Minerals, Volume 16, Issue 1 (January 2026) – 118 articles

This study aimed to design a new composite with promising antimicrobial and antioxidant properties by a simple modification process of natural bentonite (B) with polysaccharide chitosan isolated from edible mushrooms Agaricus bisporus—ChM (sample B–ChM) and subsequently with a cationic surfactant—hexadecyltrimethylammonium bromide—HB (sample B–ChM–HB) for effective removal of mycotoxin zearalenone (ZEN). Characterization confirmed the presence of ChM in B–ChM and both ChM and HB in B–ChM–HB. Compared to non- or slightly inhibitory activity of B and B–ChM, B–ChM–HB showed fungicidal activity against yeast Candida albicans and mycotoxigenic mold Aspergillus flavus, with a reduction of 6.00 log10 (CFU/mL) and 5.32 log10 (CFU/mL), respectively. B–ChM–HB showed a very high neutralization ability on •DPPH (89.03%–95.99%) in the concentration range of 0.625–5.0 mg/mL, the highest ferrous ion chelating ability (80.25%) at a concentration of 0.625 mg/mL, and did not induce lipid peroxidation in the linoleic acid model system. While B and B–ChM exhibited low adsorption of ZEN, its adsorption by B–ChM–HB was significantly higher. The equilibrium results of B–ChM–HB for ZEN were in accordance with the linear isotherm model at pH 3 and 7, pointing out that hydrophobic interactions (partitioning process) were relevant for toxin adsorption by the composite. Similar maximum ZEN adsorbed amounts under the applied experimental conditions (14.4 mg/g) at both pH values suggested that its adsorption was independent of the pH. This study reported for the first time that a novel composite of B with ChM and HB showed promising antimicrobial and antioxidant properties and was an efficient adsorbent for mycotoxin ZEN. Full article

The South Sakhalin mud volcano (Sakhalin Island, Russia) emits HCO₃-Cl/Na-Mg water, emanates CO₂ prevailing over CH₄ in the gas phase, and extrudes mud bearing five carbonate mineral species. The study focuses on the distribution, diversity, and origin of the carbonate minerals from the mud volcano (MV) ejecta, in terms of carbon cycle processes. The data presented include a synthesis of field observations, compositions of MV gases and waters, chemistry of carbonate minerals, as well as stable isotope geochemistry of MV waters (δ¹³C, δD, and δ¹⁸O) and carbonates (δ¹³C and δ¹⁸O). The sampled MV waters are isotopically heavy, with δ¹⁸O = +5.7‰ to +7.5‰ VSMOW, δD = −18.0‰ to −11.0‰ VSMOW, and ¹³C (δ¹³C_DIC = +6.9‰ to +8.1‰ VPDB). This composition may be due to the dilution of basinal water with dehydration water released during the diagenetic illitization of smectite. Carbonates in the sampled mud masses belong to three genetically different groups. Mg-rich siderite, (Fe_0.54–0.81Mg_0.04–0.30Ca_0.05–0.23Mn_0.00–0.08)CO₃, disseminated in abundance throughout the mud masses, coexists with common calcite and sporadic ankerite. The trace-element chemistry of Mg-siderite, as well as the oxygen (δ¹⁸O = +34.4‰ to +36.8‰ VSMOW) and carbon (δ¹³C = −1.3‰ to +0.6‰ VPDB) isotopic signatures, confirms its authigenic origin. Siderite formed during early diagenesis of the Upper Cretaceous sandy and clayey marine sediments mobilized by mud volcanism in the area. Another assemblage, composed of dawsonite, siderite, and vein calcite (±kaolinite), represents altered arkose sandstones found as few fragments in the mud. This assemblage may be a marker of later CO₂ flooding into the sandstone aquifer in the geological past. The trace-element chemistry, particular morphology, and heavy C (δ¹³C = +5.5‰ to +7.0‰ VPDB) and O (δ¹⁸O = +39.1‰ to +39.5‰ VSMOW) isotope compositions indicate that aragonite is the only carbonate species that is related to the current MV activity. It crystallized in a shallow reservoir and was maintained by CO₂ released from rapidly ascending liquefied mud and HCO₃-Cl/Na-Mg-type of MV waters. Full article

Illite, a clay mineral, is used in diverse fields such as agriculture, cosmetics, and the food-related industry due to its many advantages, including biocompatibility, UV protection, antibacterial activity, high adsorption capacity for hazardous substances, and cost-effectiveness. However, its relatively large size, broad size distribution, and irregular morphology limit its broader applications. This study investigated the control of particle size and distribution during wet ball milling (WBM) using five media—acetone, ethanol, water, aqueous NaCl solution, and aqueous phosphoric acid solution—over milling times of 2–10 h. Prolonged milling progressively reduced particle size and narrowed the size distribution. Acetone and ethanol exhibited notably superior size-reduction performance compared with the aqueous systems, among which phosphoric acid solution showed the least effectiveness, likely attributed to variations in their physicochemical properties, including viscosity (η) and surface tension (σ), and in their interfacial interactions with illite. Optimal milling in acetone for 10 h resulted in the smallest particles (~700 nm), the narrowest distribution, the largest specific surface area, and the highest moisture retention. Overall, these findings demonstrate that the physicochemical properties of the milling medium, which govern WBM efficiency through fluid dynamics and particle–medium interactions, thereby determine the size and distribution of milled particles. Full article

Accurate characterization of ore grindability is essential for optimizing mill throughput, reducing energy consumption, and predicting mill performance under varying ore conditions. However, the standard Bond work index (BWI) test remains time-consuming, costly, and requires a large amount of sample. This study evaluates the effectiveness of several rapid, low-cost alternatives, Leeb rebound hardness (LRH), Cerchar abrasivity Index (CAI), portable X-ray fluorescence (pXRF), and hyperspectral imaging (HSI), as proxies for grindability in gold-bearing ores. Sixty-two hand-size rock samples collected from two adjacent Canadian open-pit mines were analyzed using these techniques and subsequently grouped into ten ore groups for BWI testing. LRH and CAI effectively differentiated moderate (<15 kWh/t) from hard (>15 kWh/t) grindability classes, while geochemical features and HSI-based mineralogical attributes also showed strong predictive capability. HSI, in particular, provided non-destructive, spatially continuous data that are advantageous for complex geology and large-scale operational deployment. A conceptual workflow integrating HSI with complementary field measurements is proposed to support comminution planning and optimization, enabling more responsive and timely decision-making. While BWI testing remains necessary for circuit design, the results highlight the value of combining rapid proxy measurements with advanced analytics to enhance geometallurgical modelling, reduce operational risk, and improve overall mine-to-mill performance. Full article

