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Minerals, Volume 16, Issue 4 (April 2026) – 91 articles

Cover Story (view full-size image): The study examines comminution behavior and beneficiation potential of Li-bearing ores—zinnwaldite (Cínovec) and lepidolite (Villasrubias)—using mineralogical and mechanical characterization. It addresses challenges of low-grade, fine-grained Li-micas with strong supply potential in Europe. Quantitative microstructural analysis shows that zinnwaldite ores are coarser, highly interlocked, and rough, whereas lepidolite ores are finer, smoother, and more dispersed. Zinnwaldite-rich samples have lower compressive strength, while lepidolite-rich ores are stronger due to a more cohesive structure. Consequently, lepidolite requires higher energy input and finer crushing to achieve liberation. These properties control breakage behavior and are critical for selective separation of mica from gangue. View this paper
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30 pages, 68906 KB  
Article
Fracture Development in Alkaline Lacustrine Shales: Insights from Multi-Stage Fluid–Rock Interactions in the Permian Fengcheng Formation, Mahu Sag, Junggar Basin
by Kuan Lu, Jiakai Hou, Zhenkai Huang, Guangyou Zhu, Jianyong Liu, Jiangna Fu and Heting Gao
Minerals 2026, 16(4), 430; https://doi.org/10.3390/min16040430 - 21 Apr 2026
Viewed by 391
Abstract
The Mahu Sag, a hydrocarbon-rich depression within the Junggar Basin, hosts significant petroleum resources. Here, the Permian Fengcheng Formation shale oil reservoirs have emerged as a primary exploration target. This study investigates fracture development within these alkaline lacustrine shales, a critical factor governing [...] Read more.
The Mahu Sag, a hydrocarbon-rich depression within the Junggar Basin, hosts significant petroleum resources. Here, the Permian Fengcheng Formation shale oil reservoirs have emerged as a primary exploration target. This study investigates fracture development within these alkaline lacustrine shales, a critical factor governing hydrocarbon migration and accumulation. Through integrated petrographic and geochemical analyses, we elucidate a multifactorial fracture formation mechanism driven by the interplay of alkaline minerals, stress, and fluids. Two distinct fracture types were identified: bedding-complex fracture veins (BCFVs) and Y-shaped high-angle fracture veins (Y-HFVs). Both fracture types result from alkaline fluid–rock interactions, which induce fracture opening along specific orientations, alter fracture angles, and control aperture width and final morphology. Alkaline mineral assemblages further influence fracture evolution via dissolution–precipitation cycles. Concurrently, these assemblages preserve hydrocarbons by inhibiting the thermal maturation of organic matter, as evidenced by variations in fluid inclusion fluorescence. The fracture networks act as crucial migration pathways, with the BCFV containing higher-maturity hydrocarbons (indicated by blue-green fluorescence) and the Y-HFV retaining less mature fluids (indicated by yellow-green fluorescence). This study presents the first systematic characterization of the multifactorial controls on fractures in alkaline lake environments, proposing a cooperative “alkaline minerals–stress–fluids” mechanism. These findings provide a new framework for understanding fracture development in alkaline lacustrine shales and offer valuable insights for shale oil exploration in analogous depositional settings. Full article
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18 pages, 19170 KB  
Article
Study on Recovering Graphite from Lithium Batteries Leaching Carbon Residues via Multi-Field-Assisted Low-Temperature Molten Salt Roasting
by Yanlin Zhang, Wenyi Liang, Yunzuo Lei, Zhen Zhou, Jun Zhou, Zhen Yao, Qifan Zhong and Fuzhong Wu
Minerals 2026, 16(4), 429; https://doi.org/10.3390/min16040429 - 21 Apr 2026
Viewed by 474
Abstract
Leaching carbon residue (LCR) is a carbonaceous solid waste generated during the hydrometallurgical recycling of spent lithium-ion batteries. Although its high graphite content offers substantial potential for resource recovery, the residual heavy metals and fluorides present in LCR pose considerable environmental risks. Currently, [...] Read more.
Leaching carbon residue (LCR) is a carbonaceous solid waste generated during the hydrometallurgical recycling of spent lithium-ion batteries. Although its high graphite content offers substantial potential for resource recovery, the residual heavy metals and fluorides present in LCR pose considerable environmental risks. Currently, LCR has not garnered sufficient attention within the industry, and the lack of recycling technologies suitable for large-scale disposal results in resource wastage and environmental pollution. To address these challenges, this study proposes an innovative strategy based on the concept of multi-field synergistic enhancement. The proposed approach involves recovering and regenerating graphite (RG) from LCR via low-temperature molten salt roasting assisted by high-pressure and mechanical activation. A combination of advanced characterization techniques was employed to compare the physicochemical properties of RG and commercial graphite (CG) and to systematically evaluate the technical feasibility of using regenerated graphite as an anode material for lithium-ion batteries. The results demonstrate that, under optimized molten salt roasting and aqueous leaching conditions, the carbon content of RG reaches 99.94 wt%, indicating the efficient removal of non-carbon impurities from the graphite matrix. Compared to CG, RG retains a typical layered structure; however, a lower carbon content (99.94 wt%) and poorer structural order (ID/IG = 0.30) are observed. In terms of electrochemical performance, RG delivers a discharge specific capacity of 394.64 mAh/g during the first cycle and exhibits excellent cycling stability, with a capacity retention of 86.50% after 100 cycles. This electrochemical performance is comparable to that of commercial graphite. The proposed multi-field-assisted low-temperature molten salt roasting technique enables the efficient recovery of high-value graphite resources from LCR, establishing a full-lifecycle recycling strategy tailored for lithium-ion battery applications. Full article
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20 pages, 5246 KB  
Article
Fuzzy Logic Mineral Potential Mapping of the Tisová–Klingenthal Cu–Co Deposit
by Martin Köhler, Percy Clark, Jiří Zachariáš and Andreas Knobloch
Minerals 2026, 16(4), 428; https://doi.org/10.3390/min16040428 - 21 Apr 2026
Viewed by 579
Abstract
Fuzzy logic-based mineral potential mapping was applied to the Tisová–Klingenthal Cu–Co VMS deposit (Erzgebirge) in the Czech–German border region. The study area is characterized by heterogeneous geological and geochemical datasets derived from differing national surveys and historical mining. Using the Exploration Information System [...] Read more.
Fuzzy logic-based mineral potential mapping was applied to the Tisová–Klingenthal Cu–Co VMS deposit (Erzgebirge) in the Czech–German border region. The study area is characterized by heterogeneous geological and geochemical datasets derived from differing national surveys and historical mining. Using the Exploration Information System (EIS) toolkit, a knowledge-driven fuzzy logic approach integrated key spatial datasets, including copper and zinc soil and stream sediment anomalies and metabasalt lithology, relevant to Besshi-type VMS deposits. Three prospective anomalies were identified: the historic Tisová mine and two additional targets aligned along the same stratigraphic horizon. Artificial Neural Network (ANN) modelling was limited by insufficient training data, resulting in overfitting and reduced predictive reliability. Follow-up soil geochemical surveys conducted over the largest anomaly returned locally elevated copper values but did not conclusively confirm mineralisation. The results demonstrate that fuzzy logic provides a flexible and interpretable framework for mineral potential mapping in complex, data-scarce environments and highlight the need for iterative modelling and targeted exploration. Full article
(This article belongs to the Topic Big Data and AI for Geoscience)
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18 pages, 3535 KB  
Article
Environmental Pollution Load and Contaminant Transfer in Natura 2000 Protected Brownfield Site
by Anja Ilenič, Petra Vrhovnik, Sonja Lojen and Matej Dolenec
Minerals 2026, 16(4), 427; https://doi.org/10.3390/min16040427 - 21 Apr 2026
Viewed by 544
Abstract
Revitalisation of contaminated brownfield sites is essential for sustainable development, particularly near sensitive ecological areas like Natura 2000 sites. The lagoon in Slovenia’s Regional Park Šturmovci, an artificial wastewater convergence point created during hydroelectric construction, is a highly relevant example. This study integrates [...] Read more.
