We present the theory and simulation of attosecond transient absorption in helium atoms under the single-active-electron approximation. This study investigates the attosecond dynamics of intrinsic atomic states that interact with a field comprising v...
In this study, the attosecond transient absorption (ATA) spectrum below the excited states of the helium atom was investigated by numerically solving the fully three-dimensional time-dependent Schrödinger equation. Under single-active electron a...
Two-dimensional (2D) tri-TMDCs carrier dynamics provide a platform for studying excitons through Ultrafast Pump-Probe Transient Absorption Spectroscopy. Here we studied the ZrTe3 nanosheets (NTs) exciton dynamics by transient absorption (TA) spectrom...
We extend the first-principles analysis of attosecond transient absorption spectroscopy to two-dimensional materials. As an example of two-dimensional materials, we apply the analysis to monolayer hexagonal boron nitride (h-BN) and compute its transi...
A theoretical description of attosecond transient absorption spectroscopy for temporally and spatially overlapping XUV and optical pulses is developed, explaining the signals one can obtain in such an experiment. To this end, we employ a two-stage ap...
Rods and cones are the photoreceptor cells containing the visual pigment proteins that initiate visual phototransduction following the absorption of a photon. Photon absorption induces the photochemical transformation of a visual pigment, which resul...
Oxygenic and anoxygenic photosynthesis are initiated through the absorption of light by chlorophyll and bacteriochlorophyll photosynthetic pigments, respectively, which function as light-harvesting (antenna) and redox pigments on the photosynthetic m...
Broadband reverse saturable absorption is systematically investigated via Z-scan, transient absorption spectrum (TAS). The excited state absorption and negative refraction of Orange IV are observed in the Z-scan experiment at 532 nm. Meanwhile, two-p...
We describe a transient absorption (TA) spectroscopy system in the ultraviolet (UV) spectral range, for the study of the ultrafast optical response of biomolecules. After reviewing the techniques for the generation and characterization of ultrashort...
The two photon absorption-transient current technique (TPA-TCT) was used to investigate a silicon strip detector with illumination from the top. Measurement and analysis techniques for the TPA-TCT of segmented devices are presented and discussed usin...
We describe the basic principles and the experimental implementation of the hyperspectral transient absorption technique, based on femtosecond laser sources. In this technique the samples were optically “pumped” using the femtosecond tuna...
To gain insight into photocatalytic behavior, transient absorption spectroscopy (TAS) was used to study LaCoxMn1−xO3, LaMnxNi1−xO3 and LaNixCo1−xO3 (x = 0, 0.2, 0.4, 0.6, 0.8 and 1.0) on a microsecond time scale. The results show th...
The UV-Vis absorption, fluorescence, and phosphorescence spectra of poly(3,4-ethylenedioxythiophene/cucurbit[7]uril), polypseudorotaxane (1), and polyrotaxane (2) in water and acetonitrile solutions were investigated. To achieve a deeper insight into...
The Two-Photon Absorption–Transient Current Technique (TPA-TCT) is a device characterisation technique that enables three-dimensional spatial resolution. Laser light in the quadratic absorption regime is employed to generate excess charge carri...
We employ an extreme ultraviolet (XUV) pulse to impulsively excite dipole polarization in atoms or molecules, which corresponds to coherently prepared superposition of excited states. A delayed near infrared (NIR) pulse then perturbs the fast evolvin...
The reaction of intracomplex proton transfer (44BPY-....HO-H) ® 44BPYH. + OH- that follows the photoreduction of 4,4’-bipyridine (44BPY) into its anion radical 44BPY- in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) is investigated in acetoni...
Device simulation plays a crucial role in complementing experimental device characterisation by enabling deeper understanding of internal physical processes. However, for simulations to be trusted, experimental validation is essential to confirm the...
Conical intersections (CIs) are the most efficient channels of photodeactivation and energy transfer, while femtosecond spectroscopy is the main experimental tool delivering information on molecular CI-driven photoinduced processes. In this work, we...
A strongly temperature-dependent photo-induced transient absorption is measured in 6.5 mol% magnesium-doped lithium niobate at temperatures ranging from 45 K to 225 K. This phenomenon is interpreted as resulting from the generation and subsequent rec...
The current study investigates the impact of solar collector array, employing flat plate solar collectors (FPC) and evacuated tube solar collectors (ETC) on the transient performance of a solar-driven single-effect absorption cooling system. The inve...
The presence of surface trap states (STSs) is one of the key factors to affect the electronic and optical properties of quantum dots (QDs), however, the exact mechanism of how STSs influence QDs remains unclear. Herein, we demonstrated the impact of...
There is compelling evidence that the absorption of low-energy UV radiation directly by DNA in solution generates guanine radicals with quantum yields that are strongly dependent on the secondary structure. Key players in this unexpected phenomenon a...
This study aimed to determine the structure–function relationship (SFR) for ChCl–glycerol mixtures, a deep eutectic solvent (DES), by investigating their microscopic solvation dynamics and how it relates to their macroscopic properties ac...
Characterizing the geometric and electronic structures of individual photoexcited dye molecules in solution is an important step towards understanding the interfacial properties of photo-active electrodes. The broad family of “red sensitizers” based...
In this study, we present a comprehensive investigation into the charge generation mechanism in bulk-heterojunction organic solar cells employing non-fullerene acceptors (NFAs) both with and without the presence of processing additives. While photovo...
