The copper-based metal-organic framework (HKUST-1) exhibits interesting properties, such as high porosity and large specific surface area, which are useful as electrode materials for supercapattery. Herein, the HKUST-1 was synthesized through a facil...
This study synthesized two eco-friendly inhibitors—a chitosan–copper metal–organic framework (CS@Cu MOF) and chitosan–Schiff base–Cu complex (Schiff–CS@Cu)—for Q345 steel protection in 3.5% NaCl/1M HCl. Elect...
Optimizing efficient electrode materials that combine high energy density, rapid charge transport, and excellent cycling stability remains a challenge for advanced supercapacitors. Here, we report the synthesis of an innovative copper(I)-based metal&...
Fighting against bacterial infection and accelerating wound healing remain important and challenging in infected wound care. Metal–organic frameworks (MOFs) have received much attention for their optimized and enhanced catalytic performance in...
The electrochemical reduction of carbon dioxide (CO2) to methane (CH4) holds tremendous potential in mitigating greenhouse gas emissions and producing renewable fuels. Thus, this review provides a comprehensive overview of the utilization of copper-b...
Owing to their potential to transform traditional medical diagnostics and health monitoring, wearable biosensors have become an alternative evolutionary technology in the field of medical care. However, it is still necessary to overcome some key tech...
In the extensive terrain of catalytic procedures for the synthesis of organic molecules, metal–organic frameworks (MOFs) as heterogenous catalysts have been investigated in a variety of chemical processes, including Friedel–Crafts reactio...
Polyurethane foams (PUFs) have attracted attention as biomaterials because of their low adhesion to the wound area and suitability as biodegradable or bioactive materials. The composition of the building blocks for PUFs can be controlled with additiv...
It is quite essential to obtain an excellent CO2 adsorption capacity, CO2 adsorption selectivity and water vapor stability at the same time for practical CO2 capture after combustion. Through the combination of ultramicropore and the high density of...
As the industry of olive oil continues to grow, the management of olive mill wastewater (OMW) by-products has become an area of great interest. While many strategies for processing OMW have been established, more studies are still required to find an...
A highly porous metal-organic framework (Cu-TDPAT), constructed from a paddle-wheel type dinuclear copper cluster and 2,4,6-tris(3,5-dicarboxylphenylamino)-1,3,5-triazine (H6TDPAT), has been tested in Ullmann and Goldberg type C–N coupling reactions...
The rise in bacterial resistance to currently used antibiotics is the main focus of medical researchers. Bacterial multidrug resistance (MDR) is a major threat to humans, as it is linked to greater rates of chronic disease and mortality. Hence, there...
Metal–organic frameworks (MOFs) are hybrid inorganic–organic 3D coordination polymers with metal sites and organic linkers, which are a “hot” topic in the research of sorption, separations, catalysis, sensing, and environmental remediation. In this s...
Recent development shows that carbon-based composites are proving to be the most promising materials in hydrogen energy production, storage and conversion applications. In this study, composites of the copper-based metal-organic framework with differ...
The development of new techniques for the preparation of organic compounds is important, with catalytic processes being key to this innovation. The development of copper-based metal-organic frameworks to promote oxidative couplings has allowed the sy...
With the excessive use of fossil fuels, atmospheric carbon dioxide (CO2) concentrations have risen dramatically in recent decades, leading to serious environmental and social issues linked to global climate change. The emergence of renewable energy s...
: A copper-based metal-organic framework with 1,3,5-tricarboxylic acid linkers was prepared through a facile hydrothermal method. This MOF has not been used in organic reactions widely. Cu.BTC was employed as an affordable, competent heterogeneous ca...
The photocatalytic reduction of CO2 into high-value chemicals utilizing solar energy represents a sustainable approach to mitigating greenhouse gas emissions and advancing renewable chemical production. Recently, copper-based metal–organic fram...
The design of metal–organic frameworks (MOFs) allows the definition of properties for their final application in small-scale heterogeneous catalysis. Incorporating various catalytic centers within a single structure can produce a synergistic ef...
This research explores the integration of DUT-67 metal organic frameworks into polyethyleneimine-based hydrogels to assemble a composite system with enough mechanical strength, pore structure and chemical affinity to work as a sorbent for water remed...
Some copper-based metal–organic frameworks show promise for use as electrocatalysts because they allow for an electrode configuration in which copper species with redox and electron-conducting properties are immobilized in a three-dimensional a...
Currently, the catalytic reduction of nitrobenzene requires more efficient and low-cost catalysts. In this work, a new copper-based metal-organic framework (MOF) was designed by the calcination of Cu–MOF at 700 °C (denoted as Cu@C). The cat...
Herein, we present a one-pot hydrothermal approach for synthesizing metal–organic framework-derived copper (II) benzene-1,3,5-tricarboxylate (Cu-BTC) nanowires (NWs) using dopamine as the reducing agent and precursor for a polydopamine (PDA) su...
The efficient reduction of CO2 into valuable products such as methanol, over metal-organic frameworks (MOFs) based catalyst, has received much attention. The photocatalytic reduction is considered the most economical method due to the utilization of...
A new nanocomposite consisting of activated carbon (AC) from the Cortaderia selloana flower and copper-based metal-organic framework (HKUST-1) was synthesized through a single-step solvothermal method and applied for the removal of lead ions from aqu...
Copper-based metal–organic frameworks (MOFs) with different oxidation states and near-uniform particle sizes have been successfully synthesized. Mixed-matrix polyimide membranes incorporating 0.1–7 wt% of Cu(II) benzene-1,2,5-tricarboxyli...
