Editor’s Choice Articles

Editor’s Choice articles are based on recommendations by the scientific editors of MDPI journals from around the world. Editors select a small number of articles recently published in the journal that they believe will be particularly interesting to readers, or important in the respective research area. The aim is to provide a snapshot of some of the most exciting work published in the various research areas of the journal.

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30 pages, 12195 KB  
Article
Neodymium-Rich Monazite of the Lemhi Pass District, Idaho and Montana: Chemistry and Geochronology
by Virginia S. Gillerman, Michael J. Jercinovic and Mark D. Schmitz
Minerals 2025, 15(11), 1156; https://doi.org/10.3390/min15111156 - 31 Oct 2025
Viewed by 350
Abstract
Thorium-rare earth-iron oxide deposits of the Lemhi Pass district, Idaho and Montana, are enriched in the middle rare earth elements (REE), and particularly neodymium (Nd). Overall, thorium (Th) and total rare earth oxide (TREO) grades of the deposits are sub equal at 0.4 [...] Read more.
Thorium-rare earth-iron oxide deposits of the Lemhi Pass district, Idaho and Montana, are enriched in the middle rare earth elements (REE), and particularly neodymium (Nd). Overall, thorium (Th) and total rare earth oxide (TREO) grades of the deposits are sub equal at 0.4 wt. % but locally exceed 1 wt. % TREO. Nd-monazite, the major REE phase (35 wt. % Nd2O3) occurs in hydrothermal Th-REE mineralized quartz veins and biotite-rich shear zones of enigmatic origin. Hosted in Mesoproterozoic metasedimentary rocks, the deposits are modest in size but present over a large area with no obvious source pluton exposed. This paper documents the geochemistry of the monazite and provides the first geochronological data to constrain its origin. Elemental mapping and U-Th-total Pb EPMA dating of the monazite and thorite document a Paleozoic age for mineralization centered in the Late Devonian at approximately 355 Ma ± 20 Ma. A second period of volumetrically minor Th and REE remobilization is dated as Mesozoic (ca. 100 Ma). For context, a reactivated passive continental margin was present during the Devonian in eastern Idaho, while the Mesozoic was a time of major accretionary tectonics and arc magmatism further west. Nd and Pb isotopic data require a significant interaction of the fluids with an ancient crustal component represented by regional Mesoproterozoic metasedimentary rocks and granitoids. A source–transport–deposition model is hypothesized with metasomatic fractionation and enrichment of Nd during regional hydrothermal circulation. The aqueous fluids were hot, oxidizing, and likely saline, but the exact source of the Th and REEs and the mechanism of enrichment remains problematic. Additional analytical work and increased knowledge of the regional and district geology will improve this unconventional hypothesis for formation of Lemhi Pass’ unusual Nd-rich Th-REE-Fe mineralization. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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24 pages, 5401 KB  
Article
Investigating the Wear Evolution and Shape Optimize of SAG Mill Liners by DEM-FEM Coupled Simulation
by Xiao Mei, Huicong Du, Wenju Yao and Aibing Liu
Minerals 2025, 15(11), 1155; https://doi.org/10.3390/min15111155 - 31 Oct 2025
Viewed by 369
Abstract
The shell liner is a core component of Semi-Autogenous Grinding (SAG) mills, suffering severe wear from ore impact and friction, and its shape directly affects grinding efficiency and maintenance costs. In this study, the Finnie wear model in EDEM2022 software was improved to [...] Read more.
The shell liner is a core component of Semi-Autogenous Grinding (SAG) mills, suffering severe wear from ore impact and friction, and its shape directly affects grinding efficiency and maintenance costs. In this study, the Finnie wear model in EDEM2022 software was improved to predict the wear morphology evolution of shell liners. A Python-based coupled simulation of the Discrete Element Method (DEM, EDEM) and Finite Element Method (FEM, ABAQUS) was established to analyze liner wear mechanisms, stress states, and mill service performance (wear resistance, grinding efficiency, and stress distribution). The simulated wear profile showed high consistency with laser three-dimensional scanning (LTDS) results, confirming the improved Finnie-DEM model’s effectiveness in reproducing liner wear evolution. Shearing in crushing/grinding zones was the main wear cause, with additional contributions from relative sliding among ore, grinding balls, and liners in grinding/discharge zones. DEM-FEM coupling revealed two circumferential instantaneous wear extremes (Maxa > Maxb) and two lifter wear rate peaks (Ma > Mb). In the grinding zone, liner stress distribution matched wear distribution, with maximum instantaneous stress at characteristic points A and B—stress at A reflects liner impact degree, while stress at B indicates mill ore-crushing capacity. Optimizing flat liner shape adjusted wear rate peaks (Ma, Mb), improving overall liner wear. This optimization significantly affected stresses at A/B and ore normal collision but had little impact on mill energy efficiency. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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25 pages, 3816 KB  
Review
Unified Phase Diagram and Competition-Coupling Mechanism for Pyrite Thermal Transformation
by Mingrui Liu, Guangyuan Xie and Jie Sha
Minerals 2025, 15(11), 1139; https://doi.org/10.3390/min15111139 - 30 Oct 2025
Viewed by 466
Abstract
The thermal transformation mechanism of pyrite in coal, which governs sulfur emissions and ash deposition, remains highly controversial. There are significant discrepancies in reported activation energies (Ea) (60–310 kJ/mol) and conflicting reaction pathways. To resolve these long-standing controversies, this study proposes [...] Read more.
The thermal transformation mechanism of pyrite in coal, which governs sulfur emissions and ash deposition, remains highly controversial. There are significant discrepancies in reported activation energies (Ea) (60–310 kJ/mol) and conflicting reaction pathways. To resolve these long-standing controversies, this study proposes a competition-coupling mechanism: pyrolysis and oxidation compete under local O2 and temperature gradients, while coupling through microstructural evolution. Specifically, pyrolysis generates a porous Fe1−XS that facilitates oxidation, which in turn can form a passivating oxide/sulfate layer that promotes further pyrolysis. This mechanism reconciles longstanding kinetic controversies by showing that the apparent activation energy is not a fixed value but instead a dynamic parameter, shifting along a continuous curve that bridges pyrolysis and oxidation-dominated regimes. Furthermore, we construct a unified phase diagram by incorporating the competition-coupling mechanism into classical thermodynamic equilibria. This diagram uses the molar ratio FeS2/(FeS2 + O2) and temperature to categorize the transformation process into four distinct regions—pyrolysis-dominated, competition-coupling, oxidation-dominated, and melt-dominated. The key contribution of this work lies in the diagram which offers a practical framework for optimizing combustion and roasting systems, allowing for improved control over sulfur emissions and ash-related issues such as slagging and fouling. Full article
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21 pages, 4390 KB  
Article
Experimental Investigation of CO2–Mineral Interactions in Tight Clastic Rock Reservoirs: Implications for Geological Carbon Sequestration
by Ziyi Wang, Liehui Zhang, Shu Liu, Meng Wang, Hongming Tang, Dongyu Peng, Xinan Yu and Xingming Duan
Minerals 2025, 15(11), 1142; https://doi.org/10.3390/min15111142 - 30 Oct 2025
Viewed by 376
Abstract
Geological Carbon Sequestration (GCS) plays a crucial role in addressing climate change, particularly in oil and gas development. Understanding the reaction of supercritical CO2 under in situ conditions and its effects on minerals is essential for advancing GCS technology. This study investigates [...] Read more.
Geological Carbon Sequestration (GCS) plays a crucial role in addressing climate change, particularly in oil and gas development. Understanding the reaction of supercritical CO2 under in situ conditions and its effects on minerals is essential for advancing GCS technology. This study investigates the reaction mechanisms of feldspar (potassium and sodium feldspar) and clay minerals (chlorite, illite, montmorillonite, kaolinite) in CO2 environments. The impacts on mineral crystal structures, morphologies, and elemental compositions were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and ion concentration measurements (ICP-OES and ICP-MS). The results show that feldspar minerals exhibit lower reaction rates, with sodium feldspar dissolving faster than potassium feldspar, due to the higher solubility of sodium ions in acidic conditions. Chlorite showed significant crystal structure damage after 30 days, while montmorillonite underwent both dissolution and precipitation, influenced by interlayer cation dissociation. Kaolinite exhibited minimal reaction, primarily showing localized dissolution. Additionally, the formation of siderite (FeCO3) was observed as Fe2+ substituted for Ca2+ in CaCO3, highlighting the role of iron-bearing carbonates in CO2 interactions. The study provides insights into the factors influencing mineral reactivity, including mineral structure, ion exchange capacity, and solubility, and suggests that chlorite, montmorillonite, and illite are more reactive under reservoir conditions, while kaolinite shows higher resistance to CO2-induced reactions. These findings offer valuable data for optimizing GCS technologies and predicting long-term sequestration outcomes. Full article
(This article belongs to the Special Issue Advances in Mineral-Based Carbon Capture and Storage)
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47 pages, 20134 KB  
Article
The Arkansas Alkaline Province, Southeastern USA: A Synthesis of New and Existing Chemical and Petrologic Data and Petrogenetic Considerations
by Nelson Eby, Norman Charnley, Gino Tiella and Louis Burkhardt
Minerals 2025, 15(11), 1133; https://doi.org/10.3390/min15111133 - 29 Oct 2025
Viewed by 439
Abstract
The Arkansas alkaline province (AAP), southeastern US, consists of seven intrusions or intrusive complexes that lie along a NE–SW trend that falls on the extension of the Mississippi Valley graben. There are three distinct magmatic events: (1) emplacement of lamproites at ~104 Ma, [...] Read more.
The Arkansas alkaline province (AAP), southeastern US, consists of seven intrusions or intrusive complexes that lie along a NE–SW trend that falls on the extension of the Mississippi Valley graben. There are three distinct magmatic events: (1) emplacement of lamproites at ~104 Ma, (2) emplacement of lamprophyres, phonolites, carbonatites, ijolites, and a variety of nepheline syenites between 100 and 98 Ma, and (3) emplacement of a large nepheline syenite body at ~88 Ma. Unpublished and published mineralogical, elemental, and isotope data are used to develop an integrated model for the AAP magmatic activity. The lamproites were derived from ancient enriched subcontinental lithosphere. The carbonatite–lamprophyre–phonolite–ijolite–nepheline syenite association comprises several intrusive complexes (Magnet Cove, Potash Sulphur Springs, V-intrusive) and the Benton lamprophyre–felsic dike swarm. Magmatic evolution is controlled by fractional crystallization of pyroxene and nepheline. The carbonatites may be the result of liquid immiscibility between carbonate and lamprophyric liquids. The large nepheline syenite body (Granite Mountain and Saline County) evolved through fractional crystallization of feldspar and nepheline. Event 2 and 3 magmas were derived from an OIB-like asthenospheric source. The most likely model for the origin of the AAP is the reactivation of a zone of crustal weakness by far field stresses. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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32 pages, 9507 KB  
Article
Forensic Investigation of the Seepage-Induced Flow Failure at La Luciana Tailings Storage Facility (1960 Spain)
by Aldo Onel Oliva-González, Joanna Butlanska, José Antonio Fernández-Merodo and Roberto Lorenzo Rodríguez-Pacheco
Minerals 2025, 15(11), 1131; https://doi.org/10.3390/min15111131 - 29 Oct 2025
Viewed by 359
Abstract
This study presents a forensic investigation of the catastrophic failure of the La Luciana Tailings Storage Facility (TSF) in Reocín, Spain, in 1960. The collapse released approximately 300,000 m3 of tailings, causing 18 fatalities, extensive flooding of farmland and lakes, and the [...] Read more.
This study presents a forensic investigation of the catastrophic failure of the La Luciana Tailings Storage Facility (TSF) in Reocín, Spain, in 1960. The collapse released approximately 300,000 m3 of tailings, causing 18 fatalities, extensive flooding of farmland and lakes, and the contamination of the Besaya River, leading to long-term environmental degradation. The analysis integrates historical documentation, cartographic evidence, in situ testing, laboratory analyses, and numerical modelling to reconstruct the failure sequence and identify its causes. Geotechnical characterization based on cone penetration tests (CPTs), shear wave velocity profiles, and laboratory testing revealed pronounced heterogeneity, with alternating contractive and dilative layers. Hydraulic analyses indicate permeabilities from 10−5 m/s in sand dam materials to 10−9 m/s in fine-grained pond deposits, with evidence of capillary saturation exceeding 20 m, favouring excess pore-pressure accumulation. Limited equilibrium and finite element analyses show that when the decant pond was within ~20 m of the dam, the factor of safety dropped to unity, triggering retrogressive flowslides consistent with field evidence. The results underline critical lessons for TSF governance: maintaining unsaturated tailings, ensuring efficient drainage and decant systems, and monitoring pond proximity to the dam. These are essential to prevent flow failures. This research also demonstrates a replicable forensic methodology applicable to other historical TSF failures, enhancing predictive models and informing modern frameworks such as the EU Directive 2006/21/EC and the Global Industry Standard on Tailings Management (GISTM). Full article
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30 pages, 3046 KB  
Article
Geostatistically Enhanced Learning for Supervised Classification of Wall-Rock Alteration Using Assay Grades of Trace Elements and Sulfides
by Abhishek Borah, Parag Jyoti Dutta and Xavier Emery
Minerals 2025, 15(11), 1128; https://doi.org/10.3390/min15111128 - 29 Oct 2025
Viewed by 822
Abstract
The spatial zoning of wall-rock alteration is a useful guide for exploration of porphyry deposits. The current techniques to typify and quantify alteration types have a component of subjectivity and may not reconcile with mineralogical observations. An alternative is to apply machine learning [...] Read more.