Revitalisation of contaminated brownfield sites is essential for sustainable development, particularly near sensitive ecological areas like Natura 2000 sites. The lagoon in Slovenia’s Regional Park Šturmovci, an artificial wastewater convergence point created during hydroelectric construction, is a highly relevant example. This study integrates geochemical, mineralogical and isotopic analyses to identify sources and controlling mechanisms of contaminant distribution in lagoon sediments and assess their transfer to nearby agricultural soils during flooding events. Results indicate anaerobic conditions, with depth-related shifts in phosphorus, sulphur and redox-sensitive elements, such as rare earth elements (REE), arsenic (As), barium (Ba), cobalt (Co), chromium (Cr), lead (Pb) and vanadium (V), as well as fluctuations in pyrite-rich laminated layers, suggesting potential flood-driven remobilisation of trace elements. Lagoon sediments are highly contaminated with As (73 mg kg−1), Ba (247 mg kg−1), Pb (97 mg kg−1) and Zn (1118 mg kg−1), with elevated concentrations also observed in agricultural soil, all exceeding respective limit values of 20, 160, 85 and 200 mg kg−1. Pollutant concentrations were highest near wastewater inflows and decreased with distance, with nitrogen isotopic patterns indicating partial nitrification and surface ammonium accumulation, reflecting intensive agricultural inputs in the area. High enrichment factor (EF > 20) and geoaccumulation index (Igeo > 3) values, in particular for As, Cd and Zn, indicated severe contamination and highlighted the urgent need for effective remediation strategies, including immobilisation using biochar or cement-based binders, as well as phytoremediation approaches. Full article
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45 pages, 10083 KB  
Systematic Review
The Conservation of Architectural Heritage Structures Built with Tuff and Coral Rock: A Systematic Review and Bibliometric Analysis of Geopolymer Formulation, Application, Compatibility and Durability
by Kent Benedict Aleonar Salisid, Raul Lucero, Jr., Reymarvelos Oros, Mylah Villacorte-Tabelin, Theerayut Phengsaart, Shengguo Xue, Jiaqing Zeng, Ivy Corazon A. Mangaya-ay, Takahiko Arima, Ilhwan Park, Mayumi Ito, Sanghee Jeon and Carlito Baltazar Tabelin
Minerals 2026, 16(4), 426; https://doi.org/10.3390/min16040426 - 20 Apr 2026
Viewed by 1494
Abstract
The conservation of tuff- and coral rock-built architectural heritage structures (AHS) is challenging because access to original tuff and coral rock has become difficult and severely limited due to urbanization, land reclamation, the depletion of stone quarries, anti-mining and anti-quarrying legislation. An emerging [...] Read more.
The conservation of tuff- and coral rock-built architectural heritage structures (AHS) is challenging because access to original tuff and coral rock has become difficult and severely limited due to urbanization, land reclamation, the depletion of stone quarries, anti-mining and anti-quarrying legislation. An emerging approach to address this issue is to create compatible “replacement” rocks via geopolymerization, a process that is more sustainable and greener than the use of conventional cement and concrete. To explore the potential of geopolymers for AHS conservation strategies, the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines were implemented; 103 eligible articles were identified and classified into geopolymers for AHS (34 articles), tuff-built AHS (60 articles), and coral rock-built AHS (9 articles). Tuff substrates in AHSs appear in a variety of colors (yellowish-brown, grayish-cream, reddish-brown, pale greenish-gray and pink hues), densities (1.0–2.5 g/m3), and compressive strengths (3–100 MPa). Meanwhile, coral rock substrates in AHSs appear in whitish-cream color and are coarse-pored (1–5 MPa), fine-grained (8–15 MPa), and calcarenite (50–60 MPa). In terms of geopolymer formulation, metakaolin was reported as the most popular main precursor or admixture, while NaOH and Na2SiO3 were used simultaneously as alkaline activators. Aggregates used in geopolymer formulations depended on local availability, including quartz sand, river sand, crushed stones, carbonate stones, volcanic rock, volcanic sand, tuff, brick, ceramic tiles, and waste materials. Aesthetics, chemical composition, physical attributes, and mechanical properties have been identified as key criteria to ensure geopolymer compatibility for AHS conservation application. To date, geopolymers have been applied for AHS conservation as repair mortars, consolidants (i.e., grout and adhesives), and masonry strengthening (i.e., fiber-reinforced mortar). Finally, geopolymers formulated for AHS conservation have similar durability as the original substrate based on accelerated aging tests (i.e., salt mist, wet-dry, and freeze–thaw) and long-term outdoor exposure experiments. Full article
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28 pages, 14650 KB  
Article
Paleoclimatic Transition, Paleoenvironmental Evolution, and Organic-Rich Source Rock Formation in the Permian Pingdiquan Formation, Junggar Basin, Northwest China
by Keting Fan, Gang Gao, Xiaobing Jiao, Xinsong Wu, Miao Yu, Zhehui Jin, Jilun Kang, Youjin Zhang, Xiongfei Xu and Qiang Ma
Minerals 2026, 16(4), 425; https://doi.org/10.3390/min16040425 - 20 Apr 2026
Viewed by 710
Abstract
A climatic transition from arid to humid conditions occurred during the deposition of the Permian Pingdiquan Formation in the Shishugou Sag, Junggar Basin, Northwest China. This study reconstructs the paleoenvironmental evolution and organic matter (OM) enrichment mechanisms recorded in six stratigraphic intervals, with [...] Read more.
A climatic transition from arid to humid conditions occurred during the deposition of the Permian Pingdiquan Formation in the Shishugou Sag, Junggar Basin, Northwest China. This study reconstructs the paleoenvironmental evolution and organic matter (OM) enrichment mechanisms recorded in six stratigraphic intervals, with emphasis on the two oil shale units formed during the transgressive system tracts (TST1 and TST2). Geochemical, elemental, and biomarker data reveal that climate, salinity, and redox conditions fluctuated significantly and jointly governed OM enrichment, with paleoclimate acting as the primary background control by regulating lake hydrology, salinity, and preservation. During the early stage (SQ1), an arid climate prevailed, the TST1 oil shale formed during a transient freshening event in a deep stratified lake. Dominant algal productivity and minimal terrigenous input favored excellent preservation, yielding the highest TOC and superior hydrocarbon potential. In contrast, during the humid stage (SQ2), the TST2 oil shale was deposited in a moderately deep, weakly reducing, and slightly saline lake. Although preservation was less efficient, enhanced primary productivity under humid conditions compensated for OM loss, producing abundant but slightly lower quality OM. These results establish two depositional models, an arid freshening model (TST1) and a humid salinization model (TST2). Both transient freshening under arid conditions and salinization during humid periods facilitated the accumulation of organic-rich source rocks through different balances between productivity and preservation. This highlights the complex response of lacustrine source rock development to climatic variability. The occurrence of similar organic-rich source rocks can be anticipated under comparable paleoenvironmental transitions, particularly in saline lakes characterized by frequent fluctuations in water salinity and paleoclimate. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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20 pages, 12376 KB  
Article
In Situ LA-ICP-MS Trace-Element and Sulfur Isotope Characteristics of Sulfides from Pb-Zn Ore Bodies in the Gariatong W-Mo Polymetallic Metallogenic System, Xizang, and Their Geological Implications
by Run Cao, Fuwei Xie, Ming Jia, Yang Cao and Lutong Gao
Minerals 2026, 16(4), 424; https://doi.org/10.3390/min16040424 - 20 Apr 2026
Cited by 1 | Viewed by 383
Abstract
The peripheries of rare-metal metallogenic systems frequently host skarn-type or hydrothermal vein-type Pb-Zn deposits, though their genetic connections with parental systems remain debated. The newly identified Gariatong W-Mo polymetallic metallogenic system in the Lhasa Terrane displays well-defined Nb-Ta-Rb, Mo-W, W-Mo, W-Bi, and Pb-Zn-Ag [...] Read more.
The peripheries of rare-metal metallogenic systems frequently host skarn-type or hydrothermal vein-type Pb-Zn deposits, though their genetic connections with parental systems remain debated. The newly identified Gariatong W-Mo polymetallic metallogenic system in the Lhasa Terrane displays well-defined Nb-Ta-Rb, Mo-W, W-Mo, W-Bi, and Pb-Zn-Ag metallogenic zoning, establishing it as an exemplary site for investigating genetic relationships between Pb-Zn and rare-metal mineralization. This investigation targets skarn-type Pb-Zn deposits spatially associated with rare-metal orebodies at Gariatong, utilizing integrated analytical approaches, including in situ LA-ICP-MS trace-element analysis of sulfides, sulfur isotope geochemistry, and LA-ICP-MS elemental mapping of sphalerite, to constrain metal sources, characterize fluid evolution, and establish genetic correlations with the rare-metal system. Key findings include the following: (1) sphalerite shows enrichment in Fe, Mn, Co, and Cd, while pyrite contains elevated As, Pb, Co, Cu, and Mn. Fe, Cd, and Mn primarily occur as solid solutions or nanoparticles, whereas As and Pb exist as micro-inclusions. (2) Sphalerite Zn/Cd ratios (73.6–184) and Co-Ni-As ternary diagrams confirm a magmatic–hydrothermal skarn origin. (3) Mineralization occurred under moderate-temperature, mildly oxidized conditions, as constrained by sphalerite Fe contents and mineral assemblages. Sulfur isotope compositions (δ34S = −1.0‰ to 3.2‰; mean: 1.9‰) indicate a magmatic sulfur source. This study reveals that the Nb-Ta-Rb mineralization, quartz-vein- and greisen-type W-Mo deposits, and skarn-type Pb-Zn orebodies—all genetically associated with highly fractionated granites—constitute an integrated magmatic–hydrothermal system with vertical (depth-related) zoning relative to the granitic intrusion. These results provide critical constraints for understanding rare-metal–Pb-Zn genetic associations and suggest that Pb-Zn mineralization may serve as a key exploration indicator for rare metals in the Lhasa Terrane. Full article
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19 pages, 7398 KB  
Article
Origins of Au Deposits in Mesozoic Clastic-Hosted Ore Formations in the Great Xing’an Range, China: Constraints from the Baoxinggou Au Deposit
by Sheng Lu, Tao Liu, Tiesheng Li, Hongpeng Chen, Qingyuan Song, Zhengbo Zang and Wenlong Li
Minerals 2026, 16(4), 423; https://doi.org/10.3390/min16040423 - 19 Apr 2026
Viewed by 436
Abstract
The northern part of the Great Xing’an Range in China hosts a prominent Au mineralization belt, where Mesozoic clastic rock-hosted Au deposits represent the mineralization type. A study of the Baoxinggou Au deposit in this region might provide new perspectives on the mineralization [...] Read more.
