Search Results (2,919)

To enhance the mechanical performance and surface hydrophobicity of flat thin-sheet materials, we have developed a facile, environmentally benign, and low-cost synthesis strategy for fabricating a robust waterborne superhydrophobic coating with excellent mechanical reinforcement, via simple spray coating using a non-fluorinated material system (waterborne silicone–acrylic copolymer and silica sol). The functional coating exhibited excellent hydrophobicity (water contact angle: 150°) regardless of the compound of the substrates, which is primarily ascribed to the presence of abundant low-surface-energy methyl groups on the coating’s surface, along with the three-dimensional hierarchical network structure formed via the cross-linked silica network. Owing to the stable cross-linked structure and strong interfacial bonding between the acrylic polymer and silica network, the composite coating exhibited exceptional mechanical reinforcement, coupled with ultrahigh mechanical and chemical stability. Specifically, the maximum flexural fracture load of the modified materials increased from 119 N to 192 N, representing a 62.7% enhancement; similarly, the moisture-induced deflection of the samples had a significant increase from −14.5 mm to −3.01 mm, which confirmed that the mechanical properties of the modified sample and its deformation resistance under high humidity conditions have been significantly enhanced. Notably, the coating retained superior hydrophobicity and mechanical performance even after 50 abrasion cycles, as well as exposure to high-intensity UV radiation and corrosive acidic/alkaline environments. Furthermore, the composite functional coating demonstrated excellent self-cleaning and anti-fouling properties. This functional composite coating offers significant potential for large-scale industrial application. Full article

With the increasing demand for sustainable building materials, it is essential to investigate the durability of recycled fine aggregate concrete (RFAC) under corrosive environmental conditions. This study systematically assessed the performance of RFAC with three compressive strengths after dry–wet cycles in chloride and sulfate environments, respectively. The experimental program encompassed measurements of compressive strength, mass variation, porosity, ion penetration depth, and free ion content, complemented by comprehensive microstructural characterization. Results show that under sulfate exposure, 20 MPa and 40 MPa RFAC suffered significant strength losses of 60.1% and 18.0% after 70 cycles, while 60 MPa RFAC gained 2.5% strength. In chloride environments, 20 MPa and 40 MPa RFAC experienced strength reductions of 30.7% and 6.9%, whereas 60 MPa RFAC increased in strength by 6.6%. Compared to sulfate exposure, all groups exhibited slight mass increases or porosity reduction under chloride exposure, with high-strength RFAC showing the most noticeable densification. The chloride penetration depth in RFAC of 60 MPa was measured at 14.65 mm, representing a 41.0% reduction compared to RFAC of 20 MPa; sulfate penetration depth was 17.84 mm, which is 44.6% lower than that of the 20 MPa counterpart. Microstructural analysis revealed that sulfate-induced ettringite and gypsum formation triggered crack propagation, while chloride mainly affected pore structure through crystallization and filling, and the formation of C-S-H in high-strength RFAC inhibits pore expansion and mitigates deterioration. Full article

The Ti6Al4V alloy is considered the most beneficial of the titanium alloys for use in biomedical applications. However, it corrodes when exposed to various biocompatible fluids. This investigation aims to evaluate the corrosion inhibition performance of the Ti6Al4V in a saline solution (SS) using thiocolchicoside (TCC) drug as an environmentally acceptable corrosion inhibitor. The corrosion assessments were conducted using potentiodynamic polarization curves (PPCs), open-circuit potential (OCP), and electrochemical impedance spectroscopy (EIS) methodologies, supplemented by scanning electron microscopy (SEM), energy-dispersive X-ray (EDS) analysis, atomic force microscopy (AFM), and contact angle (CA) measurements. The outcomes indicated that the inhibitory efficacy improved with higher TCC concentrations (achieving 92.40% at 200 mg/L of TCC) and diminished with an increase in solution temperature. TCC’s physical adsorption onto the surface of the Ti6A14V, which adheres to the Langmuir adsorption isotherm, explains its mitigating power. The TCC acts as a mixed-type inhibitor. The adsorption and inhibitory impact of TCC were examined at various temperatures using PPC and EIS. When TCC is present, the corrosion’s apparent activation energy is higher (35.79 kJ mol⁻¹) than when it is absent (14.46 kJ mol⁻¹). In addition, the correlation between the structural properties of thiocolchicoside (TCC) and its corrosion inhibition performance was systematically analyzed. Density Functional Theory (DFT) calculations were utilized to characterize the adsorption mechanism, supported by Natural Bond Orbital (NBO) analysis and Molecular Dynamics (MD) simulations. The combined computational and electrochemical findings confirm that TCC provides effective and enhanced corrosion protection for the Ti6Al4V alloy in a saline environment. These characteristics provide compelling evidence for the suitability of these pharmaceutical compounds as promising corrosion inhibitors. Full article

