Fibers

In this paper we report a low cost, simple, electrochemical method for large-area growth of single crystal ZnO nanorods. The method utilizes a metallic zinc foil as the source of the necessary zinc ions for ZnO growth on indium-doped tin oxide (ITO) glass slides. The method is thoroughly discussed and investigated varying all the parameters involved. The resulting ZnO nanorods are highly oriented along c-axis and densely packed, while their length and diameter can be tuned by varying the growth parameters. Two different types of seed layers on the ITO glass slides are tested. A seed layer made by spin coating of ZnO nanoparticles results in a twofold increase of the ZnO nanorod surface density as compared with a ZnO thin film seed layer by physical vapor deposition. Additionally, the effect of oxygen supply during electrodeposition was investigated as a crucial regulatory parameter not only for the geometrical and topological characteristics of the ZnO nano-arrays but for their physical properties as well. Full article

A nanofiber mesh was prepared for the adsorption of indoxyl sulfate (IS), a toxin associated with chronic kidney disease. Removing IS is highly demanded for efficient blood purification. The objective of this study is to develop a zeolite composite nanofiber mesh to remove IS efficiently. Eight zeolites with different properties were used for IS adsorption, where a zeolite with a pore size of 7 Å, H⁺ cations, and a silica to aluminum ratio of 240 mol/mol exhibited the highest adsorption capacity. This was primarily attributed to its suitable silica to aluminum ratio. The zeolites were incorporated in biocompatible poly (ethylene-co-vinyl alcohol) (EVOH) nanofibers, and a zeolite composite nanofiber mesh was successfully fabricated via electrospinning. The nanofiber mesh exhibited an IS adsorption capacity of 107 μg/g, while the adsorption capacity by zeolite increased from 208 μg/g in powder form to 386 μg/g when dispersed in the mesh. This also led to an increase in cell viability from 86% to 96%. These results demonstrated that this zeolite composite nanofiber mesh can be safely and effectively applied in wearable blood purification devices. Full article

We report on a scalable chirped-pulse Er-doped all-fiber laser, passively mode-locked by single-wall carbon nitride nanotubes. The average output power is ~15 mW, which corresponds to a peak power of ~77 W, and pulse energy of ~1.9 nJ and was achieved using a single amplification stage. We observed chirped-pulse generation with a duration of ~24.6 ps at a relatively low repetition rate of ~7.9 MHz, with a signal-to-noise ratio of ~69 dB. To characterize the short-term stability of the obtained regime, we have measured the relative intensity noise of the laser, which is <−107 dBc/Hz in the range of 3 Hz–1000 kHz. It should be noted that the standard deviation of root mean square of average power does not exceed a magnitude of 0.9% for 3 h of measurement. Full article

Oily wastewaters are considered as one of the most dangerous types of environmental pollution. In the present study, the microfiltration (MF) process of model emulsions and real oily wastewaters was investigated. For this purpose, capillary polypropylene (PP) membranes were used. The experiments were conducted under transmembrane pressure (TMP) and feed flow rate (V_F) equal to 0.05 MPa and 0.5 m/s, respectively. It was found that the used membranes ensured a high-quality permeate with turbidity equal to about 0.4 NTU and oil concentration of 7–15 mg/L. As expected, a significant decrease in the MF process performance was noted. However, it is shown that the initial decline of permeate flux could be slightly increased by increasing the feed temperature from 25 °C to 50 °C. Furthermore, Hermia’s models were used to interpret the fouling phenomenon occurring in studied experiments. It was determined that cake formation was the dominant fouling mechanism during filtration of both synthetic and real feeds. Through detailed studies, we present different efficient methods of membrane cleaning. Results, so far, are very encouraging and may have an important impact on increasing the use of polypropylene MF membranes in oily wastewater treatments. Full article