The northern part of the Great Xing’an Range in China hosts a prominent Au mineralization belt, where Mesozoic clastic rock-hosted Au deposits represent the mineralization type. A study of the Baoxinggou Au deposit in this region might provide new perspectives on the mineralization mechanisms of these Mesozoic clastic-rock-hosted Au deposits. This study investigated the age of mineralization, origins and evolution of the ore-forming fluids, and sources of the ore-forming materials in this deposit. Rubidium–Sr dating of sulfides yielded a mineralization age of 119 ± 2 Ma. Fluid inclusion analyses revealed that the ore precipitated from fluids with temperatures of 105–415 °C and salinities of 4.3–8.8 wt.% NaCl equivalent. Hydrogen and O isotopic data show that the ore-forming fluids were of magmatic origin and, during mineralization, the proportion of meteoric waters increased gradually and eventually dominated the late mineralization stage. Fluid mixing was the primary ore-forming mechanism. Sulfur isotopic data for pyrite and chalcopyrite (δ34SV–CDT = −4.35‰ to −0.91‰) and Pb isotopic ratios (206Pb/204Pb = 18.429–18.477; 207Pb/204Pb = 15.581–15.591) indicate the ore-forming materials were magmatic in origin, with a similar source as an Early Cretaceous diorite and mixed crust–mantle materials. The results indicate the Baoxinggou Au deposit is a magmatic–hydrothermal deposit. Full article
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34 pages, 112670 KB  
Article
Introducing Dominant Tree Species Classification to the Mineral Alteration Extraction Process in Vegetation Area of Shabaosi Gold Deposit Region, Mohe City, China
by Zhuo Chen and Jiajia Yang
Minerals 2026, 16(4), 422; https://doi.org/10.3390/min16040422 - 19 Apr 2026
Viewed by 498
Abstract
The performance of remote sensing-based mineral alteration extraction is significantly restricted in the vegetation area. Spectral unmixing is one of the effective methods to address the vegetation problem during mineral alteration extraction. However, the spectral curves of different tree species vary a lot; [...] Read more.
The performance of remote sensing-based mineral alteration extraction is significantly restricted in the vegetation area. Spectral unmixing is one of the effective methods to address the vegetation problem during mineral alteration extraction. However, the spectral curves of different tree species vary a lot; if multiple tree species are regarded as a whole during the spectral unmixing stage, the proportions of vegetation would be estimated with more errors. The purpose of this study was to verify the effects of dominant tree species classification on spectral unmixing and reconstruction, and to apply the proposed method to the mineral alteration extraction practice. To accomplish this, the Shabaosi gold deposit region in Mohe City, China, with an area of 650 km2, was selected as the study area. Firstly, reference spectral curves, GaoFen-1/6 (GF-1/6) satellite imageries, ZiYuan-1F (ZY-1F) satellite imageries, Sentinel-1B satellite synthetic aperture radar (SAR) data, the ALOS digital elevation model (DEM), and sub-compartment dominant tree species data were collected; subsequently, simulated mixed-pixel reflectance images of ZY-1F, reflectance images of GF-1/6, ZY-1F, backscattering data of Sentinel-1B, slope, aspect, and 5484 tree species samples were derived from the collected data. Secondly, to verify the effect of dominant tree species classification on mineral alteration extraction, the reference spectra of pine, oak, goethite, and kaolinite were used to construct a simulated ZY-1F mixed-pixel image, and spectral unmixing and reconstruction experiments were conducted. Thirdly, fourteen independent variables were selected from the derived data, five dominant tree species classification models were trained and tested using tree species samples via the ResNet50 algorithm, and the pine- and birch-dominated parts were segmented from the ZY-1F images. Fourthly, minimum noise fraction (MNF), pixel purity index (PPI), n-dimensional visualizer auto-clustering, and spectral angle mapper (SAM) methods were separately applied to the pine- and birch-dominated parts of ZY-1F images to extract and identify endmembers; subsequently, the fully constrained least squares (FCLS) and linear spectral unmixing (LSU) methods were separately applied to the pine- and birch-dominated parts to estimate endmember proportions and generate spectrally reconstructed ZY-1F images. Fifthly, the pine- and birch-dominated parts of spectrally reconstructed ZY-1F images were mosaiced, and the SAM was utilized to extract mineral alteration in the study area. The result showed that in the spectral unmixing and reconstruction experiment, the spectral reconstruction error declined from 0.0594 (simulated ZY-1F image without segmentation) to 0.0292 and 0.0388 (simulated ZY-1F image that was segmented by pine- and oak-dominated parts), suggesting that dominant tree species classification could improve the accuracy of spectral unmixing and reconstruction and help obtain a more reliable mineral alteration extraction result. In the study area, the tested overall accuracies (OA) and Kappa coefficients of the five dominant tree species classification models were 0.75 ± 0.03 and 0.50 ± 0.05, respectively, suggesting that conducting dominant tree species classification was feasible in dense vegetation areas and could facilitate mineral alteration extraction. After segmenting the ZY-1F image by pine- and birch-dominated parts and spectral reconstruction, eight main types of alteration, including kaolinite, vesuvianite, montmorillonite, rutile, limonite, mica, sphalerite, and quartz, were identified, and nine mineral alteration areas (MA) were delineated accordingly. Full article
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23 pages, 23756 KB  
Article
Geochemistry and Ore Genesis of the Huoyanshan Cu-Zn Polymetallic Deposit, North Qilian Orogenic Belt, China: Constraints from Trace Element Compositions and Sulfur Isotopes
by Zaijia Zhang, Xiaogang Guo, Peiqing Hu, Bo Mai and Zhuang Wu
Minerals 2026, 16(4), 421; https://doi.org/10.3390/min16040421 - 19 Apr 2026
Viewed by 425
Abstract
The Huoyanshan Cu-Zn volcanogenic massive sulfide (VMS) deposit, located in the North Qilian Orogenic Belt, China, is of significant economic importance. This study provides new constraints on the ore-forming processes through high-resolution in situ trace element and sulfur isotope analyses of pyrite and [...] Read more.
The Huoyanshan Cu-Zn volcanogenic massive sulfide (VMS) deposit, located in the North Qilian Orogenic Belt, China, is of significant economic importance. This study provides new constraints on the ore-forming processes through high-resolution in situ trace element and sulfur isotope analyses of pyrite and sphalerite using LA-(MC)-ICP-MS. Petrographic and geochemical investigations identified three distinct generations of pyrite (Py l to Py III). Early-stage Py I and Py II are characterized by high trace element contents (Au, As, Bi, Cu, Pb), elevated Co/Ni ratios (>1–10), and enriched δ34S values (+4.98‰ to +7.47‰). These signatures indicate precipitation from high-temperature, reduced magmatic–hydrothermal fluids influenced by thermochemical sulfate reduction (TSR). Late-stage Py IIl exhibits markedly lower Co/Ni ratios (<0.1) and lighter δ34S values (+3.72‰ to 3.89‰). This geochemical shift reflects a transition toward a cooler, more oxidized environment driven by the incursion and mixing of ambient seawater as the hydrothermal system waned. Trace element geochemistry of sphalerite reveals an average crystallization temperature of 265.8 °C (derived from the “GGIMFis” geothermometer), consistent with fluid inclusion data and representing a thermal “snapshot” of the waning hydrothermal stage. Systematic discriminant analysis using Ga/In, Ge/In, and Co-Ni-As systematics further confirms a strong magmatic–hydrothermal affiliation. Full article
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16 pages, 28850 KB  
Article
Effects of Carbonated Recycled Aggregate on Performance of Cemented Paste Backfill
by Yin Liu, He Zhang, Shengtang Zhang, Lingran Min, Hao Fang, Hongru Rui and Hao Li
Minerals 2026, 16(4), 420; https://doi.org/10.3390/min16040420 - 19 Apr 2026
Viewed by 699
Abstract
In order to explore the outstanding problems, such as poor mechanical performance, of recycled aggregate from construction waste in the application of backfills, this study innovatively used accelerated carbonation treatment technology to pretreat the recycled aggregates, and systematically investigated the evolution of mechanical [...] Read more.