The Yawan gold deposit, located in the Western Qinling Orogen, contains gold mineralisation that is predominantly controlled by approximately east-west-trending fault systems. This study integrates field geology, petrography, cathodoluminescence imaging, electron probe microanalysis of gold-bearing minerals (pyrite and arsenopyrite), and in situ laser ablation U-Pb dating of calcite to constrain the timing of mineralisation and to elucidate the mechanisms of gold enrichment. This study reveals that the deposit is significantly structurally controlled and comprises two discrete mineralisation stages: a quartz-pyrite (Py1)-arsenopyrite (Apy1)-chalcopyrite assemblage (Stage 1), and a quartz-calcite-pyrite (Py2)-arsenopyrite (Apy2)-stibnite-sphalerite-galena assemblage (Stage 2). Py1 displays distinct zonation, with rim As contents notably higher than core values, while Co and Ni contents gradually decrease from core to rim. Py2 is characterised by high As (0.00%–4.72%), low Fe/S ratios, and a porous texture, containing gold and arsenopyrite inclusions. Invisible gold occurs in lattice-bound form in both Py1 and Py2. The As-Fe-S ternary diagram of pyrite indicates that Au⁺ likely entered the crystal lattice as a solid solution. Arsenopyrite geothermometry yields a mineralisation temperature of 389 ± 44 °C, and sulfur fugacity (ƒS₂) decreased markedly from Stage 1 to Stage 2. Combined with the S and Fe characteristics of pyrite, these features support a medium-temperature metamorphic hydrothermal environment. U-Pb dating of calcite from Stage 2 yields an age of 215.6 ± 7.1 Ma. In summary, the Yawan gold deposit belongs to the orogenic gold system, with its gold precipitation and enrichment controlled by sulfidation triggered by Late Triassic tectono-fluid activity. Full article

The Weishan rare earth element (REE) deposit, located in western Shandong, North China Block, is a typical carbonatite REE deposit and constitutes the third largest light REE resource in China. Its mineralization is closely related to the multi-stage evolution of a carbonatite magma–hydrothermal system. However, the mechanisms governing REE enrichment, migration, and precipitation remain insufficiently constrained from a mineralogical perspective, which hampers the understanding of the ore-forming processes and the establishment of predictive exploration models. Apatite is a pervasively developed REE phase in the Weishan deposit which occurs in multiple generations, and thus represents an ideal recorder of the magmatic–hydrothermal evolution. In this study, different generations of apatite hosted in carbonatite orebodies from the Weishan deposit were investigated using cathodoluminescence (CL), electron probe microanalysis (EPMA), and in situ LA-ICP-MS trace element analysis. Three types of apatite were identified. In paragenetic sequence, Ap-1 occurs as polycrystalline aggregates coexisting with calcite, is enriched in Na, Sr, and LREEs, and shows high (La/Yb)_N ratios, suggesting crystallization from an evolved carbonatite magma. Ap-2 and Ap-3 display typical replacement textures: both contain abundant dissolution pits and dissolution channels within the grains, which are filled by secondary minerals such as monazite and ancylite, and thus exhibit characteristic features of fluid-mediated dissolution–reprecipitation during the hydrothermal stage. Ap-2 is commonly associated with barite and strontianite, whereas Ap-3 is associated with pyrite and monazite and is characterized by relatively sharp grain boundaries with adjacent minerals. From Ap-1 to Ap-3, total REE contents decrease systematically, whereas Na, Sr, and P contents increase. All three apatite types lack Eu anomalies but display positive Ce anomalies. Discrimination diagrams involving LREE-Sr/Y and log(Ce)-log(Eu/Y) indicate that apatite in the Weishan REE deposit formed during the magmatic to hydrothermal evolution of a carbonatite, and that the dissolution of early magmatic apatite, followed by element remobilization and mineral reprecipitation, effectively records the progressive evolution of the ore-forming fluid. Full article

Microbial carbonates are globally known petroleum reservoirs. However, the complex interplay between deposition and diagenesis significantly influences the pore network distribution in these microbial carbonate reservoirs. The present study aims to discuss diagenetic alterations in the Jurassic microbial carbonate successions from foreland basins in the NW Himalayas. Geological field observations, petrographic analysis, scanning electron microscopy, and isotopic analysis were applied to highlight the role of diagenesis in reservoir characterization of shallow marine carbonates. The results indicate that dolomitization, dissolution, and fracturing during the early to late phase of diagenesis enhanced the reservoir pore network. However, cementation, micritization, and mechanical compaction considerably reduced the reservoir pore distribution. Furthermore, fractures and stylolites that developed perpendicular to bedding planes indicate the role of convergent tectonics in developing the fracture network that allowed fluid migration and improved the pore spaces in microbial carbonate reservoirs. Isotopic data revealed shallow-burial diagenesis with marine and meteoric influx that provides avenues for the movement of fluids. These fluids are associated with microbial activity in carbonate rocks along the faults and fractures that were developed because of compressional tectonics, evident from the perpendicular fracture network. This study recommends the integration of deposition and diagenesis to refine the pore network distribution and characterization of carbonate reservoirs around the globe. Full article

