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Polymers, Volume 17, Issue 5

2025 March-1 - 152 articles

Cover Story: The polymer industry has embraced the move towards sustainability to reduce dependency on fossil fuels. The use of renewable feedstocks, such as lignin, has been shown to be a promising alternative to fossil fuels. In this study, biobased organic diols derived from phenolic aldehyde by-products in the depolymerization of lignin for the synthesis of polyesters and polyurethanes are described, including the preparation of polyester polyols and polyurethane foams. View this paper
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Articles (152)

  • Article
  • Open Access
2,013 Views
12 Pages

6 March 2025

Rigid polyurethane-based foam is an ideal choice for sandwich-panel-filling materials due to its high strength, low thermal conductivity, high adhesion, and high chemical resistivity. Since sandwich panel materials often face cyclic mechanical loads...

  • Article
  • Open Access
3 Citations
1,386 Views
19 Pages

Investigations on Thermal Transitions in PDPP4T/PCPDTBT/AuNPs Composite Films Using Variable Temperature Ellipsometry

  • Paweł Jarka,
  • Barbara Hajduk,
  • Pallavi Kumari,
  • Henryk Janeczek,
  • Marcin Godzierz,
  • Yao Mawuena Tsekpo and
  • Tomasz Tański

6 March 2025

Herein, we report a comprehensive investigation on the thermal transitions of thin films of poly [2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione -3,6-diyl)-alt-(2,2′;5′,2″;5″,2′″-quaterthiophen-5,5&p...

  • Article
  • Open Access
11 Citations
3,084 Views
17 Pages

Bicomponent Electrospinning of PVDF-Based Nanofiber Membranes for Air Filtration and Oil–Water Separation

  • Tianxue Feng,
  • Lin Fu,
  • Zhimei Mu,
  • Wenhui Wei,
  • Wenwen Li,
  • Xiu Liang,
  • Liang Ma,
  • Yitian Wu,
  • Xiaoyu Wang and
  • Xingshuang Zhang
  • + 3 authors

6 March 2025

Particulate matter (PM) and water pollution have posed serious hazards to human health. Nanofiber membranes (NFMs) have emerged as promising candidates for the elimination of PMs and the separation of oil–water mixtures. In this study, a polyvi...

  • Article
  • Open Access
2 Citations
1,752 Views
27 Pages

6 March 2025

The study examined the sustained release of neem from the polymeric carrier system chitosan by varying the drug content, ionic strength of the release medium, and pH. Six different kinetic models, i.e., Korsmeyer–Peppas (KP), Peppas–Sahli...

  • Article
  • Open Access
2 Citations
3,901 Views
16 Pages

Identification of Aged Polypropylene with Machine Learning and Near–Infrared Spectroscopy for Improved Recycling

  • Keyu Zhu,
  • Delong Wu,
  • Songwei Yang,
  • Changlin Cao,
  • Weiming Zhou,
  • Qingrong Qian and
  • Qinghua Chen

6 March 2025

The traditional plastic sorting process primarily relies on manual operations, which are inefficient, pose safety risks, and result in suboptimal separation efficiency for mixed waste plastics. Near–infrared (NIR) spectroscopy, with its rapid a...

  • Article
  • Open Access
2 Citations
1,459 Views
16 Pages

6 March 2025

Stimuli-responsive polymeric nanostructures are compelling vectors for a wide range of application opportunities. The objective we sought was to broaden the array of self-assembling amphiphilic copolymers with stimuli-responsive characteristics by in...

  • Article
  • Open Access
1 Citations
2,190 Views
21 Pages

Influence of Surface Treatment and Protracted Ageing on the Shear Bond Strength of Orthodontic Brackets to Two Digitally Fabricated (Milled and 3D-Printed) Polymethacrylate-Based Provisional Crowns

  • Nisreen Nabiel Hassan,
  • Khurshid Mattoo,
  • Atheer Khawaji,
  • Hanan Najmi,
  • Almaha Sadeli,
  • Ahid Amer Alshahrani,
  • Abeer Ali Qahtani,
  • Abdullah Hasan Alshehri,
  • Mai Almarzouki and
  • Mohammed E. Sayed

6 March 2025

This study determined the influence of surface treatment and protracted ageing on the shear bond strength (SBS) of orthodontic brackets bonded to CADCAM (milled) and 3D-printed polymethylmethacrylate (PMMA) provisional crowns (PCs). Eighty disc-shape...

