Search Results (1,768)

The thermomechanical deformation behavior of high-entropy alloys (HEAs) is governed by complex interactions among strain, strain rate, and deformation temperature, necessitating robust constitutive models for accurate flow stress prediction and process optimization. In this study, a novel Zerilli–Armstrong (NZA) constitutive model was developed to characterize the hot deformation behavior of FeCoCrNi HEA. The proposed NZA model incorporates enhanced descriptions of strain hardening and deformation-temperature coupling to improve prediction accuracy. The predictability of the proposed NZA model was systematically evaluated and compared with that of the original Zerilli–Armstrong (ZA) and modified Zerilli–Armstrong (MZA) models using key statistical indicators, including the correlation coefficient (R), average absolute relative error (AARE), and root mean square error (RMSE). The findings demonstrate that the NZA model exhibits superior predictive performance, achieving an excellent correlation coefficient (R) of 0.997, a low AARE of 4.22%, and an RMSE of 5.82 MPa. These results confirm the reliability and effectiveness of the proposed constitutive framework in accurately describing the thermomechanical flow behavior of FeCoCrNi HEA over a wide range of deformation conditions. The proposed NZA model provides a robust framework for optimizing hot-forming processes and improving the manufacturing performance of HEA-based components while promoting sustainable manufacturing through reduced material consumption, enhanced energy efficiency, and support for SDGs 9 and 12. Full article

The Absolute Nodal Coordinate Formulation (ANCF) is extensively utilized in the field of flexible multibody dynamics because it offers a constant mass matrix and inherently eliminates Coriolis forces. However, ANCF requires the computation of complex nonlinear elastic internal forces and thermal deformation forces at each time step, which imposes a significant computational burden. To alleviate this burden, researchers have developed local linearization (LL) methods. The local linearization method constructs constant elastic and thermal stiffness matrices within a small range by means of Taylor expansion, effectively reducing the number of stiffness matrix updates. But the method suffers from error accumulation and relies on displacement-based update criteria that are inefficient for systems with large rigid-body motion. This paper proposes an improved local linearization (I-LL) method to address these issues. Two key enhancements are introduced: (1) the update criterion for the elastic and thermal stiffness matrices is modified from displacement-based to total strain-based, enabling more accurate and size-independent updates; (2) accurate elastic or thermal deformation force calculations are inserted within the local linearization iteration cycle to mitigate error accumulation. These two improvements reduce the number of calculations of the nonlinear internal forces and, at the same time, lessen the error accumulation in the simplified model. The accuracy and effectiveness of the I-LL algorithm are demonstrated through three numerical examples. Full article

Alfalfa densification is a critical step in feed utilization and biomass energy conversion because it directly affects the transport efficiency, storage stability, and energy consumption of biomass processing systems. However, the thermodynamic behavior of the densification process remains poorly understood, especially under open-die conditions without external heating. This study investigated the thermo-mechanical characteristics of alfalfa pellet open-die densification without external heating by combining experimental measurements with ANSYS macro-continuum simulation. Stress transmission and temperature field distributions were analyzed. The results showed that the pellet quality index under different process conditions remained above 800, meeting the requirements for pelleted feed. Moisture content had a more significant effect on forming pressure than other factors; as moisture content increased, the forming pressure decreased. At an aspect ratio of 5.0, the forming pressure was below 45 kN. Simulation results further indicated that aspect ratio had a stronger influence on frictional behavior during densification. Under an aspect ratio of 5.0, the energy consumption was 888.53 J, and the heat flux reached 0.0062 W/mm². These results indicate that frictional dissipation driven by radial force is the dominant mechanism governing thermo-mechanical coupling. Moisture content and aspect ratio significantly affected both peak compression force and coupling intensity. Although reducing moisture content or increasing aspect ratio improved pellet quality, it also increased die load due to enhanced radial force. The coupling intensity followed the order: peak pressure stage > moving stage > compression stage. These findings reveal the evolution of stress and temperature fields during alfalfa densification, offering critical theoretical guidance for optimizing densification process parameters. Full article

