Hyper-crosslinked polymers are attracting extensive attention owing to their ease of design and synthesis. Based on the flexibility of its molecular design, a hyper-crosslinked polymer with a π-conjugated structure and its derived carbon were synt...
Hyper-crosslinking polymers and its immobilized acid ionic liquid catalyst were prepared using cheap pitch, as a monomer, through hyper-crosslinking reactions and allyl chloride, as a chlorine source, for chloromethylation and further grafting with i...
Ambient condition-determined chemical CO2 fixation affords great promise for remitting the pressure of CO2 release. The construction of a microporous environment easily captures CO2 molecules around the reactive sites of the catalyst to reinforce the...
The preparation of porous carbons by post-synthesis treatment of hypercrosslinked polymers is described, with a careful physico-chemical characterization, to obtain new materials for gas storage and separation. Different procedures, based on chemical...
In this paper, we adopted a simple and efficient strategy to prepare a β-cyclodextrin (β-CD)-modified hyper-crosslinked polymer (CDM-HCP). The structures and physicochemical properties of the as-synthesized polymer were also evaluated. It w...
The synthesis of efficient and sustainable heterogeneous Pd-based catalysts has been an active field of research due to their crucial role in carbon–carbon coupling reactions. In this study, we developed a facile and eco-friendly in situ assembly tec...
Vascularization is one of the key components of tissue engineering and must accompany the ingrowth of new tissues to establish an environment conducive to repair and regeneration of damaged tissue. The overarching objective of this study was to inves...
Hyper-crosslinked porous organic nanomaterials, especially the hyper-crosslinked polymers (HCPs), are a unique class of materials that combine the benefits of high surface area, porous structure, and good chemical and thermal stability all rolled int...
In recent years, porous materials have been extensively studied by the scientific community owing to their excellent properties and potential use in many different areas, such as gas separation and adsorption. Hyper-crosslinked porous polymers (HCLPs...
In this study, we successfully synthesized two types of meso/microporous carbon materials through the carbonization and potassium hydroxide (KOH) activation for two different kinds of hyper-crosslinked polymers of TPE-CPOP1 and TPE-CPOP2, which were...
Acteoside (ACT) is an important medicinal component, but its content is scarce. To obtain higher purity of ACT, the adsorption method was used to purify it. In this study, a broad-pore-domain hyper-crosslinked polymer (BHP-Kae) was prepared to adsorb...
The influence of hyper-crosslinked polystyrene (HCPS) MacronetTM MN200 on the gas transport properties and aging of the highly permeable glassy polymer poly(1-trimethylsilyl-1-propyne) (PTMSP) was studied and analyzed in detail. The gas transport cha...
Mixed-matrix membranes (MMMs) are membranes that are composed of polymers embedded with inorganic particles. By combining the polymers with the inorganic fillers, improvements can be made to the permeability compared to the pure polymer membranes due...
Carbon-based materials with different morphologies have special properties suitable for application in adsorption, catalysis, energy storage, and so on. Carbon spheres and carbon monoliths are also nanostructured materials showing promising results....
Hypercrosslinked polymers (HCPs) constructed by the Friedel–Crafts alkylation reaction of aromatic compounds have emerged as a new class of porous materials with unique merit. Herein, a HCP named HCP-TPB was coated onto a capillary column throu...
Cobalt-doped graphene-coupled hypercrosslinked polymers (Co-GHCP) have been successfully prepared on a large scale, using an efficient RAFT (Reversible Addition-Fragmentation Chain Transfer Polymerization) emulsion polymerization and nucleophilic sub...
The effective conversion of carbon dioxide (CO2) into cyclic carbonates requires porous materials with high ionic content and large specific surface area. Herein, we developed a new systematic post-synthetic modification strategy for synthesizing imi...
Clean water is one of the sustainable development goals. Organic dye is one of the water pollutants affecting water quality. Hence, the conversion of dyes to safer species is crucial for water treatment. The Fenton reaction using Fe as a catalyst is...
Natural gas purification and the mitigation of carbon dioxide (CO2) emissions from flue gases are critical steps in alleviating the greenhouse effect and significantly mitigate multiple environmental challenges associated with global warming. Hypercr...
Cationic porous organic polymers have a unique advantage in removing radioactive iodine from the aqueous phase because iodine molecules exist mainly in the form of iodine-containing anions. However, halogen anions will inevitably be released into wat...
Effective capture and safe disposal of radioactive iodine (129I or 131I) during nuclear power generation processes have always been a worldwide environmental concern. Low-cost and high-efficiency iodine removal materials are urgently needed. In this...
Bone graft materials are essential for achieving arthrodesis after spine surgery. Safe bone graft products, with osteoinductive, osteoconductive properties and the ability to monitor fusion in real-time, are highly desirable. A novel hyper-crosslinke...
Novel polymers applied in economic membrane technologies are a perennial hot topic in the fields of natural gas purification and O2 enrichment. Herein, novel hypercrosslinked polymers (HCPs) incorporating 6FDA-based polyimide (PI) MMMs were prepared...
The development of solid-state polymer electrolytes is an effective way to overcome the notorious shuttle effect of polysulfides in traditional liquid lithium sulfur batteries. In this paper, cationic cyclopropenium based cross-linked polymer was fir...
The aim of this work was to investigate the adsorption performance of a highly crosslinked poly(aniline-co-benzene) (PAB) copolymeric network. This hypercrosslinked polymer (HCP) was obtained via the Friedel–Craft reaction in the presence of Fe...