The spatial zoning of wall-rock alteration is a useful guide for exploration of porphyry deposits. The current techniques to typify and quantify alteration types have a component of subjectivity and may not reconcile with mineralogical observations. An alternative is to apply machine learning (ML) to classify alteration based on geochemical and mineralogical feature variables. However, classification loses accuracy because of natural and artificial short-scale variability and missing information, or because it ignores the spatial correlations of the feature variables. Here we show that these inconveniences can be overcome by replacing these variables with proxies obtained through geostatistical simulation. The use of such proxies improves the accuracy scores by eight percentual points by removing the noise affecting the feature variables and infilling their missing values. Furthermore, the uncertainty in the classification predictions can be quantified accurately. Our results demonstrate how geostatistics enriches ML to achieve higher predictive performance and handle incomplete and noisy data sets in a spatial setting. This synergy has far-reaching consequences for decision making in mining exploration, geological modeling, and geometallurgical planning. Beyond the presented pioneering application, we expect our approach to be used in supervised classification problems that arise in varied disciplines of natural sciences and engineering and involve regionalized data. Full article
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25 pages, 8162 KB  
Article
Genesis of the Laoliwan Ag-Pb-Zn Deposit, Southern Margin of the North China Craton, China: Constrained by C-H-O-S-Pb Isotopes and Sulfide Rb-Sr Geochronology
by Jianling Xue, Zhenshan Pang, Hui Chen, Peichao Ding, Ruya Jia, Wen Tao, Ruifeng Shen, Banglu Zhang, Nini Mou and Yan Yang
Minerals 2025, 15(11), 1122; https://doi.org/10.3390/min15111122 - 28 Oct 2025
Viewed by 347
Abstract
The Laoliwan Ag-Pb-Zn deposit is situated in the southern margin of the North China Craton and represents the first large-scale Ag-Pb-Zn ore deposit discovered in the Xiaoshan District. Ag-Pb-Zn orebodies are structurally controlled by NW- and NNW-trending faults and primarily hosted within early [...] Read more.
The Laoliwan Ag-Pb-Zn deposit is situated in the southern margin of the North China Craton and represents the first large-scale Ag-Pb-Zn ore deposit discovered in the Xiaoshan District. Ag-Pb-Zn orebodies are structurally controlled by NW- and NNW-trending faults and primarily hosted within early Cretaceous granite porphyry intrusions. In this study, sulfide Rb-Sr isotope dating and C-H-O-S-Pb multiple isotope compositions were conducted to constrain the ore genesis of this deposit. The Rb-Sr isotopic data of sulfides yield a weighted mean isochron age of 132.8 ± 9.5 Ma and an initial 87Sr/86Sr ratio of 0.7115 ± 0.00016, indicating that mineralization occurred during the early Cretaceous and the ore-forming materials were derived from a crust–mantle mixed reservoir. The δ13 C (−1.3‰ to 0.7‰), δD (−96.3‰ to −86.7‰) and δ18OH2O (0.3‰ to 5.6‰) values suggest that the ore-forming fluids were mainly derived from magmatic water with a contribution of meteoric water during mineralization. The δ34S values of sulfides (+2.0‰ to +5.8‰) indicate a magmatic source. The Pb isotope data (206Pb/204Pb = 17.301–17.892, 207Pb/204Pb = 15.498–15.560, 208Pb/204Pb = 37.873–38.029) also reveal that the ore-forming materials originated from the lower crust with a small amount from the mantle source. By integrating geochronological and geochemical data, this study proposes that the Laoliwan Ag-Pb-Zn deposit is characterized as an epithermal deposit, with potential for the discovery of concealed porphyry Cu-Mo mineralization at depth. It is inferred to be related to tectonic–magmatic–fluid activities in the context of early Cretaceous lithospheric thinning along the southern margin of the North China Craton. Full article
(This article belongs to the Section Mineral Deposits)
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21 pages, 3273 KB  
Article
The Depression Effect of Micromolecular Depressant Containing Amino and Phosphonic Acid Group on Serpentine in the Flotation of Low-Grade Nickel Sulphide Ore
by Chenxu Zhang, Wei Sun, Zhiyong Gao, Bingang Lu, Xiaohui Su, Chunhua Luo, Xiangan Peng and Jian Cao
Minerals 2025, 15(11), 1116; https://doi.org/10.3390/min15111116 - 27 Oct 2025
Viewed by 353
Abstract
Selective depression of serpentine remains a major challenge in the flotation of low-grade nickel sulphide ores because serpentine slimes impair concentrate grade and recovery. In this study, four structurally related micromolecular depressants bearing amino and phosphonic functionalities were designed, synthesized and systematically evaluated. [...] Read more.
Selective depression of serpentine remains a major challenge in the flotation of low-grade nickel sulphide ores because serpentine slimes impair concentrate grade and recovery. In this study, four structurally related micromolecular depressants bearing amino and phosphonic functionalities were designed, synthesized and systematically evaluated. Micro-flotation screening (depressant range: 0–20 mg·L−1) and bench-scale tests identified an operational optimum near pH 9 and a reagent dosage of ≈18 mg·L−1; potassium butyl xanthate (PBX) was used as a collector and methyl isobutyl carbinol (MIBC) as a frother. Phosphonate-containing molecules (PMIDA and GLY) delivered the largest gains in pentlandite recovery and concentrate selectivity compared with carboxylate analogues and a benchmark depressant. Mechanistic studies (zeta potential, adsorption isotherms, FT-IR, and XPS) indicated that selective adsorption of amino and phosphonate groups on serpentine occurs via coordination with surface Mg sites and by altering the electrical double layer. The DLVO modelling showed that these reagents generate an increased repulsive barrier, mitigating slime coating and entrainment. Contact-angle measurements confirmed selective hydrophilization of serpentine while pentlandite remained hydrophobic. These findings demonstrate that incorporating targeted phosphonate chelation into small-molecule depressants is an effective strategy to control serpentine interference and to enhance flotation performance. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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18 pages, 3484 KB  
Review
Role of Natural and Modified Clay Minerals in Microbial Hydrocarbon Biodegradation
by Lei Li and Chunhui Zhang
Minerals 2025, 15(11), 1120; https://doi.org/10.3390/min15111120 - 27 Oct 2025
Viewed by 369
Abstract
Microbial hydrocarbon degradation mediated by natural/modified clay minerals represents an eco-friendly and economically viable remediation strategy for hydrocarbon contamination. However, its effects are not always positive as they depend on multiple factors, including clay mineral types, modification methods, microbial species, and hydrocarbon substrates. [...] Read more.
Microbial hydrocarbon degradation mediated by natural/modified clay minerals represents an eco-friendly and economically viable remediation strategy for hydrocarbon contamination. However, its effects are not always positive as they depend on multiple factors, including clay mineral types, modification methods, microbial species, and hydrocarbon substrates. This review systematically synthesizes existing fragmented studies concerning the impacts of natural clay minerals, modified clay minerals (acid/alkali/thermal/organic/metal ion), and clay minerals containing composite materials on microbial hydrocarbon biodegradation. Based on current findings, future research should prioritize the following recommendations: (1) avoid using concentrated strong acids in acid activation; (2) exclude metal cations that induce strong adsorption (reducing hydrocarbon bioavailability) or trigger excessive interlayer hydrolysis (some trivalent cations) in metal cation modification; (3) eliminate biologically toxic agents during organic modification; and (4) expand understanding of alkali/thermally modified clay minerals and clay mineral-containing composite materials in this direction. Natural/modified clay mineral-mediated microbial degradation is a highly promising remediation technology for hydrocarbon contamination and poised to advance and achieve breakthroughs through continuous synthesis of knowledge and innovation. Full article
(This article belongs to the Section Clays and Engineered Mineral Materials)
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26 pages, 18963 KB  
Article
Mineralogical and Geochemical Evolution During Limestone Weathering and Pedogenesis in Shimen, Hunan Province, South China
by Qi Chen, Jianlan Luo, Fengchu Liao, Xuesheng Xu, Aili Li, Liran Chen, Tuo Zhao, Tingmao Long, Suxin Li and Huan Li
Minerals 2025, 15(11), 1109; https://doi.org/10.3390/min15111109 - 25 Oct 2025
Viewed by 456
Abstract
Understanding mineralogical transformations and elemental mobility during limestone weathering is critical for deciphering carbon cycling and critical zone evolution in karst terrains. This study investigates an in situ limestone weathering profile (12.6 m depth) in Shimen, Hunan Province, using integrated mineralogical (XRD, EPMA-EDS), [...] Read more.
Understanding mineralogical transformations and elemental mobility during limestone weathering is critical for deciphering carbon cycling and critical zone evolution in karst terrains. This study investigates an in situ limestone weathering profile (12.6 m depth) in Shimen, Hunan Province, using integrated mineralogical (XRD, EPMA-EDS), elemental (XRF, ICP-MS), and Sr isotopic (MC-ICP-MS) analyses. Results reveal a two-stage pedogenic model: (1) Rapid dissolution of primary calcite (>95 wt% in bedrock to 1.1–48.5 wt% in soil) creates an abrupt bedrock–soil interface via volumetric collapse (>90%), accumulating acid-insoluble residues (quartz-dominated); (2) Subsequent weathering drives illitization of K-feldspar, trace element enrichment (e.g., Ni, Tl, Th τ up to 180) via illite adsorption, and radiogenic 87Sr/86Sr evolution (0.7076 in bedrock to 0.7292 in soil). Depth-dependent increases in chemical index of alteration (CIA: 6.79–79.96) and mass transfer coefficients confirm progressive weathering intensity. The profile acts as a net carbon source (58.5% depletion in soil inorganic carbon), highlighting significant CO2 release during pedogenesis. These findings provide mechanistic insights into subtropical critical zone evolution and element cycling in carbonate-dominated systems. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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31 pages, 20520 KB  
Article
Genesis of the Baijianshan Skarn-Type Zn-Cu Polymetallic Deposit, Chinese Eastern Tianshan: Constraints from Geology, Geochronology and Geochemistry
by Fenwei Cheng, Shuai Zhang, Jianxin Wu, Baofeng Huang and Di Zhang
Minerals 2025, 15(11), 1107; https://doi.org/10.3390/min15111107 - 24 Oct 2025
Viewed by 323
Abstract
The Baijianshan deposit is the sole skarn Zn-Cu polymetallic deposit in the Xiaoshitouquan ore field, Xinjiang, China. Its ore genesis remains controversial, which hinders understanding of the relationship between skarn-type Zn-Cu and adjacent epithermal Ag-Cu-Pb-Zn mineralization and consequently impedes further regional exploration. LA-ICP-MS [...] Read more.
The Baijianshan deposit is the sole skarn Zn-Cu polymetallic deposit in the Xiaoshitouquan ore field, Xinjiang, China. Its ore genesis remains controversial, which hinders understanding of the relationship between skarn-type Zn-Cu and adjacent epithermal Ag-Cu-Pb-Zn mineralization and consequently impedes further regional exploration. LA-ICP-MS U-Pb dating on zircons from the granite and granite porphyry from the mining area yielded ages of 311 ± 1.7 Ma and 312 ± 1.6 Ma, respectively. The corresponding zircon εHf(t) values and TDM ages are 8.7–9.9 and 624–555 Ma for the granite, and 7.2–9.9 and 673–552 Ma for the granite porphyry. These granites are metaluminous, high-K calc-alkaline I-type granites, with high LREE/HREE ratios (4.92–9.03) and pronounced negative Eu anomalies. They are enriched in K, Th, U, Zr, and Hf, with significant depletions in Sr, P, and Ti. Combined geological and geochemical evidence indicate that these Late Carboniferous granites were derived from the juvenile crustal and formed in subduction-related back basin. Two-phase aqueous inclusions in the ore-bearing quartz and calcite have homogenization temperatures ranging from 117 to 207 °C and 112 to 160 °C, respectively, with the salinities in the ranges of 0.18~7.17 and 0.53~5.26 wt% NaCl eq. The S and Pb isotopic compositions of sulfides in the ores indicate that the ore-forming metals were sourced from the medium-acidic magmatite. The δ18OH2O and δDH2O values of hydrothermal fluids range from −6.97% to −5.84% and −106.8% to −99.6%, respectively, suggesting that the ore-forming fluids originated from the mixing of magmatic and meteoric water. Fluid mixing and corresponding conductive cooling were identified as the principal mechanism triggering the metallic mineral precipitation. The Baijianshan skarn Zn-Cu polymetallic deposit shares contemporaneous magmatic-mineralization ages and analogous material sources with the epithermal polymetallic deposits in the Xiaoshitouquan ore field, collectively constituting a unified skarn-epithermal metallogenic system. This hypothesis indicates that the deep parts of the epithermal deposits within the Yamansu volcanic rocks possess potential for exploring the porphyry-skarn-type deposits. Full article
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26 pages, 1979 KB  
Review
From Single-Sensor Constraints to Multisensor Integration: Advancing Sustainable Complex Ore Sorting
by Sefiu O. Adewuyi, Angelina Anani, Kray Luxbacher and Sehliselo Ndlovu
Minerals 2025, 15(11), 1101; https://doi.org/10.3390/min15111101 - 23 Oct 2025
Viewed by 1092
Abstract
Processing complex ore remains a challenge due to energy-intensive grinding and complex beneficiation and pyrometallurgical treatments that consume large amounts of water whilst generating significant waste and polluting the environment. Sensor-based ore sorting, which separates ore particles based on their physical or chemical [...] Read more.
