Construction Materials

This study developed a conditioning framework for the sustainable use of waste-engine-oil-modified binders (WEOMBs) in 100% reclaimed asphalt pavement (RAP) mixtures. Binder with a penetration grade of 60–70 was modified by 5%, 8%, and 10% waste engine oil (WEO) by binder weight. The WEOMBs were subjected to physical, chemical, and compositional analyses. For 10% WEOMB, the results showed a reduction of the binder softening point by 18% and an increase in binder penetration of almost 8%, enhancing softening and the workability of the binder. Binder chemical and compositional analyses verified that WEO altered the binder’s colloidal structure by augmenting aliphatic fractions and molecular mobility, while diminishing resin content and promoting saturates plus aromatics content. At 160 °C for 45 min, the RAPs were conditioned with 1% WEOMB (containing different WEO percentages) by the total weight of the RAP mixture. Among all the conditioned mixtures, the 100% RAP modified with 1% WEOMB, containing 8% WEO, showed the best performance. Dynamic modulus and phase angle analyses demonstrated that RAP conditioning reduced excessive stiffness and produced a balanced viscoelastic response, enhancing the rutting resistance. The proposed conditioning framework demonstrated the feasibility of producing fully recycled mixtures with balanced mechanical performance and adequate cracking resistance. Full article

Since 2024, most electricity production on Réunion Island has been achieved through combustion of biomass, using either imported wood pellets or locally produced bagasse. Their combustion generates two types of ash, depending on the biomass source: Wood Biomass Fly Ash (WBFA) and SugarCane Bagasse Ash (SCBA). Their chemical compositions differ significantly, leading to different potential applications. The composition of SCBA is similar to that of Coal Fly Ash (CFA), with low variability between batches. Therefore, SCBA could be used as an alternative to CFA, as a Supplementary Cementitious Material (SCM) or in composite cements. SCBA also meets most of the requirements of the NF EN 450-1 standard. However, grinding of SCBA appears necessary to achieve mechanical performance required by the standard. In contrast, WBFA exhibits variable chemical composition, mainly due to differences in pellet origin prior to combustion. Nevertheless, WBFA contains significant levels of chloride ions and sulfate, which may act as activators for materials such as GGBS or metakaolin (MK). Although the high unburned carbon content of WBFA increases water demand, their incorporation into GGBS-based binders (SSC or CEM III) or metakaolin-based systems shows promising potential, particularly for improving early strength. Full article

The growing demand for sustainable construction materials has stimulated interest in alternative binders derived from waste resources. This study investigates the use of calcined crab shell (CCS), a calcium-rich marine biowaste, as a partial replacement for Portland limestone cement. Cement pastes containing 0%, 5%, 10%, and 15% CCS were prepared and evaluated through compressive strength, water absorption, open porosity, bulk density, SEM, XRD, FTIR, and TGA analyses. The results showed that incorporating 10% CCS produced the most favorable performance, increasing compressive strength from 17.6 MPa to 33.6 MPa after 28 days of curing. This improvement was accompanied by reduced porosity, increased bulk density, and the development of a denser and more homogeneous microstructure. Physicochemical analyses suggest that CCS acts both as a filler and as a source of reactive calcium species. The CaO generated during calcination may participate in hydration processes and influence the formation of hydration products, contributing to matrix densification. In contrast, the incorporation of 15% CCS resulted in increased porosity, a less homogeneous microstructure, and lower mechanical performance. These findings indicate that replacing Portland limestone cement with up to 10% CCS can improve the properties of cement pastes while promoting the valorization of marine shell waste and reducing cement consumption, thereby supporting the development of more sustainable construction materials. Full article