In this study, we report the results of the structural characterization and electrochemical evaluation of novel cobalt-free layered Ruddlesden–Popper (RP) oxides, La₂SrFe₂O_7−δ and La₂SrFe_1.8Ga_0.2O_7−δ, as electrode materials for intermediate-temperature solid oxide cells. X-ray diffraction confirmed the formation of RP phases and phase stability after reducing treatment. The materials showed compatible thermal expansion behavior, with slightly lower thermal expansion coefficients for the Ga-doped composition. Oxygen pressure relaxation measurements demonstrated that the oxygen surface exchange coefficient increases with temperature and pO₂, while Ga substitution slightly reduces the O₂/oxide exchange rate, which may be associated with a lower concentration of oxygen vacancies. The electrical conductivity in air was higher for La₂SrFe₂O_7−δ than for the Ga-doped sample, while both compositions showed much lower conductivity under reducing conditions. Symmetrical cell impedance spectroscopy showed high polarization resistance for the electrodes, which was substantially reduced by applying a Ag current collector (0.43 Ω cm² for La₂SrFe₂O_7−δ and 0.73 Ω cm² for La₂SrFe_1.8Ga_0.2O_7−δ at 800 °C), consistent with the limited electronic conductivity of the oxide layers. Overall, both oxides exhibit structural stability, acceptable thermomechanical compatibility, and measurable oxygen exchange activity, making them promising candidates for further development as cobalt-free electrodes in solid oxide cells. Full article

This study investigates the influence of PLA flowability and talc content on the performance of compostable thermoplastic starch/poly(butylene succinate) (TPS/PBS)-based systems for rigid applications. Different PLA grades with varying melt flow index (PLA23, PLA8 and PLA70) and talc contents (0, 5 and 10 wt%) were incorporated. Twelve formulations were compounded by twin-screw extrusion and processed by injection moulding. FTIR confirmed the coexistence of TPS, PBS and PLA phases without evidence of chemical interactions. Morphological analysis showed that PLA flowability plays a key role in phase distribution, with higher-flow PLA promoting improved dispersion and interfacial adhesion, while talc addition (5 and 10 wt%) increased structural heterogeneity; at higher loadings, particularly, DSC analysis revealed that talc acted as a nucleating agent for the PBS phase, increasing crystallisation temperatures from approximately 73 °C to 81 °C depending on formulation. Mechanical results showed that Young’s modulus increased from approximately 1.4 GPa to 2.7 GPa with decreasing PLA flowability and increasing talc content. Formulations containing low-flow PLA reached tensile strengths close to 32 MPa, although elongation at break decreased to values near 2%. In contrast, high-flow PLA formulations exhibited a more balanced mechanical response, with elongation values up to approximately 8%, associated with improved phase dispersion. Hybrid PLA systems showed intermediate behaviour, reaching elongations up to 22% while maintaining modulus values around 1.8 GPa. Talc provided additional reinforcement but reduced deformation capacity. HDT values remained relatively constant, indicating limited improvement in thermomechanical resistance despite increased stiffness. These results demonstrate that the combined control of PLA molecular characteristics and talc content enables tuning of the mechanical and thermomechanical performance of TPS/PBS/PLA/talc systems for rigid packaging applications. Full article

In this study, twin screw extruded Polyetherimide (PEI)/Poly(ethylene terephthalate) (PET) polymer blends (90/10, 70/30, 50/50 w/w%) were investigated to elucidate the composition–property relationship governed by morphological, structural, rheological, thermomechanical, mechanical, and electromagnetic shielding (EMI) performance behavior. Among other polymer blends, the 70/30 blend exhibits superior thermomechanical stability with a significant glass transition temperature of 132.7 °C, where a robust confinement effect effectively restricts the mobility of PET chains. This morphology, characterized by a domain size of 562 nm, provides proof of concept for interface-driven attenuation, reaching a maximum EMI shielding effectiveness of 2.54 dB within the investigated blends. This performance is primarily governed by Maxwell–Wagner–Sillars polarization at the immiscible boundaries, alongside an optimized dielectric loss of tan δ ≈ 0.065. The design of these high-temperature PEI blends provides a proof of concept for interface-driven attenuation and demonstrates their potential for developing advanced EMI shielding matrices. Full article