Processing complex ore remains a challenge due to energy-intensive grinding and complex beneficiation and pyrometallurgical treatments that consume large amounts of water whilst generating significant waste and polluting the environment. Sensor-based ore sorting, which separates ore particles based on their physical or chemical properties before downstream processing, is emerging as a transformative technology in mineral processing. However, its application to complex and heterogeneous ores remain limited by the constraints of single-sensor systems. In addition, existing hybrid sensor strategies are fragmented and a consolidated framework for implementation is lacking. This review explores these challenges and underscores the potential of multimodal sensor integration for complex ore pre-concentration. A multi-sensor framework integrating machine learning and computer vision is proposed to overcome limitations in handling complex ores and enhance sorting efficiency. This approach can improve recovery rates, reduce energy and water consumption, and optimize process performance, thereby supporting more sustainable mining practices that contribute to the United Nations Sustainable Development Goals (UNSDGs). This work provides a roadmap for advancing efficient, resilient, and next-generation mineral processing operations. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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20 pages, 31550 KB  
Article
Report of CA. 760 Ma Mafic Rocks in the Eastern Himalayan Orogen: Petrogenesis and Geodynamic Implications
by Yi Yang, Zhi Zhang, Guotao Ma and Suiliang Dong
Minerals 2025, 15(10), 1090; https://doi.org/10.3390/min15101090 - 20 Oct 2025
Viewed by 359
Abstract
Constraints on the Neoproterozoic evolution of the Himalayan terrane remain poorly understood due to the scarcity of Neoproterozoic magmatic rocks. In this study, we report for the first time Middle Neoproterozoic mafic rocks from the eastern Himalayan orogen. Zircon U–Pb dating indicates that [...] Read more.
Constraints on the Neoproterozoic evolution of the Himalayan terrane remain poorly understood due to the scarcity of Neoproterozoic magmatic rocks. In this study, we report for the first time Middle Neoproterozoic mafic rocks from the eastern Himalayan orogen. Zircon U–Pb dating indicates that these rocks crystallized at approximately 760 Ma and can be divided into two distinct groups. Group 1 mafic rocks have E-MORB-like compositions and are enriched in incompatible elements and exhibit relatively higher initial (87Sr/86Sr)i ratios (0.7053–0.7063), lower positive whole-rock εNd(t) values (3.0 to 3.4), and zircon εHf(t) values ranging from 4.9 to 10.4. They also show low Nb/Th ratios and high Th/Yb, Nb/Yb, and (La/Sm)N ratios, suggesting a lithospheric mantle source. In contrast, Group 2 mafic rocks have N-MORB-like compositions and are characterized by light rare earth element (LREE)-depleted patterns, lower initial (87Sr/86Sr)i ratios (0.7033–0.7040), and higher positive whole-rock εNd(t) (4.8 to 6.0) and zircon εHf(t) values (4.6 to 10.9). Their high Nb/Th ratios and low Th/Yb, Nb/Yb, and (La/Sm)N ratios indicate an origin involving interaction between the lithospheric mantle and depleted asthenospheric mantle. The absence of coeval volcanic and sedimentary records, combined with high La/Y and Ti/V ratios, suggests that these mafic rocks differ from typical arc or back-arc basin suites but are consistent with an intraplate setting. Integrating previous studies on multistage Neoproterozoic magmatism in India and the Himalayas, we propose that the ca. 760 Ma mafic rocks in the eastern Himalaya were likely formed within an intraplate continental rift system. Full article
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32 pages, 9494 KB  
Article
Mineral Prospectivity Maps for Critical Metals in the Clean Energy Transition: Examples for Hydrothermal Copper and Nickel Systems in the Carajás Province
by Luiz Fernandes Dutra, Lena Virgínia Soares Monteiro, Marco Antonio Couto, Jr. and Cleyton de Carvalho Carneiro
Minerals 2025, 15(10), 1086; https://doi.org/10.3390/min15101086 - 18 Oct 2025
Viewed by 774
Abstract
Machine learning algorithms are essential tools for developing Mineral Prospectivity Models (MPMs), enabling a data-driven approach to mineral exploration. This study integrated airborne geophysical, topographic, and geological data with a mineral system framework to build MPMs for iron oxide–copper–gold (IOCG) and hydrothermal nickel [...] Read more.
Machine learning algorithms are essential tools for developing Mineral Prospectivity Models (MPMs), enabling a data-driven approach to mineral exploration. This study integrated airborne geophysical, topographic, and geological data with a mineral system framework to build MPMs for iron oxide–copper–gold (IOCG) and hydrothermal nickel deposits in the Southern Copper Belt of the Carajás Province, Brazil. Seven machine learning algorithms were tested using stratified 10-fold cross-validation: Logistic Regression, k-Nearest Neighbors, AdaBoost, Support Vector Machine (SVM), Random Forest, XGBoost, and Multilayer Perceptron. SVM delivered the highest classification accuracy and robustness, highlighting new mineralized zones while minimizing false positives and negatives, and accounting for geological complexity. SHapley Additive ExPlanations (SHAP) analysis revealed that structural controls (e.g., faults, shear zones, and geochronological contacts) exert a stronger influence on mineralization patterns than lithological factors. The resulting prospectivity maps identified geologically distinct zones of IOCG and hydrothermal nickel mineralization, with high-probability closely aligned with major structural corridors oriented E–W, NE–SW, and NW–SE. Results also suggest an indirect association with volcanic units, Orosirian A1-type granites and Neoarchean A2-type granites. Full article
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20 pages, 5116 KB  
Article
Phase Guard: A False Positive Filter for Automatic Rietveld Quantitative Phase Analysis Based on Counting Statistics in HighScore Plus
by Matteo Pernechele and Sheida Makvandi
Minerals 2025, 15(10), 1041; https://doi.org/10.3390/min15101041 - 30 Sep 2025
Viewed by 804
Abstract
Accurate quantification of minor mineral phases is important in Powder X-Ray Diffraction (PXRD) and Rietveld phase quantification. The precise limit of quantification for the various phases is rarely considered but rather approximated to 0.2–2 wt% by applying a global minimum weight percentage threshold. [...] Read more.
Accurate quantification of minor mineral phases is important in Powder X-Ray Diffraction (PXRD) and Rietveld phase quantification. The precise limit of quantification for the various phases is rarely considered but rather approximated to 0.2–2 wt% by applying a global minimum weight percentage threshold. This approximation often leads to false positive or false negative phase quantity, jeopardizing the trustworthiness of the analytic method in general. In this work (1) we propose a dynamic and adaptable false positive filtering method for Rietveld Quantitative X-ray diffraction (QXRD) based on a phase-specific signal-to-noise ratio referred to as “Phase-SNR”; (2) we introduce the method baptized “Phase Guard” which is implemented in the software HighScore Plus. Phase Guard is based on peaks counting statistics and it automatically adapts to different mineral scattering powers, different mineral crystallinity, instrumental configuration and measurement time. Its applicability and benefits are demonstrated with several examples in cement and mining applications. The adoption of Phase Guard is especially beneficial for industrial black-box solutions, where all “probable” phases are included in the model, even when they are absent from the sample. Phase Guard eliminates false positives, it reduces the likelihood of false negatives, and it is an essential tool to answer the question “what is the limit of quantification for Rietveld analysis?” Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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23 pages, 13715 KB  
Article
Sedimentary Environment, Tectonic Setting, and Paleogeographic Reconstruction of the Late Jurassic Weimei Formation in Dingri, Southern Tibet
by Jie Wang, Songtao Yan, Hao Huang, Tao Liu, Chongyang Xin and Song Chen
Minerals 2025, 15(10), 1040; https://doi.org/10.3390/min15101040 - 30 Sep 2025
Viewed by 601
Abstract
The Weimei Formation, the most complete Upper Jurassic sedimentary sequence in the Tethyan Himalaya, is crucial for understanding the tectono-sedimentary evolution of the northern Indian margin. However, its depositional environment remains debated, with conflicting shallow- and deep-water interpretations. This study integrates sedimentary facies, [...] Read more.
The Weimei Formation, the most complete Upper Jurassic sedimentary sequence in the Tethyan Himalaya, is crucial for understanding the tectono-sedimentary evolution of the northern Indian margin. However, its depositional environment remains debated, with conflicting shallow- and deep-water interpretations. This study integrates sedimentary facies, petrography, zircon geochronology, and geochemical analyses to constrain the provenance, depositional environment, and tectonic setting of the Weimei Formation. The results reveal that the sedimentary system primarily consists of shoreface, delta, and shelf facies, with locally developed slope-incised valleys. Detrital zircon ages are concentrated at ~468 Ma and ~964 Ma, indicating a provenance mainly derived from the Indian continent. Geochemical characteristics, such as high SiO2, low Na2O–CaO–TiO2 contents, right-leaning REE patterns, and significant negative Eu anomalies, suggest the derivation of sediments from felsic upper crustal recycling within a passive continental margin. Stratigraphic comparison between southern and northern Tethyan Himalayan sub-zones reveals a paleogeographic “uplift–depression” pattern, characterized by the coexistence of shoreface–shelf deposits and slope-incised valleys. This study provides key evidence for reconstructing the Late Jurassic paleogeography of the northern Indian margin and the tectonic evolution of the Neo-Tethys Ocean. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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15 pages, 2671 KB  
Article
Mechanisms of Thermal Color Change in Brown Elbaite–Fluorelbaite Tourmaline: Insights from Trace Elements and Spectral Signatures
by Kun Li and Suwei Yue
Minerals 2025, 15(10), 1032; https://doi.org/10.3390/min15101032 - 29 Sep 2025
Cited by 1 | Viewed by 437
Abstract
This study investigates the mechanism behind the heat-induced color change (brown to yellowish green) in Mn- and Fe-rich elbaite tourmaline under reducing atmosphere at 500 °C. A combination of analytical techniques including gemological characterization, electron microprobe analysis (EMPA), laser ablation inductively coupled plasma [...] Read more.
This study investigates the mechanism behind the heat-induced color change (brown to yellowish green) in Mn- and Fe-rich elbaite tourmaline under reducing atmosphere at 500 °C. A combination of analytical techniques including gemological characterization, electron microprobe analysis (EMPA), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, and ultraviolet–visible (UV-Vis) spectroscopy was employed. Chemical analysis confirmed the samples as intermediate members of the elbaite–fluorelbaite series, with an average formula of X(Na0.660.26 Ca0.08) Σ1.00Y(Li1.29Al1.10Mn0.31 Fe2+0.15Ti0.01Zn0.01) Σ2.87 ZAl6T[Si6O18] (BO3)3V(OH)3.00W(OH0.51F0.49) Σ1.00, enriched in Mn (17,346–20,669 μg/g) and Fe (8396–10,750 μg/g). Heat treatment enhanced transparency and induced strong pleochroism (yellowish green parallel c-axis, brown perpendicular c-axis). UV-Vis spectroscopy identified the brown color origin in the parallel c-axis direction: absorption bands at 730 nm (Fe2+ dd transition, 5T2g5Eg), 540 nm (Fe2+→Fe3+ intervalence charge transfer, IVCT), and 415 nm (Fe2+→Ti4+ IVCT + possible Mn2+ contribution). Post-treatment, the 540 nm band vanished, creating a green transmission window and causing the color shift parallel the c-axis. The spectra perpendicular to the c-axis remained largely unchanged. The disappearance of the 540 nm band, attributed to the reduction of Fe3+ to Fe2+ eliminating the Fe2+–Fe3+ pair interaction required for IVCT, is the primary color change mechanism. The parallel c-axis section of the samples shows brown and yellow-green dichroism after heat treatment. A decrease in the IR intensity at 4170 cm−1 indicates a reduced Fe3+ concentration. The weakening or disappearance of the 4721 cm−1 absorption band of the infrared spectrum and the near-infrared 976 nm absorption band of the ultraviolet–visible spectrum provides diagnostic indicators for identifying heat treatment in similar brown elbaite–fluorelbaite. Full article
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18 pages, 5103 KB  
Article
Geochemical Characterisation of Strategic Elements (Li, Co, Ni, Cu, Ga, Ge, and REEs) in Bottom Ash from the Thermal Power Plant (Afşin–Elbistan, Türkiye)
by Leyla Kalender, Hatice Kara, Mehmet Ali Ertürk, Cihan Yalçın, Mehmet Deniz Turan and Emine Cicioğlu Sütçü
Minerals 2025, 15(10), 1026; https://doi.org/10.3390/min15101026 - 28 Sep 2025
Cited by 1 | Viewed by 581
Abstract
This study investigates the concentrations and geochemical behaviour of strategic elements—including Li, Co, Ni, Cu, Ga, Ge, rare earth elements (REEs), and yttrium (Y)—in bottom ash samples from the Afşin–Elbistan thermal power plant, Türkiye. Thirty bottom ash samples were analysed, revealing average ∑LREE [...] Read more.
This study investigates the concentrations and geochemical behaviour of strategic elements—including Li, Co, Ni, Cu, Ga, Ge, rare earth elements (REEs), and yttrium (Y)—in bottom ash samples from the Afşin–Elbistan thermal power plant, Türkiye. Thirty bottom ash samples were analysed, revealing average ∑LREE and ∑HREE concentrations of 86.3 µg/g and 3.3 µg/g, respectively, resulting in an L/H ratio of 24.9, indicating pronounced enrichment in light REEs. The total ∑REE + Y concentration (111 µg/g) is comparable to the background value for coal but approximately 1.5 times lower than those reported for average Chinese coals and the upper continental crust (UCC). REE contents significantly exceed those of sedimentary (5.36 µg/g), mafic (16.77 µg/g), and felsic (3.60 µg/g) rocks. Elevated Li (30.5 µg/g) and Ni (114.4 µg/g) concentrations point to a mafic magmatic source, whereas Cu (28.7 µg/g) likely originates from basic volcanic rocks such as those of the Dağlıca Complex and the Kemaliye Formation. Chondrite-normalised REE patterns show Dy depletion relative to mafic rocks and Ho depletion compared to sedimentary rocks. Positive δEu anomalies (>1) support a mafic or UCC provenance, while slightly positive δCe values indicate hydrothermal leaching influences. The co-precipitation of Ce with Ca–Mg hydroxides and clay minerals in coal-bearing lacustrine sediments is suggested. Ga enrichment is attributed to aluminium-rich clay minerals and organic matter. Overall, these geochemical signatures reflect combined inputs from hydrothermal leaching and volcanic weathering within a coal-bearing lacustrine environment. Full article
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29 pages, 47976 KB  
Article
An Occurrence of Pyroxmangite in the NYF Granitic Pegmatite of the Gabal El-Bakriya Intrusion, Arabian–Nubian Shield
by Danial M. Fathy, Faris A. Abanumay, Shehata Ali, Esam S. Farahat, Andrey Bekker and Mokhles K. Azer
Minerals 2025, 15(10), 1027; https://doi.org/10.3390/min15101027 - 28 Sep 2025
Viewed by 456
Abstract
We report here, for the first time on the Nubian Shield, the western half of the Arabian–Nubian Shield (ANS), pegmatite-hosted pockets with a unique mineralogy, including pyroxmangite. It represents the second discovery on the ANS, where the first one was at Jabal Aja [...] Read more.
