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Advances in Corrosion and Protection of Metallic Materials
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Advances in Corrosion and Protection of Metallic Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Corrosion".

Deadline for manuscript submissions: 20 August 2025 | Viewed by 3392

Special Issue Editors

Dr. Xiaowei Lei

E-Mail Website
Guest Editor
School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an 710072, China
Interests: corrosion; passivity and passivity breakdown; laser welding/surface treatment
Special Issues, Collections and Topics in MDPI journals
Dr. Peng Han

E-Mail Website
Guest Editor
School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
Interests: corrosion inhibition; theoretical calculation; inhibitor-coating system
Special Issues, Collections and Topics in MDPI journals
Dr. Wenlan Wei

E-Mail Website
Guest Editor Assistant
School of Mechanical Engineering, Xi’an Shiyou University, Xi’an 710065, China
Interests: corrosion; cracking and fracture mechanism; ultrafine grain strengthening

Special Issue Information

Dear Colleagues,

The corrosion of metallic materials refers to the gradual destruction of metals and alloys due to their chemical or electrochemical reactions with the corrosive environment. These processes can lead to significant losses in structural integrity, performance degradation, and, ultimately, material failure.

To combat corrosion, it is key to understand the corrosion mechanism through experimental analyses and simulations. Meanwhile, various protective measures can be employed. For instance, coatings such as paints, galvanized zinc, or polymeric materials can act as barriers between the metal and corrosive agents. Alloys with corrosion-resistant elements such as chromium or nickel also have enhanced durability. Additionally, devising high-efficiency corrosion inhibitors is also a practical method especially in engineering application scenarios. By implementing these protective strategies, we can mitigate the adverse effects of corrosion and ensure the reliability and safety of metallic components in engineering applications.

In summary, this Special Issue will present studies on the corrosion mechanisms of metallic materials and advanced anti-corrosion methodologies for corrosion protection. Original research articles, reviews, and communications are welcome. We invite you to submit manuscripts to this Special Issue, the scope of which includes, but is not limited to, the following aspects:

(1) Uniform corrosion and localized corrosion including pitting corrosion, intergranular corrosion, stress corrosion cracking, crevice corrosion, galvanic corrosion, erosion corrosion, wear corrosion, etc.;

(2) Corrosion studies using electrochemical measurements such as polarization, EIS, Mott–Schottky measurements, etc., to unravel the thermodynamics and kinetics behaviors;

(3) Surface characterizations, including SEM, EDS, TEM, XPS, AFM, etc., and surface modification through physical and chemical approaches;

(4) Organic/inorganic coatings and inhibitors designed for surface corrosion protections;

(5) Multi-scale modeling to simulate corrosion processes and corrosion protection mechanisms.

Dr. Xiaowei Lei
Dr. Peng Han
Guest Editors

Dr. Wenlan Wei
Guest Editor Assistant

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • uniform and localized corrosion
  • electrochemical corrosion
  • surface analysis and modification
  • coatings
  • inhibitors
  • modeling and simulation

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Further information on MDPI's Special Issue policies can be found here.

Published Papers (5 papers)

