Submit to Special Issue Submit Abstract to Special Issue Review for Polymers Propose a Special Issue

Journal Menu

Journal Browser

► Journal Browser

Modeling of Polymer Composites and Nanocomposites

Print Special Issue Flyer
Special Issue Editors
Special Issue Information
Keywords
Benefits of Publishing in a Special Issue
Published Papers

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Physics and Theory".

Deadline for manuscript submissions: 31 July 2025 | Viewed by 5523

Share This Special Issue

Special Issue Editor

Dr. Rafał Grzejda

E-Mail Website
Guest Editor

Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology in Szczecin, 70-310 Szczecin, Poland
Interests: mechanics of materials; finite element method; joints in mechanical engineering; stiffness of mechanical systems; composite joints
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

In addition to experimental research, materials engineering is now focusing on evaluating the behavior of various composite structures through the use of computational methods and the adoption of FE tools.

This Special Issue of Polymers targets critical findings, advances, and applications of the finite element method in all areas of materials engineering concerning polymer composites and nanocomposites. Papers related to the new developments in finite element analysis with respect to theoretical, computational, and modeling techniques and their applications in science and technology will be included.

Papers that cover a wide range of issues are expected, including (but not limited to) the following:

Finite element analysis;
Structural health monitoring;
Composite connections;
Deformation analysis;
Geometric modeling.

Dr. Rafał Grzejda
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

polymer composites
polymer nanocomposites
material properties
structural morphology
finite element analysis
optimization of composites

Benefits of Publishing in a Special Issue

Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
Reprint: MDPI Books provides the opportunity to republish successful Special Issues in book format, both online and in print.

Further information on MDPI's Special Issue policies can be found here.

Published Papers (9 papers)

Download All Papers

Order results

Result details

Show export options Show export options

Select all

Export citation of selected articles as:

Research

14 pages, 24193 KiB

Open AccessArticle

Influence of Resin Composition on the Photopolymerization of Zirconia Ceramics Fabricated by Digital Light Processing Additive Manufacturing

by Ning Kuang, Hao Qi, Wenjie Zhao and Junfei Wu

Polymers 2025, 17(10), 1354; https://doi.org/10.3390/polym17101354 - 15 May 2025

Viewed by 90

Abstract

Digital light processing (DLP) is widely recognized as one of the most promising additive manufacturing technologies for ceramic fabrication. Nevertheless, during the additive manufacturing of zirconia ceramics, debinding and sintering often lead to structural defects, which severely deteriorate the material properties and hinder their broader application. In this study, we added an oligomer into the photosensitive resin and systematically investigated the effects of oligomer content on the viscosity and curing properties of ceramic suspensions. The results demonstrated that the introduction of oligomers is conducive to enhancing the crosslinking density and reducing defects. Finally, a 45 vol% solid content zirconia ceramic slurry was prepared by adding 20 wt% oligomers to the resin system. After printing, debinding, and sintering, the final zirconia ceramics exhibited a uniform microstructure without delamination or cracks, its bending strength reached 682.4 MPa. This study demonstrates that zirconia ceramics fabricated by photopolymerization with oligomer photosensitive resin exhibit excellent mechanical properties, significantly expanding the potential applications for high-performance zirconia ceramic components with additive manufacturing. Full article

(This article belongs to the Special Issue Modeling of Polymer Composites and Nanocomposites)

