Journal of Manufacturing and Materials Processing

This research investigates the micro-mechanisms and process control associated with the recovery of platinum group metals (PGMs) from spent automotive catalysts (SACs) through iron capturing. High-temperature smelting experiments, complemented by SEM-EDS and XRD analyses, demonstrate that PGMs spontaneously migrate from the slag phase to the iron phase, driven by interfacial energy, where they are captured to form alloy droplets with a PGM content exceeding 4 wt.%. The composite flux (CaO/H₃BO₃) markedly diminishes slag viscosity and enhances the density differential between slag and metal. This facilitates the aggregation, sedimentation, and separation of alloy droplets in accordance with Stokes’ law, thereby lowering the effective capture temperature from 1700 °C to 1500 °C and reducing energy consumption. Additionally, the flux inhibits the formation of detrimental Fe-Si alloys. PGMs form substitutional solid solutions that are uniformly dispersed within the iron matrix. This study provides both the theoretical and technical foundations necessary for the development of efficient, low-energy processes aimed at capturing and recovering Fe-PGMs alloys.

This study evaluated the ballistic performance and failure mechanisms of epoxy-based hybrid laminates reinforced with abaca/UHMWPE and pineapple leaf fiber (PALF)/UHMWPE fabrics fabricated by using vacuum-assisted hand lay-up. Ballistic tests utilized 9 mm full metal jacket (FMJ) rounds (~426 m/s impact velocity) under NIJ Standard Level IIIA conditions (44 mm maximum allowable BFS). This experimental test was complemented by finite element analysis (FEA) incorporating an energy-based bilinear fracture criterion to simulate matrix cracking and fiber pull-out. The results showed that abaca/UHMWPE composites exhibited lower backface signature (BFS) and depth of penetration (DOP) values (~23 mm vs. ~42 mm BFS; ~7 mm vs. ~9 mm DOP) than PALF/UHMWPE counterparts, reflecting superior interfacial adhesion and more ductile failure modes. Accelerated weathering produced matrix microcracking and delamination in both systems, reducing overall ballistic resistance. Scanning electron microscopy confirmed improved fiber–matrix bonding in abaca composites and interfacial voids in PALF laminates. The FEA results reproduced major failure modes, such as delamination, fiber–matrix debonding, and petaling, and identified stress concentration zones that agreed with experimental observations, though the extent of delamination was slightly underpredicted. Overall, the study demonstrated that abaca/UHMWPE hybridcomposites offer enhanced ballistic performance and durability compared with PALF/UHMWPE laminates, supporting their potential as sustainable alternatives for lightweight protective applications.

Three different Gas Tungsten Arc Welding methods—DC single electrode, DC double electrode, and PC double electrode—were analyzed using SS304 steel as the base material. Numerical models were developed to simulate the arc plasmas and calculate heat flux, current density, and wall shear stress on the surface of the workpiece. These data were used as input to simulate the weld pools across all three configurations. Experimental validation showed a good agreement with the numerical results. In the double-electrode setup, electromagnetic interaction caused the arcs to deflect, resulting in an 8% reduction in the maximum heat flux and a 4% decrease in the maximum current density. Marangoni stress had a notable effect on the weld pool shape, creating a -shaped pool with the stationary single-electrode setup, whereas the double-electrode setup produced a -shaped pool after 2 s. In the moving weld pool configurations, the sizes of the pools were maximum at the trailing electrodes. The pool was 1.7 mm deep and 5.6 mm wide in DC double- and 1.4 mm deep and 5.4 mm wide in PC double-electrode configurations. The pool depth and width were only 1.0 mm and 4.2 mm when a DC single-electrode setup was used. Comparing the three methods, the DC double-electrode setup produced the largest pool size. The findings of this research offer guidance for enhancing different arc settings and electrode arrangements to attain the intended welding quality and performance.