Seepage–dissolution in carbonate rock fractures serves as the core driver governing the evolution of key engineering projects, including reservoir dam stability, CO₂ geological sequestration, and unstable rock collapse mitigation strategies. While physical heterogeneity (e.g., fracture aperture, mineral distribution) is widely recognized as a critical factor regulating dissolution processes, the specific influence of mineral distribution heterogeneity on dissolution rates still lacks quantitative quantification. To address this gap, this study focuses on limestone fractures and employs multi-component reactive transport numerical simulations to model acidic fluid (pH = 5.0) seepage–dissolution under two Darcy flux conditions (37.8/378 m·yr⁻¹). It investigates the controlling mechanisms of fracture roughness (λ_b = 0.036~0.308) and calcite contents (55%, 75%, 95%) on dissolution dynamics, and analyzes spatial variations in local Darcy velocity, reaction rate, and effective dissolution rate (R_eff,i). Results demonstrate that mineral distribution heterogeneity directly induces pronounced spatial heterogeneity in dissolution behavior: diffusion dominates under low flux (simulation duration: 48.3 days), forming discrete reaction fronts (~15 mm) controlled by mineral clusters; advection prevails under high flux (simulation duration: 4.83 days), generating alternating dissolution–deposition zones (~7.5 mm) with R_eff,i one order of magnitude greater than that under low flux. Notably, 55% calcite content yields the highest R_eff,i (1.87 × 10⁻¹¹ mol·m⁻²·s⁻¹), 0.94 orders of magnitude greater than that at 95% calcite content. A strong linear correlation (R² > 0.98) exists between the Damköhler number (Da_I) and R_eff,i at the same calcite content. Furthermore, the synergistic interaction between fracture aperture and mineral heterogeneity amplifies dissolution complexity, with high roughness (λ_b = 0.308) coupled with 55% calcite content achieving the highest R_eff,i of 2.1 × 10⁻¹¹ mol·m⁻²·s⁻¹. This study provides critical theoretical insights and quantitative data support for fractured rock mass evolution prediction models, geological hazard prevention, and geological carbon sequestration optimization. Full article

In magnetic separation processes, the capture radius R_c of magnetic particles achieved by the magnetic matrix constitutes a critical parameter governing the separation efficiency and operational performance of magnetic separation equipment. Through a systematic study of the characteristics of R_c and the factors influencing it, the application capability of separation systems can be notably improved. To address the lack of systematic research on R_c under low magnetic field intensities (<0.6 T), a key gap compared to conventional high gradient magnetic separation (HGMS) operating at ≥0.6 T, the motion trajectories of magnetic particles adjacent to a rod-shaped matrix, as well as their final capture or repulsion behaviors, were observed via a high-speed camera. Concurrently, these processes were accurately reproduced using the finite element method (FEM). This study innovatively integrates experimental validation and FEM simulation, achieving mutual verification that single-method studies cannot provide. Based on the experimentally validated FEM model, the effects of magnetic field intensity H, rod-shaped matrix diameter Φ, magnetic particle diameter d, and fluid viscosity η on the motion of magnetic particles were methodically investigated. The velocity characteristics of particles at critical positions between the capture and repulsion zones were analyzed to determine the capture radius of the rod-shaped matrix under specified conditions. Drawing on the identified parametric effects, the developed capture radius prediction model fills the research gap in low-intensity HGMS and serves as a theoretical reference for optimizing both the spacing design of industrial-scale rod-shaped matrix arrays and their matching with relevant operating parameters, and the development of energy-efficient magnetic separation equipment. Full article

The six platinum group elements (PGE) are among the rarest elements in the upper continental crust of the earth. Higher values of PGE have been detected in the upper mantle and in chondrite meteorites. The PGE are siderophile and chalcophile elements and are divided into the following: (1) the Ir subgroup (IPGE) = Os, Ir, and Ru and (2) the Pd subgroup (PPGE) = Rh, Pt, and Pd. The IPGE are more refractory and less chalcophile than the PPGE. High concentrations of PGE led, in rare cases, to the formation of mineral deposits. The PGE are carried in discrete phases, the platinum group minerals (PGM), and are included as trace elements into the structure of base metal sulphides (BM), such as pentlandite, chalcopyrite, pyrite, and pyrrhotite. Similarly to PGE, the PGM are also divided into two main groups, i.e., IPGM composed of Os, Ir, and Ru and PPGM containing Rh, Pt, and Pd. The PGM occur both in mafic and ultramafic rocks and are mainly hosted in stratiform reefs, sulphide-rich lenses, and placer deposits. Presently, there are only 169 valid PGM that represent about 2.7% of all 6176 minerals discovered so far. However, 496 PGM are listed among the valid species that have not yet been officially accepted, while a further 641 are considered as invalid or discredited species. The main reason for the incomplete characterization of PGM resides in their mode of occurrence, i.e., as grains in composite aggregates of a few microns in size, which makes it difficult to determine their crystallography. Among the PGM officially accepted by the IMA, only 13 (8%) were discovered before 1958, the year when the IMA was established. The highest number of PGM was discovered between 1970 and 1979, and 99 PGM have been accepted from 1980 until now. Of the 169 PGM accepted by the IMA, 44% are named in honour of a person, typically a scientist or geologist, and 31% are named after their discovery localities. The nomenclature of 25% of the PGM is based on their chemical composition and/or their physical properties. PGM have been discovered in 25 countries throughout the world, with 64 from Russia, 17 from Canada and South Africa (each), 15 from China, 12 from the USA, 8 from Brazil, 6 from Japan, 5 from Congo, 3 from Finland and Germany (each), 2 from the Dominican Republic, Greenland, Malaysia, and Papua New Guinea each, and only 1 from Argentine, Australia, Bulgaria, Colombia, Czech Republic, England, Ethiopia, Guyana, Mexico, Serbia, and Tanzania each. Most PGM phases contain Pd (82 phases, 48% of all accepted PGM), followed, in decreasing order of abundances, by those of Pt 35 phases (21%), Rh 23 phases (14%), Ir 18 phases (11%), Ru 7 phases (4%), and Os 4 phases (2%). The six PGE forming the PGM are bonded to other elements such as Fe, Ni, Cu, S, As, Te, Bi, Sb, Se, Sn, Hg, Ag, Zn, Si, Pb, Ge, In, Mo, and O. Thirty-two percent of the 169 valid PGM crystallize in the cubic system, 17% are orthorhombic, 16% hexagonal, 14% tetragonal, 11% trigonal, 3% monoclinic, and only 1% triclinic. Some PGM are members of a solid-solution series, which may be complete or contain a miscibility gap, providing information concerning the chemical and physical environment in which the mineral was formed. The refractory IPGM precipitate principally in primitive, high-temperature, mantle-hosted rocks such as podiform and layered chromitites. Being more chalcophile, PPGE are preferentially collected and concentrated in an immiscible sulphide liquid, and, under appropriate conditions, the PPGM can precipitate in a thermal range of about 900–300 °C in the presence of fluids and a progressive increase of oxygen fugacity (fO₂). Thus, a great number of Pt and Pd minerals have been described in Ni-Cu sulphide deposits. Two main genetic models have been proposed for the formation of PGM nuggets: (1) Detrital PGM represent magmatic grains that were mechanically liberated from their primary source by weathering and erosion with or without minor alteration processes, and (2) PGM reprecipitated in the supergene environment through a complex process that comprises solubility, the leaching of PGE from the primary PGM, and variation in Eh-pH and microbial activity. These two models do not exclude each other, and alluvial deposits may contain contributions from both processes. Full article

