Supramolecular metal–organic cages, a class of molecular containers formed via coordination-driven self-assembly, have attracted sustained attention for their applications in catalysis, due to their structural aesthetics and unique properties....
The inherent porous nature and facile tunability of metal–organic frameworks (MOFs) make them ideal candidates for use in multiple fields. MOF hybrid materials are derived from existing MOFs hybridized with other materials or small molecules us...
The determination of organic and inorganic pollutants in fish samples is a complex and demanding process, due to their high protein and fat content. Various novel sorbents including graphene, graphene oxide, molecular imprinted polymers, carbon nanot...
Metal-Organic Frameworks (MOFs) as a class of crystalline materials are constructed using metal nodes and organic spacers. Polydentate N-donor ligands play a mainstay-type role in the construction of metal−organic frameworks, especially cationic MOFs...
Entropy is a thermodynamic function used in chemistry to determine the disorder and irregularities of molecules in a specific system or process. It does this by calculating the possible configurations for each molecule. It is applicable to numerous i...
Among the water pollution sources, heavy metals are considered the most hazardous because of their high toxicity to human health and their ability to badly damage the kidneys, brain, and nerves, as well as cause birth defects. Based on the promising...
In the field of photocatalysis, metal-organic frameworks (MOFs) have drawn a lot of attention. MOFs have a number of advantages over conventional semiconductors, including high specific surface area, large number of active sites, and an easily tunabl...
Electrolysis utilizing renewable electricity is an environmentally friendly, non-polluting, and sustainable method of hydrogen production. Seawater is the most desirable and inexpensive electrolyte for this process to achieve commercial acceptance co...
This overview provides insights into organic and metal–organic polymer (OMOP) catalysts aimed at processes carried out in the liquid phase. Various types of polymers are discussed, including vinyl (various functional poly(styrene-co-divinylbenz...
A series of metal–organic coordination complexes based on alkaline-earth metal centers [Mg(II), Ca(II), and Ba(II)] and the ligand 5-aminoisophthalate (aip2−) revealed notable structural diversity, both in the materials’ dimensional...
Metal–Organic Frameworks (MOFs) are a subclass of porous materials that have unique properties, such as varieties of structures from different metals and organic linkers and tunable porosity from a structure or framework design. Moreover, modif...
Controlling the indoor air (volatile organic compound) VOCs concentration plays an important role in creating a healthy and comfortable living environment. Comparing several VOCs purification measures, solid adsorption is found to be a promising air...
Nitro group reduction is a reaction of a considerable importance for the preparation of bulk chemicals and in organic synthesis. There are reports in the literature showing that incorporation of metal nanoparticles (MNPs) inside metal–organic f...
Food samples such as milk, beverages, meat and chicken products, fish, etc. are complex and demanding matrices. Various novel materials such as molecular imprinted polymers (MIPs), carbon-based nanomaterials carbon nanotubes, graphene oxide and metal...
Metal-organic frameworks (MOFs) have found uses in adsorption, catalysis, gas storage and other industrial applications. Metal Biomolecule Frameworks (bioMOFs) represent an overlap between inorganic, material and medicinal sciences, utilising the por...
Ligands with a purely aliphatic backbone are receiving rising attention in the chemistry of coordination polymers and metal–organic frameworks. Such unique features inherent to the aliphatic bridges as increased conformational freedom, non-pola...
This paper reports a simple method to recycle plastic-bottle and Li-ion-battery waste in one process by forming valuable coordination polymers (metal–organic frameworks, MOFs). Poly(ethylene terephthalate) from plastic bottles was depolymerized...
In recent years, incredible endeavors have been devoted to the design and self-assembly of discrete metal–organic cages (MOCs) with expanding intricacy and functionality. The controlled synthesis of metal–organic supramolecular cages with...
Currently, metal–organic frame works (MOFs) as novel hybrid nanoporous materials are a top research interest, including endeavors in heterogeneous catalysis. MOF materials are promising heterogeneous catalytic systems due to their unique charac...
In this study, lanthanide metal-organic frameworks Ln(BTC)(DMF)2(H2O) (LnMOFs) are synthesized using the metal nitrates as lanthanide (Ln = La, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb and Lu) source and 1,3,5-benzenetricarboxylic acid (BTC) as a c...
The quantitative determination of xenobiotic compounds, as well as biotics in biological matrices, is generally described with the term bioanalysis. Due to the complexity of biofluids, in combination with the low concentration of the small molecules,...
Heavy metals are inorganic pollutants which pose a serious threat to human and environmental safety, and their effective removal is becoming an increasingly urgent issue. Metal–organic frameworks (MOFs) are a novel group of crystalline porous m...
The sustainable management of wastewater through recycling and utilization stands as a pressing concern in the trajectory of societal advancement. Prioritizing the elimination of diverse organic contaminants is paramount in wastewater treatment, garn...
Metal-organic frameworks (MOFs) are emerging class of ordered porous materials consisting of metal clusters and organic ligands. High porosity, adjustable topology, composition and structural diversity have earned MOFs extensive popularity in various...
Metal-organic frameworks (MOFs) are porous hybrid materials composed of metal ions and organic linkers, characterized by their crystallinity and by the highest known surface areas. MOFs structures present accessible cages, tunnels and modifiable pore...