The growing use of reclaimed asphalt pavement (RAP) in hot mix asphalt (HMA) is an important practice to achieve more sustainable pavements, as it reduces the consumption and environmental impact of virgin materials. However, aging induces binder stiffening that requires effective rejuvenation to restore overall performance. This study provides a comprehensive comparative analysis of ten chemically different waste oils—waste engine oil (WEO), waste cooking oil (WCO), yellow grease (YG), waste hydraulic oil (WHO) waste electric transformer oil (WETO), slop oil (SO), sludge-derived bio-oil (SDBO), tire pyrolysis oil (TPO), plastic pyrolysis oil (PPO), and algal residue oil (ARO)—as recycled HMA mixture rejuvenators, linking oil composition to binder regeneration and mixture performance. Binder properties were determined by rotational viscosity (RV), dynamic shear rheometer (DSR) and bending beam rheometer (BBR), whereas mixture performance was assessed in terms of Superpave mechanical properties, Hamburg wheel-tracking test (HWTT) for rutting resistance and mixture BBR for low-temperature cracking resistance. Performance grade (PG) evaluations showed that WETO and WEO restored the 50% and 75% RAP binders, respectively, to a grade close to PG 64-16 at the lowest dosages. The Superpave volumetric properties of all restored mixtures were similar to those of the control mixture, denoting corrected mixture balance and compaction level. HWTT results indicated that WETO-recycled mixtures revealed the lowest rut depth at 50% RAP, while WEO-recycled mixtures exhibited the lowest rut depth at 75% RAP after 20000 passes. Additional evidence supporting these results can be found in BBR mixture data, which demonstrated that WETO at 50% RAP and WEO/WETO at 75% RAP showed the most reduction in creep stiffness and improvement in creep rate. The correlation, regression, and PI analyses were in good agreement with the experimental results, where WETO and WEO exhibited the best overall performance at 50% and 75% RAP, respectively. In summary, these results indicate that the performance of waste oil rejuvenator in recycled HMA mixtures is highly dependent on RAP content and point to WETO and WEO as feasible, environmentally friendly options for high-RAP recycled HMA. Full article

Zinc processing generates large volumes of tailings enriched with potentially toxic elements such as zinc, lead, arsenic, and antimony, creating environmental challenges. Conventional disposal in tailings dams is associated with land occupation, contamination risks, and geotechnical concerns, reinforcing the need for more sustainable management strategies. This study presents a bibliometric and semi-systematic review of alkali-activated binders for the stabilization and solidification of zinc mine tailings, based on nine studies published between 2019 and 2026. The results indicate that this is a recent and expanding research field, with a marked concentration of studies in China. Current research mainly focuses on the links between microstructure, heavy metal immobilization, and mechanical performance. Alkali-activated systems, commonly based on blast furnace slag, fly ash, and coal gangue, can produce dense matrices with compressive strengths of up to 100.77 MPa and high immobilization efficiency. Their performance is largely governed by the type of reaction products formed, particularly calcium silicate hydrate, calcium aluminosilicate hydrate, and sodium aluminosilicate hydrate gels, which control microstructural development and stabilization mechanisms such as encapsulation, structural incorporation, and secondary phase formation. Overall, the reviewed studies suggest that alkali-activated binders have potential as alternative binders to Portland cement for the management and valorization of zinc mine tailings. Full article

Basalt-fiber-reinforced recycled aggregate concrete (BFRAC) produced with 100% recycled coarse aggregate is still constrained by the inferior quality of recycled aggregate and the difficulty of optimizing fiber reinforcement parameters. This study investigated the effects of basalt fiber length configuration and dosage on the mechanical performance and pore structure of recycled aggregate concrete incorporating recycled coarse aggregate subjected to two-step pretreatment with nano-silica and cement slurry. Four fiber length configurations, namely 6, 12, and 24 mm and a mixed-length system, were evaluated at volume fractions of 0.1, 0.2, and 0.3%. The reinforcing effect was assessed through compressive strength, splitting tensile strength, scanning electron microscopy, mercury intrusion porosimetry, and statistical analysis. The pretreatment improved recycled aggregate quality, reducing water absorption from 4.97% to 3.11% and crushing index from 20.5% to 13.4%. Basalt fiber incorporation generally enhanced mechanical performance, although the response depended on fiber length and dosage. At 28 days, BF24V1 achieved the highest compressive strength, whereas BFmixV1 exhibited the best overall performance by combining high compressive strength with the highest splitting tensile strength. Relative to the average performance of the corresponding single-length mixtures at the same dosage, the mixed-length system showed a positive synergistic effect. Microstructural observations indicated that this behavior was associated with more effective crack bridging and refinement of the pore-size distribution. The results demonstrate that a low-dosage mixed-length basalt fiber system provides an effective route for upgrading pretreated waste-derived aggregate into higher-performance recycled aggregate concrete. Full article