Siliceous rocks of various colors and types are extensively developed within the Middle–Lower Ordovician carbonate along the Northwest Tarim Basin. Their genesis provides important insights into the evolution of basinal fluids and the associated diagenetic alterations of the carbonates. Based on petrographic, geochemical, fluid inclusion, and petrophysical analyses, this study investigates the origin of siliceous rocks within the Middle–Lower Ordovician carbonate formations (Penglaiba, Yingshan, and Dawangou formations) in the Kalpin area, Tarim Basin, and investigates the impact on hydrothermal reservoirs. The results reveal two distinct episodes of siliceous diagenetic fluids: The first during the Late Ordovician involved mixed hydrothermal fluids derived from deep magmatic–metamorphic sources, formation brines, and seawater. Characterized by high temperature and moderate salinity, it generated black chert dominated by cryptocrystalline to microcrystalline quartz through replacement processes. The second episode developed in the Middle–Late Devonian as a mixture of silicon-rich fluids from deep heat sources and basinal brines. In conditions of low temperature and high salinity, it generated gray-white siliceous rocks composed of micro- to fine crystalline quartz, spherulitic-fibrous chalcedony, and quartz cements via a combination of hydrothermal replacement and precipitation. A reservoir analysis reveals that the multi-layered black siliceous rocks possess significant reservoir potential amplified by the syndiagenetic tectonic fracturing. In contrast, the white siliceous rocks, despite superior petrophysical properties, are limited in scale as they predominantly infill late-stage fractures and vugs, mainly enhancing local flow conduits. Hydrothermal alteration in black siliceous rocks is more intense in dolostone host rocks than in limestone. Thus, thick (10–20 m), continuous black siliceous layers in dolostone and the surrounding medium-crystalline dolostone alteration zones, are promising exploration targets. This study elucidates the origins of Ordovician siliceous rocks and their implications for carbonate reservoir properties. The findings may offer valuable clues for deciphering the evolution and predicting the distribution of hydrothermal reservoirs, both within the basin and in other analogous regions worldwide. Full article

In multi-phase tectonic activity areas, complex stratigraphic uplift-subsidence cycles lead to multi-phase, superimposed diagenesis. This obscures the mechanisms of reservoir property evolution and makes predicting diagenetic sweet spots difficult. This study investigates the low-permeability clastic reservoirs in the Mesozoic of the Tanhai area, Jiyang Depression. Integrating thin-section petrography, scanning electron microscopy (SEM), X-ray diffraction (XRD), high-pressure mercury injection, and burial history analysis, it reveals multi-phase diagenetic characteristics from a tectonic perspective and quantifies pore structure modification mechanisms. Results show the reservoirs underwent strong compaction and multi-phase carbonate-dominated cementation. Dissolution is further distinguished into meteoric water, organic acid, and volcanic material-related alkaline dissolution. Pore-throat evolution indicates that compaction and cementation shift pores towards micropores (<0.1 µm), while meteoric and alkaline dissolution enlarge mesopores (0.1–10 µm) crucial for permeability. Reservoir diagenesis is divided into five tectonic—diagenetic stages. A quantitative model identifies two diagenetic sweet spot types: (1) zones near unconformities intensely leached by meteoric water, and (2) relatively shallow intervals affected by alkaline dissolution related to volcanic rocks under deep burial. This study establishes a tectonic—diagenetic—pore structure framework. It provides a basis for predicting reservoir sweet spots in analogous multi-phase tectonic settings. Full article

The Huxu Au-dominated deposit is a representative intermediate sulfidation epithermal deposit in the middle section of the Gan-Hang belt. The formation of such deposits is commonly closely related to deep magmatism. However, the specific relationship between the formation of the Huxu deposit and the magmatic rocks, and the tectonic setting of the related magmatism and mineralization in this deposit still remains unclear. In this study, we present the results of U-Pb dating, major and trace element analysis, and Nd isotope analysis of the magmatic zircon and apatite from the ore-bearing quartz diorite porphyry in the Huxu deposit. The results show that the U-Pb ages of zircon and apatite from the quartz diorite porphyry are 137.9 ± 1.3 Ma and 130 ± 16 Ma, respectively; the total content of rare earth elements (ΣREEs) in the zircons ranges from 446.66 to 2752.92 ppm, exhibiting enrichment in heavy REE and depletion in light REE, with a slightly negative Eu anomaly and a slightly positive Ce anomaly; the ΣREEs in the apatite is relatively high, ranging from 3252.02 to 13,155.92 ppm, averaged 5604.16 ppm, and exhibits a right-leaning mode with light REE enrichment and heavy REE depletion, with a moderate degree of negative Eu anomaly; the distribution of ¹⁴³Nd/¹⁴⁴Nd ratios of the apatite is rather concentrated (0.512145–0.512271), and the εNd(t) value calculated based on the U-Pb age of apatite ranges from −8.31 to 5.79. By combining the geological characteristics and the geochemical data of the deposit and the ore-bearing magmatic rocks, we propose that the ore-bearing quartz diorite porphyry of the Huxu Au-dominated polymetallic deposit belongs to I-type granite; the parental magma is the mixture of juvenile and ancient crustal melts; the tectonic setting of the intrusion and mineralization is the continental margin arc related to the subduction of the ancient Pacific Ocean Plate in the Early Cretaceous Epoch; and the ore-forming fluids and metals are provided by deep magma. Full article

