Effect of Bi Substitution on Structural and AC Magnetic Susceptibility Properties of Nd1−xBixMnO3
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. Structural Analysis
3.2. FTIR Spectra
3.3. Morphology
3.4. AC Susceptibility Measurement
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Doping Content (x) | 0.0 | 0.25 | 0.50 |
---|---|---|---|
Space group | Pbnm | Pbnm | Pbnm |
Symmetry | Orthorhombic | Orthorhombic | Orthorhombic |
a (Å) | 5.4240 | 5.4292 | 5.4321 |
b (Å) | 5.5570 | 5.6534 | 5.7712 |
c (Å) | 7.6648 | 7.6323 | 7.8536 |
α = β = γ | 90 | 90 | 90 |
Volume (Å3) | 231.03 | 234.27 | 236.25 |
Doping Content (x) | 0 | 0.25 | 0.50 |
---|---|---|---|
Mn–O1 (Å) | 1.9903 (5) | 2.0407 (7) | 1.9874 (4) |
Mn–O2 (Å) | 2.0256 (5) | 1.9685 (6) | 1.9289 (3) |
< Mn–O > (Å) | 2.0080 (5) | 2.0046 (6) | 1.9581 (2) |
Mn–O1–Mn (°) | 148.62(1) | 138.45 (3) | 148.58 (9) |
Mn–O2–Mn (°) | 154.61(1) | 149.36 (12) | 154.08 (4) |
< Mn–O–Mn > (°) | 151.62 (1) | 143.91 (2) | 151.33 (6) |
χ2 | 1.038 | 2.581 | 3.812 |
RP (%) | 8.27 | 16.76 | 14.37 |
RWP (%) | 10.98 | 21.10 | 19.87 |
< rA > (Å) | 1.109 | 1.142 | 1.175 |
τ | 0.515 | 0.522 | 0.529 |
x | 0 | 0.25 | 0.50 |
---|---|---|---|
TN (K) | 64 | 64 | 55 |
TC (K) | 76 | 75 | 67 |
TG (K) | 181 | 198 | 182 |
GP (K) | 138 | 164 | 171 |
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Azhar, N.A.; Ismail, I.S.; Mohamed, N.B.; Hashim, A.; Mohamed, Z. Effect of Bi Substitution on Structural and AC Magnetic Susceptibility Properties of Nd1−xBixMnO3. Crystals 2020, 10, 521. https://doi.org/10.3390/cryst10060521
Azhar NA, Ismail IS, Mohamed NB, Hashim A, Mohamed Z. Effect of Bi Substitution on Structural and AC Magnetic Susceptibility Properties of Nd1−xBixMnO3. Crystals. 2020; 10(6):521. https://doi.org/10.3390/cryst10060521
Chicago/Turabian StyleAzhar, Nurul Atiqah, Intan Solehah Ismail, Nur Baizura Mohamed, Azhan Hashim, and Zakiah Mohamed. 2020. "Effect of Bi Substitution on Structural and AC Magnetic Susceptibility Properties of Nd1−xBixMnO3" Crystals 10, no. 6: 521. https://doi.org/10.3390/cryst10060521
APA StyleAzhar, N. A., Ismail, I. S., Mohamed, N. B., Hashim, A., & Mohamed, Z. (2020). Effect of Bi Substitution on Structural and AC Magnetic Susceptibility Properties of Nd1−xBixMnO3. Crystals, 10(6), 521. https://doi.org/10.3390/cryst10060521