The present work investigates the electrochemical behavior of the Zr2.5Nb alloy in a biomedical context, emphasizing the influence of electrochemical oxidation treatment on its stability in simulated physiological environments. The alloy samples were oxidized in 1 M H₂SO₄ under controlled voltages (200–275 V) and times (1 min), identifying 200 V–1 min as the optimal condition for obtaining a uniform porous oxide layer with an average pore diameter of ~90 nm. The corrosion resistance was evaluated using open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) in Ringer’s solution and Ringer’s solution containing 40 g/L H₂O₂ to simulate physiological and inflammatory conditions. Electrochemical tests revealed that electrochemically oxidized samples exhibited a polarization resistance up to 14.78 MΩ·cm², about 26 times higher than that of the untreated alloy (0.56 MΩ·cm²). After 77 h of immersion, the oxidized alloy maintained a high resistance (17.54 MΩ·cm²), confirming long-term stability. Scanning Electron Microscopy (SEM–EDX) and X-Ray Diffraction (XRD) analyses highlighted significant increases in oxygen content and the transformation from the monoclinic baddeleyite to the cubic arkelite phase of ZrO₂, contributing to enhanced corrosion resistance. These findings demonstrate that controlled electrochemical oxidation significantly improves the durability of Zr2.5Nb alloy in oxidative environments, supporting its potential for long-term biomedical implant applications. Full article

This study examined the combined effects of chloride ions and stray DC on reinforced concrete (RC) using electromigration and impressed-current methods under varying current densities (0.5, 3.0, 5.0 mA/cm²) and chloride concentrations (50, 1350, 5500 mg/kg). Chloride was identified as the dominant deterioration factor. At 3.0 mA/cm², cracking times in moderate and severe chloride environments decreased by 48.75% and 52.62%, respectively, compared to mild conditions. At 0.5 mA/cm² in severe conditions, the corrosion rate reached 1.317% after 20, 2.75 times that in moderate conditions. Electromigration specimens showed delayed cracking but deeper chloride penetration, while impressed-current specimens exhibited pronounced strip-shaped pitting corrosion. A quadratic polynomial model predicting cracking time based on current density and chloride concentration achieved high accuracy (R² = 0.95, mean relative error = 7.%). Actual corrosion mass loss was lower than theoretical Faraday values, with current efficiency increasing from 0.3–0.8% to 16.5–18.1% as current density and chloride content rose. These findings highlight the synergistic effect of stray current and chloride attack, emphasizing chloride concentration’s greater impact on service life. The model provides a scientific basis for RC durability design in urban rail transit and coastal engineering. Full article

Titanium and its alloys are well-suited for marine engineering owing to their high specific strength and superior corrosion resistance. However, their high cost remains a key barrier to widespread marine application. Titanium/steel (Ti/Fe) dissimilar materials provide a promising solution by integrating titanium’s corrosion resistance with the high strength of steel, thereby significantly reducing costs. This review systematically assesses the potential preparation strategies for Ti/Fe dissimilar materials, such as explosive welding, rolling, high-energy beam cladding, and cold spray, to meet the large-scale application requirements in marine engineering. Advanced welding techniques for joining Ti/Fe joints are also discussed. The advantages and issues of Ni, Cu, Fe, and Al interlayers suitable for marine engineering applications in inhibiting Fe-Ti IMCs are introduced, with a focus on their potential in promoting the development of economically efficient ocean engineering. A comprehensive evaluation is conducted on the performance of Ti/Fe dissimilar materials, particularly their corrosion resistance and fatigue resistance in marine environments. This review aims to provide a reference for the theoretical research, preparation strategies, and application expansion of low-cost Ti/Fe dissimilar materials in marine engineering. Full article