Crushing is a critical step in the efficient utilization of quasi-brittle materials such as ores and solid wastes. During this process, materials undergo fracture, and the product particles are ejected, carrying significant kinetic energy. This study investigates typical quasi-brittle materials—concrete and quartz glass—by conducting impact crushing tests using a drop-weight apparatus under varying contact modes and input energy levels. High-speed camera was employed to capture the fracture patterns of the materials and the trajectories of the ejected particles, enabling the calculation of kinetic energy during crushing. The results indicate that under point contact loading, both kinetic energy and its proportion increase significantly with rising input energy. In contrast, under surface contact loading, the kinetic energy and its proportion exhibit minimal change as input energy increases. The average ejection velocity of particles from quartz glass specimens during crushing was 6.28 m/s, which is 2.21 times that of concrete specimens. Moreover, the average proportion of kinetic energy in quartz glass crushing was 5.049%, approximately 14.43 times greater than that in concrete. Enhancing material toughness and adopting surface contact loading help reduce both the kinetic energy and its proportion during crushing. This research contributes to minimizing kinetic energy loss and improving the efficiency of energy utilization in crushing processes. Full article

The Hadamengou gold deposit, hosted in the Precambrian metamorphic basement, is a super-large gold deposit occurring along the northern margin of the North China Craton. Despite extensive investigation, the genesis of the gold mineralization is poorly understood and remains highly debated. This study integrates a comprehensive dataset, including fluid inclusion microthermometry and C-H-O-S-Pb isotopes, to better constrain the genesis and ore-forming mechanism of the deposit. Hydrothermal mineralization can be divided into pyrite–potassium feldspar–quartz (Stage I), quartz–gold–pyrite–molybdenite (Stage II), quartz–gold–polymetallic sulfide (Stage III), and quartz–carbonate stages (Stage IV). Four types of primary fluid inclusions are identified, including pure CO₂-type, composite CO₂-H₂O-type, aqueous-type, and solid-daughter mineral-bearing-type inclusions. Microthermometric and compositional data reveal that the fluids were mesothermal to hypothermal, H₂O-dominated, and CO₂-rich fluids containing significant N₂ and low-to-moderate salinity, indicative of a magmatic–hydrothermal origin. Fluid inclusion assemblages further imply that the ore-forming fluids underwent fluid immiscibility, causing CO₂ effusion and significant changes in physicochemical conditions that destabilized gold bisulfide complexes. The hydrogen–oxygen isotopic compositions, moreover, support a dominant magmatic water source, with increasing meteoric water input during later stages. The carbon–oxygen isotopes are also consistent with a magmatic carbon source. Sulfur and lead isotopes collectively imply that ore-forming materials were derived from a hybrid crust–mantle magmatic reservoir, with minor contribution from the country rocks. By synthesizing temporal–spatial relationships between magmatic activity and ore formation, and the regional tectonic evolution, we suggest that the Hadamengou is an intrusion-related magmatic–hydrothermal lode gold deposit. It is genetically associated with multi-stage magmatism induced by crust–mantle interaction, which developed within the extensional tectonic regimes. Full article

Future shortages of minerals essential for green technologies have driven the search for new supply sources. In this context, deep-sea mining (DSM) has emerged as an innovative alternative for accessing strategic metals such as manganese and cobalt, among others, through the exploitation of deposits including polymetallic nodules, ferromanganese crusts, and seafloor massive sulfides. However, while DSM could help meet the growing demand for minerals, it also presents significant challenges and opportunities. This study compiles and analyzes scientific publications on DSM to assess its potential effects. It reviews the main environmental impacts and, in addition, proposes a systematic classification of them. It also addresses the social and economic effects associated with this activity, considering human dynamics and the factors that shape its long-term viability. The results indicate that, although DSM may offer advantages over terrestrial mining, it still lacks a robust framework to mitigate impacts and anticipate future consequences. Unlike previous reviews focused on partial dimensions of sustainability, this work integrates environmental, social, and economic dimensions through a systematic impact classification. Critical challenges remain in ecological understanding, environmental monitoring, and long-term socio-economic assessment, alongside an international governance framework that is still nascent, reinforcing the need for interdisciplinary research. Full article

The Paleoproterozoic Aravalli Supergroup in northwest India hosts one of the oldest phosphorite deposits on Earth, located in the Jhamarkotra Formation, which was deposited after ca. 1762 Ma. Secondary enrichment is identified in the eastern region, resulting in upgradation of phosphate content, while primary stromatolitic columns are well-preserved in the western area of the Jhamarkotra mines. In this study, drill-core samples were collected from the unaltered western Block B and the upgraded eastern Block E to understand the alteration process. Petrographic studies reveal evidence of structural deformation and alteration. Elemental mapping of petrographic thin sections, employing SEM-EDS, indicates that dolomite has been leached out, resulting in phosphorite upgrading in the E-block. The major element oxide data support the leaching of dolomite. In the upgraded E-block, the weighted average P₂O₅ content nearly doubled (from 21% to 38%), while the MgO content decreased from 21% to 4% compared to the B-block. REE+Y contents in Block E are increased with minor Ce and Eu anomalies developed compared to the B Block. The U and Sr concentrations are also increased in Block E phosphorites. The petrographic and geochemical studies indicate that phosphorite enrichment was driven by structurally controlled, low-temperature hydrothermal alteration in the Jhamarkotra mines. Full article

The aim of the study is to assess the effect of diagenesis on the reservoir properties of Carboniferous sandstones in Western Pomerania (NW Poland). The research focuses on Mississippian (Łobżonka Shale, Gozd Arkose, and Drzewiany Sandstone formations) and Pennsylvanian (Wolin, Rega, and Dziwna formations) rocks. A comparative analysis of the sandstones in the individual formations was carried out. The sandstone samples taken from 13 deep boreholes were studied petrographically (using a polarizing microscope, cathodoluminescence, and a scanning electron microscope), and petrophysical features were measured. The Carboniferous sandstones are represented mainly by quartz arenites ranging from very fine- to medium-grained and arkosic and lithic arenites from fine- to coarse-grained. The main diagenetic processes that affected the porosity and permeability of quartz arenites were compaction and cementation. Compaction reduced the primary porosity by an average of about 60% and cementation by about 40% in the Pennsylvanian sandstones. Primary porosity of arkosic and lithic arenites was affected mainly by compaction, cementation, and dissolution. Arkosic arenites have lost an average of 80% of their primary porosity as a result of mechanical compaction. The porosity of these sandstones increased due to the dissolution of mainly feldspar grains and the formation of secondary porosity. Among the Mississippian sandstones, quartz arenites of the Łobżonka Shale Formation exhibit unfavorable reservoir properties (porosity approx. 1%, impermeable). The volcaniclastic arkosic and lithic arenites of the Gozd Arkose Formation have poor reservoir qualities (porosity usually around 5%, mostly impermeable). The quartz arenites of the Drzewiany Sandstone Formation show the best reservoir properties (porosity of about 18%, permeability up to 1000 mD). The Pennsylvanian sandstones, quartz arenites of the Wolin and Rega formations, are characterized by good reservoir qualities (porosity approx. 10%, permeability up to 200 mD), while the Dziwna Formation sandstones show worse properties (porosity approx. 10%, often impermeable). Full article

