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Inorganic Chemistry in Asia, 2nd Edition
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Inorganic Chemistry in Asia, 2nd Edition

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Inorganic Chemistry".

Deadline for manuscript submissions: 30 June 2026 | Viewed by 419

Special Issue Editor

Prof. Dr. Takashiro Akitsu

E-Mail Website
Guest Editor
Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
Interests: inorganic chemistry; coordination chemistry; Schiff base; crystallography
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear colleagues,

We are pleased to announce the second edition of the Special Issue "Inorganic Chemistry in Asia" of Molecules.

Following the success of the first edition, this Special Issue will also present a high-quality collection of work from scientists in Asian countries, as well as contributions from other countries concerning the advances in inorganic chemistry in Asia (both original research articles and comprehensive review papers are welcome).

This Special Issue will discuss new knowledge or cutting-edge developments in the broadly defined inorganic chemistry research field, including coordination chemistry, organometallic chemistry, solid-state chemistry, bioinorganic chemistry, nuclear- and radiochemistry, analytical chemistry, etc. This Special Issue is a forum for the exchange of research findings and innovative ideas in the field.

Dr. Takashiro Akitsu
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • inorganic chemistry
  • coordination chemistry
  • organometallic chemistry
  • solid-state chemistry
  • bioinorganic chemistry
  • nuclear- and radiochemistry
  • theoretical calculation

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Published Papers (1 paper)

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Research

19 pages, 4784 KiB  
Article
Investigation of the Adsorption and Reactions of Methyl Radicals on Transition Metal (M = Co, Ni, Pd, Pt) (111) Surfaces in Aqueous Suspensions
by Pankaj Kumar, Dan Meyerstein, Amir Mizrahi and Haya Kornweitz
Molecules 2025, 30(15), 3065; https://doi.org/10.3390/molecules30153065 - 22 Jul 2025
Viewed by 333
Abstract
The DFT method was used to evaluate the adsorption of methyl radicals and the evolution of ethane on the M(111) (M = Co, Ni, Pd, Pt) surfaces, eight metal atoms, in aqueous medium. A maximum of five and four radicals can be adsorbed [...] Read more.
The DFT method was used to evaluate the adsorption of methyl radicals and the evolution of ethane on the M(111) (M = Co, Ni, Pd, Pt) surfaces, eight metal atoms, in aqueous medium. A maximum of five and four radicals can be adsorbed on Co(111) and Ni(111), respectively, and six on Pd(111) and Pt(111) (top site). The ethane evolution occurs via the Langmuir–Hinshelwood (LH) or Eley–Rideal (ER) mechanisms. The production of ethane through the interaction of two adsorbed radicals is thermodynamically feasible for high coverage ratios on the four surfaces; however, kinetically, it is feasible at room temperature only on Co(111) at a coverage of (5/5) and on Pd(111) at a coverage ratio of 4/6, 5/6, and 6/6. Ethane production occurs via the ER mechanism: a collision with solvated methyl radical produces either C2H6 or CH2∗+CH4(aq). On Pd(111) the product is only C2H6, on Pt(111), both products (C2H6 or CH2∗) are plausible, and on Co(111) and Ni(111), only CH2∗+CH4(aq) is produced. Further reactions of CH2∗ with CH2∗ or CH3∗ to give C2H4∗ or C2H5∗ are thermodynamically plausible only on Pt(111); however, they are very slow due to high energy barriers, 1.48 and 1.36 eV, respectively. Full article
(This article belongs to the Special Issue Inorganic Chemistry in Asia, 2nd Edition)
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