  • Article
  • Open Access
1 Citations
1,413 Views
20 Pages

6 March 2025

The viscoelastic behavior of asphalt mixtures is a crucial consideration in the analysis of pavement mechanical responses and structural design. This study aims to elucidate the molecular structure and component evolution trends of polyphosphoric aci...

  • Article
  • Open Access
6 Citations
3,538 Views
16 Pages

Utilizing Essential Oil Components as Natural Antifungal Preservatives in the Active Packaging of Bread

  • Konstantinos Safakas,
  • Georgia C. Lainioti,
  • George Tsiamis,
  • Panagiota Stathopoulou and
  • Athanasios Ladavos

6 March 2025

The use of essential oil components as natural antifungal preservatives in the active packaging of bread is an innovative approach that leverages the antimicrobial properties of these compounds to extend the shelf life of bread and ensure its safety....

  • Article
  • Open Access
2 Citations
1,237 Views
18 Pages

5 March 2025

This research examines the free vibration characteristics of composite ring-like structures enhanced with carbon nanotubes (CNTs), taking into account the effects of CNT agglomeration. The structural framework comprises two concentric composite rings...

  • Article
  • Open Access
5 Citations
2,245 Views
14 Pages

Self-Toughened Epoxy Resin via Hybridization of Structural Isomeric Curing Agents

  • Woong Kwon,
  • Jiyeon Cheon,
  • Hei Je Jeong,
  • Jong Sung Won,
  • Byeong-Joo Kim,
  • Man Young Lee,
  • Seung Geol Lee and
  • Euigyung Jeong

5 March 2025

Fracture toughness is a key property of epoxy resins with a high glass transition temperature (Tg), used in carbon fiber/epoxy composites for aerospace applications. Conventional toughening methods rely on adding toughening agents, often compromising...

  • Article
  • Open Access
22 Citations
4,781 Views
29 Pages

Machine Learning-Driven Prediction of Composite Materials Properties Based on Experimental Testing Data

  • Khrystyna Berladir,
  • Katarzyna Antosz,
  • Vitalii Ivanov and
  • Zuzana Mitaľová

5 March 2025

The growing demand for high-performance and cost-effective composite materials necessitates advanced computational approaches for optimizing their composition and properties. This study aimed at the application of machine learning for the prediction...

  • Article
  • Open Access
7 Citations
2,671 Views
15 Pages

Development and Characterization of Antimicrobial Chitosan/Polyethylene Oxide/Bacterial Cellulose Nanofibers

  • Fatma Sude Cetin,
  • Tubanur Avci,
  • Emre Uygur,
  • Elif Ilhan,
  • Elif Kaya,
  • Gulgun Bosgelmez Tinaz,
  • Liviu Duta,
  • Canan Dogan and
  • Oguzhan Gunduz

5 March 2025

This study introduces novel chitosan (CS) and polyethylene oxide (PEO) copolymers reinforced with bacterial cellulose (BC) to fabricate nanofibers using the electrospinning method. SEM analysis confirmed uniform nanofiber formation, with CS/PEO/BC na...

  • Article
  • Open Access
1 Citations
1,509 Views
14 Pages

5 March 2025

Sustainable agriculture increasingly relies on biocontrol agents as eco-friendly solutions to combat plant diseases while improving soil health. In this context, species of the genus Bacillus, particularly Bacillus subtilis, have shown promise as eff...

  • Article
  • Open Access
1 Citations
1,464 Views
15 Pages

The Environmental Analysis of the Post-Use Management Scenarios of the Heat-Shrinkable Film

  • Patrycja Walichnowska,
  • Józef Flizikowski,
  • Andrzej Tomporowski,
  • Marek Opielak and
  • Wojciech Cieślik

5 March 2025

The post-use management of plastic films, including shrink films, poses a significant environmental and technological challenge for the industry. Due to their durability and difficulty in degradation, these wastes contribute to environmental pollutio...