In order to explore the outstanding problems, such as poor mechanical performance, of recycled aggregate from construction waste in the application of backfills, this study innovatively used accelerated carbonation treatment technology to pretreat the recycled aggregates, and systematically investigated the evolution of mechanical properties in carbonated recycled aggregate-based cemented paste backfill (CPB). By carbonizing the waste recycled concrete aggregate (RCA), carbonation recycled concrete aggregates (CRCA) were obtained, and coal gangue was replaced as the filling aggregate at 50% and 100% for mine paste filling. The mechanical properties of the CPB were measured, and the mechanism was analyzed in combination with the changes in the microstructure. The results showed that the physical properties of RCA were significantly improved by carbonation treatment compared with untreated raw RCA: the apparent density of C60d-RCA increased by 2.88% relative to non-carbonated RCA, while its crushing value decreased by 51.45%, resulting in a more stable aggregate structure. In terms of mechanical properties, the compressive strengths of the 28day carbonated backfills with 50% and 100% CRCA contents (denoted as C28d-RCA-50 and C28d-RCA-100) reached 6.38 MPa and 5.32 MPa, representing increases of 61.52% and 46.33%, respectively, compared to the control group. Microstructure and phase composition analysis showed that the carbonation reaction not only produced calcium carbonate (CaCO3) crystals to effectively fill the internal pores and reduce the total porosity of the matrix, but also promoted the generation of monocarboaluminate and provided abundant nucleation sites for calcium silicate hydrate (C-S-H) gel hydration, which significantly optimized the structure of the interfacial transition zone (ITZ) and improved its microhardness. Among all test groups, the CRCA-50 group showed the most optimized microstructure and the best mechanical properties. This study provides a theoretical reference for the resource utilization of this type of 30-year service life RCA in mine filling. Full article
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16 pages, 4817 KB  
Article
Inevitable Ion Influence and Mechanism of Action on the Flotation Behavior of Bastnaesite in BHA/OHA Combined Collector System
by Hao Jiang, Rui Jiang, Yanling Xu, Xin Teng and Yanhong Wang
Minerals 2026, 16(4), 419; https://doi.org/10.3390/min16040419 - 19 Apr 2026
Viewed by 430
Abstract
The concentration of inevitable ionic species in regenerated water significantly alters the flotation characteristics of rare earth minerals, thereby hindering the effective extraction of bastnaesite. Therefore, it is of great significance to study the influence and mechanism of inevitable ions on the flotation [...] Read more.
The concentration of inevitable ionic species in regenerated water significantly alters the flotation characteristics of rare earth minerals, thereby hindering the effective extraction of bastnaesite. Therefore, it is of great significance to study the influence and mechanism of inevitable ions on the flotation of bastnaesite. This paper systematically investigated the effects of Ca2+, Mg2+, and Fe3+ on the flotation behavior of bastnaesite using a BHA/OHA combined collector system and studied the mechanism of action using contact angle testing, Raman spectroscopy, and Visual MINTEQ solution chemistry calculations. The results showed that the BHA/OHA combined collector had good collecting performance for bastnaesite, while Ca2+, Mg2+, and Fe3+ all had varying degrees of inhibitory effects on its flotation, with the order of influence being Fe3+ > Mg2+ > Ca2+. Contact angle tests showed that the presence of inevitable ions weakened the effect of the combined collector on improving the hydrophobicity of the bastnaesite surface. Raman spectroscopy results indicated that inevitable ions interfered with the adsorption of the combined collector on the mineral surface, with Fe3+ having the most significant effect. Solution chemistry analysis further demonstrated that Ca2+ and Mg2+ have been the primary ions influencing flotation because of their interactions with the mineral surface and collector molecules, but not Fe3+, which is mainly adsorbed on the mineral surface in the form of hydrolyzed species, thereby inhibiting the reagent adsorption and enhancing the surface hydrophilicity. Based on this, this paper revealed the differentiated interference mechanisms of different inevitable ions on the flotation of bastnaesite, and applied the relevant insights to guide the recovery of rare earth resources in molybdenum tailings, providing a theoretical basis and new research ideas for the flotation control of bastnaesite and the efficient utilization of rare earth resources under complex backwater conditions. Full article
(This article belongs to the Special Issue Advances in Process Mineralogy)
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32 pages, 46734 KB  
Review
The Rio Grande Rise: Current Knowledge and Future Frontiers for Deep-Sea Science, Mineral Resources and Governance
by Luigi Jovane, Carina Ulsen, Douglas Galante, Simone Bernardini, Natascha Menezes Bergo, Elisabete de Santis Braga, Frederico P. Brandini, Ronaldo Carrion, David Lopes de Castro, Renata R. Constantino, Muhammad Bin Hassan, Valdecir de Assis Janasi, Izabel King Jeck, Luciano de Oliveira Junior, Marco Antonio Couto Junior, Fabiola A. Lima, Simone Marques, Gustavo M. Massola, Nelia C. C. Mestre, Webster Mohriak, Eduardo F. Monlevade, Carina Costa de Oliveira, Vivian Helena Pellizari, Marcelo Cecconi Portes, Adriane G. P. Praxedes, Fabio Rodrigues, Lucas C. V. Rodrigues, Francisco Javier González Sanz, Ilson C. A. da Silveira, Jules M. R. Soto, Pedro Walfir Souza-Neto, Paulo Y. G. Sumida, Gabriel T. Tagliaro, Solange Teles da Silva, Alexander Turra, Roberto Ventura Santos, Marcio Yamamoto and Sidney L. M. Melloadd Show full author list remove Hide full author list
Minerals 2026, 16(4), 418; https://doi.org/10.3390/min16040418 - 17 Apr 2026
Cited by 1 | Viewed by 2141
Abstract
The Rio Grande Rise (RGR) is the largest oceanic plateau in the South Atlantic and represents a key natural laboratory for understanding oceanic plateau formation, deep-sea circulation, ecosystem functioning, and ferromanganese crust development. This study presents a critical synthesis of current scientific knowledge [...] Read more.
The Rio Grande Rise (RGR) is the largest oceanic plateau in the South Atlantic and represents a key natural laboratory for understanding oceanic plateau formation, deep-sea circulation, ecosystem functioning, and ferromanganese crust development. This study presents a critical synthesis of current scientific knowledge on the RGR, integrating geological, geophysical, oceanographic, biological, and geochemical evidence published over the last two decades. Geophysical data reveal a complex tectono-magmatic evolution involving Late Cretaceous plume-related volcanism, crustal thickening, rifting, and subsequent subsidence. The structural framework of the plateau is dominated by the Cruzeiro do Sul Rift, which plays a central role in controlling sedimentation, magmatism, and seawater circulation. Oceanographic studies demonstrate that the interaction between the southern branch of the South Equatorial Current and the complex topography of the RGR generates intense internal tides and bottom currents, strongly influencing sediment transport and benthic habitats. Biological investigations indicate that the RGR hosts diverse deep-sea communities, including sponge grounds, cold-water corals, and associated fauna, whose distribution is tightly linked to geomorphology and hydrodynamics. Ferromanganese crusts occurring on the plateau preserve valuable geochemical records of oceanographic and redox conditions, although their spatial distribution, thickness, and metal budgets remain incompletely constrained. Despite major advances, significant knowledge gaps persist regarding crustal structure, sedimentary evolution, ecosystem functioning, and mineral formation processes. This review highlights these uncertainties and outlines research priorities necessary to improve understanding of oceanic plateaus and deep-sea systems in the South Atlantic. Full article
(This article belongs to the Special Issue Geology, Exploration and Mining of Deep-Sea Mineral Resources)
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59 pages, 14350 KB  
Review
REE Mineralogical Evolution in a F-Rich Peralkaline System: A Review on the REE Mineralization Associated with the Madeira Sn-Nb-Ta-Cryolite (REE, U, Th, Zr, Li) Deposit (Amazonas, Brazil)
by Artur C. Bastos Neto, Ingrid W. Hadlich, Harald G. Dill and Vitor P. Pereira
Minerals 2026, 16(4), 417; https://doi.org/10.3390/min16040417 - 17 Apr 2026
Viewed by 606
Abstract
This study is centered on REE distribution in several minerals exhibiting exceptionally rare mineralogical and chemical compositions in the 1.8 Ga Madeira albite-enriched granite (AEG). This is a peralkaline A-type granite and corresponds to the Madeira Sn-Nb-Ta-cryolite (REE, Th, U, Zr, Li) world-class [...] Read more.