► Show Figures

Figure 1

20 pages, 2892 KiB

Open AccessArticle

Untapped Potential of Recycled Thermoplastic Blends in UD Composites via Finite Element Analysis

by Pei Hao, Ninghan Tang, Juan Miguel Tiscar and Francisco A. Gilabert

Polymers 2025, 17(9), 1168; https://doi.org/10.3390/polym17091168 - 25 Apr 2025

Viewed by 260

Abstract

The increasing demand for fully recyclable composites has spurred extensive research on thermoplastics, valued for their recyclability and excellent mechanical properties. High-performance thermoplastics such as PEEK and PPS have been widely adopted in aerospace applications due to their outstanding load-bearing capabilities, which are well documented. Recently, thermoplastic polymer blends have gained attention for their enhanced recyclability and sustainability, as well as their ability to improve thermal stability, viscosity, and manufacturability. However, limited data are available on the mechanical characterization of composites that incorporate these blends, particularly when recycled thermoplastics are used. In this study, we first examine the stress–strain behavior of the following three polymer blends relevant for structural applications: PES/PEEK, PPS/PEEK, and HDPE/PP. We then perform a numerical analysis to predict the mechanical performance of unidirectional fiber-reinforced composites using each blend as the matrix. This involves a micromechanical Representative Volume Element (RVE) approach combined with an advanced polymer model previously validated against experimental data. The findings are discussed to critically assess the suitability of these blends for producing fully matrix-recycled composites. Full article

(This article belongs to the Special Issue Modeling of Polymer Composites and Nanocomposites)

► Show Figures

Figure 1

21 pages, 15989 KiB

Open AccessArticle

Deformation Characterization of Glass Fiber and Carbon Fiber-Reinforced 3D Printing Filaments Using Digital Image Correlation

by Vivien Nemes, Szabolcs Szalai, Brigitta Fruzsina Szívós, Mykola Sysyn, Dmytro Kurhan and Szabolcs Fischer

Polymers 2025, 17(7), 934; https://doi.org/10.3390/polym17070934 - 29 Mar 2025

Viewed by 364

Abstract

The paper offers an in-depth deformation study of glass fiber-reinforced and carbon composite filaments of 3D printers. During the certification, the authors used DIC (Digital Image Correlation) as a full-field strain measurement technique to explore key material traits as a non-contact optical measurement method. The insights captured through the DIC technology enabled to better understand the localized strain distributions during the loading of these reinforced filaments. The paper analyzes the glass fiber and carbon fiber filaments used in 3D printing that are reinforced with these materials and are subjected to bending and compressive loading. The segment presents how loading affects the performance of reinforced filaments when varying such factors as the deposition patterns, layer orientation, and other process parameters. Different types and combinations of reinforcements and printing variables were tested, and the resulting dependencies of mechanical parameters and failure modes were established for each case. Key conclusions demonstrate that the mechanical behavior of both carbon- and glass fiber-reinforced filaments is strongly affected by the 3D printing parameters, particularly infill density, pattern, and build orientation. The application of Digital Image Correlation (DIC) allowed for a precise, full-field analysis of strain distribution and deformation behavior, offering new insights into the structural performance of fiber-reinforced 3D printed composites. The findings from the study provide guidance for the proper choice of filling material and the optimal parameters for the 3D printing process of models with high-performance indexes and seamless applications in the automotive and industrial manufacturing sectors. Full article

(This article belongs to the Special Issue Modeling of Polymer Composites and Nanocomposites)

► Show Figures

Figure 1

14 pages, 20648 KiB

Open AccessArticle

Microcanonical Analysis of Semiflexible Homopolymers with Variable-Width Bending Potential

by Matthew J. Williams and Michael C. Gray

Polymers 2025, 17(7), 906; https://doi.org/10.3390/polym17070906 - 27 Mar 2025

Viewed by 285

Abstract

Understanding the structural dynamics of semiflexible polymers in an implicit solvent under varying conditions provides valuable insights into their behavior in diverse environments. In this work, we systematically investigate the effect of the angular width of the bending potential on structural state behavior and conformational variability using microcanonical analysis. A range of angular widths is explored, with the widest value corresponding directly to the classic semiflexible polymer model, which exhibits a diverse set of structural states, including Two-Strand, Three-Strand, Four-Strand, Ring, Random Coil, and Globule configurations. As the angular width narrows, structural variability within states decreases, overlap between structural states is reduced, and conformations become more stable, leading to an expansion of the parameter space dominated by individual structures. By examining microcanonical entropy and its derivatives, we identify transitions analogous to first-, second-, and third-order thermodynamic transitions, providing a deeper understanding of the configurational landscape of semiflexible polymers. Full article