  • Article
  • Open Access
3 Citations
1,991 Views
15 Pages

Moisture-Driven Morphology Changes in the Thermal and Dielectric Properties of TPU-Based Syntactic Foams

  • Sabarinathan Pushparaj Subramaniyan,
  • Partha Pratim Das,
  • Rassel Raihan and
  • Pavana Prabhakar

5 March 2025

Syntactic foams are a promising candidate for applications in marine, oil and gas industries in underwater cables and pipelines due to their excellent insulation properties. The effective transmission of electrical energy through cables requires insu...

  • Article
  • Open Access
2,194 Views
19 Pages

4 March 2025

The removal of surface residues from single-layer graphene (SLG), including poly(methyl methacrylate) (PMMA) polymers and Cl ions, during the transfer process remains a significant challenge with regard to preserving the intrinsic properties o...

  • Article
  • Open Access
1,152 Views
12 Pages

4 March 2025

Following the concept of “waste into resources”, a mild and controllable light grafting technique was used to immobilize pancreatic lipase (PPL) in situ on modified organic, chromium-free tanned leather scraps to catalyze the hydrolysis o...

  • Article
  • Open Access
2 Citations
2,688 Views
17 Pages

Biopolymer-Based Microencapsulation of Procyanidins from Litchi Peel and Coffee Pulp: Characterization, Bioactivity Preservation, and Stability During Simulated Gastrointestinal Digestion

  • María de los Ángeles Vázquez-Nuñez,
  • Nuria E. Rocha-Guzmán,
  • Pedro Aguilar-Zárate,
  • Romeo Rojas,
  • Guillermo Cristian G. Martínez-Ávila,
  • Abigail Reyes and
  • Mariela R. Michel

4 March 2025

The need for encapsulation processes in compounds such as procyanidins (PCs) is related to their functional stability, which may limit their application in functional foods. The aim of this study was to evaluate the in vitro digestion of microencapsu...

  • Article
  • Open Access
1 Citations
2,458 Views
14 Pages

Use of Natamycin for the Development of Polymer Systems with Antifungal Activity for Packaging Applications

  • Vincenzo Titone,
  • Manuela Ceraulo,
  • Francesco Lopresti,
  • Giuliana Garofalo,
  • Raimondo Gaglio,
  • Maria Chiara Mistretta and
  • Luigi Botta

4 March 2025

Recently, there has been a rapid growth in the use of biodegradable polymers as alternatives to petroleum-based polymers, particularly in the packaging sector, to reduce environmental pollution. In this scenario, the aim of this work was to study the...

  • Article
  • Open Access
1,790 Views
22 Pages

Unraveling of Poly(lactic acid) (PLA)/Natural Wax/Titanium Dioxide Nanoparticle Composites for Disposable Plastic Applications

  • Jacqueline Guadalupe Bocarando-Chacón,
  • Iván Alziri Estrada-Moreno,
  • Imelda Olivas-Armendáriz,
  • Alejandro Vega-Rios and
  • Mónica Elvira Mendoza-Duarte

4 March 2025

The present research is a comprehensive study that developed poly(lactic acid) PLA/natural wax (Wx)/non-functionalized titanium dioxide nanoparticles (TiO2-NF) and PLA/Wx/titanium dioxide nanoparticles functionalized with triethoxysilane (TiO2-F) com...

  • Article
  • Open Access
1,417 Views
15 Pages

Highly Branched Poly(Adipic Anhydride-Co-Mannitol Adipate): Synthesis, Characterization, and Thermal Properties

  • Mahir A. Jalal,
  • Einas A. Abood,
  • Zainab J. Sweah,
  • Hadi S. Al-Lami,
  • Alyaa Abdulhasan Abdulkarem and
  • Haider Abdulelah

4 March 2025

In this study, modification of poly(adipic anhydride) through branching its chains was carried out via melt condensation polymerization with D-mannitol. The percentage of mannitol was varied (3, 4, 5, 10, 15, and 20 Wt.%) and the resulting copolymers...

  • Article
  • Open Access
2 Citations
1,459 Views
23 Pages

4 March 2025

Food waste has a significant social impact but can be revalued as a source of bioactive compounds, such as condensed tannins. This abundant biomass, corresponding to a polymeric antioxidant, must be depolymerized to become bioavailable. Previous stud...