This study investigates the effect of nano-zeolite and lime on the resistance of reconstituted soil using an integrated experimental and explainable machine learning framework. Soil samples were prepared with varying proportions of nano-zeolite, lime, and fines, and cured under controlled temperature and time conditions. Soil resistance (q) was measured to evaluate the mechanical performance of each mixture. Eight machine learning models, including artificial neural networks (ANN), random forest (RF), random tree (RT), random committee–random tree (RC-RT), M5Rules, KStar, RBFS, and additive regression–decision stump (AR-DS), were developed using Weka 3.8.6 to predict soil resistance based on the input parameters. Model performance was assessed using SSE, MAE, MSE, RMSE, Error %, Accuracy %, R², correlation coefficient, Willmott Index, Nash–Sutcliffe Efficiency, Kling–Gupta Efficiency, and SMAPE. ANN and RF achieved superior accuracy (R² ≥ 0.98) with minimal prediction error, effectively capturing the nonlinear interactions between stabilizer content, curing time, and environmental conditions. Sensitivity analyses using the analysis index and SHAP values revealed that nano-zeolite, lime, and curing time were the dominant factors influencing soil resistance, while fines content and curing temperature had secondary effects. The results demonstrate that nano-zeolite and lime significantly enhance soil resistance and that explainable machine learning models can reliably predict and interpret soil performance, providing a data-driven framework for optimized soil stabilization in geotechnical engineering applications. Full article

This study experimentally investigates the structural behavior of hexagonal- and square-shaped composite specimens subjected to vertical compression, vertical tension, and diagonal tension loading. The specimens were fabricated using four- and six-layer alkali-resistant (AR) glass textile reinforcements embedded in a modified cementitious mortar via pull, pour, and roll manufacturing techniques. The mechanical performance of polyvinyl alcohol (PVA) fiber-reinforced composite connectors and steel clamp-type elements was also evaluated at the joints of hexagonal specimens under vertical tension and lateral shear loading. The results show that increasing the number of textile layers significantly enhances structural performance. A 50% increase in textile layers improved load-carrying capacity by up to 56% in compression, 104% in tension, and 216% in diagonal tension. Corresponding increases of approximately 20–42% in ductility and up to 266% in energy dissipation capacity were observed. No failure occurred in the connecting elements, confirming their adequate stiffness, strength, and ductility. In addition, validated three-dimensional finite element models were developed to simulate the response of the hexagonal specimens. Overall, the proposed system demonstrates strong potential for applications such as infill walls, cladding, and sandwich panels due to its favorable strength, ductility, and energy absorption capacity. Full article

The abrupt failure of shear-deficient RC beams may lead to harmful consequences under dynamic loading. The use of Carbon Fiber Reinforced Polymers (CFRP) aims to convert this brittle fracture into a ductile one. However, the complexity of the multiple damage mechanisms makes it difficult to assess their condition using conventional testing methods. In this study, the damage evolution of a shear-critical reference beam and its CFRP-strengthened counterpart was monitored using the acoustic emission (AE) technique. After correcting attenuated AE amplitudes, damage analysis was performed using the Shannon entropy approach based on true source amplitudes. The entropy analysis performed with these corrected data clearly revealed the shear failure in the reference beam through abrupt drops in entropy, indicating damage homogenization. In contrast, the entropy remaining high and dynamically varying over a much longer deflection range in the CFRP-strengthened beam demonstrated that CFRP distributes damage over a wider region and that different damage mechanisms, such as debonding and fiber breakage, in addition to concrete cracking, were simultaneously active. Full article