(This article belongs to the Special Issue Modeling of Polymer Composites and Nanocomposites)

► Show Figures

Graphical abstract

19 pages, 5025 KiB

Open AccessArticle

Investigations on Thermal Transitions in PDPP4T/PCPDTBT/AuNPs Composite Films Using Variable Temperature Ellipsometry

by Paweł Jarka, Barbara Hajduk, Pallavi Kumari, Henryk Janeczek, Marcin Godzierz, Yao Mawuena Tsekpo and Tomasz Tański

Polymers 2025, 17(5), 704; https://doi.org/10.3390/polym17050704 - 6 Mar 2025

Viewed by 581

Abstract

Herein, we report a comprehensive investigation on the thermal transitions of thin films of poly [2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione -3,6-diyl)-alt-(2,2′;5′,2″;5″,2′″-quaterthiophen-5,5′″-diyl)]PDPP4T, poly[2,6-(4,4-bis-(2-ethy-lhexyl)-4H-cyclopenta [2,1-b;3,4-b′]dithiophene)-alt-4,7(2,1,3-benzothiadiazole)] PCPDTBT, 1:1 blend of PDPP4T and PCPDTBT, and their composites with gold nanoparticles (AuNPs). The thermal transitions of these materials were studied using variable temperature spectroscopic ellipsometry (VTSE), with differential scanning calorimetry (DSC) serving as the reference method. Based on obtained VTSE results, for the first time, we have determined the phase diagrams of PDPP4T/PCPDTBT and their AuNPs composites. The VTSE measurements revealed distinct thermal transitions in the thin films, including characteristic temperatures corresponding to the pure phases of PDPP4T and PCPDTBT within their blends. These transitions were markedly different in the AuNPs composites compared to the neat materials, highlighting the unique interactions between the polymer matrix and AuNPs. Additionally, we explored the optical properties, surface morphology, and crystallinity of the materials. We hypothesize that the observed variations in thermal transitions, as well as the improvement in optical properties and crystallinity, are likely influenced by localized surface plasmon resonance (LSPR) and passivation phenomena induced by the AuNPs in the composite films. These findings could have important implications for the design and optimization of materials for optoelectronic applications. Full article

(This article belongs to the Special Issue Modeling of Polymer Composites and Nanocomposites)

► Show Figures

Figure 1

18 pages, 13148 KiB

Open AccessArticle

Enhancing Radiation Shielding Efficiency of Nigella sativa Eumelanin Polymer Through Heavy Metals Doping