  • Article
  • Open Access
1,797 Views
19 Pages

4 March 2025

Recent advancements in smart textiles have facilitated their extensive application in wearable health monitoring, particularly in brain activity measurement. This study introduces a flexible and washable fabric dry electroencephalography (EEG) electr...

  • Article
  • Open Access
1 Citations
2,676 Views
25 Pages

4 March 2025

Frontal polymerization (FP) technology has attracted significant attention as an efficient, low-energy curing method for thermosetting resins. By enabling self-sustaining polymerization reactions, FP significantly reduces curing time and minimizes ex...

  • Article
  • Open Access
1,414 Views
14 Pages

4 March 2025

Josef Albers’ Structural Constellations series, created between 1948 and 1966, represents a pioneering exploration of plastic laminates as an artistic medium. Leveraging the unique properties of these materials, including their smooth surfaces,...

  • Article
  • Open Access
1,460 Views
15 Pages

4 March 2025

Bamboo, recognized as a nutrient-dense biomass material, exhibits a high susceptibility to mold infestations, which can result in discoloration and a notable decrease in longevity, thereby posing potential health risks to humans. In this study, melam...

  • Article
  • Open Access
1,876 Views
22 Pages

Dissipative Particle Dynamics: Simulation of Chitosan–Citral Microcapsules

  • Wensheng Wu,
  • Zhiwei Li,
  • Dachun Feng,
  • Qing Tang,
  • Shuijiao Liu and
  • Wenjing Lin

3 March 2025

In this paper, the dissipative particle dynamics (DPD) method is used to simulate the self-assembly process, appearance, mesoscopic structure, and wrapping properties of microcapsules formed with citral as the core material and chitosan and sodium al...

  • Article
  • Open Access
11 Citations
2,562 Views
28 Pages

3 March 2025

Fused filament fabrication (FFF) has recently emerged as a sustainable digital manufacturing technology to fabricate polymer composite parts with complex structures and minimal waste. However, FFF-printed composite parts frequently exhibit heterogene...

  • Article
  • Open Access
4 Citations
2,019 Views
11 Pages

Biofilm Formation on Three High-Performance Polymeric CAD/CAM Composites: An In Vitro Study

  • Sarah Almuhayya,
  • Reema Alshahrani,
  • Rehaf Alsania,
  • Alhanoof Albassam,
  • Hammad Alnemari and
  • Rua Babaier

3 March 2025

Reinforced polymeric materials are investigated as novel non-metal alternatives for prosthetic frameworks. This study examined the adherence of Streptococcus mutans to three high-performance polymeric (HPP) composites focusing on their microstructura...

  • Article
  • Open Access
10 Citations
2,517 Views
21 Pages

Biodegradation of Polyhydroxybutyrate, Polylactide, and Their Blends by Microorganisms, Including Antarctic Species: Insights from Weight Loss, XRD, and Thermal Studies

  • Volodymyr Skorokhoda,
  • Ihor Semeniuk,
  • Taras Peretyatko,
  • Viktoria Kochubei,
  • Oleksandr Ivanukh,
  • Yuriy Melnyk and
  • Yurij Stetsyshyn

2 March 2025

This study explores the biodegradation of polyhydroxybutyrate (PHB), polylactide (PLA), and their blends by 11 bacterial species (including Antarctic strains) and 6 fungal species. Aeration significantly enhanced PHB degradation by mold fungi (Asperg...

  • Article
  • Open Access
2 Citations
1,233 Views
27 Pages

Monte Carlo Micro-Stress Field Simulations in Flax/E-Glass Composite Laminae with Non-Circular Flax Fibres

  • Nenglong Yang,
  • Zhenmin Zou,
  • Constantinos Soutis,
  • Prasad Potluri and
  • Kali Babu Katnam

2 March 2025

This study explores the mechanical behaviour of intra-laminar hybrid flax/E-glass composites, focusing on the role of micro-scale irregularities in flax fibres. By employing computational micromechanics and Monte Carlo simulations, it analyses the in...