The performance and durability of asphalt pavements are strongly influenced by the rheological properties of asphalt binders, particularly under severe climatic and traffic conditions. This study investigates the synergistic effects of incorporating multi-walled carbon nanotubes (CNTs) at dosages ranging from 0.25% to 1% into AC 40-50 asphalt binders modified with 4% Styrene–Butadiene–Styrene (SBS). A comprehensive experimental program involving physical, rheological, and chemical characterization tests was conducted, including penetration, softening point, viscosity, storage stability, a Dynamic Shear Rheometer (DSR), Multiple Stress Creep Recovery (MSCR), Linear Amplitude Sweep (LAS), Fourier Transform Infrared Spectroscopy (FTIR), and Glover-Rowe (G-R) analysis. Statistical inference using one-way ANOVA was also conducted to evaluate the significance of differences among the binder formulations investigated. The results showed a continuous increase in binder stiffness with increasing CNT content, as indicated by decreasing penetration values, higher softening points, and increased viscosity. Incorporating 1% CNT reduced the softening-point difference from 3.1 °C to 1.6 °C in SBS-modified binders, indicating improved storage stability. Rheological evaluations showed that 0.75% CNT increased the high-temperature performance grade from 82 °C to 88 °C and provided the best rutting resistance, as indicated by MSCR results. In contrast, the 0.5% CNT formulation exhibited superior fatigue resistance and the lowest Glover-Rowe index, indicating improved cracking resistance and durability. Overall, the findings demonstrate that CNTs can effectively enhance the performance of SBS-modified asphalt binders, with 0.75% CNT being optimal for hot-climate applications, while 0.5% CNT exhibited improved fatigue and cracking resistance under moderate-temperature conditions. Full article

The integration of advanced additive manufacturing technologies, particularly 3D printing (3DP), also known as Additive Construction (AC), could influence a shift in the construction industry towards improved efficiency and automation. This research evaluated the effect on hardened properties of two different concrete mixes for use in 3DP based on the presence or absence of alkaline-resistant (AR) glass fibers. Furthermore, three different curing methods were evaluated: air-curing, plastic-covered curing, and spray-curing. Concrete beams were printed for flexural testing, and cores were taken from other depositions to evaluate compressive strength and split-tensile strength. An analysis of the size and location of cracks on the beams after curing was performed for the different mixes and curing methods. For beams without fibers, plastic-covered curing produced the highest flexural modulus values, and air-curing produced the lowest flexural modulus values. Plastic-cured beams with fibers had higher flexural modulus values than the air-cured beams with fibers. However, the spray-cured beams with fibers produced somewhat anomalous results, with one flexural modulus value being larger than those of the plastic-cured beams, and the other flexural modulus value being less than those of the air-cured beams. All 28-day compressive strengths and split-tensile strengths across mixes and curing conditions fell within a small band ranging between ~19.3–22.1 MPa and ~1.7–2.0 MPa (~2800–3200 psi, and 240–290 psi), respectively. There was a large amount of scatter in some of the tests. It appears that neither the presence of the AR-glass fibers, nor the type of curing had a large influence on compressive strength or split-tensile strength. Results showed that the addition of fibers and the use of the plastic during curing significantly reduced the occurrence, the width, and the depth of cracks as a result resulting from the curing process. Plastic-curing was the most effective curing method for minimizing the occurrence of cracks. Any cracks that formed during plastic-curing were extremely fine and had little or no effect on mechanical properties. Full article

Seawater and sea sand as constituents in concrete are valuable alternatives to freshwater and river sand. Further, the use of seawater and sea sand in projects located in the proximity of a sea/ocean can reduce the overall project cost and lower the carbon footprint. Nevertheless, seawater contains high concentrations of chloride (Cl⁻), sulphate (SO₄²⁻) and magnesium (Mg²⁺), which can react with tricalcium aluminate (C₃A) in cement and the byproduct calcium hydroxide (Ca(OH)₂), and form Friedel’s salt, delayed ettringite and brucite, respectively. These chemical compounds are aggressive and can degrade the strength and durability of the concrete. Differences in the physical properties of sea sand compared to river sand can also lead to weak and porous concrete. In reinforced concrete, steel bars are susceptible to corrosion due to the formation of corrosion products as a result of high concentrations of Cl⁻. Whilst mitigation strategies such as the use of supplementary cementitious materials (SCMs) and fibre-reinforced polymer (FRP) reinforcements have been investigated in the literature, no validated method that enables the use of concrete with seawater and sea sand has been established. Based on research reported in the literature, the present study investigates the chemistry, strength and microstructure of concrete mixed with seawater and sea sand as a means of establishing their use in concrete without compromising the properties of the concrete. The study shows that the compressive strength of seawater–sea sand mixed concrete (SWSSC) is increased in the short term (up to 28 days) due to the formation of additional chemical compounds in the former. However, the long-term (i.e., beyond 28 days) compressive strength of concrete reduces by up to 20% after one year due to the weakening of the microstructure (more flaws/expansions), which further reduces the durability of the reinforced concrete. Although the long-term degradation of SWSSC has been noticed, the underlying causes are not fully understood. The present critical review study provides chemical and microstructural insight into the degradation of concrete with seawater and sea sand, and the current developing understanding is used to develop a mitigation strategy towards the use of seawater and sea sand in real-world concrete applications. Full article