We report here, for the first time on the Nubian Shield, the western half of the Arabian–Nubian Shield (ANS), pegmatite-hosted pockets with a unique mineralogy, including pyroxmangite. It represents the second discovery on the ANS, where the first one was at Jabal Aja on the Arabian Shield, the eastern half of the ANS. One of the most remarkable aspects of pyroxmangite is its rarity and the potential economic value of its use in jewelry and decorative applications. Pegmatites are associated with A-type granites of the Gabal El-Bakriya intrusion (GEBI), Eastern Desert, Egypt. Mineralized pegmatites occur at the margin of the alkali-feldspar granite and exhibit gradational contacts with the host rocks. The pegmatites were emplaced as plugs and dikes within the intrusion and along its periphery. Pyroxmangite appears as coarse-grained, massive black aggregates or as disseminated crystals. The pegmatites are composed of K-feldspars and quartz, with subordinate amounts of albite, micas, and mafic minerals. Accessory phases include monazite-(Ce), zircon, fergusonite, xenotime, fluorite, pyrochlore, allanite, thorite, bastnäsite, samarskite, cassiterite, beryl, and pyrochlore. Pyroxmangite-bearing assemblages consist essentially of pyroxmangite and garnet, with accessory pyrochroite, quartz, zircon, magnetite, and fluorite. Geochemically, the pegmatites are highly evolved, with elevated SiO2 content (76.51–80.69 wt.%) and variable concentrations of trace elements. They show significant enrichment in Nb (Nb > Ta), Y, REE, Zr, Th, U, and F, consistent with NYF-type pegmatites. REE contents range from 173.94 to 518.21 ppm, reflecting diverse accessory mineral assemblages. Tectonically, the pegmatites crystallized in a post-collisional setting, representing a late-stage differentiate of the A-type GEBI magma. Mineralization is concentrated in the apical and marginal zones of the granitic cupola and is dominated by barite, fluorite, Nb-Ta oxides, REE minerals, and uranium-bearing phases. The highly evolved granites, greisens, pegmatites, and quartz-fluorite veins of the GEBI have a high economic potential, deserving further exploration. Full article
(This article belongs to the Special Issue Igneous Rocks and Related Mineral Deposits)
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16 pages, 1274 KB  
Article
Study on the Effect of Grinding Media Material and Proportion on the Cyanide Gold Extraction Process
by Guiqiang Niu, Yunfeng Shao, Qingfei Xiao, Mengtao Wang, Saizhen Jin, Guobin Wang and Yijun Cao
Minerals 2025, 15(10), 1031; https://doi.org/10.3390/min15101031 - 28 Sep 2025
Viewed by 635
Abstract
Laboratory and industrial tests were conducted to study the impact of grinding media material on key indicators such as grinding product particle size, sodium cyanide consumption, gold recovery rate, unit power consumption, and ball consumption. Laboratory test results indicate that the reasonable mixing [...] Read more.
Laboratory and industrial tests were conducted to study the impact of grinding media material on key indicators such as grinding product particle size, sodium cyanide consumption, gold recovery rate, unit power consumption, and ball consumption. Laboratory test results indicate that the reasonable mixing of ceramic and steel balls can achieve an increase of more than 2.8% in the fineness of the grinding product (−0.038 mm), an increase of 0.3% in the gold recovery rate, and a decrease of 1.3 kg/t in the consumption of sodium cyanide. Industrial trial studies indicate that, compared to the traditional steel ball scheme, using a ceramic ball to steel ball mass ratio of 3:1 under conditions of processing 50,000 tons of gold concentrate annually can save a total of 1.31 million yuan in annual ball consumption, electricity consumption, and cyanide consumption costs. Additionally, the improved recovery rate generates an additional economic benefit of 3.63 million yuan, resulting in an annual comprehensive economic benefit increase of 4.94 million yuan. In summary, in gold cyanide leaching grinding, the mixture ratio between ceramic balls and steel balls demonstrates significant potential for energy conservation, cost reduction, and efficiency enhancement, providing a theoretical basis and technical support for subsequent process optimization and green gold extraction. Full article
(This article belongs to the Collection Advances in Comminution: From Crushing to Grinding Optimization)
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16 pages, 3586 KB  
Article
Preparation of High-Purity Quartz by Roasting–Water Quenching and Ultrasound-Assisted Acid Leaching Process
by Liran Jiao, Yong Huang, Yingshuang Zhang, Sining Li, Yubin Liu, Guirong Wei and Linlong Wei
Minerals 2025, 15(10), 1028; https://doi.org/10.3390/min15101028 - 28 Sep 2025
Cited by 1 | Viewed by 707
Abstract
High-purity quartz is a key material for photovoltaics, semiconductors, and optical fibers. The raw material for high-purity quartz mainly comes from natural crystal and pegmatite. It is an attractive research field to excavate alternative feedstocks for traditional materials. Quartz conglomerate is a coarse-grained, [...] Read more.
High-purity quartz is a key material for photovoltaics, semiconductors, and optical fibers. The raw material for high-purity quartz mainly comes from natural crystal and pegmatite. It is an attractive research field to excavate alternative feedstocks for traditional materials. Quartz conglomerate is a coarse-grained, clastic sedimentary rock that is cemented by a secondary silica or siliceous matrix. Economically, quartz conglomerate is gaining attention as a strategic alternative to depleting high-grade quartz veins and pegmatites. In this study, high-purity quartz was prepared by purifying quartz conglomerate from Jimunai, Altay, Xinjiang. The method combined high-temperature roasting, water quenching, and ultrasonic-assisted acid leaching. The effects of process parameters on purification efficiency were systematically investigated with the aid of XRD, SEM-EDS, and ICP-OES quantitative element detection. Many cracks formed on the quartz during roasting and quenching. These cracks exposed gap-filling impurities. Gas–liquid inclusions were removed, improving acid leaching. Under optimal ultrasonic-assisted acid leaching conditions (80 °C, 4 h, 10% oxalic acid + 12% hydrochloric acid, 180 W), the Fe content decreased to 6.95 mg/kg, with an 85.6% removal rate. The total impurity content decreased to 210.43 mg/kg. The SiO2 grade increased from 99.77% to 99.98%. Compared to traditional acid leaching, ultrasonic-assisted acid leaching improved Fe removal and reduced environmental pollution. Full article
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25 pages, 46515 KB  
Article
Parental Affinities and Environments of Bauxite Genesis in the Salt Range, Northwestern Himalayas, Pakistan
by Muhammad Khubab, Michael Wagreich, Andrea Mindszenty, Shahid Iqbal, Katerina Schöpfer and Matee Ullah
Minerals 2025, 15(9), 993; https://doi.org/10.3390/min15090993 - 19 Sep 2025
Viewed by 773
Abstract
As the residual products of severe chemical weathering, bauxite deposits serve both as essential economic Al-Fe resources and geochemical archives that reveal information about the parent rocks’ composition, paleoenvironments and paleoclimates, and the tectonic settings responsible for their genesis. The well-developed Early Paleocene [...] Read more.
As the residual products of severe chemical weathering, bauxite deposits serve both as essential economic Al-Fe resources and geochemical archives that reveal information about the parent rocks’ composition, paleoenvironments and paleoclimates, and the tectonic settings responsible for their genesis. The well-developed Early Paleocene bauxite deposits of the Salt Range, Pakistan, provide an opportunity for deciphering their ore genesis and parental affinities. The deposits occur as lenticular bodies and are typically composed of three consecutive stratigraphic facies from base to top: (1) massive dark-red facies (L-1), (2) composite conglomeratic–pisolitic facies (L-2), and (3) Kaolinite-rich clayey facies (L-3). Results from optical microscopy, X-ray powder diffraction (XRPD), and scanning electron microscopy with Energy-Dispersive X-Ray Spectroscopy (SEM-EDS) reveal that facies L-1 contains kaolinite, hematite, and goethite as major minerals, with minor amounts of muscovite, quartz, anatase, and rutile. In contrast, facies L-2 primarily consists of kaolinite, boehmite, hematite, gibbsite, goethite, alunite/natroalunite, and zaherite, with anatase, rutile, and quartz as minor constituents. L-3 is dominated by kaolinite, quartz, and anatase, while hematite and goethite exist in minor concentrations. Geochemical analysis reveals elevated concentrations of Al2O3, Fe2O3, SiO2, and TiO2. Trace elements, including Th, U, Ga, Y, Zr, Nb, Hf, V, and Cr, exhibit a positive trend across all sections when normalized to Upper Continental Crust (UCC) values. Field observations and analytical data suggest a polygenetic origin of these deposits. L-1 suggests in situ lateritization of some sort of precursor materials, with enrichment in stable and ultra-stable heavy minerals such as zircon, tourmaline, rutile, and monazite. This facies is mineralogically mature with bauxitic components, but lacks the typical bauxitic textures. In contrast, L-2 is texturally and mineralogically mature, characterized by various-sized pisoids and ooids within a microgranular-to-microclastic matrix. The L-3 mineralogy and texture suggest that the conditions were still favorable for bauxite formation. However, the ongoing tectonic activities and wet–dry climate cycles post-depositionally disrupted the bauxitization process. The accumulation of highly stable detrital minerals, such as zircon, rutile, tourmaline, and monazite, indicates prolonged weathering and multiple cycles of sedimentary reworking. These deposits have parental affinity with acidic-to-intermediate/-argillaceous rocks, resulting from the weathering of sediments derived from UCC sources, including cratonic sandstone and shale. Full article
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14 pages, 1544 KB  
Article
Kinetics of Sulfide Dissolution Controlled by Sulfur Radical Diffusion: Implications for Sulfur Transport and Triggering of Volcanic Eruptions
by Anastassia Borisova
Minerals 2025, 15(9), 989; https://doi.org/10.3390/min15090989 - 17 Sep 2025
Viewed by 496
Abstract
Chemical mixing of different types of magma, such as basaltic magma and silica-rich, hydrous magma, often triggers volcanic eruptions. However, the kinetics, mechanisms, and rates of sulfide dissolution reactions in hydrous melts are currently unknown, despite the fact that these reactions can influence [...] Read more.
Chemical mixing of different types of magma, such as basaltic magma and silica-rich, hydrous magma, often triggers volcanic eruptions. However, the kinetics, mechanisms, and rates of sulfide dissolution reactions in hydrous melts are currently unknown, despite the fact that these reactions can influence the sulfur budget in the crust and mantle. I experimentally model dissolution of pyrrhotite minerals in hydrous rhyolite melt at conditions corresponding to the sulfate–sulfide transition field at 1 GPa pressure. The reaction results in the production of FeO, SO42−, H2, H2S and di- and tri-sulfur radical ions, (S2 or S3) in fluid/melt. The calculated sulfur diffusion coefficient implies extremely fast sulfur diffusion in the hydrous hybrid melt. The production of S-rich magma is controlled by the fastest-ever-recorded chemical diffusion of sulfur in the form of S2 or S3 in hybrid magma under sulfate-sulfide transition conditions. I demonstrate that such dissolution reactions can be responsible for triggering explosive volcanic eruptions (e.g., the 1991 Mount Pinatubo eruption) in volcanic arc settings. The sulfide dissolution reaction can also promote the production of chalcophile metal (sulfur-loving Au, Cu and Pt) ore deposits associated with the formation of volcanic arcs. Full article
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41 pages, 5058 KB  
Review
Review of Enargite Flotation—Part I: Surface Characterization and Advances in Selective Flotation
by Pablo Miranda-Villagrán, Rodrigo Yepsen, Andrés Ramírez-Madrid, Jorge H. Saavedra and Leopoldo Gutiérrez
Minerals 2025, 15(9), 971; https://doi.org/10.3390/min15090971 - 13 Sep 2025
Viewed by 874
Abstract
Enargite (Cu3AsS4), a copper–arsenic sulfosalt, represents a critical challenge in copper mineral processing due to its high arsenic content, which poses significant environmental, metallurgical, and economic issues. Its flotation behavior closely resembles that of other copper sulfides such as [...] Read more.
Enargite (Cu3AsS4), a copper–arsenic sulfosalt, represents a critical challenge in copper mineral processing due to its high arsenic content, which poses significant environmental, metallurgical, and economic issues. Its flotation behavior closely resembles that of other copper sulfides such as chalcopyrite and chalcocite, complicating selective separation at early beneficiation stages. This review presents a comprehensive examination of enargite’s surface chemistry and electrochemical behavior, focusing on the influence of oxidation, pH, and pulp potential on surface reactivity, charge distribution (zeta potential), and hydrophobicity. Detailed insights into the formation of surface oxidation layers, passivation mechanisms, and contact angle variations are provided to elucidate collector-mineral interactions. Advances in selective flotation techniques are also discussed, including the use of depressant reagents, controlled redox environments, and reagent conditioning strategies. Special attention is given to flotation in seawater, where ionic strength and multivalent ions significantly influence mineral-reagent interactions and flotation outcomes. Galvanic interactions between enargite and other sulfide minerals are identified as critical factors affecting floatability and selectivity. The review consolidates findings from recent experimental and electrochemical studies, highlighting promising approaches to enhance enargite rejection and copper concentrate purity. It concludes with perspectives on future research aimed at optimizing flotation processes and developing sustainable solutions for processing arsenic-bearing copper ores. Full article
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17 pages, 7660 KB  
Article
Subresolution Porosity Estimation of Porous Rocks from CT Images: Incorporating X-Ray Mass Attenuation Coefficients
by Jianhuang Chen, Zhongjian Zhang, Zhenyu Long, Qiong Zhang and Zhongqi Yue
Minerals 2025, 15(9), 966; https://doi.org/10.3390/min15090966 - 12 Sep 2025
Viewed by 606
Abstract
Rock porosity is a key parameter for quantifying fluid flow properties and predicting mechanical behaviour. Although X-ray CT imaging has been widely used to estimate porosity, the accuracy of such methods is still hindered by beam energy and mineralogical heterogeneity. In this study, [...] Read more.