Polarization is measured very often to study the interaction of light and matter, so the description of the polarization of light beams is of both practical and fundamental interest. This review discusses the polarization properties of structured light in multimode graded-index optical fibers, with an emphasis on the recent advances in the area of spin-orbit interactions. The basic physical principles and properties of twisted light propagating in a graded index fiber are described: rotation of the polarization plane, Laguerre–Gauss vector beams with polarization-orbital angular momentum entanglement, splitting of degenerate modes due to spin-orbit interaction, depolarization of light beams, Berry phase and 2D and 3D degrees of polarizations, etc. Special attention is paid to analytical methods for solving the Maxwell equations of a three-component field using perturbation analysis and quantum mechanical approaches. Vector and tensor polarization degrees for the description of strongly focused light beams and their geometrical interpretation are also discussed. Full article

Research on carbon fiber oxide coatings is primarily focused on metal matrix composites. Such coatings act as a diffusion barrier between a matrix and a fiber and, in addition, they can be weak boundaries that significantly increase the mechanical properties of metal matrix composites. A simple and economical method of coating deposition is the sol-gel method. However, it does not allow for control of the thickness of the carbon fiber coating. To eliminate this limitation, a combined method is used that includes sol-gel technology and electrochemical deposition. The paper presents the results of studies on the production of SiO₂ coatings on carbon fibers by the above method. The effect of current density, deposition time, salt concentration, pH of the reaction medium, TEOS/H₂O molar ratio, and alcohol concentration in the reaction medium on the structure and thickness of the coatings was studied. Full article

Analyzing representative volume elements with the finite element method is one method to calculate the local stress at the microscale of short fiber reinforced plastics. It can be shown with Monte-Carlo simulations that the stress distribution depends on the local arrangement of the fibers and is therefore unique for each fiber constellation. In this contribution the stress distribution and the effective composite properties are examined as a function of the considered volume of the representative volume elements. Moreover, the influence of locally varying fiber volume fraction is examined, using statistical volume elements. The results show that the average stress probability distribution is independent of the number of fibers and independent of local fluctuation of the fiber volume fraction. Furthermore, it is derived from the stress distributions that the statistical deviation of the effective composite properties should not be neglected in the case of injection molded components. A finite element analysis indicates that the macroscopic stresses and strains on component level are significantly influenced by local, statistical fluctuation of the composite properties. Full article

An irreversible swelling was detected in laminated beech veneer lumber within the initial moistening. Supported by the facts that the lay-up of the glued veneers is exposed to high pressure during hot pressing, and that the density of the finished material exceeds that of solid beech, it was hypothesised that the wood substance is compressed. Laboratory X-ray density profile scans were performed to check this and to identify the part of the material cross section in which the densification has taken place. The higher density was found to be located in the area of the adhesive joints, uniformly over the cross section, while the density in the middle of the veneers corresponds to that of solid beech wood. Full article

Raw earth is one of the oldest building materials, which is suitable for various uses: from the construction of load-bearing walls to use for plasters and finishes. The presence of straw fibers can give different behavior to this material. The present paper illustrates preliminary sensory and qualitative analyses, and subsequent laboratory tests that allow the characterization of the raw earth material with straw fibers for rammed earth constructions through mechanized compaction and the identification of a compatible earth mortar. The raw material considered in this study is mainly clayey; for this reason, a mix design usable with the pisé (or clay) technique has been developed. Cylindrical samples have been made through a press and subject to unconfined compression and indirect tensile tests. The results of the tests showed consistent tensile and compressive strength values in the context of earth materials. At the same time, a study for the realization of a mortar with the same base soil was carried out considering four mixtures, in order to investigate the best compromise between workability, shrinkage and compressive strengths. The purpose of the study was to investigate the mechanical characteristics of the local material through preliminary and laboratory tests, to classify it according to the Unified Soil Classification System (USCS) and to verify its suitability for a possible use in the construction field. Full article

The existing non-ductile RC structures built prior to the 1960s–1970s were mainly conceived to carry only vertical loads. As a result, the columns of these structures demonstrate poor overall hysteresis behavior during strong earthquakes, dominated by brittle shear or/and premature excessive slipping of the inadequately lap-spliced reinforcement. In the present study, the effectiveness of two different strengthening systems (including either the wrapping of the columns by carbon-fiber-reinforced polymer textile or the use of thin high-strength reinforced concrete jackets), was experimentally and analytically investigated. The main variables examined were the strengthening material, the length of the lap splices and the amount of confinement provided by the jackets. Three cantilever column specimens were constructed without incorporating modern design code requirements for preserving seismic safety and structural integrity. Subsequently, the specimens were strengthened and subjected to earthquake-type loading. Their hysteresis performances were compared, while also evaluated with respect to the response of two similar original specimens and the behavior of a control one with continuous reinforcement, tested in a previous study. The predictions of the proposed analytical formulation for the hysteresis behavior of the strengthened specimens were satisfactorily verified by the experimental results. Full article