Marine concrete structures are continuously exposed to harsh marine environments—salt, waves, and biological fouling—that accelerate corrosion and cracking, increasing maintenance costs. Traditional Non-Destructive Testing (NDT) techniques often fail to detect early damage due to signal attenuation and noise in underwater conditions. This study critically reviews recent advances in Artificial Intelligence-integrated NDT (AI-NDT) technologies for marine concrete, focusing on their quantitative performance improvements and practical applicability. To be specific, a systematic comparison of vision-based and signal-based AI-NDT techniques was carried out across reported field cases. It was confirmed that the integration of AI improved detection accuracy by 17–25%, on average, compared with traditional methods. Vision-based AI models such as YOLOX-DG, Cycle GAN, and MSDA increased mean mAP 0.5 by 4%, while signal-based methods using CNN, LSTM, and Random Forest enhanced prediction accuracy by 15–20% in GPR, AE, and ultrasonic data. These results confirm that AI effectively compensates for environmental distortions, corrects noise, and standardizes data interpretation across variable marine conditions. Lastly, the study highlights that AI-enabled NDT not only automates data interpretation but also establishes the foundation for predictive and preventive maintenance frameworks. By linking data acquisition, digital twin-based prediction, and lifecycle monitoring, AI-NDT can transform current reactive maintenance strategies into sustainable, intelligence-driven management for marine infrastructure. Full article

Conductivity sensors play a vital role in monitoring production data in oil wells to ensure efficient oilfield operations, and their service performance depends on the durability of Invar alloy electrodes. The alloy electrodes are susceptible to damage from abrasive solid particles, corrosive media, and oil fluids in downhole environments. The degradation of the alloy electrodes directly compromises the signal stability of conductivity sensors, resulting in inaccurate monitoring data. Inspired by the intrinsic oleophobic properties of fish scales, we developed a fluorinated boron-doped diamond (FBDD) film with biomimetic micro–nano structures to enhance the wear resistance, corrosion resistance, and amphiphobicity of Invar alloy electrodes. The fish scale architecture was fabricated through argon-rich hot-filament chemical vapor deposition (90% Ar, 8 h) followed by fluorination. FBDD-coated electrodes surpass industrial benchmarks, exhibiting a friction coefficient of 0.08, wear rate of 5.1 × 10⁻⁷ mm³/(N·mm), corrosion rate of 3.581 × 10⁻³ mm/a, and oil/water contact angles of 95.32°/106.47°. The following underlying improvement mechanisms of FBDD films are proposed: (i) the wear-resistant matrix preserves the oleophobic nanostructures during abrasive contact; (ii) the corrosion barrier maintains electrical conductivity by preventing surface oxidation; (iii) the oil-repellent surface minimizes fouling that could mask corrosion or wear damage. Full article

As a zero-carbon energy carrier, hydrogen is playing an increasingly vital role in the decarbonization of maritime transportation. The hydrogen pressure reducing valve (PRV) is a core component of ship-borne hydrogen storage systems, directly influencing the safety, efficiency, and reliability of hydrogen-powered vessels. However, the marine environment—characterized by persistent vibrations, salt spray corrosion, and temperature fluctuations—poses significant challenges to PRV performance, including material degradation, flow instability, and reduced operational lifespan. This review comprehensively summarizes and analyzes recent advances in the study of high-pressure hydrogen PRVs for marine applications, with a focus on transient flow dynamics, turbulence and compressible flow characteristics, multi-stage throttling strategies, and valve core geometric optimization. Through a systematic review of theoretical modeling, numerical simulations, and experimental studies, we identify key bottlenecks such as multi-physics coupling effects under extreme conditions and the lack of marine-adapted validation frameworks. Finally, we conducted a preliminary discussion on future research directions, covering aspects such as the construction of coupled multi-physics field models, the development of marine environment simulation experimental platforms, the research on new materials resistant to vibration and corrosion, and the establishment of a standardized testing system. This review aims to provide fundamental references and technical development ideas for the research and development of high-performance marine hydrogen pressure reducing valves, with the expectation of facilitating the safe and efficient application and promotion of hydrogen-powered shipping technology worldwide. Full article