This study is centered on REE distribution in several minerals exhibiting exceptionally rare mineralogical and chemical compositions in the 1.8 Ga Madeira albite-enriched granite (AEG). This is a peralkaline A-type granite and corresponds to the Madeira Sn-Nb-Ta-cryolite (REE, Th, U, Zr, Li) world-class deposit (195 Mt) (Amazonas, Brazil). The REE mineralization ranks among the major deposits associated with alkaline and peralkaline magmatism in intracontinental and extensional anorogenic environments in terms of tonnage and grades. However, with respect to REE paragenesis and structure, it differs from all other known REE deposits. The REE mineralization (xenotime, gagarinite, fluocerite, thorite, pyrochlore, zircon, fluorite, and cryolite) is disseminated and zoned. In addition, in the central part of the deposit, there is a massive hydrothermal cryolite body, whose feasibility for REE extracting has been demonstrated. The evolution of rare earth minerals followed a precise order, with minimal formation of compound minerals and minerals with compositions distinct from their typical occurrences. Small pegmatites very rich in xenotime and gagarinite occur in the core AEG. These characteristics are due to the very high F activity in the magma, buffered by cryolite crystallization, to progressive, undisturbed crystallization from the margins toward the center, and to minimal CO2 activity. The alteration of primary REE minerals by F-rich hydrothermal fluids, the origin of these fluids, and the formation of secondary REE minerals are also discussed. Full article
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25 pages, 3958 KB  
Article
Complex Pressure Distribution and Genesis Analysis of the Shaximiao Formation in Central and Western Sichuan Basin
by Yilin Liang, Lurui Dang, Xiaojuan Wang, Dongxia Chen, Xu Guan, Shuangling Chen, Ke Pan, Zijian Wang, Xiaoli Zhang and Xiaoting Pang
Minerals 2026, 16(4), 416; https://doi.org/10.3390/min16040416 - 17 Apr 2026
Viewed by 395
Abstract
The distribution and evolution of complex formation pressures fundamentally control natural gas accumulation patterns and the prediction of favorable zones. To elucidate the controlling factors behind complex pressure distribution in tight sandstone gas reservoirs with source-reservoir separation, this study investigated the Shaximiao Formation [...] Read more.
The distribution and evolution of complex formation pressures fundamentally control natural gas accumulation patterns and the prediction of favorable zones. To elucidate the controlling factors behind complex pressure distribution in tight sandstone gas reservoirs with source-reservoir separation, this study investigated the Shaximiao Formation in the central-western Sichuan Basin. Integrating statistical, physical, and rock mechanics analyses with reservoir properties and gas compositional data, this study characterized the present-day pressure regime using seismic interpretation, well logs, measured pressure data, and drilling records. This study clarifies the genetic mechanisms, establishes a differential enrichment model, and identifies future exploration targets. Results reveal a present-day pressure distribution trending from high in the north and west to low in the south and east. Erosional unloading and strata cooling, mechanisms that lead to an average pressure reduction of about 4–15 MPa, jointly contribute to the development of abnormally negative pressure in the central Sichuan Basin. Vertically, pressure magnitude within sand groups shows a positive correlation with productivity. The pressure evolution is governed by a quadruple mechanism: hydrocarbon-generation pressurization, fault-mediated transmission, gas charging, and uplift-induced release. Consequently, future exploration should prioritize areas where high-quality reservoirs adjacent to active hydrocarbon kitchens, significant source-reservoir pressure differentials, and effective fault-sandbody transport pathways are optimally combined. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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18 pages, 13541 KB  
Article
Provenance Analysis of Marine–Continental Transitional Sediments Using Integrated Geochemistry and Detrital Zircon U–Pb Data: A Case Study from the Lower Permian Shanxi Formation, Southern North China Basin
by Enran Liu, Tianxu Guo, Peng Qiao, Disi Zhu, Qiuchen Xu, Dishi Shi, Degang Mou and Rong Chen
Minerals 2026, 16(4), 415; https://doi.org/10.3390/min16040415 - 17 Apr 2026
Viewed by 484
Abstract
The reliability of bulk geochemical proxies for provenance analysis in heterogeneous clastic systems remains a critical yet underexplored issue. This study investigates the Lower Permian Shanxi Formation in the Southern North China Basin (SNCB) using an integrated approach combining major and trace element [...] Read more.
The reliability of bulk geochemical proxies for provenance analysis in heterogeneous clastic systems remains a critical yet underexplored issue. This study investigates the Lower Permian Shanxi Formation in the Southern North China Basin (SNCB) using an integrated approach combining major and trace element geochemistry, rare earth elements (REEs), and detrital zircon U–Pb geochronology. The results show that major element compositions have been significantly modified by diagenetic processes in tidal flat environments, limiting their applicability in tectonic discrimination. In contrast, immobile trace elements and REE patterns provide more robust constraints on source rock composition, suggesting predominantly felsic upper continental crustal sources. Detrital zircon age spectra reveal two dominant populations at 290–440 Ma and 1800–2500 Ma, indicating mixed provenance from the North Qinling Region (NQR) and the North China Craton (NCC). However, the application of classical discrimination diagrams is challenged by lithological heterogeneity, as the mixed presence of sandstone, sandy mudstone, and mudstone introduces compositional bias. Spatial variations among wells suggest differential contributions from continental island arc and active continental margin, likely controlled by paleogeographic configuration and sediment transport pathways. This study emphasizes the necessity of multi-proxy integration for reliable provenance reconstruction in complex sedimentary systems. Full article
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29 pages, 11787 KB  
Article
Zircon Trace Element Constraints on the Evolution of the Continental Crust in the Western Domain of the Congo Craton
by Ngong Divine Njinchuki, Evine Laure Njiosseu Tanko, Philomène Nga Essomba Tsoungui, Brice Woguia Kamguia, Marvine Nzepang Tankwa, Landry Soh Tamehe, Donald Hermann Fossi and Jean Paul Nzenti
Minerals 2026, 16(4), 414; https://doi.org/10.3390/min16040414 - 16 Apr 2026
Viewed by 609
Abstract
This study integrates LA-ICP-MS zircon U–Pb ages and the first zircon trace element data from metasedimentary and metaigneous rocks of the Nyong Complex (NyC) in the NW Congo Craton, southern Cameroon, to constrain its petrogenesis, tectonic setting, and crustal evolution. Chondrite-normalized REE patterns [...] Read more.
This study integrates LA-ICP-MS zircon U–Pb ages and the first zircon trace element data from metasedimentary and metaigneous rocks of the Nyong Complex (NyC) in the NW Congo Craton, southern Cameroon, to constrain its petrogenesis, tectonic setting, and crustal evolution. Chondrite-normalized REE patterns show strong HREE enrichment, depleted LREE–MREE, and pronounced positive Ce and negative Eu anomalies, indicating a magmatic origin for the zircons. Trace element signatures suggest that the zircons derived from continental crustal magmas generated under variable oxidation conditions in a long-lived arc-related tectonic environment. Detrital zircon ages range from Archean to Paleoproterozoic, with five major age peaks at 2885 ± 8 Ma, 2775 ± 6 Ma, 2654 ± 7 Ma, 2469 ± 11 Ma, and 2316 ± 11 Ma. These ages correspond to major magmatic and metamorphic events recognized in both the Congo and São Francisco cratons. The preservation of felsic continental crust between 2.9 and 2.2 Ga in the NyC and the Borborema Province (NE Brazil) likely records a critical transition in Earth’s geodynamic regime, marked by enhanced consumption and recycling of mafic crust during Proterozoic accretion compared to the late Archean. This transition reflects the onset of modern-style plate tectonics, enabling craton stabilization and contributing to the assembly of the Nuna/Columbia supercontinent. The NyC is thus interpreted as part of the Trans-Amazonian belt, analogous to that in NE Brazil, and formed during the collision between the Congo and São Francisco cratons. Full article
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23 pages, 19492 KB  
Article
Geochemical Compositions of Zircon and Apatite from the Langdu Intrusions in the Zhongdian Arc: Implications for Porphyry–Skarn Cu Mineralization
by Lei Mo, Chengbiao Leng, Hongze Gao, Kaixuan Li, Xilian Chen, Yanjun Wang, Tao Dong, Wanquan Luo and Haijun Yu
Minerals 2026, 16(4), 413; https://doi.org/10.3390/min16040413 - 16 Apr 2026
Viewed by 441
Abstract
The Zhongdian Arc is an important copper polymetallic ore cluster in China’s Sanjiang Tethyan Metallogenic Domain, and the Langdu deposit is a representative porphyry–skarn Cu deposit in this region. This study aims to constrain the timing of magmatic activity at the Langdu deposit. [...] Read more.
