Nanomanufacturing

Simultaneous hydrogen fuel and value-added chemical production from renewable resources is a key strategy in sustainable catalysis. This work presents a novel strategy employing metal–organic frameworks (MOFs) as precursors for synthesizing advanced titanium dioxide (TiO₂) photocatalysts with enhanced structural and optical properties. Two photocatalysts, M-BDC and M-2,5PDC, were synthesized via controlled calcination of MIL-125(Ti) using terephthalic and 2,5-pyridinedicarboxylic acids, respectively. Characterization confirmed the formation of mixed anatase/rutile TiO₂ phases with mesoporous structures. Notably, nitrogen incorporation in M-2,5PDC reduced the optical band gap to 2.94 eV compared with 3.08 eV for M-BDC, enhancing visible-light absorption. Photocatalytic experiments conducted at near-neutral pH (6.0) demonstrated effective simultaneous glycerol oxidation and hydrogen evolution without the use of alkaline additives. M-BDC achieved 30% glycerol conversion with 78.85% selectivity toward dihydroxyacetone and 21.15% toward glyceraldehyde, while M-2,5PDC exhibited selectivities of 71.55% and 28.45%, respectively. Glycerol underwent partial oxidation without complete mineralization, generating high-value products in parallel with hydrogen production. Both catalysts displayed excellent reuse stability across three consecutive cycles, with M-BDC showing enhanced dihydroxyacetone selectivity (78.85% to 84.42% between cycles). This MOF-derived TiO₂ platform integrates controlled synthesis, near-neutral pH operation, high selectivity, and catalytic stability, thereby establishing a viable strategy for the simultaneous production of clean fuel and value-added chemicals from renewable resources.

TiO₂ films with a thickness of 20 nm were obtained by anodizing a titanium film with an aluminum sublayer on a glass substrate. The I–V characteristics were studied in a temperature range of 100–300 K. Three linear sections can be distinguished on the I–V curves in logarithmic coordinates with a bias voltage of up to 2.5 V. The first section is an ohmic section with a bias voltage sweep from 0 V. The second section is associated with the space-charge-limited currents. The third section is characterized by the flow of Poole–Frenkel currents. In the third section, the slope of the approximating line is greater than in the second one due to the flow of higher currents. This is explained by the transition of electrons from donor centers to trap levels, which leads to a decrease in the number of free traps available for capturing electrons injected from the contacts into the conduction band. The obtained values of the Fermi energy of 0.032 and 0.028 eV for temperatures from 100 to 300 K, respectively, indicate that the electron traps in the forbidden zone of TiO₂ are shallow. The value of the donor level energy E = 0.082 eV is close to the values of the activation energy of thermal conductivity. This indicates the formation of donor centers in anodic TiO₂ by the mechanism of donor vacancies. In anodic TiO₂ films, the concentration of electron traps is 10¹⁵ cm⁻³, which is approximately three orders of magnitude less than their concentration in anodic TiO₂ films obtained by vacuum deposition.

Although recycled poly(ethylene terephthalate) (rPET) is an attractive, sustainable feedstock for electrospinning, optimization of processing variables for filtration performance remains limited. This study quantifies how polymer concentration, flow rate, and applied voltage govern fiber morphology and key filtration metrics—collection efficiency (η), pressure drop (ΔP), quality factor (Q_f), and porosity—in rPET membranes. A fractional factorial design was employed to model interactions and identify trade-offs in filtration performance. The optimal condition was obtained at 16 wt.% PET, 1.2 mL·h⁻¹, and 22 kV, yielding uniform fibers with an average diameter of 328.6 nm and high filtration efficiencies (95.65–99.99%). The permeability constants were 1.07 × 10⁻¹² m² (20 wt.% PET) and 1.15 × 10⁻¹³ m² (8 wt.% PET), indicating an increase in permeability with increasing polymer concentration and fiber diameter. The 20 wt.% PET membrane delivered the highest Q_f of 0.0646 Pa⁻¹ with a low ΔP of 48.5 Pa at 4.8 cm·s⁻¹, reflecting a favorable balance between collection and airflow resistance. In summary, higher PET concentrations reduce flow resistance and improve Q_f, whereas lower concentrations yield finer fibers and high η at the expense of permeability. rPET nanofiber membranes, therefore, represent a sustainable and versatile route to high-efficiency, lower-pressure-drop air filters for residential, industrial, and commercial environments.