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Preparation of [email protected]2O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol

Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University, Busan 609-765, Korea
Department of Naval Architecture & Ocean Engineering, Pusan National University, Busan 609-735, Korea
Department of Physics, Pusan National University, Busan 609-735, Korea
Authors to whom correspondence should be addressed.
These authors contributed equally to this work.
Academic Editor: Nicola Cioffi
Molecules 2016, 21(11), 1467;
Received: 30 August 2016 / Revised: 25 October 2016 / Accepted: 26 October 2016 / Published: 2 November 2016
(This article belongs to the Special Issue Metal Nanocatalysts in Green Synthesis and Energy Applications)
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HKUST-1, a copper-based metal organic framework (MOF), has been investigated as a catalyst in various reactions. However, the HKUST-1 shows low catalytic activity in the oxidation of catechol. Therefore, we synthesized Fe3O4@HKUST-1 by layer-by layer assembly strategy and [email protected]2O by reduction of HKUST-1 for enhancement of catalytic activity. [email protected]2O nanoparticles exhibited highly effective catalytic activity in oxidation of 3,5-di-tert-butylcatechol. Through this method, MOF can maintain the original core-shell structure and be used in various other reactions with enhanced catalytic activity. View Full-Text
Keywords: nanoparticles; HKUST-1; oxidation; catechol nanoparticles; HKUST-1; oxidation; catechol

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Jang, S.; Yoon, C.; Lee, J.M.; Park, S.; Park, K.H. Preparation of [email protected]2O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol. Molecules 2016, 21, 1467.

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