Rock porosity is a key parameter for quantifying fluid flow properties and predicting mechanical behaviour. Although X-ray CT imaging has been widely used to estimate porosity, the accuracy of such methods is still hindered by beam energy and mineralogical heterogeneity. In this study, a methodology for the estimation of subresolution porosity is proposed, taking into account the relative relationship of X-ray mass attenuation coefficients (MACs) among minerals. The approach segments macroparticles, matrix, and macropores and calibrates their relative X-ray MAC relationships to establish the upper and lower bounds of the matrix LAC. Subresolution porosity is then estimated based on these calibrated limits. Taking Belgian Fieldstone and Bentheimer Sandstone as examples, the method described in this paper has stronger connectivity than does the binarised porosity estimation method and higher estimation accuracy than does the subresolution porosity calculation method, which does not consider the MAC. The proposed method is intended to refine the rationality of the subresolution porosity calculation and to broaden its theoretical scope of application. Full article
(This article belongs to the Section Clays and Engineered Mineral Materials)
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28 pages, 4033 KB  
Article
Assessing Jarosite Kinetic Dissolution Rates at Acidic Conditions and Different Temperatures
by Mateus De Souza Buriti, Marie Poulain, Pierre Cézac and Lidia Casás
Minerals 2025, 15(9), 965; https://doi.org/10.3390/min15090965 - 11 Sep 2025
Viewed by 913
Abstract
K-jarosite (KFe3(SO4)2(OH)6), the most common jarosite-type mineral in natural and industrial settings, has been widely studied to understand its dissolution behavior in both environmental and industrial contexts. However, reported kinetic data remain inconsistent due to [...] Read more.
K-jarosite (KFe3(SO4)2(OH)6), the most common jarosite-type mineral in natural and industrial settings, has been widely studied to understand its dissolution behavior in both environmental and industrial contexts. However, reported kinetic data remain inconsistent due to the combined influence of kinetic factors, despite the importance of such data for optimizing system conditions and improving process control and environmental management. The present work aims to help elucidate K-jarosite dissolution by carrying out new experiments in sulfuric acid medium (pH 1 and 2) at different temperatures (296, 323 and 343 K) and using two initial concentrations (0.4 and 1 g of K-jarosite/kg of solution). K-jarosite was synthesized and characterized by analytical techniques (XRD, SEM and BET), and the composition was determined by induction-coupled plasma optical emission spectroscopy (ICP-OES). Derivative (DVKM), Noyes–Whitney (NWKM) and Shrinking Core (SCKM) kinetic models previously used in the literature of jarosite-type compounds were adjusted to the data obtained here and compared. The results showed that higher temperatures and lower pH led to faster dissolution rates. Smaller initial concentrations decreased the rates slightly but had less impact than the other variables. Experiments at pH 1 led to the dissolution of all jarosite solids, while at pH 2 they led to incomplete dissolution. Remarkably, at pH 2 and at higher temperatures (mainly at 343 K), there was slight reprecipitation of the iron. XRD analysis identified no peak other than K-jarosite peaks after dissolution. DVKM and NWKM represented the effect of the studied parameters well. However, only using SCKM was a kinetic equation describing the dissolution process obtained. While the behavior of the kinetic curve is well established, the model fails to correctly describe the induction period. Under extreme conditions (>323 K, pH 1), dissolution is described by a chemical reaction controlling stage and it changes to mass transport in mild conditions. As theoretically expected, the results obtained in this work give important information about the prediction of the behavior of jarosite dissolution in terrestrial environments (acid mine and acid rock drainages) and hydrometallurgical process in mild acidic conditions and high temperatures. Full article
(This article belongs to the Section Environmental Mineralogy and Biogeochemistry)
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20 pages, 11423 KB  
Article
Clay Mineral Characteristics and Smectite-to-Illite Transformation in the Chang-7 Shale, Ordos Basin: Processes and Controlling Factors
by Kun Ling, Ziyi Wang, Yaqi Cao, Yifei Liu and Lin Dong
Minerals 2025, 15(9), 951; https://doi.org/10.3390/min15090951 - 5 Sep 2025
Cited by 1 | Viewed by 1520
Abstract
As critical components in continental shale systems, the composition and evolution of clay minerals are fundamental to their diagenetic processes and petrophysical properties. The Chang-7 shales in the Ordos Basin exhibit abundant clay mineral content, offering a valuable case study for clay mineral [...] Read more.
As critical components in continental shale systems, the composition and evolution of clay minerals are fundamental to their diagenetic processes and petrophysical properties. The Chang-7 shales in the Ordos Basin exhibit abundant clay mineral content, offering a valuable case study for clay mineral research under moderate diagenetic conditions. This study employed XRD analysis to determine the whole-rock mineralogy, clay mineral composition, and the evolution characteristics of illite-smectite mixed-layer minerals (I/S). Comprehensive clay mineral datasets compiled from 13 newly analyzed wells and existing literature revealed distinct lateral distribution patterns. Total Organic Carbon (TOC) analysis and vitrinite reflectance (Ro) measurements provided systematic quantification of organic matter abundance and thermal maturation parameters in the studied samples. The results reveal that the Chang-7 shale exhibits a characteristic clay mineral assemblage, with I/S (average 44.2%) predominating over illite (34.7%), followed by chlorite (15.6%) and limited kaolinite (5.4%). Frequent volcanic activities provided substantial precursor materials for smectite formation, which actively participated in subsequent illitization processes, while chlorite and kaolinite distributions were predominantly controlled by provenance inputs and sedimentary facies, respectively. Inconsistencies exist between diagenetic stages inferred from I/S mixed-layer ratios and Ro values, particularly in low-maturity samples exhibiting accelerated illitization. The observed negative correlation between TOC content and mixed-layer ratios in Well YY1 and YSC Section samples demonstrates the catalytic role of organic matter in facilitating smectite-to-illite transformation. These results systematically clarify the coupled effects of sedimentary-diagenetic processes, offering new insights into the mutual interactions between inorganic and organic phases during illitization under natural geological conditions. The findings advance the understanding of Chang-7 shale oil and gas systems and offer practical guidance for future exploration. Full article
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40 pages, 3732 KB  
Review
Applications and Prospects of Muography in Strategic Deposits
by Xingwen Zhou, Juntao Liu, Baopeng Su, Kaiqiang Yao, Xinyu Cai, Rongqing Zhang, Ting Li, Hengliang Deng, Jiangkun Li, Shi Yan and Zhiyi Liu
Minerals 2025, 15(9), 945; https://doi.org/10.3390/min15090945 - 4 Sep 2025
Viewed by 1673
Abstract
With strategic mineral exploration extending to deep and complex geological settings, traditional methods increasingly struggle to dissect metallogenic systems and locate ore bodies precisely. This synthesis of current progress in muon imaging (a technology leveraging cosmic ray muons’ high penetration) aims to address [...] Read more.
With strategic mineral exploration extending to deep and complex geological settings, traditional methods increasingly struggle to dissect metallogenic systems and locate ore bodies precisely. This synthesis of current progress in muon imaging (a technology leveraging cosmic ray muons’ high penetration) aims to address these exploration challenges. Muon imaging operates by exploiting the energy attenuation of cosmic ray muons when penetrating earth media. It records muon transmission trajectories via high-precision detector arrays and constructs detailed subsurface density distribution images through advanced 3D inversion algorithms, enabling non-invasive detection of deep ore bodies. This review is organized into four thematic sections: (1) technical principles of muon imaging; (2) practical applications and advantages in ore exploration; (3) current challenges in deployment; (4) optimization strategies and future prospects. In practical applications, muon imaging has demonstrated unique advantages: it penetrates thick overburden and high-resistance rock masses to delineate blind ore bodies, with simultaneous gains in exploration efficiency and cost reduction. Optimized data acquisition and processing further allow it to capture dynamic changes in rock mass structure over hours to days, supporting proactive mine safety management. However, challenges remain, including complex muon event analysis, long data acquisition cycles, and limited distinguishability for low-density-contrast formations. It discusses solutions via multi-source geophysical data integration, optimized acquisition strategies, detector performance improvements, and intelligent data processing algorithms to enhance practicality and reliability. Future advancements in muon imaging are expected to drive breakthroughs in ultra-deep ore-forming system exploration, positioning it as a key force in innovating strategic mineral resource exploration technologies. Full article
(This article belongs to the Special Issue 3D Mineral Prospectivity Modeling Applied to Mineral Deposits)
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32 pages, 2165 KB  
Review
Biogeochemical Interactions and Their Role in European Underground Hydrogen Storage
by Frank E. Viveros, Na Liu and Martin A. Fernø
Minerals 2025, 15(9), 929; https://doi.org/10.3390/min15090929 - 1 Sep 2025
Viewed by 1364
Abstract
Integrating renewable energy requires robust, large-scale storage solutions to balance intermittent supply. Underground hydrogen storage (UHS) in geological formations, such as salt caverns, depleted hydrocarbon reservoirs, or aquifers, offers a promising way to store large volumes of energy for seasonal periods. This review [...] Read more.
Integrating renewable energy requires robust, large-scale storage solutions to balance intermittent supply. Underground hydrogen storage (UHS) in geological formations, such as salt caverns, depleted hydrocarbon reservoirs, or aquifers, offers a promising way to store large volumes of energy for seasonal periods. This review focuses on the biological aspects of UHS, examining the biogeochemical interactions between H2, reservoir minerals, and key hydrogenotrophic microorganisms such as sulfate-reducing bacteria, methanogens, acetogens, and iron-reducing bacteria within the gas–liquid–rock–microorganism system. These microbial groups use H2 as an electron donor, triggering biogeochemical reactions that can affect storage efficiency through gas loss and mineral dissolution–precipitation cycles. This review discusses their metabolic pathways and the geochemical interactions driven by microbial byproducts such as H2S, CH4, acetate, and Fe2+ and considers biofilm formation by microbial consortia, which can further change the petrophysical reservoir properties. In addition, the review maps 76 ongoing European projects focused on UHS, showing 71% target salt caverns, 22% depleted hydrocarbon reservoirs, and 7% aquifers, with emphasis on potential biogeochemical interactions. It also identifies key knowledge gaps, including the lack of in situ kinetic data, limited field-scale monitoring of microbial activity, and insufficient understanding of mineral–microbe interactions that may affect gas purity. Finally, the review highlights the need to study microbial adaptation over time and the influence of mineralogy on tolerance thresholds. By analyzing these processes across different geological settings and integrating findings from European research initiatives, this work evaluates the impact of microbial and geochemical factors on the safety, efficiency, and long-term performance of UHS. Full article
(This article belongs to the Special Issue Mineral Dissolution and Precipitation in Geologic Porous Media)
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22 pages, 5306 KB  
Article
Geochemical Signatures and Element Interactions of Volcanic-Hosted Agates: Insights from Interpretable Machine Learning
by Peng Zhang, Xi Xi and Bo-Chao Wang
Minerals 2025, 15(9), 923; https://doi.org/10.3390/min15090923 - 29 Aug 2025
Viewed by 587
Abstract
To unravel the link between agate geochemistry, host volcanic rocks, and ore-forming processes, this study integrated elemental correlation analysis, interaction interpretation, and interpretable machine learning (LightGBM-SHAP framework with SMOTE and 5-fold cross-validation) using 203 in-situ element datasets from 16 global deposits. The framework [...] Read more.
To unravel the link between agate geochemistry, host volcanic rocks, and ore-forming processes, this study integrated elemental correlation analysis, interaction interpretation, and interpretable machine learning (LightGBM-SHAP framework with SMOTE and 5-fold cross-validation) using 203 in-situ element datasets from 16 global deposits. The framework achieved 99.01% test accuracy and 97.4% independent prediction accuracy in discriminating host volcanic rock types. Key findings reveal divergence between statistical elemental correlations and geological interactions. Synergies reflect co-migration/co-precipitation, while antagonisms stem from source competition or precipitation inhibition, unraveling processes like stepwise crystallization. Rhyolite-hosted agates form via a “crust-derived magmatic hydrothermal fluid—medium-low salinity complexation—multi-stage precipitation” model, driven by high-silica fluids enriching Sb/Zn. Andesite-hosted agates follow a “contaminated fluid—hydrothermal alteration—precipitation window differentiation” model, controlled by crustal contamination. Basalt-hosted agates form through a “low-temperature hydrothermal fluid—basic alteration—progressive mineral decomposition” model, with meteoric water regulating Na-Zn relationships. Zn acts as a cross-lithology indicator, tracing crust-derived fluid processes in rhyolites, feldspar alteration intensity in andesites, and alteration timing in basalts. This work advances volcanic-agate genetic studies via “correlation—interaction—mineralization model” coupling, with future directions focusing on large-scale micro-area elemental analysis. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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29 pages, 5957 KB  
Article
Multistage Fluid Evolution and P-T Path at Ity Gold Deposit and Dahapleu Prospect (Western Ivory Coast)
by Yacouba Coulibaly, Michel Cathelineau and Marie-Christine Boiron
Minerals 2025, 15(9), 918; https://doi.org/10.3390/min15090918 - 28 Aug 2025
Viewed by 976
Abstract
Gold mineralisation at Ity (Ivory Coast) is spatially associated with skarns formed at contacts between carbonate-rich Birimian volcano-sedimentary rocks and felsic intrusions, whereas at Dahapleu, a nearby skarn-free prospect, gold occurs in structurally controlled shear zones. Gold occurs as native gold in pyrite [...] Read more.