This study deals with the investigation of the phase state of the polymer systems from polysulfone (PSF) with the addition of polyethylene glycol (PEG-400, M_n = 400 g·mol⁻¹) and polyvinylpyrrolidone (PVP K-30, M_n = 40,000 g·mol⁻¹) in N,N-dimethylacetamide (DMA), which feature lower critical solution temperatures (LCSTs). A fragment of the phase state diagram of the system PSF —PEG-400—PVP K-30—DMA was experimentally constructed in the following range of component concentrations: PSF 20–24 wt.%, PEG-400—35–38 wt.% and PVP—0–8 wt.%. It has been established that PVP addition substantially reduces the phase separation temperature down to 50–60 °C. Based on the obtained phase diagrams, a method for preparation of highly permeable hollow fiber membranes from PSF, which involves the processing of the dope solution at a temperature close to the LCST and the temperature of the bore fluid above the LCST, was proposed. Hollow fiber membranes with pure water flux of 1200 L·m⁻²·h⁻¹ and a sponge-like macrovoid-free structure were obtained via LCST-thermally induced phase separation by free fall spinning technique. Full article

This work presents fabricated silica microstructured optical fiber with special equiangular spiral six-ray geometry, an outer diameter of 125 µm (that corresponds to conventional commercially available telecommunication optical fibers of ratified ITU-T recommendations), and induced chirality with twisting of 200 revolutions per minute (or e.g., under a drawing speed of 3 m per minute, 66 revolutions per 1 m). We discuss the fabrication of twisted microstructured optical fibers. Some results of tests, performed with pilot samples of designed and manufactured stellar chiral silica microstructured optical fiber, including basic transmission parameters, as well as measurements of near-field laser beam profile and spectral and pulse responses, are represented. Full article

Reconstruction of buildings and structures is becoming one of the main directions in the field of construction, and the design and production of works during reconstruction are significantly different from the ones of new buildings and structures. After carrying out a number of studies on the inspection of the technical condition of buildings in order to determine the effect of defects on the bearing capacity, the criteria for assessing the state of floor slab structures were identified. Conclusions on the state and further work of elements of reinforced concrete structures are considered. The authors achieve the aim of reinforcing flexural elements of reinforced concrete structures with fiber-reinforced mortar, which is especially important for floor elements with increased operational requirements. A technique for constructing a reinforcement layer using fiber-reinforced mortar from coarse basalt fiber has been developed. The parameters of basalt fiber in the reinforcement layer are substantiated. A method for solving problems of the operation of multilayer coatings under the influence of operational loads is used, in which the model prerequisites for describing the operation of layers are simplified, where the bearing layers are represented by classical Kirchhoff-Love plates. When solving problems, the maximum possible number of design features of flexural members is taken into account, in combination with appropriate experimental studies, the method allows us to consider all the variety of structures for reinforcing coatings and meet the needs of their practical application. Full article

Cellulose microfibrils (CMFs) and micronized rubber powder (MRP) can be derived from low or negative-cost agricultural/industrial waste streams and offer environment-friendly and cost-effective pathways to develop engineering products. This study investigated the efficacy of adding these micromodifiers on the performance characteristics of asphalt binders. In this work, samples were produced using a mixture of slow-setting anionic asphalt emulsion with various combinations of MRP (at 0, 2 and 10 wt %) and four types of CMFs (hydrophobic and hydrophilic with crystalline ratios of 86% and 95%) at 0, 2 and 5 wt %. The performance of modified asphalt samples was assessed by penetration depth (PD), softening point (SP), and penetration index (PI). Linear regression analysis showed that adding CMFs and/or MRP reduced PD and increased SP values. The type of CMFs significantly affected the performance, which becomes more distinct with the increased weight content of CMFs. While hydrophilic CMFs caused increases in SP and PI values, no clear trend was seen to determine the effect of CMF crystallinity. It was also discovered that the combined addition of CMF and MRP achieved similar PI values at lower total weight content compared to using MRP alone. Full article