The Jianggang sand ridges (JSR) in the southwestern Yellow Sea are a radiating tidal sand ridge system that plays crucial roles in ecological preservation, coastal protection, and terrestrial resource supply. Clay and silt fractions constitute important sediment components of the Jianggang sand ridges. In this study, the Sr-Nd isotopes of clay fractions and the Pb isotopes of K-feldspar in the silt fractions, along with their elemental geochemistry, are investigated to reveal the provenance and transport patterns of clay-size and silt-size sediments in the study areas. The results show that in both the clay-size sediments and the K-feldspar of the silt-size sediments, Ba exhibits the highest content, with the ranges of 432.24 μg/g to 531.05 μg/g and 398.02 μg/g to 2822.36 μg/g, respectively. In contrast, Lu shows the lowest abundance (<0.5 μg/g and <0.1 μg/g, respectively). The ⁸⁷Sr/⁸⁶Sr and ε_Nd(0) values of the clay fraction vary from 0.7158 to 0.7265 and from −14.65 to −10.92, respectively. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb of K-feldspar in silt fraction are 17.959~18.429, 15.450~15.689, and 38.066~38.551, respectively. Through the MixSIAR model, it is suggested that the Yangtze River Mouth is the dominant contributor to clay-size sediments in both the onshore and offshore sand ridges (53.9 ± 8.8% and 51.9 ± 8.4%, respectively), followed by the Modern Yellow River Mouth and the Old Yellow River Delta (sum of contributions: <36%). For the silt fraction, the primary sediment sources of the onshore and offshore sand ridges are the Yangtze River Mouth (46.8 ± 5.5%) and the Old Yellow River Delta (42.4 ± 5.3%), while the Modern Yellow River contributes less than 16%. The Northern Chinese Deserts and the Korean rivers make only minor contributions to both fractions. Elemental and isotopic tracers indicate that the silt-size and clay-size sediments derived from the Modern Yellow River are transported southward along the Jiangsu coast by the Subei Coastal Current. Meanwhile, the silt fraction from the Yangtze River Mouth is carried northward along the coast under the influence of the Subei Coastal Current, whereas the clay fraction of it has another longer path, which moves through the central Yellow Sea and migrates southward along the Jiangsu coast to the Jianggang sand ridges under the influence of the Yellow Sea Warm Current. This study enriches the geochemical dataset of the southern Yellow Sea. Full article

Ultrapotassic lamprophyre dykes are spatially closely related to gold deposits in collision tectonic belts. However, the potential implication of these lamprophyre dykes to gold deposits remains poorly constrained. Abundant ultrapotassic lamprophyre dykes in the Baiyun gold deposit of Liaodong Peninsula, NE China, are closely associated with Au orebodies. This presents an excellent opportunity to investigate the genesis and tectonic significance of these dykes, as well as their potential connection to gold mineralization. Here, based on LA-ICPMS zircon U-Pb age, petrogeochemistry, and Sr-Nd-Hf isotopic composition characteristics, we studied the ultrapotassic lamprophyre dykes in the Baiyun gold deposit. Zircon U-Pb dating of lamprophyre dykes is 225.7 ± 1.3 Ma, which is consistent with the previous auriferous pyrite Re-Os data results within error, indicating that the lamprophyre dykes and gold deposits formed simultaneously in the Late Triassic, which coincided with the exhumation of the deeply subducted South Chin Block (SCB). The lamprophyre dykes belong to the shoshonitic series (K₂O + Na₂O = 6.39–7.57 wt.%, K₂O/Na₂O = 3.99–8.74) and are enriched with magnesium (MgO = 5.33–6.40 wt.%, Mg^# = 58–65), barium (Ba = 2225–3046 ppm), and strontium (Sr = 792–927 ppm), and their (⁸⁷Sr/⁸⁶Sr)_i isotopic composition ranges from 0.712514 to 0.714831, ε_Nd(t) ranges from −15.4 to −14.1, and zircon ε_Hf(t) values range from −14.3 to −12.5. These correspond to Paleoproterozoic model ages between 2.1 and 2.3 Ga, which are comparable to the ultra-high-pressure metamorphic rocks with the SCB nature found in the Dabie–Sulu orogenic belt. The results demonstrate that the overlying lithospheric mantle was possibly metasomatized by subducted SCB-derived melts before magma generation under the North China Block (NCB) in the Late Triassic. The lamprophyre dykes with high Nb/U and Th/Yb values, enriched Ba, Sr, REE, Na₂O + K₂O, K₂O/Na₂O, and the LOI demonstrate that the metasomatic agents were hydrous, high-pressure melts. These melts likely resulted from the partial melting of subducted continental crust, which is attributed to phengite breakdown in the subduction continental channel. The silica-rich melts migrate from the plate into the sub-continental lithospheric mantle (SCLM) and form potassic- and volatile-enriched metasomatized SCLM. Subsequently, the partial melting of metasomatized SCLM due to the decompression and thinning may be the main mechanism to generate the syn-exhumation ultrapotassic magma in a post-collision setting. This study suggests that the SCLM, metasomatized by melts derived from continental crust, plays a key role in generating volatile-rich hydrous SCLM during the continental subduction and collision stage. In contrast, during the post-collision stage, as tectonic forces transition from compressional to extensional, the abundant volatiles and ultrapotassic magma produced from the partially melted and metasomatized lithospheric mantle may significantly contribute to the transportation, enrichment, and precipitation of gold through magmatic-hydrothermal processes, facilitating the formation of gold deposits. Full article