The Zhongdian Arc is an important copper polymetallic ore cluster in China’s Sanjiang Tethyan Metallogenic Domain, and the Langdu deposit is a representative porphyry–skarn Cu deposit in this region. This study aims to constrain the timing of magmatic activity at the Langdu deposit. It also seeks to reveal the magma’s physical–chemical properties and evolution, and to identify the factors controlling mineralization. To achieve these objectives, this study used LA-ICP-MS zircon U-Pb dating and elemental analysis, combined with halogen and trace element data from apatite. Zircon U–Pb dating shows that the Langdu intrusions were emplaced at ca. 216 Ma in a continental arc setting associated with the westward subduction of the Garzê–Litang oceanic crust during the Late Triassic. Geochemical and mineralogical features indicate that the Langdu intrusions are I-type granite. They originated from partial melting of the mantle wedge metasomatized by subduction fluids. During their ascent, these magmas experienced fractional crystallization dominated by amphibole, titanite, rutile, and monazite. Geochemical records from zircon and apatite further reveal that the ore-forming magma of the Langdu intrusions exhibited high oxygen fugacity (ΔFMQ = +1.53), elevated H2O content (avg. 7.63 wt.%), and enrichment in S (avg. 560 ppm) and Cl (avg. 2141 ppm). This Cl-rich magma experienced fluid exsolution during its early evolutionary stage. This provided the necessary conditions for metal extraction and transport. In summary, the key factors controlling the formation of the Langdu porphyry–skarn Cu deposit are high-oxygen-fugacity magma enriched in water and volatiles (S and Cl), coupled with efficient fluid exsolution. This understanding is important for better understanding regional metallogeny and for guiding mineral exploration. Full article
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43 pages, 5021 KB  
Article
Comprehensive Comparison of Machine Learning Approaches—Deterministic and Stochastic—In Modeling the Production and Power of an SAG Mill: A Case Study of the Chilean Copper Mining Industry
by Manuel Saldana, Edelmira Gálvez, Mauricio Sales-Cruz, Eleazar Salinas-Rodríguez, Ramon G. Salinas-Maldonado, Jonathan Castillo, Norman Toro, Dayana Arias and Luis A. Cisternas
Minerals 2026, 16(4), 412; https://doi.org/10.3390/min16040412 - 16 Apr 2026
Viewed by 596
Abstract
SAG grinding mills represent critical energy-intensive operations in copper concentrators, accounting for 30%–50% of total plant energy consumption. The accurate prediction of mill power draw and production rate under varying operational conditions is essential for real-time control, production planning, and energy management. This [...] Read more.
SAG grinding mills represent critical energy-intensive operations in copper concentrators, accounting for 30%–50% of total plant energy consumption. The accurate prediction of mill power draw and production rate under varying operational conditions is essential for real-time control, production planning, and energy management. This study presents a comprehensive comparison of ML algorithms for modeling Production and Power in a Chilean copper mining industry. Deterministic and stochastic models were fitted and validated using industrial data from a Chilean copper operation. More representative models were re-estimated and subsequently evaluated under different operating regimes to examine their predictive performance under aggregated conditions of the feeding variables. This procedure allowed for the identification of the modeling approaches that provide the most robust performance across varying operational regimes. The results show that XGB achieved the best predictive performance, with test RMSE and R2 values of 87.98 and 97.35% for SAG Production, and 431.11 and 95.11% for SAG Power, respectively. Stochastic approaches provided complementary uncertainty quantification, supporting risk-informed decision making under variable operating conditions. The analysis by operational regime indicates that XGB presents better fit in the Thick hydraulic regime, for both responses’ variables, which could be explained why a dense pulp operation provides more predictable grinding dynamics. The comparative analysis reveals trade-offs between model complexity, interpretability, computational requirements, and predictive performance, offering practical guidance for selecting appropriate modeling frameworks based on specific operational objectives and data availability in mineral processing applications. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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22 pages, 13774 KB  
Article
Identification of Geochemical Anomalies by Pattern Recognition: A Case Study of Wulonggou Area in Qinghai Province, China
by Xiangning Ren, Gongwen Wang and Nini Mou
Minerals 2026, 16(4), 411; https://doi.org/10.3390/min16040411 - 16 Apr 2026
Viewed by 618
Abstract
The Wulonggou gold district is located on the northern margin of the Qinghai–Tibet Plateau and represents the most promising area for mineral exploration within the East Kunlun mineralized belt in Qinghai Province. Previous studies on this gold district have lacked a comprehensive assessment [...] Read more.
The Wulonggou gold district is located on the northern margin of the Qinghai–Tibet Plateau and represents the most promising area for mineral exploration within the East Kunlun mineralized belt in Qinghai Province. Previous studies on this gold district have lacked a comprehensive assessment of its metal mineralization potential. This paper conducts a comprehensive investigation of the distribution patterns of geochemical data in the Wulonggou gold district, employing multivariate statistical analysis to explore the distribution characteristics of different geochemical elements. Based on the analysis of geochemical anomaly patterns, the median + 2MAD method and fractal method were further introduced to delineate geochemical anomalies. For comparison, machine learning methods—including the radial basis function link network (RBFLN) model and the Bayesian-optimized random forest (BO-RF) model—were also applied to generate different geochemical anomaly maps. By comparing the results obtained from each method, we found that the BO-RF model performed best in predicting geochemical anomalies. Based on the above information, the BO-RF model was integrated with geological background information to delineate prospective areas. These findings provide important clues for mineral exploration and development in the Wulonggou area and can serve as a reference for other regions with similar geological backgrounds. Full article
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35 pages, 123403 KB  
Article
Lithofacies-Constrained Pore Networks in Lacustrine Shales: Multi-Scale Characterization of the Lower Cretaceous Shahezi Formation, NE China
by Yunfeng Bai, Jinyou Zhang, Jing Bai, Tiefeng Lin, Dejiang Kang, Jinwei Wang and Wei Wu
Minerals 2026, 16(4), 410; https://doi.org/10.3390/min16040410 - 16 Apr 2026
Viewed by 572
Abstract
This study investigates the heterogeneity of pore structures in lacustrine shale gas reservoirs, with a specific focus on shales from the Lower Cretaceous Shahezi Formation in the Lishu Fault Sag of the Songliao Basin. By integrating multi-scale characterization techniques—including high-pressure mercury intrusion, N [...] Read more.
This study investigates the heterogeneity of pore structures in lacustrine shale gas reservoirs, with a specific focus on shales from the Lower Cretaceous Shahezi Formation in the Lishu Fault Sag of the Songliao Basin. By integrating multi-scale characterization techniques—including high-pressure mercury intrusion, N2/CO2 adsorption, and nuclear magnetic resonance (NMR)—we examined the pore networks across five identified lithofacies: organic-rich clayey shale, organic-rich mixed shale, organic-rich siliceous shale, organic clayey shale, and organic mixed shale. The results indicate that mesopores (2–50 nm) constitute the dominant fraction of pore volume (31.7%–56.6%), followed by micropores (<2 nm) and macropores (>10 μm). Notable lithofacies-dependent variations were observed: organic-rich clayey shale exhibits abundant organic pores, clay interlayer pores, and intragranular dissolution pores with favorable connectivity; organic-rich siliceous shale is mainly dominated by inorganic pores with limited organic porosity; mixed shales are characterized by clay mineral contraction fractures and intergranular pores. The key controlling factors are mineral composition and organic matter abundance: clay content shows a positive correlation with pore volume and surface area in organic-rich clayey shale, but a negative correlation in organic mixed shale. Brittle minerals (quartz and feldspar) generally reduce porosity through compaction. Total organic carbon (TOC) displays a weak positive correlation with mesopore volume, while thermal maturity (Ro = 1.2%–1.73%) exerts influences that vary by lithofacies. In contrast to marine shales—which are dominated by high-maturity (Ro > 2.0%) organic pores and quartz-supported frameworks—terrestrial shales primarily rely on inorganic pores derived from clay minerals (e.g., illite). This study clarifies the relationships among lithofacies, pore structure, and controlling factors, thereby providing a basis for evaluating the gas potential of terrestrial shales. Full article
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20 pages, 14326 KB  
Article
Hydrodynamic Mechanisms of a Fractal Blade Enhancing the Pulp Conditioning and Flotation Separation of Fine-Grained Malachite and Quartz
by Binqing Liu, Guohua Gu, Yanhong Wang, Yuan Chen, Yanming Wu, Yuankun Yang, Shengli Yu, Chongzhong Ouyang and Bingchao Lv
Minerals 2026, 16(4), 409; https://doi.org/10.3390/min16040409 - 16 Apr 2026
Viewed by 551
Abstract
High-intensity conditioning (HIC) is a common pretreatment process for enhancing the flotation of fine-grained minerals. This study introduces fractal theory into the structural design of pulp conditioning impellers. A fractal blade with multi-scale fractal edge features was proposed, and its separation performance was [...] Read more.