Plant fibres and especially flax can be distinguished from most synthetic fibres by their intricate shape and intrinsic porosity called lumen, which is usually assumed to be tubular. However, the real shape appears more complex and thus might induce stress concentrations influencing the fibre performance. This study proposes a novel representation of flax fibre lumen and its variations along the fibre, an interpretation of its origin and effect on flax fibre tensile properties. This investigation was conducted at the crossroads of complementary characterization techniques: optical and scanning electron microscopy (SEM), high-resolution X-ray microtomography (µCT) and mechanical tests at the cell-wall and fibre scale by atomic force microscopy (AFM) in Peak-Force Quantitative Nano-Mechanical property mapping (PF-QNM) mode and micromechanical tensile testing. Converging results highlight the difficulty of drawing a single geometric reference for the lumen. AFM and optical microscopy depict central cavities of different sizes and shapes. Porosity contents, varying from 0.4 to 7.2%, are estimated by high-resolution µCT. Furthermore, variations of lumen size are reported along the fibres. This intricate lumen shape might originate from the cell wall thickening and cell death but particular attention should also be paid to the effects of post mortem processes such as drying, retting and mechanical extraction of the fibre as well as sample preparation. Finally, SEM observation following tensile testing demonstrates the combined effect of geometrical inhomogeneities such as defects and intricate lumen porosity to drive the failure of the fibre. Full article

Fiber-reinforced geopolymer composites (FRGCs) were considered in terms of application in various areas, and a review is presented in this article. FRGCs are emerging as environmentally friendly materials, replacing cement in the construction industry. An alternative inorganic binder such as a geopolymer matrix promotes environmental awareness on releasing less CO₂. The inorganic matrix geopolymer is considered a greener cement for FRGCs. Various types of fiber reinforcements and their role toward the improvement of tensile, flexural, impact strength, fracture toughness, and energy absorption in overall mechanical performance in FRGCs were discussed. FRGCs and their properties in mechanical response, with correlation toward microstructure evolution at room and elevated temperatures, were also discussed. Simultaneously, the durability and impact strength of FRGCs and damage area as a function of the energy absorption were presented with 3D reconstruction images. Moreover, 3D images will cover the internal volume of the FRGCs with internal porosity and fiber orientation. Hybrid fiber reinforcement adds an extra step for the application of geopolymer composites for structural applications. Full article

The present paper proposes a useful closed-form solution for a wide class of mechanical problems, among which one of the most relevant and debated is the deboning process of Fiber-Reinforced Polymer (FRP) strips glued to generic materials and possibly intended as a mode-II fracture process. Specifically, after outlining well-known equations, a novel piecewise analytical formulation based on a cascading solution process is proposed with the aim of keeping the mathematical expressions of the relevant mechanical quantities as simple as possible. Although other analytical solutions and numerical procedures are already available in the literature, the present one is capable of handling the softening or snap-back response deriving from the full-range simulation of the depending process with no need for complex numerical techniques. This is obtained by considering the slip at the free end of the strip as the main displacement control parameter. After some comparisons between the proposed closed-form solution and experimental results available in the literature, some mechanical considerations are highlighted by elaborating on the results of a parametric study considering the variation of the main geometric and mechanical quantities. The numerical code implemented as part of the present study is available to readers in Open Access. Full article

We show numerically that ultra-short pulses can be generated in the mid-infrared when a gas filled hollow-core fiber is pumped by a fundamental pulse and its second harmonic. The generation process originates from a cascaded nonlinear phenomenon starting from a spectral broadening of the two pulses followed by an induced phase-matched four wave-mixing lying in the mid-infrared combined with a dispersive wave. By selecting this mid-infrared band with a spectral filter, we demonstrate the generation of ultra-short 60 fs pulses at a 3–4 µm band and a pulse duration of 20 fs can be reached with an additional phase compensator. Full article