Recent progress about a novel organic–inorganic hybrid materials, namely cyclodextrins (CDs) modified/coated metal–organic frameworks (MOFs) is summarized by using a special categorization method focusing on the interactions between CDs a...
This research explores the application of surfactants as green solvents for the rapid microwave synthesis of metal-organic framework (MOF) materials. Lead, copper, and iron metal-organic framework materials were synthesized using surfactant-thermal m...
Supercapacitors (SCs), one of the most popular types of energy-storage devices, present lots of advantages, such as large power density and fast charge/discharge capability. Being the promising SCs electrode materials, metal–organic frameworks...
In recent years, metal–organic frameworks (MOFs) have garnered significant attention as highly efficient catalysts for CO2 photoreduction, owing to their unique electronic configurations and exceptional CO2 adsorption properties. This review pr...
The growing demand for energy, coupled with the unsustainable nature of fossil fuels due to global warming and the greenhouse effect, have led to the advancement of renewable energy production concepts. Innovations such as photovoltaics, wind energy,...
Among the numerous fascinating properties of metal–organic frameworks (MOFs), their rotational dynamics is perhaps one of the most intriguing, with clear consequences for adsorption and separation of molecules, as well as for optical and mechan...
Metal–organic frameworks (MOFs) are crystalline materials that are formed by self-assembling organic linkers and metal ions with large specific areas and pore volumes. Their chemical tunability, structural diversity, and tailor-ability make the...
In this study, a novel porphyrin-based metal–organic framework (Co-Por MOF) was successfully synthesized by a simple one-step solvothermal method. We report a metal–organic framework based on the covalent interaction of an organic linker, 5,10,15,20-...
Metal-organic frameworks (MOFs) are an evolving class of crystalline porous materials made of organic linkers and metallic nodes. The rich chemistry of MOFs allows them to have an almost infinite number of possible structures. Consequently, they have...
During the last two decades, metal-organic cages (MOCs) have been extensively investigated and well documented. Meanwhile, phosphorescent MOCs have emerged as a kind of new MOC material but have not been given much attention. The diversity of their s...
Metal nanomaterials have been reported as effective absorbents for the removal of pollutants in the water system, but the release of ions from these nanomaterials brings another concern. Herein, silver nanoclusters (AgNCs) were encapsulated in porous...
Much has been written about the fundamental aspects of the metal–organic frameworks (MOFs). Still, details concerning the MOFs with structural flexibility are not comprehensively understood. However, a dramatic increase in research activities c...
Electrochemical glucose sensors play a crucial role in medicine, bioscience, food science, and agricultural science. Metal–organic frameworks possess exceptional properties, such as large specific surface area, high porosity, tunable pore struc...
Among the different alternatives for catalysis using metal–organic frameworks (MOFs) or covalent organic frameworks (COFs), photocatalysis has remarkably evolved during the last decade. Photocatalytic reticular materials allowed recyclability a...
The focus of discussion of this review is the application of the most recent synthesized hydrophobic metal-organic frameworks (MOFs). The most promising hydrophobic MOFs are mentioned with their applications and discussed. The various MOFs considered...
In this work, diamondoid metal-organic frameworks (MOFs) were efficiently prepared by sonochemical synthesis and grown on polyimide (PI), aiming to improve the anti-wear performance of the PI matrix. By introducing MOFs into the PI matrix, the free m...
Three isostructural metal-organic frameworks, (MOFs), [Fe(OH)(1,4-NDC)] (1), [Al(OH)(1,4-NDC)] (2), and [In(OH)(1,4-NDC)] (3) have been synthesized hydrothermally by using 1,4-naphthalene dicarboxylate (1,4-NDC) as a linker. The MOFs were characteriz...
Volatile organic compounds (VOCs) are a major threat to human life and health. The technologies currently used to remove VOCs mainly include adsorption and photocatalysis. Adsorption is the most straightforward strategy, but it cannot ultimately elim...
In the past decade, advances in electrically conductive metal–organic frameworks (MOFs) and MOF-based electronic devices have created new opportunities for the development of next-generation sensors. Here we review this rapidly-growing field, with a...
Environmental pollution caused by organic effluents emitted by industry has become a worldwide issue and poses a serious threat to the public and the ecosystem. Metal–organic frameworks (MOFs), comprising metal-containing clusters and organic b...
Metal-organic frameworks represent a porous class of materials that are build up from metal ions or oligonuclear metallic complexes and organic ligands. They can be considered as sub-class of coordination polymers and can be extended into one-dimensi...
Metal–organic frameworks (MOFs) are emerging porous materials with highly tunable structures developed in the 1990s, while organometallic chemistry is of fundamental importance for catalytic transformation in the academic and industrial world for man...
Epoxy coatings are developing fast in order to meet the requirements of advanced materials and systems. Progress in nanomaterial science and technology has opened a new era of engineering for tailoring the bulk and surface properties of organic coati...
Ammonia (NH3) emissions during agricultural production can cause serious consequences on animal and human health, and it is quite vital to develop high-efficiency adsorbents for NH3 removal from emission sources or air. Porous metal–organic fra...
Recently, the emerging class of hydroxamate-based metal–organic frameworks (MOFs) has demonstrated significant structural diversity and chemical robustness, both essential for potential applications. Combining the favorable hard–hard Bi-O...
of 207