  • Article
  • Open Access
2 Citations
1,305 Views
16 Pages

Experimental Investigation on the Application of Polymer Agents in Offshore Sandstone Reservoirs: Optimization Design for Enhanced Oil Recovery

  • Yanyue Li,
  • Changlong Liu,
  • Yaqian Zhang,
  • Baoqing Xue,
  • Jinlong Lv,
  • Chuanhui Miao,
  • Yiqiang Li and
  • Zheyu Liu

2 March 2025

The conventional polymer gel has high initial viscosity and short gelation time, making it difficult to meet the requirements of deep profile control in offshore reservoirs with large well spacing and strong heterogeneity. This paper evaluates the pe...

  • Article
  • Open Access
1,575 Views
15 Pages

2 March 2025

We studied the influence of different supporting electrolytes (TBAPF6, TMAPF6, TEAPF6, TBAClO4, and LiClO4) on the morphology of PEDOT films electrochemically polymerized on screen-printed carbon electrodes, as part of which the synthesis of gold nan...

  • Article
  • Open Access
7 Citations
4,664 Views
17 Pages

2 March 2025

3D-printed short-carbon-fiber-reinforced thermoplastic composites have attracted significant attention from both the academic and industrial communities due to their remarkable advantages such as lightweight, high strength, and recyclability. However...

  • Review
  • Open Access
37 Citations
6,529 Views
29 Pages

1 March 2025

This review provides a comprehensive analysis of the role of chemical agents in enhancing the performance of geopolymers for the stabilization and adsorption of heavy metals. Geopolymers, synthesized from aluminosilicate sources activated under alkal...

  • Review
  • Open Access
2 Citations
1,638 Views
28 Pages

28 February 2025

Superabsorbent materials (SAMs), featuring a three-dimensional (3D) hydrophilic polymer network, can absorb and retain water up to thousands of times their own weight, even under pressure. This makes them indispensable in various fields, including hy...

  • Article
  • Open Access
2 Citations
1,266 Views
24 Pages

Experimental Design (24) to Improve the Reaction Conditions of Non-Segmented Poly(ester-urethanes) (PEUs) Derived from α,ω-Hydroxy Telechelic Poly(ε-caprolactone) (HOPCLOH)

  • Jaime Maldonado-Estudillo,
  • Rodrigo Navarro Crespo,
  • Ángel Marcos-Fernández,
  • María Dolores de Dios Caputto,
  • Gustavo Cruz-Jiménez and
  • José E. Báez

28 February 2025

Aliphatic unsegmented polyurethanes (PUs) have garnered relatively limited attention in the literature, despite their valuable properties such as UV resistance and biocompatibility, making them suitable for biomedical applications. This study focuses...

  • Article
  • Open Access
4 Citations
2,754 Views
16 Pages

Citrus Wastes as Source of Pectin and Bioactive Compounds Extracted via One-Pot Microwave Process: An In Situ Path to Modulated Property Control

  • Domenico Zannini,
  • Martina Monteforte,
  • Luca Gargiulo,
  • Tiziana Marino,
  • Giovanna Gomez d’Ayala,
  • Gabriella Santagata and
  • Giovanni Dal Poggetto

28 February 2025

In this paper, citrus pomace was used as a source of pectin and polyphenols extracted in one pot solution by microwave-assisted extraction (MAE) and conventional extraction (CE) methods. MAE parameters were optimized to maximize yield and adjust in s...

  • Article
  • Open Access
1 Citations
2,117 Views
16 Pages

Processing and Characterization of Unidirectional Flax Fiber-Reinforced Bio-Based Polyamide 11 Biocomposites

  • Patrick Hirsch,
  • Benjamin Tillner,
  • André Henkel,
  • Nico Teuscher,
  • Ivonne Jahn and
  • Maik Feldmann

28 February 2025

Within this study, the impregnation behavior and resulting mechanical properties of unidirectional flax fiber-reinforced polyamide 11 biocomposites were investigated. Therefore, different grades of bio-based polyamide 11 have been evaluated regarding...

  • Article
  • Open Access
1,645 Views
12 Pages

28 February 2025

Stearic acid was used to modify the surface of a mixed flame-retardant powder consisting of aluminum hydroxide and ammonium polyphosphate by an uneven nucleation method, aiming to improve its dispersion in a vinyl resin matrix. This study investigate...