This study investigated lithium beneficiation from nepheline syenite ore containing 242.57 ppm Li, identifying biotite as the primary lithium-bearing mineral. A high-intensity dry magnetic separation produced a pre-concentrate assaying at approximately 850–1000 ppm Li, and flotation tests were conducted on both the run-of-mine ore and this magnetic product. Flotation performance was systematically evaluated using two top sizes (−500 and −300 µm), six size fractions (−500 + 75, −500 + 53, −500 + 38, −300 + 75, −300 + 53, −300 + 38 µm), four pH values (2.5, 4.0, 6.5, 9.5), and three collectors (DAHC, Derna 7, and Der A4). Among the reagents, Der A4 yielded the most promising results. Optimization using sodium silicate as a depressant demonstrated that, at 20 g/t Der A4, 500 g/t Na₂SiO₃, and pH 4.0, the −300 + 75 µm fraction of the run-of-mine ore reached approximately 5300 ppm Li. Applying the same parameters to the magnetic pre-concentrate resulted in a 6326.46 ppm Li concentrate with roughly 80% of flotation recovery. Mineralogical characterization using MLA, XRD, modal mineralogy, and SEM-EDS confirmed that the optimized product consisted predominantly of biotite, accompanied by K-feldspar, nepheline, and albite. Liberation results showed high liberation levels and the free surface, supporting the efficiency of combining magnetic separation with flotation for upgrading nepheline syenite as a potential lithium resource. Full article

Topaz is one of the most economically important fluorine-rich nesosilicates, which are predominantly colorless in natural crystals. Hence, the trade relies almost entirely on irradiated blue topaz with an unstable color center, which has been shown to fade over time. The cobalt (Co) diffusion treatment is a stable alternative process for converting colorless topaz to blue by a solid-state diffusion mechanism. To investigate the potential role of Co²⁺ substitution in the formation of the blue layer and the coupled behavior of F/OH dehydroxylation in facilitating this process, systematic diffusion treatments have been successfully conducted and compared. In this study, gem-quality topazes were annealed in air at 1000 °C for 20–40 h (hr) along with CoO, Fe₂O₃, Cr₂O₃, and CuO powders. The diffused products were characterized using Scanning Electron Microscope (SEM), Ultraviolet-Visible absorption spectroscopy (UV-Vis), Near-Mid Infrared spectroscopy (NMIR), and X-ray photoelectron spectroscopy (XPS). Parallel runs with CuO, Fe₂O₃, or Cr₂O₃ alone confirmed that none of these oxides produces a stable blue layer, underscoring the unique role of Co. The Co-diffused sample displays an intense blue layer characterized by a Co²⁺ octahedral isomorphism triplet at 540, 580, and 630 nm, which are absent from both untreated and heat-only controls. XPS analysis reveals the emergence of Co²⁺ (binding energy: 780.63 eV) and a concomitant depletion in F⁻, along with the disappearance of the OH overtone absorption at 7123 cm⁻¹. These observations confirm that defluorination generates octahedral vacancies accommodated by the coupled substitution: CoF₂ (solid reactant) + (AlO₂)⁻ (fragment of topaz structure) → AlOF (solid product) + (CoOF)⁻ (fragment of topaz structure). Prolonged annealing leads to decreased relative atomic percentages of K⁺ and F⁻ ions, consistent with volatilization losses during the high-temperature process, thereby directly correlating color intensity with cobalt valence state, which transfers from Co²⁺ to Co³⁺. These findings establish a Co-incorporation chronometer for F–rich aluminosilicate systems, with an optimal annealing time of approximately 20 hr at 1000 °C. Furthermore, the above results demonstrate that the color mechanism in nesosilicate gems is simultaneously governed by volatile release and cation availability. Full article

Soil contamination by potentially toxic elements (PTEs) is a growing environmental concern, particularly in agricultural regions where soil quality directly affects crop safety and human health. This study evaluates PTE concentrations and ecological risks in agricultural soils of Hautat Sudair, central Saudi Arabia, using contamination indices, multivariate statistics, and GIS-based spatial modeling supported by RS-derived land use/land cover (LULC) mapping. The results show that the mean concentrations of Ni (35.97 mg/kg) and Mn (1230 mg/kg) exceed international thresholds in several locations, while Pb (8.34 mg/kg), Cr (33.00 mg/kg), Zn (60.09 mg/kg), and As (4.25 mg/kg) remain within permissible limits in most samples. Contamination indices, including the Enrichment Factor (EF), Contamination Factor (CF), and Geo-Accumulation Index (Igeo), highlight hotspot behavior, with isolated sites showing elevated concentrations approaching screening levels (e.g., Pb up to 32.0 mg/kg and Cr up to 52.0 mg/kg), whereas Ni and Mn exhibit the most pronounced local enrichment. The Pollution Load Index (PLI) varies from 0.24 to 0.80, indicating low to moderate contamination levels, while the Risk Index (RI) ranges from 10.43 to 41.38, signifying low ecological risk. Multivariate statistical analyses, including correlation matrices and principal component analysis (PCA), reveal that Ni, Cr, and Mn share a common source, possibly linked to anthropogenic inputs and natural geological background. Kaiser–Meyer–Olkin (KMO) and Bartlett’s test confirm the adequacy of the dataset for PCA (KMO = 0.797; χ² = 563.845, p < 0.001). Spatial distribution maps generated using GIS and RS highlight contamination hotspots, reinforcing the necessity for periodic monitoring. By integrating indices, multivariate patterns, and spatial context, this study provides a replicable, research-driven framework for interpreting PTE controls in arid agricultural soils. Full article