Gold mineralisation at Ity (Ivory Coast) is spatially associated with skarns formed at contacts between carbonate-rich Birimian volcano-sedimentary rocks and felsic intrusions, whereas at Dahapleu, a nearby skarn-free prospect, gold occurs in structurally controlled shear zones. Gold occurs as native gold in pyrite or as a Bi–Te–Au–Ag telluride assemblage. Fluid inclusion data indicate that Ity formed through a hybrid model: a mesothermal orogenic gold system dominated by CO2–CH4 fluids at >350 °C, superimposed on earlier skarn mineralisation characterised by saline fluids. At Dahapleu, no skarn fluids were identified, but volatile-rich inclusions with more variable signatures (CO2, CO2–CH4, CO2–N2) indicate metamorphic fluids circulating in convective, fault-related systems and recording distinct fluid–rock interactions. The Ity–Dahapleu mineralising system thus displays fluid inclusion characteristics typical of mesothermal orogenic gold systems, likely at higher temperatures than most West African Birimian deposits. Overall, the Ity system reflects a long-lived thermal anomaly driving fluid circulation and metal deposition, with successive favourable events: rapid exhumation of hot lithospheric crust, granite intrusion, and skarn formation, followed by shear deformation and hydrothermal activity. Full article
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42 pages, 1483 KB  
Review
An Overview of Applications, Toxicology and Separation Methods of Lithium
by Ma. del Rosario Moreno-Virgen, Blanca Paloma Escalera-Velasco, Hilda Elizabeth Reynel-Ávila, Herson Antonio González-Ponce, Alvaro Rodrigo Videla-Leiva, Arturo Ignacio Morandé-Thompson, Marco Ludovico-Marques, Noemi Sogari and Adrián Bonilla-Petriciolet
Minerals 2025, 15(9), 917; https://doi.org/10.3390/min15090917 - 28 Aug 2025
Viewed by 1945
Abstract
Lithium has emerged as a critical element in contemporary society. It has been classified as an indispensable feedstock in the manufacture of lithium-ion batteries for electric mobility, portable electronics, and stationary energy storage systems, which are essential for the integration of intermittent renewable [...] Read more.
Lithium has emerged as a critical element in contemporary society. It has been classified as an indispensable feedstock in the manufacture of lithium-ion batteries for electric mobility, portable electronics, and stationary energy storage systems, which are essential for the integration of intermittent renewable energy sources. This metal also has other industrial applications and is projected to support future developments in semiconductor and aerospace technology. However, the exponential growth in global Li demand driven by energy transition and technological innovation requires a resilient and sustainable supply chain where both technological and environmental challenges should be addressed. This review discusses and analyzes some of current challenges associated with the Li supply chain given a particular emphasis on its separation methods. First, statistics of the Li market and its applications are provided, including the main sources from which to recover Li and the environmental impact associated with conventional Li extraction techniques from mineral ores and salar brines. Different separation methods (e.g., solvent extraction, adsorption, ion exchange, membrane technology) to recover Li from different sources are reviewed. Recent advances and developments in these separation strategies are described, including a brief analysis of their main limitations and capabilities. The importance and potential of recycling strategies for end-of-life batteries and industrial residues are also highlighted. A perspective on the gaps to be resolved with the aim of consolidating the Li supply chain to support the energy transition agenda is provided in this review. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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13 pages, 3828 KB  
Article
Effects of Fluid Inclusion Component Release on Flotation Behavior of Fluorite Minerals
by Renji Zheng, Shilin Hong, Sheng Wang, Honghu Tang and Zhiyong Gao
Minerals 2025, 15(9), 912; https://doi.org/10.3390/min15090912 - 27 Aug 2025
Viewed by 633
Abstract
Fluid inclusions, ubiquitously present within fluorite during diagenesis and mineralization, are released as inevitable ionic components in the pulp during mineral crushing and grinding. This study, grounded in geochemistry, combined microstructural analysis, spectroscopy, and X-ray computed tomography (X-CT) to investigate the morphology and [...] Read more.
Fluid inclusions, ubiquitously present within fluorite during diagenesis and mineralization, are released as inevitable ionic components in the pulp during mineral crushing and grinding. This study, grounded in geochemistry, combined microstructural analysis, spectroscopy, and X-ray computed tomography (X-CT) to investigate the morphology and petrographic characteristics of fluid inclusions in fluorite minerals. Building on this foundation, inductively coupled plasma optical emission spectrometry (ICP-OES) and ion chromatography (IC) were employed to analyze the release patterns of fluid inclusion components and their impact on fluorite flotation. The results reveal that fluid inclusions within fluorite are predominantly liquid-rich, two-phase (vapor-liquid) inclusions, exhibiting a spatial distribution density as high as 14.1%. Furthermore, fluid components are released during fluorite grinding, particularly homonymous Ca2+ ions, which significantly influence fluorite flotation behavior. Low concentrations of Ca2+ can activate fluorite flotation, whereas high concentrations of Ca2+ consume the collector (sodium oleate) in solution through competitive adsorption. This competition inhibits the adsorption of sodium oleate onto the fluorite mineral surface. The findings of this research provide theoretical support for in-depth studies on fluid inclusions in minerals and their effects on mineral flotation behavior, thereby facilitating the clean and efficient recovery of strategic fluorite mineral resources. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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15 pages, 7780 KB  
Article
Geochronological Constraints on the Genesis of the Changshitougounao Gold Deposit, Qinling Orogen
by Xian-Fa Xue, Sheng-Xiang Lu, Shou-Xu Wang, Da-Hu Yuan, Zheng-Wang Zeng, Jin-Hong Qiu and Jie Wang
Minerals 2025, 15(9), 903; https://doi.org/10.3390/min15090903 - 26 Aug 2025
Viewed by 1109
Abstract
The Western Qinling Orogenic Belt, China’s second-largest Au-metallogenic province, hosts numerous polymetallic deposits, with gold resources particularly concentrated in the northwestern Xiahe–Hezuo area. The Changshitougounao gold deposit, located south of the Xiahe Fault, comprises disseminated ores controlled by near E–W-trending faults and is [...] Read more.
The Western Qinling Orogenic Belt, China’s second-largest Au-metallogenic province, hosts numerous polymetallic deposits, with gold resources particularly concentrated in the northwestern Xiahe–Hezuo area. The Changshitougounao gold deposit, located south of the Xiahe Fault, comprises disseminated ores controlled by near E–W-trending faults and is primarily hosted in quartz diorite and the Lower Triassic Longwuhe Formation. Zircon LA–ICP–MS U–Pb dating of fresh quartz diorite yields an age of 241.8 ± 2.6 Ma. Two generations of monazite were identified: type I magmatic monazite and type II hydrothermal monazite. Type I monazite is intergrown with feldspar, quartz, and biotite, and in situ LA–ICP–MS U–Pb analysis gives an age of 239.2 ± 2.2 Ma. Type II monazite occurs as irregular granular aggregates associated with Au-bearing sulfides and hydrothermal sericite, with an in situ U–Pb age of 230 ± 3.5 Ma. Apatite, also coeval with Au-bearing sulfides and type II monazite, yields an LA–ICP–MS U–Pb age of 230.9 ± 2.5 Ma and 230.7 ± 3.0 Ma. Zircon and type I monazite thus constrain the emplacement of the ore-bearing quartz diorite to ca. 240 Ma, whereas hydrothermal type II monazite and apatite constrain the timing of mineralization to ca. 230 Ma. The ~10 Ma interval between magmatism and mineralization indicates that goldmineralization in the Changshitougounao deposit is decoupled from Early Triassic magmatic activity. Integrating previous studies of the West Qinling geodynamic evolution, we infer that the Changshitougounao deposit formed during collisional orogenesis, in response to the closure of the Paleo-Tethys Ocean. Consequently, the Changshitougounao gold deposit is best classified as an orogenic gold system. Pyrite–arsenopyrite and sericite alteration serve as effective exploration vectors, and the contact zone between quartz diorite veins and slate represents a favorable structural setting for ore prospecting. Full article
(This article belongs to the Special Issue Gold–Polymetallic Deposits in Convergent Margins)
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13 pages, 5817 KB  
Article
Dissolution of Diamond in Water–Chloride Fluids at Mantle P-T Conditions
by Alexander Khokhryakov, Alexey Kruk, Alexander Sokol and Denis Nechaev
Minerals 2025, 15(9), 897; https://doi.org/10.3390/min15090897 - 24 Aug 2025
Viewed by 859
Abstract
Syngenetic fluid inclusions in natural diamonds are indicators of the composition of fluids responsible for growth and crystallization conditions. The chloride concentration in saline fluid inclusions of natural diamonds reaches 50 wt%. We study the dissolution of diamonds in the H2O-KCl-NaCl [...] Read more.
Syngenetic fluid inclusions in natural diamonds are indicators of the composition of fluids responsible for growth and crystallization conditions. The chloride concentration in saline fluid inclusions of natural diamonds reaches 50 wt%. We study the dissolution of diamonds in the H2O-KCl-NaCl system at temperatures of 1200 °C and 1400 °C and a pressure of 5.5 GPa using a BARS high-pressure multi-anvil apparatus. Two scenarios of diamond dissolution were experimentally investigated: (i) metasomatism by saline brines at high oxygen fugacity of the magnetite–hematite buffer; (ii) interaction with reduced carbon-unsaturated water–chloride fluid at low fO2 imposed by the iron–wüstite buffer. It is found that the presence of alkaline chlorides in the aqueous fluid significantly accelerates diamond dissolution at high oxygen fugacity but inhibits the process under reduced conditions. The morphology of diamond dissolution features is controlled by the presence of water in the fluid over the entire range of the studied P-T-fO2 conditions. Experimental results indicate that the interaction with oxidizing highly saline fluids during metasomatic events could negatively affect diamond preservation in mantle rocks and eventually lead to the formation of uneconomic kimberlites. Under reducing conditions, water–chloride fluids favor diamond preservation. Full article
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33 pages, 8102 KB  
Article
Fluid Components in Cordierites from Granulite- and Amphibolite-Facies Rocks of the Aldan Shield and Yenisei Ridge, Russia: Evidence from Pyrolysis-Free GC-MS, Raman, and IR Spectroscopy
by Ksenia Zatolokina, Anatoly Tomilenko, Taras Bul’bak and Nikolay Popov
Minerals 2025, 15(9), 890; https://doi.org/10.3390/min15090890 - 22 Aug 2025
Viewed by 886
Abstract
This study provides the first comprehensive characterization of fluid components in cordierites from both moderate- to high-pressure granulite facies of the Aldan Shield (Sutam and Nimnyr blocks), and granulite–amphibolite facies of the Yenisei Ridge (Kan and Yenisei series of the Angara–Kan complex), Russia, [...] Read more.
This study provides the first comprehensive characterization of fluid components in cordierites from both moderate- to high-pressure granulite facies of the Aldan Shield (Sutam and Nimnyr blocks), and granulite–amphibolite facies of the Yenisei Ridge (Kan and Yenisei series of the Angara–Kan complex), Russia, using integrated infrared and Raman spectroscopy coupled with pyrolysis-free gas chromatography–mass spectrometry (GC-MS). Granulite-facies cordierites record CO2-dominated fluids (XCO2 = CO2/(H2O + CO2) = 0.74–0.99) with elevated values (XCO2 = 0.89–0.99) in high-pressure, high-temperature (high-P-T) samples from the Sutam block and Kan series compared to moderate-P-T samples from the Nimnyr block (XCO2 = 0.74–0.84). Amphibolite-facies cordierites (Yenisei series) show significantly lower CO2 contents (XCO2 = 0.51–0.57) and higher H2O concentrations relative to high-pressure granulites. Critically, we report the first identification in cordierites of at least 12 homologous series of organic compounds and nitrogenated, sulfonated, and halogenated compounds. These results provide new constraints on fluid behavior across metamorphic facies transitions. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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35 pages, 10915 KB  
Review
Geochemistry of Mars with Laser-Induced Breakdown Spectroscopy (LIBS): ChemCam, SuperCam, and MarSCoDe
by Roger C. Wiens, Agnes Cousin, Samuel M. Clegg, Olivier Gasnault, Zhaopeng Chen, Sylvestre Maurice and Rong Shu
Minerals 2025, 15(8), 882; https://doi.org/10.3390/min15080882 - 21 Aug 2025
Cited by 1 | Viewed by 1271
Abstract
Laser-induced breakdown spectroscopy (LIBS) has been used to explore the chemistry of three regions of Mars on respective missions by NASA and CNSA, with CNES contributions. All three LIBS instruments use ~100 mm diameter telescopes projecting pulsed infrared laser beams of 10–14 mJ [...] Read more.
Laser-induced breakdown spectroscopy (LIBS) has been used to explore the chemistry of three regions of Mars on respective missions by NASA and CNSA, with CNES contributions. All three LIBS instruments use ~100 mm diameter telescopes projecting pulsed infrared laser beams of 10–14 mJ to enable LIBS at 2–10 m distances, eliminating the need to position the rover and instrument directly onto targets. Over 1.3 million LIBS spectra have been used to provide routine compositions for eight major elements and several minor and trace elements on >3000 targets on Mars. Onboard calibration targets common to all three instruments allow careful intercomparison of results. Operating over thirteen years, ChemCam on Curiosity has explored lacustrine sediments and diagenetic features in Gale crater, which was a long-lasting (>1 My) lake during Mars’ Hesperian period. SuperCam on Perseverance is exploring the ultramafic igneous floor, fluvial–deltaic features, and the rim of Jezero crater. MarSCoDe on the Zhurong rover investigated for one year the local blocks, soils, and transverse aeolian ridges of Utopia Planitia. The pioneering work of these three stand-off LIBS instruments paves the way for future space exploration with LIBS, where advantages of light-element (H, C, N, O) quantification can be used on icy regions. Full article
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13 pages, 7481 KB  
Article
Influence of Hydration on Shale Reservoirs: A Case Study of Gulong Shale Oil
by Feifei Fang, Ke Xu, Yu Zhang, Yu Wang, Zhimin Xu, Sijie He, Hui Huang, Hailong Wang, Weixiang Jin and Yue Gong
Minerals 2025, 15(8), 878; https://doi.org/10.3390/min15080878 - 21 Aug 2025
Viewed by 744
Abstract
In the process of the exploration and development of shale oil, the influence of hydration on shale reservoirs is complex, as it can not only improve porosity and permeability, but also lead to reservoir instability. At present, there is a lack of systematic [...] Read more.