Two series of hyper-cross-linked microporous polyacetylene networks containing either -[CH=C(CH=O)]- or -[CH=C(CH2OH)]- monomeric units are reported. Networks are prepared by chain-growth copolymerization of acetal-protected propargyl aldehyde and ac...
The influence of a polymerisation mechanism (reversible addition–fragmentation chain transfer; RAFT vs. free radical polymerisation; FRP) on the porous structure of highly porous poly(styrene-co-divinylbenzene) polymers was investigated. The hi...
Ethylene glycol dimethacrylate (EGDMA) is used as a crosslinker in poly(acrylonitrile (AN)-co-vinylbenzyl chloride (VBC)) to investigate the effect of long-chain crosslinker to the porosity of the terpolymer system. Poly(AN-co-EGDMA-co-VBC) is synthe...
With the aim to study the influence of monomer ratio in poly(high internal phase emulsions) (polyHIPEs) on the polymer network architecture and morphology of poly(vinylbenzyl chloride-co-divinylbenzene-co-styrene) after hypercrosslinking via the inte...
In this paper, we describe the synthesis and gas adsorption properties of a porous carbonaceous material, obtained from commercial expanded polystyrene. The first step consists of the Friedel-Craft reaction of the dissolved polystyrene chains with a...
Bacteria pose significant threats to human health, industrial production, and daily life, with widespread microbial contamination remaining a critical challenge for global public health. Conventional porous materials often suffer from insufficient an...
In the pursuit of advancing materials for methane storage, a critical consideration arises given the prominence of natural gas (NG) as a clean transportation fuel, which holds substantial potential for alleviating the strain on both energy resources...
Platform chemicals, also known as chemical building blocks, are substances that serve as starting materials for the synthesis of various value-added products, which find a wide range of applications. These chemicals are the key ingredients for many f...
Supercritical (SC) fluid technologies are well-established methods in modern green chemical synthesis. Using SC fluids as solvents instead of traditional liquids gives benefits of higher diffusivity and lower viscosity, which allows mass transfer int...
Functionalized hypercrosslinked polymers (HCPs) with surface areas between 213 and 1124 m2/g based on a range of monomers containing different chemical moieties were evaluated for CO2 capture using a pressure swing adsorption (PSA) methodology under...
Among different polymers nanostructured cross-linked aromatics have the greatest potential as catalytic supports due to their exceptional thermal and chemical stability and preservation of the active phase morphology. This work studies the ability of...
We successfully prepared two different classes of hypercrosslinked porous organic polymers (HPPs)—the tetraphenylethene (TPE) and (4-(5,6-Diphenyl-1H-Benzimidazol-2-yl)-triphenylamine (DPT) HPPs—through the Friedel−Crafts polymeriza...
Hyper-crosslinked (HCL) polystyrenes show outstanding properties, such as high specific surface area and adsorption capability. Several researches have been recently focused on tailoring their performance for specific applications, such as gas adsorp...
Catalytic transformation of carbon dioxide (CO2) into high-value-added chemicals represents a promising approach for CO2 emission reduction and utilization. Herein, single-atom ruthenium (Ru) supported on N-heterocyclic carbene (NHC)-functionalized h...
The development of new styrene-based hyper-crosslinked nanocomposites (HCLN) containing mesoporous silica nanoparticles (MSN) is reported here as a new strategy to obtain functional high surface area materials with an enhanced hydrophilic character....
Mercury, a highly toxic metal and pollutant, poses a significant risk to human health and the environment. This study describes the synthesis of a new nitrogen-doped heteroaromatic hyper-crosslinked polyamine (HCPA) via the polycondensation of 2,6-di...
With the increasing trend of high-rise, large-scale, and functional modern architectural structures, lightweight aggregate (LWA) concrete that exhibits excellent strength and high functionality has garnered active research attention. In particular, a...
Hybrid materials based on porous organic polymers (POPs) and metal–organic frameworks (MOFs) are increasing attention for advanced separation processes due to the possibility to combine their properties. POPs provide high surface areas, chemica...
Hydrogen (H2) is one of the best candidates to replace current petroleum energy resources due to its rich abundance and clean combustion. However, the storage of H2 presents a major challenge. There are two methods for storing H2 fuel, chemical and p...
The vast cache of methods used in polymeric monolithic column modification is presented herein, with specific attention to post-polymerization modification reactions. The modification of polymeric monolithic columns is defined and can include the mo...
The adsorption isotherms and intraparticle mass transfer coefficients of a novel adsorbent with various VOCs at different temperatures during the desorption process are investigated. Firstly, the adsorption isotherms of an HCP-5 adsorbent with o-xyle...
A viable tactic to effectively address the climate crisis is the production of renewable fuels via photocatalytic reactions using solar energy and available resources like carbon dioxide (CO2) and water. Organic polymer material-based photocatalytic...
Eco-friendly soybean protein adhesives could be an ideal substitute for replacing traditional formaldehyde-based adhesives in wood industry. However, a large number of cross-linking agents are required in soy protein adhesive formulations to obtain s...
Lignin obtained by hydrogenolysis of lignocellulose biomass is a prospective source of valuable green fuels and chemicals such as monophenols. One of the key factors in the chemical decomposition of lignin to monophenols is an efficient catalyst. Ine...
Solid-state batteries are an emerging option for next-generation traction batteries because they are safe and have a high energy density. Accordingly, in polymer research, one of the main goals is to achieve solid polymer electrolytes (SPEs) that cou...
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