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Eng

Eng is an international, peer-reviewed, open access journal on all areas of engineering, published monthly online by MDPI.

Quartile Ranking JCR - Q2 (Engineering, Multidisciplinary)

All Articles (920)

Depositing Cs-Co3O4 on Ceramic Foam Fosters Industrial N2O Decomposition Catalysis

  • Anna Klegová,
  • Kateřina Pacultová and
  • Lucie Obalová
  • + 3 authors

N2O emissions exacerbate the greenhouse effect, urgently demanding advances in abatement technologies. Catalytic decomposition of N2O over cobalt-based oxides with alkali metal promoters remains challenging because these catalysts are used in pelletized form, limiting their activity to a narrow outer-shell region due to internal diffusion limitations. However, research efforts continue to focus on enhancing Co–alkali metal contact on unsupported powder samples under inert conditions, even though, under industrial conditions, catalysts are exposed to inhibitory components of waste gases and N2O, and the powder form is unsuitable for practical application. This study aims at testing N2O decomposition over catalysts with a Co3O4-Cs active phase supported on a ceramic foam. For this purpose, we characterized these catalysts by H2 temperature-programmed reduction, H2O and NO temperature-programmed desorption, atomic absorption spectroscopy, and X-ray diffraction and assessed their catalytic performance under an inert-gas atmosphere and with O2, water vapor, and NO to simulate industrial conditions. Using a pseudo-homogeneous, one-dimensional model of an ideal plug flow reactor in an isothermal regime, the simulation calculations for a full-scale catalytic reactor for N2O abatement in waste gas from HNO3 production were performed. The Cs2CO3 precursor significantly enhanced catalyst reducibility and electron transferability, increasing N2O decomposition efficiency in inert gas, but its high hygroscopicity decreased resistance to water vapor and NO, overriding its advantages under industrial conditions. Conversely, glycerol-assisted impregnation enhanced catalyst performance regardless of Cs precursor. These foam-supported catalysts offered several other advantages, including lower pressure drop and lower active phase loading with matching catalytic activity. Based on our findings, depositing Cs2CO3 on ceramic foam through glycerol-assisted impregnation may facilitate catalytic N2O decomposition at the industrial level and, therefore, promote environmental sustainability by reducing N2O emissions.

13 February 2026

Combined (A) XRD (where numbers correspond to phases as follows: 1- corundum, 2- mullite, 3- spinel), (B) thermogravimetry, (C) H2-TPR, (D) H2O- and (E) NO-temperature programmed desorption analysis, (F) correlation between reducibility and catalytic activity. The results show that (A,B) all cobalt-based catalysts deposited on ceramic foam contain cesium in the form of undecomposed precursor, either CsNO3 or Cs2CO3 in line with [64] albeit with no effect on the phase composition of the catalyst. (C) Cs2CO3 enhances the reducibility of all cobalt active sites, regardless of preparation method. Nevertheless, glycerol-assisted impregnation enhances catalyst reducibility, as described in detail in our previous study [43]. (D) For all catalysts, water vapor stays adsorbed even at 500 °C, as evidenced by H2O-TPD profiles monitored by mass spectrometry (m/z = 18), and (E) both the glycerol method and Cs2CO3 increased NO adsorption, thus worsening resistance to NO. (F) shows the variation in N2O conversion at 300 °C as a function of catalyst reducibility. Lower reduction temperatures correspond to more reducible catalysts, whereas higher reduction temperatures indicate lower reducibility.

The high dependence on fossil fuels for energy supply in hospitals compromises their operational sustainability, increases costs, and contributes significantly to polluting emissions. This study evaluates the technical, economic, and environmental feasibility of integrating photovoltaic and solar thermal systems in a hospital located in a tropical Caribbean environment, characterized by continuous operation and high energy demand. The methodology combines advanced simulation using PVsyst for the photovoltaic subsystem and the f-chart method for the solar thermal system, using real data on electricity and domestic hot water demand. The proposed system achieves an installed photovoltaic power of close to 390 kWp, with an annual production of around 0.7 GWh and an average performance ratio of 0.80, demonstrating high technical performance. The solar thermal subsystem covers approximately two-thirds of the annual domestic hot water demand, supported by thermal storage suitable for hospital operation. From an economic standpoint, the total estimated investment is recovered in less than 10 years, with a positive net present value, confirming the system’s profitability over its useful life. In environmental terms, hybrid integration avoids more than 400 t of CO2 per year, contributing significantly to the decarbonization of the health sector and the strengthening of energy security. The results obtained demonstrate that photovoltaic–thermal integration in tropical hospitals is technically and economically viable and constitutes a replicable solution for regions with high solar radiation and energy vulnerability. This research provides a comprehensive and reproducible methodological framework that can support sustainable energy planning and the design of public policies aimed at low-emission healthcare infrastructure.

13 February 2026

Photovoltaic–thermal assessment framework.

To meet the requirements of high-efficiency thermal management without external power in long-distance and distributed multi-heat source scenarios, this paper proposes a dual compensation chamber multi-evaporator loop heat pipe system (DCCME-LHP). The system uses a capillary pump to provide capillary driving force, and through the step-by-step advancement of multiple condenser-evaporator combination, it achieves heat transfer and long-distance transportation among multi-heat sources. The experimental system investigates the effects of working fluid charge ratio, time interval, and heat load on the system’s hydrodynamic stability and heat transfer limit. The results show the optimal comprehensive performance of startup and steady state can be achieved with the charge ratio of 75% and a time interval of 8–10 min. The system operates stably under a total heat load of 270 W (90 W for the capillary pump and 60 W for each of the three evaporators). When the heat load of a single-stage evaporator rises to 70 W, the system enters the operation failure zone, and the steady-state temperature plateau jumps. This study provides a theoretical basis and experimental support for the design and stable operation strategy of long-distance multi-heat source thermal control systems.

13 February 2026

(a) Schematic diagram of the conventional loop heat pipe system. (b) Schematic and physical diagram of the DCCME-LHP system.

Stable circumstances and an improved voltage profile need power compensators integrated with energy storage elements in AC power systems. The control of these compensators is of paramount importance for obtaining high accuracy, reliability, and better system dynamics, which involves careful controller design considerations and small-signal analysis. This paper focuses on the use of a static synchronous compensator (STATCOM) and supercapacitor energy storage system (SCESS) for achieving voltage stability, grid support, and better system dynamics. After the primary load is shifted to the grid, real power assistance is promptly injected into the AC grid to enhance the DC-link voltage, as well as the grid voltage, and reduce supply current from the grid using a vector control technique. The SCESS is handled with the help of a bidirectional DC–DC converter, which facilitates charging and discharging during boost and buck operations, respectively. Using small-signal modeling, the stable system is designed to obtain a reliable and stable output, which is confirmed by the systematic simulations and experiments.

13 February 2026

Flow chart showing the steps involved in the research.

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Eng - ISSN 2673-4117