In this study, the Nb from the lightweight Ti₆₅(AlCrNbV)₃₅ medium-entropy alloy was replaced with Zr to create lower-density Ti_x(AlCrZrV)_100−x (x = 65, 67, 70, or 75) alloys. All alloy ingots were fabricated through vacuum arc melting and drop casting. X-ray diffraction analysis revealed all as-cast alloys exhibited only a single body-centered cubic structure. As the Ti content increased, the strength of the as-cast alloys decreased from 1247 to 981 MPa, whereas their elongation marginally improved. Moreover, the mechanical properties of these alloys were considerably enhanced through thermomechanical treatment (50% hot rolling and 80% cold rolling) and then rapid annealing at 700 °C, 800 °C, or 900 °C. An increase in the annealing temperature led to a notable decrease in the yield strength of the alloys but a considerable increase in their ductility. Ti65, Ti67, and Ti70 alloys annealed at 700 °C or 800 °C exhibited a yield strength of ≥1200 MPa and a ductility of ≥10%. Of the fabricated alloys, the Ti67 alloy annealed at 700 °C exhibited the optimal mechanical properties (yield strength of 1552 MPa and ductility of 13.6%). It exhibited low density (4.89 g/cm³) and a specific yield strength of 317 MPa·cm³/g, thus demonstrating considerable potential for transportation and energy applications. Full article

Mg–Y–Zn alloys have attracted considerable attention for lightweight structural applications; however, the influence of extrusion temperature on microstructural evolution and the underlying mechanisms governing strength–ductility synergy remains insufficiently understood. In this study, a novel YZG921 (Mg–9Y–1.8Zn–1.2Gd–0.5Zr–0.3Ca, wt.%) alloy was fabricated by hot extrusion at temperatures ranging from 480 to 520 °C. The microstructure, mechanical properties, and deformation behavior were systematically investigated using SEM, TEM, EBSD, in situ EBSD, and slip-trace analysis. The results show that extrusion temperature significantly affects the evolution of secondary phases, grain size, and texture intensity. At 500 °C, an 18R-LPSO phase was formed, accompanied by a more homogeneous distribution of secondary phases and the finest grain structure (~3.8 μm), whereas the average grain size remained close to 10 μm for the alloys extruded at 480 °C and 520 °C. Meanwhile, the maximum basal texture intensity decreased from 4.16 to 4.79 m.r.d. to 2.18–2.58 m.r.d. Mechanical testing revealed that the alloy extruded at 500 °C exhibited the optimum strength–ductility balance, with an ultimate tensile strength of 498.4 MPa and an elongation of 13.8%. In situ EBSD analysis showed that the fraction of low-angle grain boundaries increased from ~7% to 43% during tensile deformation, while the average KAM value increased from ~0.5° to 0.88°. Slip-trace analysis further demonstrated that plastic deformation was predominantly governed by basal slip, accounting for approximately 84.2% of the activated slip systems. The superior mechanical performance achieved at 500 °C is attributed to the synergistic effects of grain refinement, LPSO and second-phase strengthening, texture weakening, and sustained strain hardening. These findings provide insights into microstructure–property relationships and offer guidance for the optimization of thermomechanical processing parameters in Mg–Y–Zn alloys. Full article

The present study investigates the application of electric resistive heating to photovoltaic (PV) panels, aimed at enabling their subsequent thermo-mechanical delamination. The key process parameters—namely current magnitude and applied voltage—required for direct electro-resistive heating are identified, and the process is experimentally demonstrated under laboratory conditions. The electric resistive heating of a composite photovoltaic panel, consisting of a solar cell layer (crystalline silicon, c-Si, with a metallic grid), a backsheet, and a glass layer, is analyzed in detail using a virtual model of a single-crystal silicon solar cell implemented as coupled electric-thermal analysis. The temperature dependence of the electrical resistance of the solar cell layer is experimentally measured, and exponential relationships are derived and subsequently incorporated into the numerical model. The virtual model results are validated, demonstrating that, for a given geometry and configuration of the conductive metallic grid (busbars and fingers), the electrical resistance of the semiconductor layer containing the p–n junction governs the temperature achieved during electro-resistive heating as a function of the applied current. Furthermore, results for the terminal current and voltage, current density in the busbars and fingers, electric field intensity, and the resulting temperature within the semiconductor layer of the single-crystal silicon solar cell are presented and analyzed. Full article