by Mohammad Marashdeh and Nawal Madkhali

Polymers 2025, 17(5), 609; https://doi.org/10.3390/polym17050609 - 25 Feb 2025

Viewed by 527

Abstract

Gamma radiation shielding is necessary for many applications; nevertheless, lead creates environmental risks. Eumelanin, a natural polymer, is a viable alternative, although its effectiveness is limited to lower gamma-ray energy. This research looks at how doping the herbal eumelanin polymer (Nigella sativa) with heavy metals including iron (Fe), copper (Cu), and zinc (Zn) affects its gamma radiation shielding characteristics. The inclusion of these metals considerably increases the linear attenuation coefficient (μ) and mass attenuation coefficient (μ_m) of eumelanin, especially at lower photon energies where the photoelectric effect is prominent. The μ value of pure eumelanin is 0.193 cm⁻¹ at 59.5 keV. It goes up to 0.309 cm⁻¹, 0.420 cm⁻¹, and 0.393 cm⁻¹ when Fe, Cu, and Zn are added, in that order. Similarly, the mass attenuation coefficients increase from 0.153 cm²/g for pure eumelanin to 0.230, 0.316, and 0.302 cm²/g for the Fe-, Cu-, and Zn-doped samples. At intermediate and higher energies (661.7 keV-to-1332.5 keV), where Compton scattering is the main interaction, differences in attenuation coefficients between samples are not as noticeable, which means that metal additions have less of an effect. The mean free path (MFP) and radiation protection efficiency (RPE) also show these behaviors. For example, at 59.5 keV the MFP drops from 5.172 cm for pure eumelanin to 3.244 cm for Mel-Fe, 2.385 cm for Mel-Cu, and 2.540 cm for Mel-Zn. RPE values also go up a lot at low energies. For example, at 59.5 keV Cu-doped eumelanin has the highest RPE of 34.251%, while pure eumelanin only has an RPE of 17.581%. However, at higher energies the RPE values for all samples converge, suggesting a more consistent performance. These findings suggest that doping eumelanin with Fe, Cu, and Zn is particularly effective for enhancing gamma-ray shielding at low energies, with copper (Cu) providing the most significant improvement overall, making these composites suitable for applications requiring enhanced radiation protection at lower gamma-ray energies. Full article

(This article belongs to the Special Issue Modeling of Polymer Composites and Nanocomposites)

► Show Figures

Figure 1

25 pages, 7471 KiB

Open AccessArticle

Multiscale Numerical Study of Enhanced Ductility Ratios and Capacity in Carbon Fiber-Reinforced Polymer Concrete Beams for Safety Design

by Moab Maidi, Gili Lifshitz Sherzer and Erez Gal

Polymers 2025, 17(2), 234; https://doi.org/10.3390/polym17020234 - 17 Jan 2025

Cited by 1 | Viewed by 701

Abstract

Rigid reinforced concrete (RC) frames are generally adopted as stiff elements to make the building structures resistant to seismic forces. However, a method has yet to be fully sought to provide earthquake resistance through optimizing beam and column performance in a rigid frame. Due to its high corrosion resistance, the integration of CFRP offers an opportunity to reduce frequent repairs and increase durability. This paper presents the structural response of CFRP beams integrated into rigid frames when subjected to seismic events. Without any design provision for CFRP systems in extreme events, multiscale simulations and parametric analyses were performed to optimize the residual state and global performance. Macroparameters, represented by the ductility ratio and microfactors, have been analyzed using a customized version of the modified compression field theory (MCFT). The main parameters considered were reinforcement under tension and compression, strength of concrete, height-to-width ratio, section cover, and confinement level, all of which are important to understand their influence on seismic performance. The parametric analysis results highlight the increased ductility and higher load-carrying capacity of the CFRP-reinforced tested component compared to the RC component. These results shed light on the possibility of designing CFRP-reinforced concrete components that could improve ductile frames with increased energy dissipation and be suitable for applications in non-corrosive seismic-resistant buildings. This also shows reduced brittleness and enhancement in the failure mode. Numerical simulations and experimental results showed a strong correlation with a deviation of about 8.3%, underlining the reliability of the proposed approach for designing seismic-resistant CFRP-reinforced structures. Full article

(This article belongs to the Special Issue Modeling of Polymer Composites and Nanocomposites)

► Show Figures

Figure 1

17 pages, 3242 KiB

Open AccessArticle

A Multi-Phase Analytical Model for Effective Electrical Conductivity of Polymer Matrix Composites Containing Micro-SiC Whiskers and Nano-Carbon Black Hybrids