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Research

11 pages, 1722 KiB  
Communication
Comparative Study of Corrosion Inhibition Properties of Q345 Steel by Chitosan MOF and Chitosan Schiff Base
by Lizhen Huang, Jingwen Liu, Li Wan, Bojie Li, Xianwei Wang, Silin Kang and Lei Zhu
Materials 2025, 18(13), 3031; https://doi.org/10.3390/ma18133031 - 26 Jun 2025
Viewed by 347
Abstract
This study synthesized two eco-friendly inhibitors—a chitosan–copper metal–organic framework (CS@Cu MOF) and chitosan–Schiff base–Cu complex (Schiff–CS@Cu)—for Q345 steel protection in 3.5% NaCl/1M HCl. Electrochemical and weight loss analyses demonstrated exceptional corrosion inhibition: untreated specimens showed a 25.889 g/(m2·h) corrosion rate, while [...] Read more.
This study synthesized two eco-friendly inhibitors—a chitosan–copper metal–organic framework (CS@Cu MOF) and chitosan–Schiff base–Cu complex (Schiff–CS@Cu)—for Q345 steel protection in 3.5% NaCl/1M HCl. Electrochemical and weight loss analyses demonstrated exceptional corrosion inhibition: untreated specimens showed a 25.889 g/(m2·h) corrosion rate, while 100 mg/L of CS@Cu MOF and Schiff–CS@Cu reduced rates to 2.50 g/(m2·h) (90.34% efficiency) and 1.67 g/(m2·h) (93.56%), respectively. Schiff–CS@Cu’s superiority stemmed from its pyridine–Cu2+ chelation forming a dense coordination barrier that impeded Cl−/H+ penetration, whereas CS@Cu MOF relied on physical adsorption and micro-galvanic interactions. Surface characterization revealed that Schiff–CS@Cu suppressed pitting nucleation through chemical coordination, contrasting with CS@Cu MOF’s porous film delaying uniform corrosion. Both inhibitors achieved optimal performance at 100 mg/L concentration. This work establishes a molecular design strategy for green inhibitors, combining metal–organic coordination chemistry with biopolymer modification, offering practical solutions for marine infrastructure and acid-processing equipment protection. Full article
(This article belongs to the Special Issue Advances in Corrosion and Protection of Metallic Materials)
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17 pages, 10861 KiB  
Article
Corrosion Behaviors of Ni80A Alloy Valve in Marine Engine Within Ammonia-Rich Environment
by Ying-ying Liu, Guo-zheng Quan, Yan-ze Yu, Wen-jing Ran and Wei Xiong
Materials 2025, 18(13), 3006; https://doi.org/10.3390/ma18133006 - 25 Jun 2025
Viewed by 346
Abstract
Ammonia fuel is regarded as a promising zero-carbon alternative to diesel in next-generation marine engines. However, the high-temperature ammonia-rich environment poses significant corrosion challenges to hot-end components such as valves. This study investigates the corrosion behavior of Ni80A alloy marine valves under the [...] Read more.
Ammonia fuel is regarded as a promising zero-carbon alternative to diesel in next-generation marine engines. However, the high-temperature ammonia-rich environment poses significant corrosion challenges to hot-end components such as valves. This study investigates the corrosion behavior of Ni80A alloy marine valves under the coupled effects of a high temperature and ammonia atmosphere. Using computational fluid dynamics (CFD), the service temperature of the valve and the ammonia concentration distribution inside the engine cylinder were identified. High-temperature corrosion experiments were conducted with a custom-designed setup. Results show that corrosion kinetics accelerated markedly with temperature: the initial corrosion rate at 800 °C was four times that at 500 °C, and the maximum corrosion layer thickness reached 37 μm—double that at lower temperatures. Microstructural analysis revealed a transition from a dense, defect-free corrosion layer at 500 °C to a non-uniform layer with coarse CrN particles and aggregated nitrides at 800 °C. Notably, surface hardness increased at both temperatures, peaking at 590 HV at 500 °C, while matrix hardness at 800 °C declined due to γ′ phase coarsening and grain growth. This work provides detailed insight into the temperature-dependent ammonia corrosion mechanisms of marine Ni-based alloy valves, offering essential data for material design and durability assessment in ammonia-fueled marine engines. Full article
(This article belongs to the Special Issue Advances in Corrosion and Protection of Metallic Materials)
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28 pages, 6157 KiB  
Article
Towards a Sustainable Material Protection: Olanzapine Drugs and Their Derivatives as Corrosion Inhibitors for C1018 Steel in 1 M Hydrochloric Acid
by Habibah M. A. Omar, Nestor Ankah, Mohamed S. Gomaa, Malak Y. Alkhaldi, Nadir M. A. Osman, Abdullah R. Al-Subaie, Ibrahim Aldossary, Irshad Baig, Ashraf A. Bahraq, Marwah Aljohani, Ihsan Ulhaq Toor and Aeshah H. Alamri
Materials 2025, 18(12), 2902; https://doi.org/10.3390/ma18122902 - 19 Jun 2025
Viewed by 430
Abstract
This study investigates the synthesis process and characterization methods and evaluates the inhibition behavior of olanzapine (2-methyl-4-(4-methyl-1-piperazinyl)-10H-thieno-[2,3-b] 1,5]benzodiazepine (OLZ)) and its derivatives, such as 3-(2-methyl-4-(4-methylpiperazin-1-yl)-10H-benzo[b]thieno[2,3-e] [1,4]diazepin-10-yl) propenamide (OLZ1) and Ethyl 2-(2-methyl-4-(4-methylpiperazin-1-yl)-10H-benzo[b]thieno[2,3-e][1,4]diazepin-10 yl) acetate (OLZ2) for carbon steel (C1018) in a 1 M HCl [...] Read more.