Residual stresses and distortions are critical challenges in laser beam powder bed fusion (PBF-LB) of Ti6Al4V components (PBF-LB/M/Ti6Al4V), impacting structural integrity and dimensional accuracy. This study assesses the inherent strain method (ISM) as a computationally efficient alternative to full thermomechanical simulations for predicting these effects. By integrating ISM with experimental validation via the contour method, the research provides specific insights into stress distribution patterns in geometries featuring stress concentrators such as notches. Results demonstrate a strong correlation between simulation and experimental data, particularly at the mid-height regions. Quantitatively, the orthotropic ISM successfully predicted the peak residual stress at 1101.4 MPa, showing excellent agreement within a 4% error margin against the experimental maximum of 1144 MPa captured via the contour method. These findings underscore how ISM can be effectively applied to practical engineering components to predict high-stress zones, enabling the design of distortion-compensated parts without the high computational cost of traditional models. Ultimately, this method facilitates more robust process optimization and enhances the quality and reliability of Ti6Al4V components manufactured via PBF-LB. Full article

The extreme thermal environment during the underground coal gasification (UCG) process poses a severe threat to the stability of the gasification cavity and the integrity of the surrounding rock. This paper aims to reveal the thermo-mechanical response characteristics and damage evolution mechanism of sandstone under true triaxial unloading conditions following exposure to high temperatures. Sandstone specimens were thermally pre-treated at five temperature gradients (25 °C, 200 °C, 400 °C, 600 °C, and 800 °C) and subsequently subjected to true triaxial loading and unloading experiments. The effects of varying temperatures on the strength, deformation parameters, dilation angle evolution, and macroscopic failure modes of the sandstone were systematically analyzed. The results indicate a significant critical transition point in the mechanical behavior of the sandstone at 400 °C. Below this threshold, thermal-induced microcrack closure leads to an increase in peak strength (with the peak strength at 800 °C increasing by approximately 67% compared to room temperature). Conversely, above 400 °C, thermal damage to the mineral grains intensifies, causing the crack propagation pattern to transition from brittle shear to a complex tension-shear splitting mode, accompanied by severe dilatancy (with a generalized Poisson’s ratio exceeding 0.8). Based on these findings, this study proposes a stage-wise damage evolution model alongside a targeted zonal support strategy, recommending the application of high-prestressed support in high-temperature zones above 400 °C to suppress tensile failure. Ultimately, this research provides a crucial theoretical basis for evaluating the long-term stability of high-temperature underground engineering projects and ensuring operational safety. Full article

Five modifications of polytetrafluoroethylene (PTFE) are considered as a modern alternative to PTFE as sliding layers of bridge bearing parts. Radiation-modified PTFE without additives and with nano-additives as well as composites based on PTFE with bronze inclusions and nanomodified carbon fiber fillers were investigated. Ultra-high-molecular-weight polyethylene (UHMWPE) and classic pure PTFE were considered as control samples. The thermomechanical properties of the materials were studied within the framework of dynamic mechanical analysis in the operating temperature range of bridge structures [−40; +80] °C. The exit zones from the linear theory of viscoelasticity were established for all the materials considered. Temperature dependencies of the storage modulus and the loss modulus were determined. Thermoviscoelastic models of material behavior were constructed using a numerical identification procedure, experimental data, and simulation models. The thermomechanics of materials during the deformation of the spherical support part of the bridge were analyzed. Temperature dependencies of the parameters of the contact stress-strain state were determined with an average coefficient of determination R² = 0.97 and an average error size RMSE = 0.092. Full article