This study investigates the effect of mass-based replacement of natural coarse aggregate with electric arc furnace (EAF) slag on the performance of ordinary Portland cement (OPC) concrete. Replacement levels of 0%, 30%, 50%, and 100% were examined, with particular attention to the volumetric changes induced by the higher density of EAF slag, which leads to an increase in paste volume. Fresh, mechanical, durability-related, and microstructural properties were evaluated. Results show a continuous reduction in workability with increasing slag content, despite the increase in paste volume, indicating the dominant influence of aggregate morphology on rheological behavior. Mechanical performance exhibited a non-linear response. Within the tested series, the 50% replacement mixture showed the highest mean compressive and splitting tensile strengths; however, the compressive strength difference relative to the control mixture remained small and within typical experimental scatter. In contrast, water absorption decreased progressively, reflecting improved matrix densification. However, this densification did not translate into enhanced mechanical performance, highlighting a decoupling between durability-related indicators and strength. A screening-level CO₂ assessment further showed that reductions in aggregate-related emissions were offset by increased cement content associated with mass-based replacement. The results emphasize the importance of considering volumetric effects when interpreting the behavior and sustainability of slag-based concrete. Note: all strength comparisons are based on mean values from three-specimen sets without formal statistical testing and should be regarded as exploratory observations. Full article

The formation of blisters in reactive resin coatings on concrete is a widely known phenomenon that is also a subject of debate in the literature. In particular, blisters forming after curing of the coating can lead to extensive damage. This study was focused on the investigation of blistering between the concrete substrate and the resin coating. The hypothesis is that the cementitious material and the overlying reactive resin coating form a system that leads to damage under certain boundary conditions regarding material composition, as well as moisture and mass transport. Systematic investigations were carried out in an extensive testing program with various substrate mortars that differ in cement type, water–cement ratio, and aggregate. As coating systems, two different EP primers were used with a transparent EP topcoat. The long-term testing was conducted on potential blistering of composite test specimens stored under various (practically relevant) conditions prior and after the coating. It was found that a higher moisture content of the substrate reduces blistering of the EP coating system. EP systems containing benzyl alcohol do not automatically tend to blister. Furthermore, condensation in the substrate provides sufficient amounts of water to cause blistering and ASR can contribute to blister formation. Full article

Recycled aggregates (RAs) from construction and demolition waste (CDW) provide substantial circular-economy benefits, yet their elevated porosity, adhered mortar, and heterogeneity typically impair the mechanical performance and durability of recycled aggregate concrete (RAC). This PRISMA 2020-compliant systematic review synthesises 2180 records (2015–2026) to evaluate advanced strategies for enhancing RA quality prior to structural use. This paper critically compares removal-based treatments (mechanical, thermal, acid cleaning) with strengthening and densification approaches, including accelerated carbonation, pozzolanic and nano-silica coatings, polymer impregnation, microbial-induced calcium carbonate precipitation (MICP), and modified mixing methods such as triple-stage mixing (TSMA). Evidence shows that while all RA types (including recycled fine aggregate (RFA), recycled coarse aggregate (RCA), and their combination (RFCA)) can slightly reduce compressive strength and 30% replacement serves as a critical threshold, beyond this, strength loss accelerates, particularly in RCA and RFCA mixes. However, accelerated carbonation and TSMA consistently refine the interfacial transition zone, reduce water absorption by 17–30%, and recover 85–94% of natural aggregate concrete strength. Bio-deposition reduces water absorption by 13–21%, while acid/silica fume treatments improve late-age strength but carry environmental trade-offs. This review formulates a practice-oriented implementation framework for structural-grade RAC. Sustainability analyses indicate that carbonated RA can achieve net-positive CO₂ abatement when under low-carbon energy supply. A mechanistic schematic is presented to synthesise treatment-to-pore-structure/durability pathways across the four principal treatment routes, and a quantitative synthesis plot compares water absorption reductions across all treatment types using 13 data points drawn from included studies. A structured treatment comparison evaluates the energy intensity, industrial scalability, CO₂ footprint, and technology readiness level for each strategy. The remaining challenges include a lack of hybrid treatment studies, limited real-scale durability data, and insufficient mechanistic models linking treatment to pore structure evolution. This review recommends harmonised durability-based criteria and updates to standards (e.g., BS 8500, EN 12620) to support the scalable deployment of treated RA. Full article

