Table of Contents
Molecules, Volume 22, Issue 11 (November 2017)
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Cover Story (view full-size image) The strained dispiro hydrocarbon was endowed with high electron donating ability, which undergo [...] Read more. The strained dispiro hydrocarbon was endowed with high electron donating ability, which undergo 2e-oxidation to give a stable dication through fission of the elongated C-C bond. Upon 2e-reduction of the salt, the colorless dispiro compound was regenerated. Due to the deep purple color of dibenzotropylium, reversible hydrocarbon electrochromism was demonstrated upon electrolysis in CH2Cl2. Only by changing the solvent polarity, can the dication be selectively converted into another spiro species. View this paper