36 Results Found

Perovskite manganites (AMnO₃) and perovskite-like manganites (A′_1−xA_xMnO₃) are complex oxide materials that have attracted significant attention from the scientific community in recent years due to their structural flexibility, mixed-vale...

Transition metal functional oxides, e.g., perovskite manganites, with strong electron, spin and lattice correlations, are well-known for different phase transitions and field-induced colossal effects at the phase transition. Recently, the interfaces...

Four perovskite manganite samples, La_0.80Ag_0.20MnO₃ (LA), La_0.78Eu_0.02Ag_0.20MnO₃ (LEA), La_0.80Pb_0.05Ag_0.15MnO₃ (LPA), and La_0.77Eu_0.03Pb_0.05Ag_0.15MnO₃ (LEPA), were prepared by the Pechini sol–gel method. The samples were characterized by X-ray...

The use of perovskite manganite nanoparticles in magnetic hyperthermia has attracted significant attention due to their tunable magnetic properties and high specific absorption rate (SAR). In this work, we present a combined experimental and theoreti...

This study reports the structural, morphological, and magnetic properties of ruthenium doping at the manganese site in Pr_0.67Ba_0.33MnO₃ manganites. Rietveld refinement X-ray powder diffraction (XRD) data show that Pr_0.67Ba_0.33MnO₃ and Pr_0.67Ba_0.33Mn₀...

This work investigates nanostructured Ho_0.5Ca_0.5MnO₃, considered a model system of the Ln_0.5Ca_0.5MnO₃ series of manganites with perovskite structures featuring small lanthanide (Ln) ions half-substituted by Ca ions. Here, we propose a modified hybrid...

An improved understanding of the correlation between the electronic properties of Mn-O bonds, activity and stability of electro-catalysts for the oxygen evolution reaction (OER) is of great importance for an improved catalyst design. Here, an in-dept...

Lateral compositionally-graded thin films are powerful media for the observation of phase boundaries as well as for high-throughput materials exploration. We herein propose a method to prepare epitaxial lateral compositionally-graded films using a du...

Here we report the synthesis and investigation of bulk and nano-sized La_0.7Ba_0.3−xCa_xMnO₃ (x = 0, 0.15, 0.2 and 0.25) compounds that are promising candidates for magnetic refrigeration applications. We compare the structural and magnetic proper...

Here, we report synthesis and investigations of bulk and nano-sized La_(0.7−x)Eu_xBa_0.3MnO₃ (x ≤ 0.4) compounds. The study presents a comparison between the structural and magnetic properties of the nano- and polycrystalline manganites La_(0.7&...

Magnetic perovskite films have promising properties for use in energy-efficient spintronic devices and magnetic refrigeration. Here, an epitaxial ferromagnetic La_0.67Ba_0.33Mn_0.95Ti_0.05O₃ (LBMTO-5) thin film was grown on SrTiO₃(001) single crystal sub...

Double-layered manganites are natural superlattices with low thermal conductivity, which is of importance for potential thermoelectric applications. The Gd_2−2xSr_1+2xMn₂O₇ (x = 0.5; 0.625; 0.75) were prepared by the solid-state reaction method....

Lanthanum manganite (LMO) thin films were deposited by co-sputtering La and Mn targets in an Ar and O₂ gas mixture. The films were synthesized on silicon and fused silica substrates. The influences of thermal annealing on the structure, optical and e...

Here we report investigations of bulk and nano-sized Pr_0.65Sr_(0.35−x)Ca_xMnO₃ compounds (x ≤ 0.3). Solid-state reaction was implemented for polycrystalline compounds and a modified sol–gel method was used for nanocrystalline compounds....

The inclusion of La-Mn vacancies in LaMnO₃ nanoparticles leads to a noticeable change in conductivity behavior. The sample retains its overall insulator characteristic, with a typical thermal activation mechanism at high temperatures, but it presents...

Experimental and numerical investigations of the alternating current (AC) susceptibility, $\mathsf{\chi }\left(H\right) ~ \mathrm{d}M/\mathrm{d}H,$ examined multigrain La_0.66Sr_0.34MnO₃ (LSMO) thin films (thickness d = 250 nm) grown by radio-frequency (RF) magnetron sputtering on la...

This study synthesizes the neodymium-based manganites with Bi doping, Nd_1−xBi_xMnO₃ (x = 0, 0.25 and 0.50) using the solid-state reaction route. The crystal structural, morphological and magnetic properties were determined using X-ray diffractio...