Microwave heating is a method with a uniform heating effect and environmental friendliness in in-place hot recycling, but the microwave absorption capacity of traditional asphalt mixtures is still insufficient. As an excellent microwave-absorbing material, magnetite powder has the characteristics of high temperature resistance, corrosion resistance, and good thermodynamic stability. This study selects it as the microwave-absorbing material, prepares AC (Asphalt Concrete) type and SMA (Stone Mastic Asphalt) type microwave asphalt mixtures by adjusting its content, and investigates its influence on the microwave-heating characteristics and pavement performance of the mixtures. Simulations of the microwave-heating process of AC-type mixtures using COMSOL software (COMSOL Multiphysics 6.2) show that magnetite powder achieves optimal performance in terms of heating effect and economic efficiency when its content is 0.5%. Subsequently, laboratory tests are conducted to study the wave absorption and temperature rise performance of AC and SMA microwave asphalt mixtures; combined with economic factors, the optimal contents of magnetite powder for the two types of mixtures are determined to be 0.5% and 1%, respectively, and at the same time, these results are explained based on multiple physical theories. Furthermore, pavement performance is investigated through laboratory tests, including high-temperature rutting tests, low-temperature bending tests, immersed Marshall tests, and freeze–thaw cycle durability tests, and the results indicate that the high-temperature performance, low-temperature performance, and water stability of the microwave asphalt mixtures all meet the specification requirements for pavement performance. Subsequently, after 15 freeze–thaw cycles, the splitting tensile strength retention rate and stiffness modulus of the two types of mixtures show minimal differences from those of ordinary mixtures, and there is no durability degradation caused by the incorporation of magnetite powder. Finally, outdoor environment verification is carried out, and the results show that under complex conditions such as environmental factors, the wave absorption and temperature rise rates of AC and SMA mixtures at optimal contents are 52.2% and 14.6% higher than those of ordinary AC and SMA asphalt mixtures, respectively. In addition, these microwave asphalt mixtures have the advantages of both sustainability and reduced carbon emissions. By combining simulation methods and experimental verification, this study finally prepared two types of microwave asphalt mixtures with excellent performance, not only improving the microwave absorption and heating performance of asphalt mixtures, but also reducing environmental pollution and energy consumption, which conforms to the development of green transportation. Full article

Analysis of the impact of aging processes induced by environmental conditions, particularly aggressive ones, on the properties of polymeric materials and products made from them has been the subject of intensive research for many years. Developing materials characterized by high resistance to the specific external factors in which these materials are used is a key issue in the context of developing a sustainable economy aimed at minimizing waste and extending the service life of polymeric components. The main objective of this research was to assess and quantify the degradation mechanisms of polymeric materials manufactured using additive Fused Deposition Modeling (FDM) technology when exposed to aggressive marine environments. To achieve this, the study analyzed the influence of seawater corrosion conditions on the changes in mechanical and rheological properties of two polymeric materials: recycled polylactide (rPLA) and a wood–polymer composite (WPC) based on PLA reinforced with wood flour (MD). The results revealed that rPLA exhibited an approximately 16% decrease in average molecular weight after 9 months of seawater exposure, accompanied by a 37% reduction in tensile strength and a 24% decrease in elastic modulus. In the case of the WPC, the molecular weight decreased by about 20%, while tensile strength and elastic modulus dropped by 30% and 51%, respectively. The findings provide quantitative evidence of the susceptibility of additively manufactured biodegradable polymers to marine-induced degradation, highlighting the necessity of further optimization for maritime and coastal applications. Full article

The exploitation of China’s oil and gas resources has advanced into the “ten-thousand-meter” ultra-deep realm. Downhole tubulars and well control equipment materials face severe corrosion challenges under the extreme high-temperature, high-pressure, and highly acidic environments prevalent in such formations. However, the corrosion mechanisms and patterns of materials under these harsh conditions remain insufficiently elucidated, necessitating systematic research. This study focuses on the typical casing material P110SS, investigating its corrosion behavior in high-temperature, high-pressure H₂S/CO₂ environments. The results show that at a partial pressure of H₂S of 0.5 MPa, the corrosion rate of P110SS increases with temperature. A significant increase in the corrosion rate and the occurrence of pitting corrosion were observed between 100 °C and 140 °C. The corrosion product transformed from mackinawite to pyrrhotite. At 60 °C, increasing the partial pressure of H₂S led to a slight increase in the corrosion rate, while at 160 °C, the corrosion rate slightly decreased. However, temperature changes did not cause any alteration in the corrosion products. Full article