High-intensity conditioning (HIC) is a common pretreatment process for enhancing the flotation of fine-grained minerals. This study introduces fractal theory into the structural design of pulp conditioning impellers. A fractal blade with multi-scale fractal edge features was proposed, and its separation performance was evaluated in a fine-grained malachite (−20 μm) and quartz flotation system. Computational fluid dynamics simulation revealed that the fractal blade altered the energy dissipation pattern. Compared with conventional rectangular blades, it induced stronger fluid compression and collision effects in localized regions. These hydrodynamic changes improved the suspension homogeneity and dispersion efficiency of fine-grained malachite. Furthermore, the fractal blade reduced the scale of turbulent vortices while increasing local turbulent kinetic energy and shear rates. This optimized turbulent flow field effectively reduced mass-transfer resistance and promoted interfacial interactions between flotation reagents and mineral particles. Adsorption experiments and optical microscopy indicated that after conditioning at 1500 rpm for 3 min, the fractal blade increased sodium oleate adsorption on malachite compared to the conventional blade. This enhanced adsorption promoted the aggregation of fine-grained malachite, increasing its aggregate size by 15.52%, while no significant aggregation was observed for quartz particles. Consequently, the single mineral flotation recovery of fine-grained malachite increased by 4.13%. For artificial mixed minerals, the copper concentrate grade and recovery were improved by 2.28% and 1.04%, respectively. This study provides a theoretical basis for equipment optimization and structural innovation design in HIC processes. Full article
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19 pages, 5723 KB  
Article
Linking Mineralogical Characteristics to Dense-Medium Separation Performance: A Case Study of the Dahongliutan Spodumene Deposit in Xinjiang
by Bao Cui, Shuming Wen, Jian Liu and Aoxiang Fei
Minerals 2026, 16(4), 408; https://doi.org/10.3390/min16040408 - 15 Apr 2026
Viewed by 612
Abstract
The lithium resource reserves in Xinjiang’s Dahongliutan reach 1.1 million tons, making it one of the most representative spodumene deposits in China. Through process mineralogy analysis, the ore was identified as having inherent characteristics that control density-based separation: Coarse crystallization, a high monomer [...] Read more.
The lithium resource reserves in Xinjiang’s Dahongliutan reach 1.1 million tons, making it one of the most representative spodumene deposits in China. Through process mineralogy analysis, the ore was identified as having inherent characteristics that control density-based separation: Coarse crystallization, a high monomer dissociation degree, and a density contrast. Based on these mineralogical characteristics, dense-medium separation experiments were conducted to investigate the mineralogically controlled separation behavior as a function of particle size and medium density. Three process flows (two-product, pressureless three-product, and two-stage, two-product) were further designed and comparatively evaluated. It indicated that the dense-medium separation efficiency is positively correlated with the monomer dissociation degree of spodumene, and the 0.5~6 mm size fraction is the optimal particle size range because it achieves a balance between ore crushing dissociation and coarse-grain dense-medium separation adaptation. Furthermore, all three dense media processes can save grinding energy, and each of them has its own advantages and disadvantages. Comprehensively considering the grade of the concentrate, recovery, the grade of the tailings, and grinding energy consumption, it is recommended to adopt a combined process of two-stage, two-product dense-medium separation and flotation. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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23 pages, 77839 KB  
Article
The Provenance and Tectonic Settings of the Kolyma–Omolon Margin During the Closure of the South Anyui Ocean
by Elena Vatrushkina, Elena Starikova, Alexander Khanchuk and Aina Gagieva
Minerals 2026, 16(4), 407; https://doi.org/10.3390/min16040407 - 15 Apr 2026
Viewed by 395
Abstract
The Late Jurassic–Early Cretaceous Oloy complex was formed in the setting of convergence between the Chukotka microcontinent and the Kolyma–Omolon margin. Its evolution reflects the closure of the South Anyui Ocean, with controversial timing estimates. This study emphasizes the integration of lithological data [...] Read more.
The Late Jurassic–Early Cretaceous Oloy complex was formed in the setting of convergence between the Chukotka microcontinent and the Kolyma–Omolon margin. Its evolution reflects the closure of the South Anyui Ocean, with controversial timing estimates. This study emphasizes the integration of lithological data with magmatic and metallogenic information to reconstruct geodynamic processes. The article presents the results of detailed petrographic and geochemical studies, Sm-Nd isotope analyses, and U-Pb dating of detrital zircons from Kimmeridgian–Lower Hauterivian volcaniclastic and epiclastic sandstones. Petrographic studies and U-Pb dating of detrital zircons identified the main sources at different stages and the amount of synchronous pyroclastic material. Isotope-geochemical investigations suggest a young undifferentiated arc provenance for Kimmeridgian deposits, whereas Tithonian–Valanginian sediments accumulated due to the erosion of more differentiated igneous rocks and input of clastic material from the continent. New data on changes in sedimentation environments and provenance enabled the tracing of the evolution of the Oloy arc. In the Kimmeridgian, the Oloy island arc existed on a heterogeneous basement, with south-dipping subduction towards the Kolyma–Omolon margin. During the Late Tithonian, the arc accreted and magmatic activity continued in the active margin setting. Collision initiated in the latter half of the Berriasian, reaching its active phase in the Valanginian time. Full article
(This article belongs to the Special Issue Tectonic Setting and Provenance of Sedimentary Rocks)
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23 pages, 3585 KB  
Review
Photocatalytic Wastewater Treatment Using Oxide Coatings with Immobilized Zeolites Obtained by Plasma Electrolytic Oxidation—A Review
by Kristina Mojsilović, Srna Stojanović, Rastko Vasilić and Ljiljana Damjanović-Vasilić
Minerals 2026, 16(4), 406; https://doi.org/10.3390/min16040406 - 15 Apr 2026
Viewed by 572
Abstract
This review presents recent results focused on immobilization of zeolites onto inexpensive aluminum substrate using plasma electrolytic oxidation (PEO) processing in various electrolyte solutions applying different electrical regimes. PEO is recognized as a useful technique for the formation of oxide coatings with photocatalytic [...] Read more.
This review presents recent results focused on immobilization of zeolites onto inexpensive aluminum substrate using plasma electrolytic oxidation (PEO) processing in various electrolyte solutions applying different electrical regimes. PEO is recognized as a useful technique for the formation of oxide coatings with photocatalytic properties on various metals and alloys. Thin film photocatalysts are more practical than powder/nanoparticle photocatalysts because the photocatalyst does not need to be filtered/separated after the wastewater degradation treatment, which is an expensive and time-consuming process. Addition of zeolites to supporting electrolyte solutions influences structural, morphological and chemical properties of formed oxide coatings. Furthermore, introduction of zeolites loaded with cerium through an ion-exchange procedure is investigated. It is shown that the addition of both parent zeolites and Ce-exchanged zeolites is beneficial for photocatalytic decomposition of model organic pollutant (methyl orange). The most promising results are obtained under ultra-low duty cycle electrical conditions with Ce-exchanged 13X zeolite added to the electrolyte, where about 60% of the model organic pollutant is decomposed during 6 h of treatment under simulated sunlight irradiation (16,000 lx) for 3 cm2 surface area of sample exposed to irradiation. Full article
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36 pages, 17973 KB  
Article
A Multi-Analytical Approach to the Study of Phosphatic Materials from the Lower Cambrian of Spain
by Yihao Xie, Aili Zhu, Ting Huang, Lei Jin and David C. Fernández-Remolar
Minerals 2026, 16(4), 405; https://doi.org/10.3390/min16040405 - 15 Apr 2026
Viewed by 475
Abstract
Phosphatic deposits from the Lower Cambrian Pedroche Formation (Sierra de Córdoba, Spain) provide key insights into early diagenetic mineralization processes during the Cambrian radiation. This study applies an integrated multi-analytical approach combining Raman spectroscopy, SEM–EDS, LA-ICP-MS, and ToF-SIMS to investigate mineralogical, elemental, and [...] Read more.
Phosphatic deposits from the Lower Cambrian Pedroche Formation (Sierra de Córdoba, Spain) provide key insights into early diagenetic mineralization processes during the Cambrian radiation. This study applies an integrated multi-analytical approach combining Raman spectroscopy, SEM–EDS, LA-ICP-MS, and ToF-SIMS to investigate mineralogical, elemental, and molecular signatures of phosphatized bioclastic carbonates and associated siliciclastic facies from the Los Lagares-1 borehole. Results reveal a systematic phosphatization gradient from carbonate-dominated skeletal rims to phosphate-rich interiors composed of carbonate fluorapatite with variable carbonate and hydroxyl substitution. Trace-element systematics and REE patterns indicate seawater-influenced phosphogenesis under suboxic porewater conditions, coupled to iron reduction and early diagenetic clay mineral formation. In contrast, the siliciclastic siltstone facies preserves poorly crystalline phosphate phases associated with detrital aluminosilicates and chlorite, reflecting distinct porewater chemistry and crystallization kinetics. ToF-SIMS mapping demonstrates spatial coupling between fluorine and phosphate within fossil structures, confirming fluorapatite formation and localized organic matter entombment. These results highlight the strong control of host lithology on phosphate crystallization pathways and trace-element redistribution, and provide new constraints on microbially mediated phosphogenesis in restricted Early Cambrian reef–lagoon systems along the northern Gondwanan margin. Full article
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22 pages, 4968 KB  
Review
Materials for Acid Activation: New Principles and Recent Advances
by Larissa Vieira Rocha, Madeleing Taborda Barraza, Carlos Maurício Fontes Vieira, Afonso Rangel Garcez de Azevedo and Markssuel Teixeira Marvila
Minerals 2026, 16(4), 404; https://doi.org/10.3390/min16040404 - 15 Apr 2026
Viewed by 780
Abstract
Population growth and rapid urbanization have significantly increased construction activities and the demand for building materials. It is estimated that approximately 39% of global CO2 emissions are associated with the construction sector, with nearly 8% directly attributed to Portland cement production. In [...] Read more.