  • Article
  • Open Access
2 Citations
1,098 Views
14 Pages

Effect of Poly (Caprolactone) Introduction Site on the Network Structure and Properties of Glycidyl Azide Polymer Adhesive

  • Chengzhao Tu,
  • Zhengyuan Wang,
  • Fengdan Zhu,
  • Dengsheng Yang,
  • Chang Liu,
  • Chaofei Bai,
  • Guoping Li and
  • Yunjun Luo

28 February 2025

Copolymers of glycidyl azide polymer (GAP) and poly (caprolactone) (PCL) were obtained by introducing PCL molecular chains at both ends or side groups of GAP molecular chains, respectively. GAP/PCL elastomers were prepared via polyurethane curing rea...

  • Article
  • Open Access
1 Citations
1,389 Views
16 Pages

Facile Electret Fabrication for Energy Harvesting from Human Gait

  • Michele Zanoletti,
  • Paolo Vitulo,
  • Riccardo Morina,
  • Daniele Callegari,
  • Riccardo Viola,
  • Piercarlo Mustarelli and
  • Maddalena Patrini

28 February 2025

Dielectric elastomer generators (DEGs) are electrostatic transducers capable of harvesting electrical energy from oscillating mechanical parts and storing it in a battery or supercapacitor. The energy conversion element typically consists of a flexib...

  • Article
  • Open Access
2 Citations
3,017 Views
27 Pages

28 February 2025

The genitourinary syndrome of menopause (GSM) is a prevalent condition impacting a substantial number of women globally. Presently, the management of GSM typically entails the administration of estrogen via oral, dermal, or vaginal routes for a prolo...

  • Article
  • Open Access
2 Citations
1,259 Views
12 Pages

28 February 2025

Wearable, non-invasive sweat sensors capable of continuously monitoring the pH of sweat, which is a key indicator related to metabolism and homeostasis level, are highly desirable for personal health management. However, ensuring the stability and ac...

  • Article
  • Open Access
1,676 Views
15 Pages

28 February 2025

Waste stone sludge generated by the extractive industry has traditionally posed significant disposal challenges. This study redefines stone sludge as a valuable raw material by incorporating it into polylactic acid (PLA) to create sustainable composi...

  • Article
  • Open Access
3 Citations
1,380 Views
23 Pages

28 February 2025

Hydroxyl-terminated polyether (HTPE) propellants are attractive in the weapons materials and equipment industry for their insensitive properties. Storage, combustion, and explosion of solid propellants are affected by their mechanical properties, so...

  • Article
  • Open Access
3 Citations
1,516 Views
15 Pages

28 February 2025

In the field of liquid composite moulding (LCM) simulations, a long-standing assumption has dominated–the belief in constant resin viscosity. While effective in many cases, this assumption may not hold for the infusion process, which lasts for...

  • Review
  • Open Access
8 Citations
4,657 Views
37 Pages

Regulatory Frameworks and State-of-the-Art Decontamination Technologies for Recycled Polystyrene for Food Contact Applications

  • Javiera Sepúlveda-Carter,
  • José L. Moreno de Castro,
  • Laura Marín,
  • Paula Baños,
  • Marcos Sánchez Rodríguez and
  • Marina P. Arrieta

28 February 2025

Recycling post-consumer plastics for food contact applications is crucial for the circular economy; however, it presents challenges due to potential contamination and regulatory requirements. This review outlines the current European and U.S. legisla...

  • Article
  • Open Access
1,203 Views
14 Pages

Preservation of Soil Ruins After High Temperatures: Water Absorption and Compressive Strength

  • Miao Li,
  • Yifan Zhang,
  • Zhilin Du,
  • Yao Zheng,
  • Senbiao Liu,
  • Hongjie Luo,
  • Waraz Abdul and
  • Jianfeng Zhu

28 February 2025

Soil ruins hold historical significance and serve as witnesses to past civilizations. High temperatures cause soil moisture to evaporate and soil to shrink, leading to cracking issues and making preservation a global challenge. P(AA-AM-AMPS) (Acrylic...

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Polymers - ISSN 2073-4360