum threshold of CS coating required to provide an improved interface. Full article