This study systematically investigates the effect of substituting Copper (Cu) with Nickel (Ni) on the glass-forming ability (GFA) and corrosion resistance of a Pt-based bulk metallic glass (BMG). We demonstrate that a minor substitution of 5 at.% Ni for Cu in the Pt₄₀Pd₂₀Cu₂₀P₂₀ base alloy significantly enhances both properties. The GFA is markedly improved, as evidenced by the supercooled liquid region (ΔTx) widening from 68 K to 91 K. The optimized Pt₄₀Pd₂₀Cu₁₅Ni₅P₂₀ alloy exhibits a compressive fracture strength of 1.38 GPa. Electrochemical tests in a 3.5 wt.% NaCl solution reveal a substantial improvement in corrosion resistance. Compared to the Ni-free baseline alloy, the passive film resistance (R_f) and charge-transfer resistance (R_ct) of the Ni-containing alloy are enhanced by factors of 2.75 and 2.60, respectively. This superior performance is attributed to a synergistic effect wherein Ni alloying both stabilizes the amorphous structure and promotes the formation of a more robust passive film. This work presents a viable strategy for designing cost-effective, high-performance multi-component BMGs for applications in aggressive chloride environments. Full article

To enhance its surface properties, the Ti-6Al-4V alloy was subjected to a nitrogen atmosphere at elevated temperatures. An orthogonal experiment was employed to investigate the effects of nitriding temperature, nitriding duration, and nitrogen flow rate on the surface hardness and the thickness of the nitrided layer. Mechanical properties were assessed using a micro-Vickers hardness tester and a universal material testing machine. Accelerated corrosion tests were performed by immersing the samples in solutions with varying HF concentrations, while wear resistance was evaluated via a circumferential dry sliding wear test. The results indicate that after nitriding, the subsurface region is primarily composed of TiN, Ti₂N, and Ti₂AlN. Nitriding temperature exerts the greatest influence on the thickness of the nitrided layer, whereas nitrogen flow rate has the least impact. Conversely, nitrogen flow rate shows the strongest effect on surface hardness, with nitriding temperature having the weakest influence. After nitriding, the microstructure becomes coarse with a decrease in substrate hardness. As nitriding temperature and time increase, the thickness of the nitrided layer grows, but both the tensile strength and percentage elongation after fracture decline. The sample nitrided at 850 °C for 2 h under a nitrogen flow rate of 20 mL·min⁻¹ exhibits favorable overall properties. Compared with the as-received sample, its surface hardness increases noticeably, though both the tensile strength and percentage elongation after fracture decrease. In comparison to the continuous weight loss of the as-received sample when immersed in HF solution, the nitrided sample exhibits an initial mass loss of nearly zero, which suggests that the nitrided layer has a protective efficacy. After nitriding, the wear rate is reduced to no more than 3% of that of the as-received sample. Therefore, gas nitriding is considered a feasible technique for improving the surface properties of Ti-6Al-4V in complex environments. Full article

Small-scale wind turbines are becoming increasingly important in renewable energy systems due to their ability to operate in low-wind-speed environments and adapt to various installation locations, especially in areas with energy shortages. This paper presents the design, analysis and development of a Helical Vertical Axis type Wind Turbine (H-VAWT) using uPVC pipe as the blade material, offering a lightweight, low-cost, and corrosion resistant solution. The blade structure is optimized for use in residential and off-grid areas with unstable wind conditions. Structural analysis is conducted in ANSYS, including static load analysis (deformation, equivalent stress, shear stress, maximum stress), torsional and bending stress, and modal analysis to assess mechanical performance and vibrational stability. Three blade designs are initially considered, and the helical model (0–45° twist) is selected based on simulation results. The prototype is successfully fabricated and tested under different wind speeds, showing effective power generation, with favorable results in power output, power coefficient, tip-speed ratio (TSR), and relative velocity. Full article