Population growth and rapid urbanization have significantly increased construction activities and the demand for building materials. It is estimated that approximately 39% of global CO2 emissions are associated with the construction sector, with nearly 8% directly attributed to Portland cement production. In addition to greenhouse gas emissions, the cement industry is responsible for substantial environmental impacts, including natural resource depletion, soil degradation, and air and water pollution. In this context, the development of alternative and more sustainable binder systems has become a global research priority. Geopolymers have emerged as promising materials produced through either alkaline or acid activation routes, offering advantages such as a reduced carbon footprint, high durability, and rapid strength development. Among these systems, acid-activated materials, particularly phosphate-based geopolymers, differ fundamentally from conventional alkali-activated binders in terms of reaction chemistry and binding phases. The formation of aluminum phosphate (AlPO4) networks plays a key role in governing the mechanical performance and microstructural stability of these materials. This mini-review provides a critical overview of the fundamental principles of acid activation applied to alternative cementitious materials, with emphasis on dissolution mechanisms, polycondensation reactions, and the nature of binding phases in phosphate-based systems. Unlike previous reviews, this study integrates recent findings on reaction mechanisms with a comparative analysis between acid and alkaline activation routes, highlighting underexplored aspects of precursor reactivity and binder formation. The main types of acids used as activators, the influence of precursor chemical composition, and the conceptual differences between acid and alkaline activation are discussed. In addition, recent advances, current challenges, and future perspectives of acid activation are addressed, highlighting its potential as a viable low-carbon binder route for sustainable construction materials, with strong prospects for partially replacing Portland cement, particularly in high-performance applications requiring enhanced chemical resistance and thermal stability. Full article
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25 pages, 14653 KB  
Article
From Diorite to Monzogranite: The Early–Middle Jurassic Arc Magmatic Sequence of Xifengshan and Its Constraints on the Southward Subduction of the Mongol–Okhotsk Ocean
by Wen-Bin Wu, Ji-Yu Du, Jing-Sheng Chen, Bin Li, Yu-Jin Zhang and Yan Wang
Minerals 2026, 16(4), 403; https://doi.org/10.3390/min16040403 - 14 Apr 2026
Viewed by 477
Abstract
The subduction polarity of the Mongol–Okhotsk Ocean (MOO) during the Mesozoic remains contentious, with competing models advocating for southward, northward, or bidirectional subduction. The Xifengshan area in the northern Great Xing’an Range, located south of the Mongol–Okhotsk suture, preserves Early–Middle Jurassic calc-alkaline intrusions, [...] Read more.
The subduction polarity of the Mongol–Okhotsk Ocean (MOO) during the Mesozoic remains contentious, with competing models advocating for southward, northward, or bidirectional subduction. The Xifengshan area in the northern Great Xing’an Range, located south of the Mongol–Okhotsk suture, preserves Early–Middle Jurassic calc-alkaline intrusions, which provides important constraints on this debate. We present zircon U–Pb ages, whole-rock geochemistry, and Lu–Hf isotopes for diorite, granodiorite, and monzogranite from this area. Zircon U–Pb dating yields ages of 178–173 Ma, defining a short-lived magmatic pulse. The suite is calc-alkaline, enriched in LILE and depleted in Nb–Ta–Ti, typical of arc magmas. The diorite represents the most mantle-proximal preserved end-member of the system and records substantial mantle input from a slab-modified mantle wedge. Geochemical trends (increasing Rb/Th, decreasing Sr with differentiation) reflect plagioclase-dominated fractional crystallization with minor AFC. Local adakitic-like signatures are better interpreted as differentiation-related effects than as direct evidence for slab melting. Zircon εHf(t) values (+1.62 to +11.55) and TDM1 ages (363–772 Ma) are greater than the crystallization ages, indicating substantial juvenile input together with the variable involvement of previously accreted crustal components. We suggest that mantle wedge-derived magmas modified by slab-related components triggered the partial melting of the arc crust, whereas subsequent intracrustal differentiation produced the observed intrusive sequence. The continental arc system provides robust evidence for the southeastward subduction of the MOO during the Early–Middle Jurassic, resolving the long-standing polarity controversy. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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15 pages, 6469 KB  
Article
Sequential Thermochemical–Hydrometallurgical Processing of Chromite Beneficiation Tailings for Chromium Recovery and Platinum Enrichment
by Rinat Abdulvaliyev, Bulat Sukurov, Nazym Akhmadiyeva, Yerkezhan Abikak, Abhilash, Nurila Burabayeva and Valeriy Pozmogov
Minerals 2026, 16(4), 402; https://doi.org/10.3390/min16040402 - 14 Apr 2026
Viewed by 818
Abstract
Chromite beneficiation tailings (CBTs) represent a significant environmental challenge, while simultaneously containing valuable metals that remain largely unrecovered. In this study, a sequential thermochemical–hydrometallurgical route was investigated for selective chromium extraction and the enrichment of platinum group metals (PGMs) from CBTs generated at [...] Read more.
Chromite beneficiation tailings (CBTs) represent a significant environmental challenge, while simultaneously containing valuable metals that remain largely unrecovered. In this study, a sequential thermochemical–hydrometallurgical route was investigated for selective chromium extraction and the enrichment of platinum group metals (PGMs) from CBTs generated at the Donskoy Mining and Processing Plant. Alkaline sintering with Na2CO3 at 1000 °C followed by aqueous leaching enabled the transfer of up to 98%–99% of chromium into solution. The resulting residue was enriched in non-ferrous metals, rare earth elements, and PGMs. Subsequent sulfation roasting and water leaching promoted the dissolution of magnesium, nickel, and rare earth elements, while platinum and palladium remained predominantly in the solid phase, due to their low solubility under the applied conditions. Microstructural analysis using SEM–EPMA revealed that PGMs are selectively concentrated in Ni-bearing micro-inclusions, with local platinum content reaching up to 3.8 wt.% in Ni-rich regions. The proposed sequential processing strategy enables efficient chromium recovery and significant PGM enrichment in the residual phase, demonstrating the potential of CBTs as a secondary resource for integrated metal recovery. Full article
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33 pages, 29597 KB  
Article
Geomechanical Justification of Open-Pit Slope Stability and Beneficiation Process Solutions for Rare Earth and Noble Elements
by Raissa Zhanakova, Talgat Almenov, Mels Shautenov, Nazym Akkazina, Nikita Kadukhin and Din-Mukhammed Shabaz
Minerals 2026, 16(4), 401; https://doi.org/10.3390/min16040401 - 14 Apr 2026
Viewed by 1407
Abstract
The rapid advancement of high-technology industries critically depends on the supply of rare earth elements (REEs), which constitute strategic raw materials for knowledge-intensive sectors. This study proposes an integrated methodological framework for the development of the Kundybay REE deposit, combining geomechanical substantiation of [...] Read more.
The rapid advancement of high-technology industries critically depends on the supply of rare earth elements (REEs), which constitute strategic raw materials for knowledge-intensive sectors. This study proposes an integrated methodological framework for the development of the Kundybay REE deposit, combining geomechanical substantiation of open-pit slope stability with beneficiation optimization of weathering-crust ores. The novelty of the research lies in the justification of rational pit-wall parameters based on a coupled 3D geological–geotechnical model implemented in the Micromine environment. Structurally disturbed zones were identified and subjected to detailed stability analysis using numerical modeling techniques. Particular emphasis was placed on the delineation of geotechnical domains and factor-of-safety evaluation in Slide2, which enabled refinement of design solutions and optimization of slope geometry. Simultaneously, the study addresses processing challenges of refractory weathering-crust ores through the application of ultrasonic aerohydraulic desliming combined with a vibro-centrifugal separation device. Optimization of slope parameters resulted in a 30 Mt reduction in stripping volume, corresponding to a 16.7% economic gain. The proposed flowsheet achieved a concentrate grade of 948.89 g/t REEs with an overall recovery of 45.66%. The results confirm that integrating geomechanical design with process engineering provides a technically robust and economically efficient basis for REE deposit development. Full article
(This article belongs to the Section Mineral Deposits)
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