Drying shrinkage is a critical durability issue in concrete structures, particularly in high-strength concrete (HSC), which is more susceptible to early-age cracking due to its low water–cement ratio and dense microstructure. This study experimentally evaluates the restrained drying shrinkage behavior of fiber-reinforced concretes with compressive strengths ranging from 23 to 84 MPa, employing a total of 84 ASTM C1581 ring specimens exposed to three exposure conditions: outdoor climate, indoor laboratory conditions (25 °C, 50% RH), and a controlled chamber (50 °C, 30% RH). Plain concretes exhibited increasing shrinkage with both strength and environmental severity. Under indoor exposure, 90-day shrinkage reached approximately 660 × 10⁻⁶ (23 MPa), 291 × 10⁻⁶ (40 MPa), 753 × 10⁻⁶ (60 MPa), and 338 × 10⁻⁶ (84 MPa), with high-strength mixes showing greater cracking susceptibility. Fiber incorporation significantly mitigated both strain and cracking in a dosage-dependent manner. Steel fibers at 1.0–1.5% reduced shrinkage by up to 75% in 40–60 MPa concretes, while polypropylene fibers at 0.25–0.5% achieved reductions up to 66% and eliminated cracking in several cases. Results demonstrate that concrete strength, exposure condition, fiber type, and dosage collectively govern shrinkage and cracking resistance. Full article

In designing tall buildings, the primary concern is ensuring an effective lateral load-resisting system in addition to the gravity load system, since it largely governs the overall design. This study investigates the influence of X-cable bracing on the structural weight of tall steel frame buildings subjected to service and wind loading. Three numerical case studies, 10-story, 20-story, and 30-story planar steel frames, were modeled and analyzed using SAP2000, then optimized using Differential Evolution (DE) and Enhanced Colliding Bodies Optimization (ECBO) algorithms. These designs were evaluated under both service and wind load conditions, considering strength and drift constraints. The results indicate that the inclusion of wind loads in addition to service loads leads to a higher total structural weight than considering service loads alone, while cable bracing effectively reduces the overall mass by up to 6%, 38%, and 20% for the 10-story, 20-story, and 30-story frames, respectively, compared to unbraced structures, by improving the internal force distribution among structural components. Strength demands, reflected by the interaction ratio, governed all design cases, while lateral displacement was always less than the maximum limit according to AISC and ASCE requirements. Overall, the results highlight the potential of cable bracing systems to deliver efficient tall building designs; however, further studies are needed to generalize these findings to a broader range of building configurations. Full article

Concrete linings are used for water containment, in particular in reservoirs and canals. When the soil underlying a concrete lining has a high permeability, seepage into the ground of water from concrete-lined reservoirs and canals is essentially governed by leakage of water through the concrete linings. Therefore, it is essential to properly evaluate the hydraulic conductivity of concrete linings. It is known that cracks generally develop in concrete linings. This article provides material data and a method for the evaluation of the hydraulic conductivity of concrete linings, in particular cracked concrete linings, through two approaches. The first approach consists of a review of selected published values of the measured hydraulic conductivity of intact and cracked concrete. The second approach consists in developing an original analytical method to determine the hydraulic conductivity of cracked concrete using the results of an experimental evaluation of the influence, on water flow, of the tortuosity and rugosity of concrete cracks. The results obtained with the two approaches are compared and numerical examples are presented. Based on these results, practical guidance is provided to design engineers for a safe evaluation of the hydraulic conductivity of concrete linings, cracked or not cracked. Full article