Artificial photocatalytic energy conversion is a very interesting strategy to solve energy crises and environmental problems by directly collecting solar energy, but low photocatalytic conversion efficiency is a bottleneck that restricts the practica...
(1) Background: The modeling, characterization, and mitigation of transient lasers, thermal stress, and thermo-optic effects (TOEs) occurring inside high energy lasers have become hot research topics in laser physics over the past few decades. The ph...
In all kinds of liquid desiccant dehumidification systems, the temperature increase of the desiccant solution due to the effect of absorptive heating is one of the main reasons of performance deterioration. In this study, we look into the thermal eff...
In this presentation, absorption (transient absorption) and emission (steady state and time-resolved fluorescence) spectroscopy were used to study, investigate and characterize the mechanisms of fluorescence quenching and obtain new sensors with whic...
Organic photovoltaic materials and nonlinear optical materials share inherent commonalities in molecular characteristics—such as strong light absorption, high charge carrier mobility, and tunable energy levels. Therefore, this study selects a b...
Numerical pump-probe simulations for the sub-cycle transient spectroscopy of thin film diamond under intense few cycle pulse laser field is reported. The electron dynamics is calculated by the time-dependent Kohn-Sham equation. Simultaneously, the pr...
Melamine may have been an important prebiotic information carrier, but its excited-state dynamics, which determine its stability under UV radiation, have never been characterized. The ability of melamine to withstand the strong UV radiation present o...
Biocomposites are defined as eco-friendly materials from an environmental point of view. Because of the importance of this class of materials, their study is important, especially in moist and heated conditions. In this sense, this work aims to evalu...
The 3′,5′-dimethoxybenzoin (DMB) system has been widely investigated as a photoremovable protecting group (PRPG) for the elimination of various functional groups and has been applied in many fields. The photolysis of DMB fluoride leads to...
The Ti3C2 nanosheet, as a new two-dimensional (2D) group, has been found to have attractive characteristics as material for electromagnetic shielding and energy storage. In this study, the nonlinear broadband absorption and ultrafast dynamics of the...
Photophysical properties of two Re(I) complexes [ReCl(CO)3(R-C6H4-terpy-κ2N)] with remote amine groups, N-methyl-piperazinyl (1) and (2-cyanoethyl)methylamine (2), were investigated. The complexes show strong absorption in the visible region co...
A simultaneous steady-state and transient photothermal-lens modality was used for both the thermal and optical parameters of aqueous dispersed systems (carbon and silica nanoparticles, metal iodides, surfactants, heme proteins, albumin, and their com...
The pulsed laser has gradually become the standard method of studying the single-event effects of micro-nano devices, and it is a powerful supplement to heavy ion experiments on single-event effects. In particular, with the continuous improvement of...
Understanding the primary steps following UV photoexcitation in sulphur-substituted DNA bases (thiobases) is fundamental for developing new phototherapeutic drugs. However, the investigation of the excited-state dynamics in sub-100 fs time scales has...
Intermolecular interactions on inorganic substrates can have a critical impact on the electrochemical and photophysical properties of the materials and subsequent performance in hybrid electronics. Critical to the intentional formation or inhibition...
We report on numerical results revealing line-shape asymmetry changes of electronic transitions in atoms near-resonantly driven by intense extreme-ultraviolet (XUV) electric fields by monitoring their transient absorption spectrum after transmission...
Based on the discovery of the surge absorption capability of supercapacitors, a transient protector named supercapacitor-assisted surge absorber (SCASA) was designed and implemented in a commercial device. Despite its simplicity, the circuit topology...
Benzoin is one of the most commonly used photoinitiators to induce free radical polymerization. Here, improved benzoin properties could be accomplished by the introduction of two methoxy substituents, leading to the formation of 3’,5’-dim...
The present study investigates the photochemical properties of potential photosensitizers for photodynamic therapy, namely four commercial heptamethinecyanine dyes (IR125, IR780, IR813, IR820). Spectroscopic studies were made by means of laser induce...
The electronic nature of 4-hydroxy-1H-pyrrolo[3,4-c]pyridine-1,3,6(2H,5H)-trione (HPPT) was comprehensively investigated in liquid media at room temperature using steady-state and time-resolved femtosecond transient absorption spectroscopic technique...
This paper presents a set of steady-state and transient data for dynamic process model validation of the chemical absorption process with monoethanolamine (MEA) for post-combustion CO2 capture of exhaust gas from a natural gas-fired power plant. The...
Gold films are widely used for different applications. We present the results of third- and high-order nonlinear optical studies of the thin films fabricated from Au nanoparticle solutions by spin-coating methods. These nanoparticles were synthesized...
It is essential to develop pattern-related process windows on substrate surface for reducing the dislocation density of wide bandgap semiconductor film growth. For extremely high instantaneous intensity and excellent photon absorption rate, femtoseco...
Excited state dynamics of two-dimensional-like conjugated copolymers PFDCN and PFSDCN based on alternating fluorene and triphenylamine main chains and malononitrile pendant acceptor groups with thiophene as π-bridge, have been investigated by using t...
Interdot coherent excitonic dynamics in nanometric colloidal CdSe quantum dots (QD) dimers lead to interdot charge migration and energy transfer. We show by electronic quantum dynamical simulations that the interdot coherent response to ultrashort fs...
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