10,419 Results Found

To investigate the influence of the crosslinked polyethylene (XLPE) structure on electrical performance, various analytical methods were employed to study polyethylene structures with different degrees of crosslinking. Dynamic rheological analysis wa...

DNA-crosslinks are one of the most severe types of DNA lesions. Crosslinks (CLs) can be subdivided into DNA-intrastrand CLs, DNA-interstrand CLs (ICLs) and DNA-protein crosslinks (DPCs), and arise by various exogenous and endogenous sources. If left...

In this work, molecular dynamics (MD) and molecular mechanics (MM) simulations are used to study well-equilibrated models of 4,4′-bis(3,4-dicyanophenoxy)biphenyl (BPh)–1,3-bis(3-aminophenoxy)benzene (m-APB) phthalonitrile (PN) system with a range of...

The mechanical properties of type I collagen gel vary due to different polymerization parameters. In this work, the role of crosslinks in terms of density and stiffness on the macroscopic behavior of collagen gel were investigated through computation...

The crosslink density plays a key role in the mechanical response of the amorphous polymers in previous experiments. However, the mechanism of the influence is still not clear. In this paper, the influence of crosslink density on the failure behavior...

Optimal conditions for maximum efficacy of photoinitiated polymerization are theoretically presented. Analytic formulas are shown for the crosslink time, crosslink depth, and efficacy function. The roles of photoinitiator (PI) concentration, diffusio...

Thermoset polyurethanes invite industrial interest for their versatility and chemical and mechanical resistance due to their permanently crosslinked networks; yet this structural feature severely limits their recyclability. Recent advances in Covalen...

The extreme elasticity and reversible deformability of rubber, which is one of the most versatile polymers in modern society, is dependent on several factors, including the processing conditions, curing system, and types of additives used. Since the...

This paper is focused on a simple preparation of functional acrylic latex coating binders comprising embedded nanoparticles originating from ZnO and MgO, respectively, in the role of interfacial ionic self-crosslinking agents. The incorporation of su...

Water in Sephadex^® (crosslinked dextran) gels is known to indicate different freezing behavior which is dependent on the density of the crosslinks, and water in a Sephadex^® G25 gel remains partially unfrozen during cooling and crystallizes du...

Outdoor air pollution is a mixture of multiple atmospheric pollutants, among which nitrogen oxide (NOx) stands out due to its association with several diseases. NOx reactivity can conduct to DNA damage as severe as interstrand crosslinks (ICL) format...

With growth in data volume from space missions, interest in laser communications has increased, owing to their importance for high-speed data transfer in the commercial and defense fields, spaceborne remote sensing, and surveillance. Here, we propose...

Polymers are widely used in various industries because of their characteristics such as elasticity, abrasion resistance, fatigue resistance and low temperature. In particular, the tensile characteristic of rubber composites is important for the stabi...

Studies addressing electroconductive composites based on rubber have attracted great interest for many engineering applications. To contribute to obtaining useful materials with reproducible behavior, this study focused on understanding the mechanism...

Gelatin is a promising candidate for making bioplastic film; however, the water soluble property has limited its applications. Here, we have successfully fabricated a water-insoluble gelatin film with the assistance of biocatalysis. This innovative g...

1-Ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC) alone, and in combination with N-hydroxysuccinimide (NHS) or sulfoNHS were employed for crosslinking anti-human fetuin A (HFA) antibodies on 3-aminopropyltriethoxysilane (APTES)-functionalized surf...

Numerous cases of spontaneous humeral fracture in primiparous dairy cows from New Zealand have prompted the study of the condition to establish probable causes or risk factors associated with the condition. Previous studies identified inadequate prot...

Classification of the crosslink density level of para rubber medical gloves by using near-infrared spectral data combined with machine learning is the first time reported in this paper. The spectra of medical glove samples with different crosslink de...

Uric acid is considered the main substrate for peroxidases in plasma. The oxidation of uric acid by human peroxidases generates urate free radical and urate hydroperoxide, which might affect endothelial function and explain, at least in part, the har...

Anti-inflammatory wound healing involves targeted drug delivery to the wound site using hydrogel materials to prolong drug effectiveness. In this work, hydrogel films were fabricated using carboxymethyl cellulose (CMC) and poly(vinyl alcohol) (PVA) c...

In the field of water-based inks, the use of alkali-soluble resins (ASRs) as polymeric surfactants for synthesizing polyacrylate latexes has become a mainstream method. This study first designed and prepared crosslinkable ASRs with a diacetone acryla...

Collagen nanofibrous materials have become integral to tissue engineering due to their exceptional properties and biocompatibility. Dehydrothermal crosslinking (DHT) enhances stability and maintains structural integrity without the formation of toxic...

Staphylococcus aureus is a Gram-positive bacterium that plays a role in the pathogenesis of skin lesions in diabetes mellitus, atopic dermatitis, and psoriasis, all of which are associated with elevated non-enzymatic glycation biomarkers. The product...

A fundamental understanding of the effect of a crosslinker on gel properties is important for the design of novel soft materials because a crosslinking is a key component of polymer gels. We focused on post-polymerization crosslinking (PPC) system ut...

The ultraviolet (UV) irradiation crosslinking reactions of polyethylene and the electronic properties of photo-initiators and reaction products are theoretically investigated by the first-principles calculations. The crosslinked polyethylene (XLPE) m...