The thermo-mechanical degradation of the base–subgrade interface in airport pavements was investigated using a three-dimensional sequentially coupled finite element framework in ABAQUS 2023, in which progressive interfacial debonding was described by a bilinear cohesive-zone model through the damage variable CSDMG. The results show that thermal loading markedly accelerates interface degradation when combined with moving wheel loads. Compared with the wheel-loading-only condition, thermo-mechanical coupling advances the first damage initiation from 0.04993 h to 0.00254 h and shortens the severe-degradation stage from 1.000 h to 0.00927 h. This acceleration is attributed to a thermal stress pre-weakening effect, whereby constrained thermal deformation partially consumes the available cohesive resistance and shifts the interface closer to the softening threshold before external loading is applied. A decomposition of the mixed-mode initiation criterion further indicates that the first damage event is governed by synergistic normal–shear interaction, with the normalized contribution ratio (t_n/t_n⁰)²:(t_s/t_s⁰)² = 0.38:0.62, showing that wheel-induced shear is the dominant trigger while tensile opening induced by thermal curling provides substantial preconditioning assistance. In addition, a representative normalized comparison between simulated average CSDMG and cumulative AE hit count demonstrates a consistent stage evolution from distributed deformation to accelerated localization and residual stabilization. These findings indicate that the base–subgrade interface should be treated as a temperature-sensitive weak layer in airport pavement assessment, particularly near joints and other discontinuity-controlled regions. Full article

Hot forging of Ti-6Al-4V is extensively utilized in the manufacture of orthopedic implants; however, the coupled influence of strain rate and temperature on ductile damage evolution during the forging of femoral stems remains insufficiently quantified. In this study, a finite element framework is developed to analyze and optimize the hot forging process, incorporating strain rate- and temperature-dependent plasticity, as well as the Johnson–Cook damage criterion. Mesh convergence is established, and the assumption of quasi-adiabatic conditions is substantiated via Péclet number analysis. A full factorial design is implemented by varying the ram velocity (0.1–0.5 m/s) and initial billet temperature (850–950 °C) to evaluate the forging load, stress triaxiality, equivalent plastic strain, and damage accumulation. Results indicate that process kinetics govern the mechanical response: increasing the ram velocity enhances strain-rate hardening, resulting in higher peak loads, while explicitly reducing stress triaxiality and suppressing ductile damage evolution. Conversely, temperature exhibits a secondary influence within the investigated domain. Validation of the damage criterion confirms safe operating windows, identifying low-velocity forging as a high-risk condition for localized defect formation. These findings provide practical guidelines for the strain-rate-based optimization of thermomechanical processing parameters for Ti-6Al-4V femoral stems. Full article

Plantar orthoses play an important role in podiatric care, as they help to redistribute plantar loads, improve foot function, and support the treatment of various conditions, including diabetic foot disease. In this context, additive manufacturing has substantially expanded the capacity to produce customized orthoses through digital geometry acquisition, computational design, and controlled fabrication. From a biomimetic and bionic perspective, 3D-printed plantar orthoses can be understood as engineered interfaces that reproduce, support, or modulate key biomechanical functions of the human foot, including load redistribution, shock attenuation, adaptive stiffness, and gait stabilization. Additive manufacturing enables these biological and biomechanical principles to be translated into patient-specific devices through controlled geometry, graded structures, and material selection. Moreover, from a sustainability perspective, recycled polylactic acid (rPLA) has emerged as a material of potential interest for this type of application, not only because of its compatibility with 3D-printing processes but also because it offers the possibility of reusing polymer waste and reducing the consumption of virgin raw materials in devices whose service life may be limited. This review examines the conditional viability of recycled PLA for 3D-printed plantar orthoses by integrating direct clinical evidence on orthotic function with indirect technical evidence from material-level and process-level studies. The reviewed literature indicates that recycled PLA may offer environmental and economic benefits; however, repeated thermomechanical reprocessing may alter viscosity, dimensional consistency, crystallinity, interlayer adhesion, and mechanical reliability. Recent orthosis-focused studies show that extrusion-based technologies can be applied to customized insoles, lattice or internally reinforced structures, multimaterial systems, and emerging smart concepts; however, most of these developments still rely on virgin or ad hoc-designed materials rather than recycled feedstocks. Overall, the available evidence suggests that recycled PLA should not yet be regarded as a direct substitute for virgin PLA in plantar orthoses. At present, the evidence supporting the use of recycled PLA in plantar orthoses is predominantly indirect and technical rather than directly clinical. Its use appears technically promising, but its viability remains conditional and depends on feedstock traceability, control of the manufacturing process, the suitability of material properties for device function, and validation of the orthosis under clinical conditions. Full article