In the process of the exploration and development of shale oil, the influence of hydration on shale reservoirs is complex, as it can not only improve porosity and permeability, but also lead to reservoir instability. At present, there is a lack of systematic understanding of the influence of hydration on the physical and chemical properties of shale oil reservoirs. Therefore, in this study, taking the Gulong shale oil reservoir in Songliao Basin as the research object, X-ray diffraction mineral composition analysis, electron microscope scanning, and micro-CT scanning were used to study the micro–macro-changes in shale caused by hydration, and the effects of different fracturing fluids on hydration were evaluated. The results show the following: (1) Hydration increases the porosity and permeability of Gulong shale through clay dispersion and dissolution pore formation, though these transient effects may compromise long-term reservoir stability due to pore-throat clogging. (2) Prolonged hydration significantly enhanced pore structure complexity, with tortuosity increasing by 64.7% (from 2.19 to 3.60) and the fractal dimension rising by 7.5% (from 1.99 to 2.14) with hydration time, and the proportion of larger pores (50–100 μm) increased significantly. (3) Hydration leads to crack propagation and new cracks, and the intersection of cracks reduces the core strength, which may eventually lead to macroscopic damage. (4) The influence of different fracturing fluids on the hydration reaction is obviously different. The higher the concentration, the stronger the hydration effect. Distilled water helps to increase porosity and permeability, but long-term effects may affect reservoir stability. The results of this paper reveal the changes in micro- and macro-characteristics of shale oil reservoirs under hydration, which is of great significance for analyzing the mechanism of hydration and provides theoretical support for improving shale oil recovery. Full article
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33 pages, 7573 KB  
Article
A Stochastic Framework for Mineral Resource Uncertainty Quantification and Management at Compañía Minera Doña Inés de Collahuasi
by Alejandro Cáceres, Xavier Emery, Felipe Ibarra, Jorge Pérez, Sebastián Seguel, Gonzalo Fuster, Andrés Pérez and Rodrigo Riquelme
Minerals 2025, 15(8), 855; https://doi.org/10.3390/min15080855 - 13 Aug 2025
Cited by 1 | Viewed by 21992
Abstract
Mineral resource classification plays a critical role in communicating confidence levels, yet supporting methodologies such as drill-hole spacing analysis and geostatistical simulations are not consistently applied in routine updates of deterministic resource models. As a result, both local and global uncertainty quantification remain [...] Read more.
Mineral resource classification plays a critical role in communicating confidence levels, yet supporting methodologies such as drill-hole spacing analysis and geostatistical simulations are not consistently applied in routine updates of deterministic resource models. As a result, both local and global uncertainty quantification remain underutilized, and drilling requirements are often defined without a clear link to uncertainty reduction. This paper introduces a mineral resource uncertainty and drilling policy framework developed and applied at Compañía Minera Doña Inés de Collahuasi (CMDIC). The framework quantifies the uncertainty of each mineral resource model update when new data are available and provides an initial approach to determining drilling requirements based on CMDIC’s risk acceptance policies for different project stages. The proposed approach is a stochastic workflow that uses the current deterministic mineral resource model and database to generate geostatistical simulations. These simulations account for data quality, quantity, geological variability, and copper-grade variability. They form the basis for mineral resource classification with an explicit uncertainty quantification and provide an optimized drilling campaign to achieve desired risk levels subject to budget constraints. Because stochastic modeling updates faster than deterministic modeling, it provides timely insights from new drilling campaigns and delivers valuable insights for subsequent deterministic geological and grade modeling updates. The implementation of this workflow demonstrates its feasibility as a standard step following deterministic modeling, leading to cost-effective mineral resource development and management by aligning technical practices with the organization’s strategic objectives and risk preferences. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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39 pages, 13361 KB  
Article
Mineralogical, Petrological, 3D Modeling Study and Geostatistical Mineral Resources Estimation of the Zone C Gold Prospect, Kofi (Mali)
by Jean-Jacques Royer and Niakalé Camara
Minerals 2025, 15(8), 843; https://doi.org/10.3390/min15080843 - 8 Aug 2025
Viewed by 1692
Abstract
A 3D model integrating mineralogical, petrological, and geostatistical resource estimation was developed for Zone C of the Kofi Birimian gold deposit in Western Mali. Petrographic analysis identified two forms of gold mineralization: (i) native gold or electrum inclusions within pyrite, and (ii) disseminated [...] Read more.
A 3D model integrating mineralogical, petrological, and geostatistical resource estimation was developed for Zone C of the Kofi Birimian gold deposit in Western Mali. Petrographic analysis identified two forms of gold mineralization: (i) native gold or electrum inclusions within pyrite, and (ii) disseminated native gold along pyrite fractures. Four types of hydrothermal alteration–epidotization, chloritization, carbonatization, and albitization were observed microscopically. Statistical analysis of geochemical data classified five lithologies: mafic dyke, felsic dyke, diabase, faulted breccia, and intermediate quartz diorite. Minerals identified petrographically were corroborated by multivariate correlations among elements (Cr, Fe, Ni, Al, Ti, Na, and Ca), as revealed by Principal Component Analysis (PCA). A 3D borehole-based model revealed spatial correlations between hydrothermal alteration zones and associated geochemical anomalies, notably tourmalinization (B) and albitization (Na), with the latter serving as a key indicator for new exploration targets. The spatial associations of anomalous Ag, B, Hg, As, and Na commonly linked to tourmalinization suggest favorable zones for gold and silver mineralization. Geostatistical analysis identified isotropic continuous mineralized structures for most elements, including gold. Spherical isotropic variograms with ranges from 35 to 75 m were fitted for in situ resource estimation (e.g., silver ≈ 40 m; gold ≈ 60 m). The resulting estimated resources (indicated + inferred), based on a 1.0 g/t Au cut-off, are 2.476 Mt at 3.5 g/t Au indicated (0.278 Moz or 8.67 t), and 1.254 Mt at 2.78 g/t Au inferred (0.112 Moz or 3.49 t). This study provides a framework for identifying new mineralized zones, and the multidisciplinary approach demonstrates the connections between mineralogy and the information embedded in geochemical datasets, which are revealed through appropriate tools and an understanding of the underlying processes. Full article
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35 pages, 8847 KB  
Article
From Pulp to Froth: Decoding the Role of Nanoparticle Colloidal Silica in Scheelite Flotation as a Calcite Depressant
by Borhane Ben Said, Suvarna Patil, Martin Rudolph, Daniel Goldmann and Lucas Pereira
Minerals 2025, 15(8), 834; https://doi.org/10.3390/min15080834 - 6 Aug 2025
Viewed by 3214
Abstract
Colloidal silica acts as a multifunctional reagent in the froth flotation process of semi-soluble salt-type minerals, enabling the selective depression of calcite. This study investigates its effect on four key minerals—calcite, scheelite, apatite, and fluorite—using a comprehensive suite of techniques to identify the [...] Read more.
Colloidal silica acts as a multifunctional reagent in the froth flotation process of semi-soluble salt-type minerals, enabling the selective depression of calcite. This study investigates its effect on four key minerals—calcite, scheelite, apatite, and fluorite—using a comprehensive suite of techniques to identify the flotation subprocesses modulated by colloidal silica. This work also aims to determine the specific flotation zones affected by colloidal silica, assessing the influence of its dosage, surface modification, and specific surface area on metallurgical outcomes. Atomic force microscopy revealed mineral-specific surface responses to colloidal silica conditioning: calcite exhibited localized nanoparticle adsorption, whereas apatite underwent a dissolution–reprecipitation mechanism. Scheelite and fluorite, in contrast, showed minimal surface modifications. These differences are attributed to variations in surface reactivity, hydration behavior, and crystallographic structure, with calcite offering a uniquely favorable environment for colloidal silica attachment. Mechanistic insights show that colloidal silica—especially the aluminate-modified type with high specific surface area—influences both the pulp and froth zones by producing small, stable bubbles, enhancing fine scheelite recovery, stabilizing froth, and effectively depressing calcite. In contrast, non-functionalized colloidal silica resulted in poor bubble control and unstable froth. These findings elucidate the subprocess-specific mechanisms by which colloidal silica operates and highlight its potential as a tunable, multifunctional reagent for improving selectivity in the flotation of semi-soluble salt-type minerals. Full article
(This article belongs to the Special Issue Application of Nanomaterials in Mineral Processing)
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22 pages, 5351 KB  
Article
Hydrometallurgical Leaching of Copper and Cobalt from a Copper–Cobalt Ore by Aqueous Choline Chloride-Based Deep Eutectic Solvent Solutions
by Emmanuel Anuoluwapo Oke, Yorkabel Fedai and Johannes Hermanus Potgieter
Minerals 2025, 15(8), 815; https://doi.org/10.3390/min15080815 - 31 Jul 2025
Cited by 5 | Viewed by 2119
Abstract
The sustainable recovery of valuable metals such as Cu and Co from ores is a pressing need considering environmental and economic challenges. Therefore, this study evaluates the effectiveness of deep eutectic solvents (DESs) as alternative leaching agents for Cu and Co extraction. Four [...] Read more.
The sustainable recovery of valuable metals such as Cu and Co from ores is a pressing need considering environmental and economic challenges. Therefore, this study evaluates the effectiveness of deep eutectic solvents (DESs) as alternative leaching agents for Cu and Co extraction. Four DESs were prepared using choline chloride (ChCl) as a hydrogen bond acceptor (HBA) and oxalic acid (OA), ethylene glycol (EG), urea (U) and thiourea (TU) as hydrogen bond donors (HBDs). Leaching experiments were conducted with DESs supplemented with 30 wt.% water at varying temperatures, various solid-to-liquid ratios, and time durations. The ChCl:OA DES demonstrated the highest leaching efficiencies among the DESs tested on pure CuO and CoO, achieving 89.2% for Cu and 92.4% for Co (60 °C, 400 rpm, 6 h, −75 + 53 µm particle size, and 1:10 solid-to-liquid ratio). In addition, the dissolution kinetics, analysed using the shrinking core model (SCM), showed that the leaching process was mainly controlled by surface chemical reactions. The activation energy values for Cu and Co leaching were 46.8 kJ mol−1 and 51.4 kJ mol−1, respectively, supporting a surface chemical control mechanism. The results highlight the potential of ChCl:OA as a sustainable alternative for metal recovery. Full article
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31 pages, 29045 KB  
Article
Earliest Cambrian Carbonate Platform Evolution, Environmental Change, and Organic Matter Accumulation in the Northwestern Yangtze Block, South China
by Jincheng Liu, Qingchun Jiang, Yan Zhang, Jingjiang Liu, Yifei Ai, Pengzhen Duan and Guangyou Zhu
Minerals 2025, 15(8), 812; https://doi.org/10.3390/min15080812 - 31 Jul 2025
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Abstract
The earliest Cambrian (ca., 538.8–524.8 Ma) was an important period in geological history witnessing significant environmental change, during which organic-rich facies were developed in the Yangtze Platform, South China. However, the contemporaneous paleogeographic and stratigraphic framework within which the environmental change and organic [...] Read more.
The earliest Cambrian (ca., 538.8–524.8 Ma) was an important period in geological history witnessing significant environmental change, during which organic-rich facies were developed in the Yangtze Platform, South China. However, the contemporaneous paleogeographic and stratigraphic framework within which the environmental change and organic matter accumulation took place remains poorly understood. We investigate this based on facies, sequence stratigraphic, and geochemical analyses of the lowermost Cambrian Maidiping and Zhujiaqing formations in the northwestern Yangtze Block. The results show that the terminal Ediacaran rimmed platform changed into a foredeep carbonate ramp and backbulge basin after the onset of the earliest Cambrian transgression. Across the Ediacaran–Cambrian boundary, the shallow-marine redox condition rapidly transitioned from relative euxinia to an oxygen-rich state. During the late transgression to highstand normal regression, the foredeep carbonate ramp expanded to the cratonic interior, and nutrients brought by intensified continental weathering and upwelling promoted significant phytoplankton proliferation, an increase in oxygen level and primary productivity, and then organic matter enrichment. During the forced regression, the carbonate ramp gradually changed into a rimmed platform. The weakening continental weathering and expanding anoxic area during the forced to lowstand normal regression led to the significant organic carbon burial in the foredeep basin. Full article
(This article belongs to the Special Issue Organic Petrology and Geochemistry: Exploring the Organic-Rich Facies)
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26 pages, 8845 KB  
Article
Occurrence State and Genesis of Large Particle Marcasite in a Thick Coal Seam of the Zhundong Coalfield in Xinjiang
by Xue Wu, Ning Lü, Shuo Feng, Wenfeng Wang, Jijun Tian, Xin Li and Hayerhan Xadethan
Minerals 2025, 15(8), 816; https://doi.org/10.3390/min15080816 - 31 Jul 2025
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Abstract
The Junggar Basin contains a large amount of coal resources and is an important coal production base in China. The coal seam in Zhundong coalfield has a large single-layer thickness and high content of inertinite, but large particle Fe-sulphide minerals are associated with [...] Read more.