Cross-linked polyethylene (XLPE) obtained by the crossing-linking reaction of polyethylene (PE) can greatly enhance the mechanical properties and other properties of PE, which makes XLPE widely applied in the field of electric power engineering. Howe...

To investigate the impact of temperature variations during the secondary crosslinking of cross-linked polyethylene (XLPE) on the insulation performance of the interface layer, commercial XLPE cable pellets were subjected to flat hot pressing at 140 &...

The purpose of this work was to cross-link chloroprene rubber (CR) with silver(I) oxide (Ag₂O) and to investigate the properties of the obtained vulcanizates. Silver(I) oxide was chosen as an alternative to zinc oxide (ZnO), which is part of the stan...

Crosslinking of proteins has gained immense significance in the fabrication of biomaterials for various health care applications. Various novel chemical-based strategies are being continuously developed for intra-/inter-molecular crosslinking of prot...

This article provides a systematic review of the crosslinking strategies used to produce microgel particles in microfluidic chips. Various ionic crosslinking methods for the gelation of charged polymers are discussed, including external gelation via...

Both ionic and enzymatic crosslink are efficient strategies for constructing network materials of high biocompatibility. Here chitosan was modified firstly and then crosslinked by these two methods for complementary advantages. The preparation method...

Chitosan films containing citric acid were prepared using a multi-step process called heterogeneous crosslinking. These films were neutralized first, followed by citric acid addition, and then heat treated at 150 °C/0.5 h in order to potentially...

Cross-linked membranes for polymer electrolyte membrane fuel cell application are prepared using highly sulfonated poly(arylene ether sulfone) (SPAES) and polymeric cross-linkers having different hydrophilicities by facile in-situ casting and heating...

We propose a simple but rapid strategy to fabricate self-crosslinked dual-crosslinking elastomers (SCDCEs) with high mechanical properties. The SCDCEs are synthesized through one-pot copolymerization of Butyl acrylate (BA), acrylic amide (AM), and 3-...

The influence of the coordination of (reversible) cross-links on the mechanical properties of aligned fiber bundles is investigated. Two polymeric systems containing cross-links of different coordination (two- and three-fold coordination) but having...

The development of high-performance biocomposites based on poly vinyl alcohol (PVA) and lignin is often hindered by the limited interfacial compatibility. Herein, we reporte a synchronized crosslinking strategy to seamlessly integrate lignin and PVA...

Hydrogels are hydrophilic polymer materials that can swell but are insoluble in water. Hydrogels can be synthesized with synthetic or natural polymers, but natural polymers are preferred because they are similar to natural tissues, which can absorb a...

The application of biodegradable chitosan fiber for healthy and hygienic textiles is limited due to its poor acid resistance in wet processing and poor antioxidant activity. In order to prepare chitosan fiber with good acid resistance and high antiox...

For the development of biodegradable superabsorbent polymers, the effect of the cross-linking length on the absorption characteristics of the Na salt of polyaspartic acid (PAspNa) was demonstrated using different concentrations of diamine cross-linki...

DNA–protein crosslinks (DPCs) represent a unique and complex form of DNA damage formed by covalent attachment of proteins to DNA. DPCs are formed through a variety of mechanisms and can significantly impede essential cellular processes such as...

Native rice starch lacks the versatility necessary to function adequately under rigorous industrial processing, so modified starches are needed to meet the functional properties required in food products. This work investigated the impact of enzymati...

In this investigation, we systematically explored the intricate relationship between the structural attributes of polyvinyl alcohol (PVA) membranes and their multifaceted properties relevant to fuel cell applications, encompassing diverse crosslinkin...

The water-resistant characteristics of ultraviolet crosslinked polyethylene (UV-XLPE) are investigated specially for the dependence on the hydrophilicities of auxiliary crosslinkers, which is significant to develop high-voltage insulating cable mater...

Background/Objectives: DNA-damaging agents can contribute to genetic instability, and such agents are often used in cancer chemotherapeutic regimens due to their cytotoxicity. Thus, understanding the mechanisms involved in DNA damage processing can n...

Due to excellent chemical resistance and impermeability, high-density polyethylene (HDPE) is widely used in petrochemical transportation, product packaging, sports equipment, and marine applications. Yet, with the wide variety of service environments...

Collagen crosslinking provides the mechanical strength required for physiological maintenance of the extracellular matrix in most tissues in the human body, including the cornea. Aging and diabetes mellitus (DM) are processes that are both associated...

Gelatin methacryloyl (GelMA) hydrogels have been used in tissue engineering and regenerative medicine because of their biocompatibility, photopatternability, printability, and tunable mechanical and rheological properties. However, low mechanical str...

The in vitro enzymatic degradation of cross-linked poly(trimethylene carbonate) networks (PTMC-Ns) was performed in lipase solutions at 37 °C, and the effect of the initial molecular weight and cross-linker amount as well as the cross-linker type on...

Electrospinning can be used to prepare nanofiber mats from diverse polymers, polymer blends, or polymers doped with other materials. Amongst this broad range of usable materials, biopolymers play an important role in biotechnological, biomedical, and...

Crosslinking polymers to form networks is a universal and routinely applied strategy to improve their stability and endow them with solvent resistance, adhesion properties, etc. However, the chemical crosslinking of common commercial polymers, especi...