This study investigates the synthesis process and characterization methods and evaluates the inhibition behavior of olanzapine (2-methyl-4-(4-methyl-1-piperazinyl)-10H-thieno-[2,3-b] 1,5]benzodiazepine (OLZ)) and its derivatives, such as 3-(2-methyl-4-(4-methylpiperazin-1-yl)-10H-benzo[b]thieno[2,3-e] [1,4]diazepin-10-yl) propenamide (OLZ1) and Ethyl 2-(2-methyl-4-(4-methylpiperazin-1-yl)-10H-benzo[b]thieno[2,3-e][1,4]diazepin-10 yl) acetate (OLZ2) for carbon steel (C1018) in a 1 M HCl acidic solution. Fourier Transform Infrared Spectroscopy (FTIR) and Nuclear Magnetic Resonance (NMR) were employed to verify their molecular structures and functional groups, which characterized the derivatives after synthesis. Their corrosion inhibition potential for C1018 steel in acidic media was estimated by weight loss (WL) and electrochemical techniques, such as electrochemical impedance spectroscopy (EIS), linear polarization resistance (LPR), and potentiodynamic polarization (PDP), accompanied by surface analysis methods. The findings revealed that all three derivatives demonstrated exceptional inhibition performance, achieving maximum efficiencies of 88.83%, 91.20%, and 91.82% for OLZ, OLZ1, and OLZ2 at 300 ppm, respectively. Weight loss experiments across different temperatures further explored their inhibitory behavior. Although inhibition efficiency decreased with a temperature increase to 318 K, the derivatives still displayed notable performance, with maximum efficiencies of 74.75% for OLZ, 81.63% for OLZ1, and 79.44% for OLZ2. Polarization studies identified the corrosion inhibition mechanisms as an anodic type. Surface characterization of the C1018 steel coupons, both with and without the inhibitors, was performed using FTIR and scanning electron microscopy (SEM) combined with energy-dispersive X-ray spectroscopy (EDX). These analyses indicated the creation of a protective inhibitor layer on the carbon steel surface, reducing corrosion in the acidic environment. Overall, this study underscores the potential of these drug derivatives as corrosion inhibitors, combining structural insights and performance assessments to support their industrial application. Full article
(This article belongs to the Special Issue Advances in Corrosion and Protection of Metallic Materials)
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16 pages, 8657 KiB  
Article
Impact of NaHCO3/Na2CO3 Buffer Reagent on Mitigating the Corrosion of C110 Steel in Water-Based Annulus Protection Fluid at Ultrahigh Temperature
by Zhi Zhang, Mifeng Zhao, Yan Li, Junfeng Xie, Wenwen Song, Juantao Zhang, Mengkai Wang, Jie Zhou, Yuan Wang, Xiaowei Lei and Danping Li
Materials 2025, 18(7), 1668; https://doi.org/10.3390/ma18071668 - 5 Apr 2025
Viewed by 665
Abstract
The drilling of ultradeep oil wells brings many challenges to the downhole tubular materials, where corrosion induced by halide annulus protection fluid is one major problem. In this work, the Na2CO3/NaHCO3 buffer system is employed to mitigate the [...] Read more.
The drilling of ultradeep oil wells brings many challenges to the downhole tubular materials, where corrosion induced by halide annulus protection fluid is one major problem. In this work, the Na2CO3/NaHCO3 buffer system is employed to mitigate the corrosion of C110 steel in NaBr annulus protection fluid at 220 °C. Weight loss tests, corrosion morphologies characterizations, and electrochemical measurements were used to investigate the inhibition effect. X-ray diffraction and X-ray photo-electron spectroscopy were employed to analyze the surface phase compositions. It is found that the Na2CO3/NaHCO3 buffer reagents effectively inhibit the corrosion of C110 steel, and the inhibition efficiency can reach 96.1%. The higher pH leads to the better inhibition performance, and, particularly, the buffer system is more effective in the corrosion environment of greater aggressivity. Without buffer reagents, the steel substrate is subjected to higher degree of uniform etching and pitting corrosion due to the formation of loose and porous corrosion products. In contrast, the addition of buffer reagents facilitates the formation of thinner but denser and more protective Fe3O4 passive film, contributing the high corrosion inhibition efficiency. Our work paves the way for the safe service of NaBr annulus protection fluid at 220 °C in ultradeep oil wells. Full article
(This article belongs to the Special Issue Advances in Corrosion and Protection of Metallic Materials)
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21 pages, 17144 KiB  
Article
Failure and Degradation Mechanisms of Steel Pipelines: Analysis and Development of Effective Preventive Strategies
by Marcin Kowalczyk, Jakub Andruszko, Paweł Stefanek and Robert Mazur
Materials 2025, 18(1), 134; https://doi.org/10.3390/ma18010134 - 31 Dec 2024
Viewed by 1213
Abstract
The increasing challenges related to the reliability and durability of steel pipeline infrastructure necessitate a detailed understanding of degradation and failure mechanisms. This study focuses on selective corrosion and erosion as critical factors, analyzing their impact on pipeline integrity using advanced methods, including [...] Read more.
The increasing challenges related to the reliability and durability of steel pipeline infrastructure necessitate a detailed understanding of degradation and failure mechanisms. This study focuses on selective corrosion and erosion as critical factors, analyzing their impact on pipeline integrity using advanced methods, including macroscopic analysis, corrosion testing, microscopic examination, tensile strength testing, and finite element method (FEM) modeling. Selective corrosion in the heat-affected zones (HAZs) of longitudinal welds was identified as the dominant degradation mechanism, with pit depths reaching up to 6 mm, leading to tensile strength reductions of 30%. FEM analysis showed that material loss exceeding 8 mm in weld areas under standard operating pressure (16 bar) induces critical stress levels, risking pipeline failure. Erosion was found to exacerbate selective corrosion, accelerating degradation in high-stress zones. Practical recommendations include the use of corrosion-resistant materials, such as duplex steels, and implementing integrated monitoring strategies combining non-destructive testing with FEM-based predictive modeling. These insights contribute to developing robust preventive measures to ensure the safety and longevity of pipeline infrastructure. Full article
(This article belongs to the Special Issue Advances in Corrosion and Protection of Metallic Materials)
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