In this study, a MOF-199/Ag@Au SERS sensing structure was successfully synthesized by combining metal–organic frameworks (MOFs) with surface-enhanced Raman scattering (SERS) technology for the efficient detection of dopamine (DA), a biomarker f...
Two-dimensional (2D) metal-organic frameworks (MOFs) are fascinating photocatalytic materials because of their unique physical and catalytic properties. Herein, we report a new (E)-4-(3-carboxyacrylamido) benzoic acid [ABA–MA] ligand synthesize...
Emerging new metal-organic structures with tunable physicochemical properties is an exciting research field for diverse applications. In this work, a novel metal-organic framework Cu(HIT)(DMF)0.5, named URJC-1, with a three-dimensional non-interpenet...
HKUST-1, a copper-based metal organic framework (MOF), has been investigated as a catalyst in various reactions. However, the HKUST-1 shows low catalytic activity in the oxidation of catechol. Therefore, we synthesized Fe3O4@HKUST-1 by layer-by layer...
In recent years, organic dye contamination has posed a significant threat to water safety. This study presents a novel composite photocatalyst comprising graphitic carbon nitride quantum dots (g-C3N4QDs) supported on a copper-based metal–organi...
Green synthesis plays a crucial role in advancing sustainability within materials science. This study explores the integration of metal–organic frameworks (MOFs), obtained through green synthesis, using an electrospinning post-processing techni...
The crystal structure of a copper squarate metal-organic framework is fully determined using first principles methods based in density functional theory. The compressibility of this material is studied by optimizing the structure under different isot...
Infection control and bone regeneration remain critical challenges in bone defect treatment. We developed a 3D-printed scaffold incorporating copper-based metal–organic framework-74 (Cu-MOF-74) within a polycaprolactone/hydroxyapatite composite...
Copper squarate is a metal–organic framework with an oxo-carbonic anion organic linker and a doubly charged metal mode. Its structure features large channels that facilitate the adsorption of relatively small molecules. This study focuses on ex...
Hydroxychloroquine (HCQ), a cornerstone therapeutic agent for autoimmune diseases, requires precise serum concentration monitoring due to its narrow therapeutic window. Current HCQ monitoring methods such as HPLC and LC-MS/MS are sensitive but costly...
A prototypical metal-organic framework (MOF), a 2D periodic porous structure based on the assembly of copper ions and benzene dicarboxylate (bdc) ligands (Cu(bdc)·xH2O), was grown successfully as a thin film on interdigitated electrodes (IDEs). IDEs...
The activity and recyclability of Cu-MOF-74 as a catalyst was studied for the ligand-free C–O cross-coupling reaction of 4-nitrobenzaldehyde (NB) with phenol (Ph) to form 4-formyldiphenyl ether (FDE). Cu-MOF-74 is characterized by having unsaturated...
Synthesis of anionic metal–organic framework Na[Ce(BDC)2(DMF)2] based on cerium (III)–sodium terephthalate was performed. The crystal structure, studied by the Rietveld method, consists of anionic [Ce(BDC)2]− layers, connected by in...
The direct oxidation of methane to methanol (MTM) is a significant challenge in catalysis and holds profound economic implications for the modern chemical industry. Bioinspired metal–organic frameworks (MOFs) with active iron and copper sites h...
Metal–organic frameworks (MOFs) are highly versatile materials. Here, two novel MOFs, branded as IEF-23 and IEF-24 and based on an antibacterial tricarboxylate linker and zinc or copper cations, and holding antibacterial properties, are present...
This work presents a novel approach to synthesizing magnetic core-shell nanocomposites, consisting of magnetic nanoparticles and a metal-organic framework, for environmental applications. The synthesis is based on the encapsulation of magnetic Fe3O4...
The present work developed an electrochemical genosensor for the detection of virulence outer membrane protein A (ompA, tDNA) gene of Cronobacter sakazakii (C. sakazakii) by exploiting the excellent glucose-oxidase-mimicking activity of copper Metal-...
Methylene blue (MB) is a commonly used dye that generates a large amount of dye wastewater during its application. If discharged untreated, it poses a serious threat to water environments and human health. Therefore, the removal of methylene blue fro...
Here, a novel copper p-aminophenol metal–organic framework (Cu(PAP)2) is first reported. Powder X-ray diffraction (PXRD), infrared spectra (FTIR), Raman spectra, transmission electron microscopy (TEM) and X-ray photoemission spectroscopy (XPS),...
Metal-organic frameworks (MOFs) were supported on polymer membrane substrates for the fabrication of composite polymer membranes based on unmodified and modified polymer of intrinsic microporosity (PIM-1). Layers of two different MOFs, zeolitic imida...
Direct conversion of methane to methanol is an effective and practical process to improve the efficiency of natural gas utilization. Copper (Cu)-based catalysts have attracted great research attention, due to their unique ability to selectively catal...
In the critical domain of wastewater treatment, the development of cost-effective, durable, and recyclable adsorbents with high adsorption capacities remains a significant challenge. This study introduces a novel magnetic bimetallic Metal–Organic Fra...
HKUST-1 (HKUST = Hong Kong University of Science and Technology) is one of the most recognized metal-organic frameworks (MOFs) based on copper and trimesate, extensively studied for a variety of applications, such as gas storage, separation, adsorpti...
The synthesis and characterization of an isomorphous series of copper-containing microporous metal-organic frameworks (MOFs) based on triazolyl isophthalate linkers with the general formula [Cu4(μ3-OH)2(R1-R2-trz-ia)3(H2O)x] are presented. Through si...
of 2