by Usama Umer, Mustufa Haider Abidi, Zeyad Almutairi and Mohamed K. Aboudaif

Polymers 2025, 17(2), 128; https://doi.org/10.3390/polym17020128 - 7 Jan 2025

Viewed by 822

Abstract

Multifunctional polymer composites containing micro/nano hybrid reinforcements have attracted intensive attention in the field of materials science and engineering. This paper develops a multi-phase analytical model for investigating the effective electrical conductivity of micro-silicon carbide (SiC) whisker/nano-carbon black (CB) polymer composites. First, CB nanoparticles are dispersed within the non-conducting epoxy to achieve a conductive CB-filled nanocomposite and its electrical conductivity is predicted. Some critical microstructures such as volume percentage and size of nanoparticles, and interphase characteristics surrounding the CB are micromechanically captured. Next, the electrical conductivity of randomly oriented SiC-containing composites in which the nanocomposite and whisker are considered as the matrix and reinforcement phases, respectively, is estimated. Influences of whisker aspect ratio and volume fraction on the effective electrical conductivity of the SiC/CB-containing polymer composites are explored. Some comparison studies are performed to validate the accuracy of the model. It is observed before the percolation threshold that the addition of nanoparticles with a uniform dispersion can improve the electrical conductivity of the polymer composites containing SiC/CB hybrids. Moreover, the results show that the electrical conductivity is more enhanced by the decrease in nanoparticle size. Interestingly, the composite percolation threshold is significantly reduced when SiC whiskers with a higher aspect ratio are added. This work will be favorable for the design of electro-conductive polymer composites with high performances. Full article

(This article belongs to the Special Issue Modeling of Polymer Composites and Nanocomposites)

► Show Figures

Figure 1

19 pages, 3611 KiB

Open AccessArticle

Effects of Silica Nanoparticles on the Piezoelectro-Elastic Response of PZT-7A–Polyimide Nanocomposites: Micromechanics Modeling Technique

by Usama Umer, Mustufa Haider Abidi, Syed Hammad Mian, Fahad Alasim and Mohammed K. Aboudaif

Polymers 2024, 16(20), 2860; https://doi.org/10.3390/polym16202860 - 10 Oct 2024

Viewed by 1087

Abstract

By using piezoelectric materials, it is possible to convert clean and renewable energy sources into electrical energy. In this paper, the effect on the piezoelectro-elastic response of piezoelectric-fiber-reinforced nanocomposites by adding silica nanoparticles into the polyimide matrix is investigated by a micromechanical method. First, the Ji and Mori–Tanaka models are used to calculate the properties of the nanoscale silica-filled polymer. The nanoparticle agglomeration and silica–polymer interphase are considered in the micromechanical modeling. Then, considering the filled polymer as the matrix and the piezoelectric fiber as the reinforcement, the Mori–Tanaka model is used to estimate the elastic and piezoelectric constants of the piezoelectric fibrous nanocomposites. It was found that adding silica nanoparticles into the polymer improves the elastic and piezoelectric properties of the piezoelectric fibrous nanocomposites. When the fiber volume fraction is 60%, the nanocomposite with the 3% silica-filled polyimide exhibits 39%, 31.8%, and 37% improvements in the transverse Young’s modulus

E_{T}

, transverse shear modulus

G_{T L}

, and piezoelectric coefficient

e_{31}

in comparison with the composite without nanoparticles. Furthermore, the piezoelectro-elastic properties such as

E_{T}

G_{T L}

, and

e_{31}

can be improved as the nanoparticle diameter decreases. However, the elastic and piezoelectric constants of the piezoelectric fibrous nanocomposites decrease once the nanoparticles are agglomerated in the polymer matrix. A thick interphase with a high stiffness enhances the nanocomposite’s piezoelectro-elastic performance. Also, the influence of volume fractions of the silica nanoparticles and piezoelectric fibers on the nanocomposite properties is studied. Full article

(This article belongs to the Special Issue Modeling of Polymer Composites and Nanocomposites)

► Show Figures

Journal Menu

Journal Browser

Modeling of Polymer Composites and Nanocomposites

Share This Special Issue

Special Issue Editor

Special Issue Information

Keywords

Benefits of Publishing in a Special Issue

Published Papers (9 papers)

Research

Further Information

Guidelines

MDPI Initiatives

Follow MDPI