This study systematically investigates the lithofacies, sedimentary microfacies, vertical evolution, and spatial distribution of the braided river delta–shallow lacustrine carbonate mixed sedimentary rocks of the Upper Ganchaigou Formation in the Huatugou Oilfield of the Qaidam Basin, China. This study integrates data from field outcrops, core observations, thin section petrography, laboratory analyses, and well-logging interpretations. Based on these datasets, the sedimentary characteristics are identified, and a comprehensive sedimentary model is constructed. The results reveal that the study area contains five clastic facies, three types of mixed sedimentary facies, and ten sedimentary microfacies. Two distinct modes of mixed sedimentation are recognized: component mixing and stratigraphic mixing. A full lacustrine transgression–regression cycle is formed by the two types of mixed sedimentation characteristics, which exhibit noticeable differences in vertical evolution. Component mixing, which occurs in a mixed environment of continuous clastic supply and carbonate precipitation during the transgression, is the primary characteristic of the VIII–X oil formation. The mixed strata that make up the VI–VII oil formation show rhythmic interbedding of carbonate and clastic rocks. During the lacustrine regression, it shows the alternating sedimentary environment regulated by frequent variations in lacustrine levels. The planar distribution is affected by both intensity of sediment from the west and the changes in lacustrine level. During the lacustrine transgression, it is dominated by littoral-shallow lacustrine mixed beach bar and mixed sedimentary delta. On the other hand, during the lacustrine regression, it is dominated by laterally amalgamated sand bodies in the braided-river delta front. Based on this, a mixed sedimentary evolution model controlled by the coupling of “source–lacustrine level” is established. It offers a guide for reconstructing the sedimentary environment in basins that are similar to it and reveals the evolution path of mixed sedimentation in the short-axis source area of arid saline lacustrine basins. Full article

As a potential strategic resource of critical metals, deep-sea cobalt-rich crusts represent one of the most promising metal reservoirs within oceanic seamount systems, and their metallogenic mechanism constitutes a frontier topic in deep-sea geoscience research. This review focuses on the cobalt-rich crusts from the Magellan Seamount region in the northwestern Pacific and synthesizes existing geological, mineralogical, and geochemical studies to systematically elucidate their mineralization processes and metal enrichment mechanisms from a microstructural perspective, with particular emphasis on cobalt enrichment and its controlling factors. Based on published observations and experimental evidence, the formation of cobalt-rich crusts is divided into three stages: (1) Mn/Fe colloid formation—At the chemical interface between oxygen-rich bottom water and the oxygen minimum zone (OMZ), Mn²⁺ and Fe²⁺ are oxidized to form hydrated oxide colloids such as δ-MnO₂ and Fe(OH)₃. (2) Key metal adsorption—Colloidal particles adsorb metal ions such as Co²⁺, Ni²⁺, and Cu²⁺ through surface complexation and oxidation–substitution reactions, among which Co²⁺ is further oxidized to Co³⁺ and stably incorporated into MnO₆ octahedral vacancies. (3) Colloid deposition and mineralization—Mn–Fe colloids aggregate, dehydrate, and cement on the exposed seamount bedrock surface to form layered cobalt-rich crusts. This process is dominated by the Fe/Mn redox cycle, representing a continuous evolution from colloidal reactions to solid-phase mineral formation. Biological processes play a crucial catalytic role in the microstructural evolution of the crusts. Mn-oxidizing bacteria and extracellular polymeric substances (EPS) accelerate Mn oxidation, regulate mineral-oriented growth, and enhance particle cementation, thereby significantly improving the oxidation and adsorption efficiency of metal ions. Tectonic and paleoceanographic evolution, seamount topography, and the circulation of Antarctic Bottom Water jointly control the metallogenic environment and metal sources, while crystal defects, redox gradients, and biological activity collectively drive metal enrichment. This review establishes a conceptual framework of a multi-level metallogenic model linking macroscopic oceanic circulation and geological evolution with microscopic chemical and biological processes, providing a theoretical basis for the exploration, prediction, and sustainable development of potential cobalt-rich crust deposits. Full article

Tungsten is one of the critical materials with important applications in many areas. Electrolysis of Na₂WO₄-based salt is a short and green process for the production of tungsten metal and alloys. The conventional process for producing Na₂WO₄ is expensive and time-consuming. Scheelite (CaWO₄) is becoming the most important resource for the extraction of tungsten. Based on thermodynamic calculations and phase equilibrium studies, a novel process is proposed to prepare Na₂WO₄-based salt directly from scheelite through a high-temperature process. By reacting with silica and sodium oxide, immiscible layers of liquid salt and slag are formed from scheelite between 1200 and 1300 °C. High-density salt containing Na₂WO₄ is separated from the silicate slag, which is composed of impurities and fluxes. The effects of fluxing agents, smelting temperature, and reaction time on the direct yield of WO₃ and purity of sodium tungsten are investigated in combination with thermodynamic calculations and high-temperature experiments. The salt containing up to 99% Na₂WO₄ is obtained directly in a single process, which can be used for the production of other tungsten chemicals. This study provides a novel research method and detailed information to produce low-cost sodium tungstate directly from scheelite. Full article

Ataúro Island, located in the inner Banda Arc, provides a natural laboratory to investigate the interplay between magmatic evolution, hydrothermal circulation, and near-surface weathering in an active arc–continent collision setting. This study presents the first systematic island-wide geochemical baseline for Ataúro Island, based on multi-element analyses of stream sediments integrated with updated geological, structural, and hydromorphological information. Compositional Data Analysis (CoDA–CLR–PCA), combined with anomaly mapping and spatial overlays, defines a coherent three-tier geochemical framework comprising: (i) a lithogenic component dominated by Fe–Ti–Mg–Ni–Co–Cr, reflecting the geochemical signature of basaltic to andesitic volcanic rocks; (ii) a hydrothermal component characterized by Ag–As–Sb–S–Au associations spatially linked to structurally controlled zones; and (iii) an oxidative–supergene component marked by Fe–V–Zn redistribution along drainage convergence areas. These domains are defined strictly on geochemical criteria and represent geochemical process domains rather than proven metallogenic provinces. Rare earth element (REE) systematics further constrain the geotectonic setting and indicate that the primary geochemical patterns are largely controlled by lithological and magmatic differentiation processes. Spatial integration of geochemical patterns with fault architecture highlights the importance of NW–SE and NE–SW structural corridors in focusing hydrothermal fluid circulation and associated metal dispersion. The identified Ag–As–Sb–Au associations are interpreted as epithermal-style hydrothermal geochemical enrichment and exploration-relevant geochemical footprints, rather than as evidence of confirmed or economic mineralization. Overall, Ataúro Island emerges as a compact natural analogue of post-arc geochemical system evolution in the eastern Banda Arc, where lithogenic background, hydrothermal fluid–rock interaction, and early supergene processes are superimposed. The integrated geochemical framework presented here provides a robust baseline for future targeted investigations aimed at distinguishing lithogenic from hydrothermal contributions and evaluating the potential significance of the identified geochemical enrichments. Full article