The magnetic and magnetocaloric effects of potassium-substituted La_0.8−xK_xBa_0.05Sr_0.15MnO₃ (0 ≤ x ≤ 0.20) manganite were explored. The samples in polycrystalline form were synthesized by the sol–gel method, with a final sintering te...

The effects of an applied strain tensor on the electrical resistivity of a manganite granular system are investigated using a simple approach describing the induced deformation in terms of the tilt angle between adjacent grains. The results obtained...

YMnO₃ is a P-type semiconductor with a perovskite-type structure (ABO₃). It presents two crystalline systems: rhombohedral and hexagonal, the latter being the most stable and studied. In the hexagonal system, Mn³⁺ ions are coordinated by five oxygen...

Hole-doped manganese oxides exhibit a gigantic negative magnetoresistance, referred to as colossal magnetoresistance (CMR), owing to the interplay between double-exchange (DE) ferromagnetic metal and charge-ordered antiferromagnetic insulator/semicon...

The Curie temperature (Tc) of LaMnO₃-based perovskites is one of the most important properties associated with their magnetic and spintronic applications. The search for new perovskites with even higher Tc is a challenging problem in material design....

Cubic and rhombohedral phases of lanthanum manganite were synthesized in a high-pressure reactor. A mixture of La and Mn nitrates with ethylene glycol at a synthesis temperature of 200 °C and a calcination temperature of up to 1000 °C, result...

The appearance of spin-induced ferroelectric polarization in the so-called type-II multiferroic materials has received a lot of attention. The nature and mechanisms of such polarization were intensively studied using perovskite rare-earth manganites,...

Studying catalysts in situ is of high interest for understanding their surface structure and electronic states in operation. Herein, we present a study of epitaxial manganite perovskite thin films (Pr_1−xCa_xMnO₃) active for the oxygen evolution reacti...

The progressive research trends in the development of low-cost, commercially competitive solid oxide fuel cells with reduced operating temperatures are closely linked to the search for new functional materials as well as technologies to improve the p...

Chemical doping via insertion of ions into the lattice of a host material is a key strategy to flexibly manipulate functionalities of materials. In this work, we present a novel case study on the topotactic insertion of fluoride ions into oxygen-defi...

In this study, Strontium (Sr)-doped perovskite lanthanum manganite (La_1−xSr_xMnO₃) nanoparticles were prepared by the sol–gel method and used as electrode materials of supercapacitors. Microstructures, morphologies, and electrochemical pro...

A revisited study of perovskite-based manganite La_0.67Sr_0.33MnO₃ (LSMO) deposited onto corning-glass (CG) substrates is reported here. The LSMO films were fabricated with RF sputtering with different deposition times, varying from 60 to 180 min, resu...

Developing a highly stable and non-precious, low-cost, bifunctional electrocatalyst is essential for energy storage and energy conversion devices due to the increasing demand from the consumers. Therefore, the fabrication of a bifunctional electrocat...

The structural phase transition and associated orientational domain configurations in perovskite-type Bi_xCa_1−xMnO₃ ceramics were investigated in this work. A series of Bi_xCa_1−xMnO₃ solid solutions with x = 0.05, 0.25, 0.33 were synthesize...

The study reports the synthesis and characterization of the magnetic and magnetocaloric effects of metal-oxide (MO) modified La_0.7Ca_0.3MnO₃ perovskites manganite. The powder composite samples, with a nominal composition of (1 − x)La_0.7Ca_0.3MnO₃...

Oxide systems with the nominal composition LaCaCuVMnO_7.5 and composites modified with the YBa₂Cu₃O_x phase were synthesized by the solid-state reaction method. The phase composition and structural features were systematically investigated by X-ray dif...

This paper presents a comprehensive investigation into the synthesis, morphological characteristics, electrical conductivity, dielectric behavior, and electrocatalytic activity of perovskite-structured iron manganite (FeMnO₃), with a specific focus o...

In this report, lanthanum strontium manganite at different Sr²⁺ ion concentrations, as well as Gd³⁺ or Sm³⁺ ion substituted La_0.5−YM_YSr_0.5MnO₃ (M = Gd and Sm, y = 0.2), have been purposefully tailored using a sol gel auto-combustion approach. XRD pro...

A-site-ordered quadruple perovskite manganites, AMn₇O₁₂, show many interesting physical phenomena, including orbital and spin modulations, spin-induced multiferroic properties, and competitions between different magnetic ground states. Doping with Cu...