The Junggar Basin contains a large amount of coal resources and is an important coal production base in China. The coal seam in Zhundong coalfield has a large single-layer thickness and high content of inertinite, but large particle Fe-sulphide minerals are associated with coal seams in some mining areas. A series of economic and environmental problems caused by the combustion of large-grained Fe-sulphide minerals in coal have seriously affected the economic, clean and efficient utilization of coal. In this paper, the ultra-thick coal seam of the Xishanyao formation in the Yihua open-pit mine of the Zhundong coalfield is taken as the research object. Through the analysis of coal quality, X-ray fluorescence spectrometer test of major elements in coal, inductively coupled plasma mass spectrometry test of trace elements, SEM-Raman identification of Fe-sulphide minerals in coal and LA-MC-ICP-MS test of sulfur isotope of marcasite, the coal quality characteristics, main and trace element characteristics, macro and micro occurrence characteristics of Fe-sulphide minerals and sulfur isotope characteristics of marcasite in the ultra-thick coal seam of the Xishanyao formation are tested. On this basis, the occurrence state and genesis of large particle Fe-sulphide minerals in the ultra-thick coal seam of the Xishanyao formation are clarified. The main results and understandings are as follows: (1) the occurrence state of Fe-sulphide minerals in extremely thick coal seams is clarified. The Fe-sulphide minerals in the extremely thick coal seam are mainly marcasite, and concentrated in the YH-2, YH-3, YH-8, YH-9, YH-14, YH-15 and YH-16 horizons. Macroscopically, Fe-sulphide minerals mainly occur in three forms: thin film Fe-sulphide minerals, nodular Fe-sulphide minerals, and disseminated Fe-sulphide minerals. Microscopically, they mainly occur in four forms: flake, block, spearhead, and crack filling. (2) The difference in sulfur isotope of marcasite was discussed, and the formation period of marcasite was preliminarily divided. The overall variation range of the δ34S value of marcasite is wide, and the extreme values are quite different. The polyflake marcasite was formed in the early stage of diagenesis and the δ34S value was negative, while the fissure filling marcasite was formed in the late stage of diagenesis and the δ34S value was positive. (3) The coal quality characteristics of the thick coal seam were analyzed. The organic components in the thick coal seam are mainly inertinite, and the inorganic components are mainly clay minerals and marcasite. (4) The difference between the element content in the thick coal seam of the Zhundong coalfield and the average element content of Chinese coal was compared. The major element oxides in the thick coal seam are mainly CaO and MgO, followed by SiO2, Al2O3, Fe2O3 and Na2O. Li, Ga, Ba, U and Th are enriched in trace elements. (5) The coal-accumulating environment characteristics of the extremely thick coal seam are revealed. The whole thick coal seam is formed in an acidic oxidation environment, and the horizon with Fe-sulphide minerals is in an acidic reduction environment. The acidic reduction environment is conducive to the formation of marcasite and is not conducive to the formation of pyrite. (6) There are many matrix vitrinite, inertinite content, clay content, and terrigenous debris in the extremely thick coal seam. The good supply of peat swamp, suitable reduction environment and pH value, as well as groundwater leaching and infiltration, together cause the occurrence of large-grained Fe-sulphide minerals in the extremely thick coal seam of the Xishanyao formation in the Zhundong coalfield. Full article
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31 pages, 10410 KB  
Article
Integrated Prospectivity Mapping for Copper Mineralization in the Koldar Massif, Kazakhstan
by Dinara Talgarbayeva, Andrey Vilayev, Elmira Serikbayeva, Elmira Orynbassarova, Hemayatullah Ahmadi, Zhanibek Saurykov, Nurmakhambet Sydyk, Aigerim Bermukhanova and Berik Iskakov
Minerals 2025, 15(8), 805; https://doi.org/10.3390/min15080805 - 30 Jul 2025
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Abstract
This study developed a copper mineral prospectivity map for the Koldar massif, Kazakhstan, using an integrated approach combining geophysical and satellite methods. A strong spatialgenetic link was identified between faults and hydrothermal mineralization, with faults acting as key conduits for ore-bearing fluids. Lineament [...] Read more.
This study developed a copper mineral prospectivity map for the Koldar massif, Kazakhstan, using an integrated approach combining geophysical and satellite methods. A strong spatialgenetic link was identified between faults and hydrothermal mineralization, with faults acting as key conduits for ore-bearing fluids. Lineament analysis and density mapping confirmed the high permeability of the Koldar massif, indicating its structural prospectivity. Hyperspectral and multispectral data (ASTER, PRISMA, WorldView-3) were applied for detailed mapping of hydrothermal alteration (phyllic, propylitic, argillic zones), which are critical for discovering porphyry copper deposits. In particular, WorldView-3 imagery facilitated the identification of new prospective zones. The transformation of magnetic and gravity data successfully delineated geological features and structural boundaries, confirming the fractured nature of the massif, a key structural factor for mineralization. The resulting map of prospective zones, created by normalizing and integrating four evidential layers (lineament density, PRISMA-derived hydrothermal alteration, magnetic, and gravity anomalies), is thoroughly validated, successfully outlining the known Aktogay, Aidarly, and Kyzylkiya deposits. Furthermore, new, previously underestimated prospective areas were identified. This work fills a significant knowledge gap concerning the Koldar massif, which had not been extensively studied using satellite methods previously. The key advantage of this research lies in its comprehensive approach and the successful application of high-quality hyperspectral imagery for mapping new prospective zones, offering a cost-effective and efficient alternative to traditional ground-based investigations. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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20 pages, 6964 KB  
Article
Mineralogical Analysis of Factors Affecting the Grade of High-Gradient Magnetic Separation Concentrates and Experimental Study on TiO2 Enrichment Using ARC
by Yifei Liu, Zhenqiang Liu, Yuhua Wang, Yuxin Zhang and Dongfang Lu
Minerals 2025, 15(8), 799; https://doi.org/10.3390/min15080799 - 30 Jul 2025
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Abstract
High-gradient magnetic separation is a key step in the pre-concentration of ilmenite before flotation, particularly in the gravity separation process. However, as the amount of weakly magnetic gangue minerals increases, the grade of the coarse concentrate from high-gradient magnetic separation decreases. This paper [...] Read more.
High-gradient magnetic separation is a key step in the pre-concentration of ilmenite before flotation, particularly in the gravity separation process. However, as the amount of weakly magnetic gangue minerals increases, the grade of the coarse concentrate from high-gradient magnetic separation decreases. This paper investigates the mineralogical factors affecting the enrichment efficiency of high-gradient magnetic separation. Additionally, a newly developed stirred fluidized bed device, an agitated reflux classifier (ARC), was successfully applied to remove weakly magnetic gangue minerals that are difficult to separate by high-gradient magnetic separation (HGMS). For low-grade ilmenite with a feed grade of 3.97%, a combined process of magnetic separation and gravity separation was employed, achieving a concentrate with a grade of 16.50% and a recovery rate of 54.11%. This concentrate meets the requirements for flotation feed. This study provides a new approach for the beneficiation of low-grade ilmenite. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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10 pages, 1262 KB  
Communication
Gold as Pollution Tracer in Holocene Sediments of the Doñana National Park, the Largest Biological Reserve in Europe
by Verónica Romero, Francisco Ruiz, María Luz González-Regalado, María Isabel Carretero, Manuel Pozo, Guadalupe Monge, Luis Miguel Cáceres, Joaquín Rodríguez Vidal, Manuel Abad, Tatiana Izquierdo, Antonio Toscano, Paula Gómez and Gabriel Gómez
Minerals 2025, 15(8), 801; https://doi.org/10.3390/min15080801 - 30 Jul 2025
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Abstract
Estuaries are excellent containers for the prehistorical and historical pollution that develops in their river basins. This paper studies the Au contents obtained by inductively coupled plasma spectrometry of two cores extracted from the Doñana National Park (Guadalquivir Estuary, SW Spain). Concentrations of [...] Read more.
Estuaries are excellent containers for the prehistorical and historical pollution that develops in their river basins. This paper studies the Au contents obtained by inductively coupled plasma spectrometry of two cores extracted from the Doñana National Park (Guadalquivir Estuary, SW Spain). Concentrations of this precious metal have been associated with the different prehistoric and historical stages of exploitation of the Iberian Pyritic Belt. The three detected peaks correspond to the first mining operations in the area around the park, the first systematic Tartessian mining and strong exploitation during the Roman period. Consequently, Au is an appropriate marker of the contamination phases prior to its current extraordinary biological diversity. Full article
(This article belongs to the Section Environmental Mineralogy and Biogeochemistry)
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25 pages, 15689 KB  
Article
Mineralogical and Chemical Properties and REE Content of Bauxites in the Seydişehir (Konya, Türkiye) Region
by Muazzez Çelik Karakaya and Necati Karakaya
Minerals 2025, 15(8), 798; https://doi.org/10.3390/min15080798 - 29 Jul 2025
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Abstract
The most important bauxite deposits in Türkiye are located in the Seydişehir (Konya) and Akseki (Antalya) regions, situated along the western Taurus Mountain, with a total reserve of approximately 44 million tons. Some of the bauxite deposits have been exploited for alumina since [...] Read more.
The most important bauxite deposits in Türkiye are located in the Seydişehir (Konya) and Akseki (Antalya) regions, situated along the western Taurus Mountain, with a total reserve of approximately 44 million tons. Some of the bauxite deposits have been exploited for alumina since the 1970s. In this study, bauxite samples, collected from six different deposits were examined to determine their mineralogical and chemical composition, as well as their REE content, with the aim of identifying which bauxite types are enriched in REEs and assessing their economic potential. The samples included massive, oolitic, and brecciated bauxite types, which were analyzed using optical microscopy, X-ray diffraction (XRD), X-ray fluorescence (XRF) and inductive coupled plasma-mass spectrometry (ICP-MS), field emission scanning electron microscopy (FESEM-EDX), and electron probe micro-analysis (EPMA). Massive bauxites were found to be more homogeneous in both mineralogical and chemical composition, predominantly composed of diaspore, boehmite, and rare gibbsite. Hematite is the most abundant iron oxide mineral in all bauxites, while goethite, rutile, and anatase occur in smaller quantities. Quartz, feldspar, kaolinite, dolomite, and pyrite were specifically determined in brecciated bauxites. Average oxide contents were determined as 52.94% Al2O3, 18.21% Fe2O3, 7.04% TiO2, and 2.69% SiO2. Na2O, K2O, and MgO values are typically below 0.5%, while CaO averages 3.54%. The total REE content of the bauxites ranged from 161 to 4072 ppm, with an average of 723 ppm. Oolitic-massive bauxites exhibit the highest REE enrichment. Cerium (Ce) was the most abundant REE, ranging from 87 to 453 ppm (avg. 218 ppm), followed by lanthanum (La), which reached up to 2561 ppm in some of the massive bauxite samples. LREEs such as La, Ce, Pr, and Nd were notably enriched compared to HREEs. The lack of a positive correlation between REEs and major element oxides, as well as with their occurrences in distinct association with Al- and Fe-oxides-hydroxides based on FESEM-EDS and EPMA analyses, suggests that the REEs are present as discrete mineral phases. Furthermore, these findings indicate that the REEs are not incorporated into the crystal structures of other minerals through isomorphic substitution or adsorption. Full article
(This article belongs to the Special Issue Critical Metal Minerals, 2nd Edition)
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39 pages, 8119 KB  
Article
Magmatic Redox Evolution and Porphyry–Skarn Transition in Multiphase Cu-Mo-W-Au Systems of the Eocene Tavşanlı Belt, NW Türkiye
by Hüseyin Kocatürk, Mustafa Kumral, Hüseyin Sendir, Mustafa Kaya, Robert A. Creaser and Amr Abdelnasser
Minerals 2025, 15(8), 792; https://doi.org/10.3390/min15080792 - 28 Jul 2025
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Abstract
This study explores the magmatic and hydrothermal evolution of porphyry–skarn–transitional Cu-Mo-W-Au systems within the Nilüfer Mineralization Complex (NMC), located in the westernmost segment of the Eocene Tavşanlı Metallogenic Belt, NW Türkiye. Through integration of field data, whole-rock geochemistry, Re–Os molybdenite dating, and amphibole–biotite [...] Read more.
This study explores the magmatic and hydrothermal evolution of porphyry–skarn–transitional Cu-Mo-W-Au systems within the Nilüfer Mineralization Complex (NMC), located in the westernmost segment of the Eocene Tavşanlı Metallogenic Belt, NW Türkiye. Through integration of field data, whole-rock geochemistry, Re–Os molybdenite dating, and amphibole–biotite mineral chemistry, the petrogenetic controls on mineralization across four spatially associated mineralized regions (Kirazgedik, Güneybudaklar, Kozbudaklar, and Delice) were examined. The earliest and thermally most distinct phase is represented by the Kirazgedik porphyry system, characterized by high temperature (~930 °C), oxidized quartz monzodioritic intrusions emplaced at ~2.7 kbar. Rising fO2 and volatile enrichment during magma ascent facilitated structurally focused Cu-Mo mineralization. At Güneybudaklar, Re–Os geochronology yields an age of ~49.9 Ma, linking Mo- and W-rich mineralization to a transitional porphyry–skarn environment developed under moderately oxidized (ΔFMQ + 1.8 to +0.5) and hydrous (up to 7 wt.% H2O) magmatic conditions. Kozbudaklar represents a more reduced, volatile-poor skarn system, leading to Mo-enriched scheelite mineralization typical of late-stage W-skarns. The Delice system, developed at the contact of felsic cupolas and carbonates, records the broadest range of redox and fluid compositions. Mixed oxidized–reduced fluid signatures and intense fluid–rock interaction reflect complex, multistage fluid evolution involving both magmatic and external inputs. Geochemical and mineralogical trends—from increasing silica and Rb to decreasing Sr and V—trace a systematic evolution from mantle-derived to felsic, volatile-rich magmas. Structurally, mineralization is controlled by oblique fault zones that localize magma emplacement and hydrothermal flow. These findings support a unified genetic model in which porphyry and skarn mineralization styles evolved continuously from multiphase magmatic systems during syn-to-post-subduction processes, offering implications for exploration models in the Western Tethyan domain. Full article
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