Traces of Molybdenum (Mo) in drinking water pose potent dangers owing to its harmful effects on the health of humans. This study used nanoscale zero-valent iron (Fe0) supported by activated carbon (NZVI/AC) for removing Mo(VI) from raw water. In an a...
A novel method for the spectrophotometric determination of trace amounts of molybdenum has been developed. This method utilizes a centrifuge-less cloud point extraction (CL-CPE) in a mixed micellar (MM) system containing a nonionic surfactant (Triton...
Reaction of the bulky bi-phenols 2,2′-RCH[4,6-(t-Bu)2C6H2OH]2 (R = Me L1MeH2, Ph L1PhH2) with the bis(imido) molybdenum(VI) tert-butoxides [Mo(NR1)(NR2)(Ot-Bu)2] (R1 = R2 = 2,6-C6H3-i-Pr2; R1 = t-Bu, R2 = C6F5) afforded, following the successive remo...
A new liquid—liquid extraction system for molybdenum(VI) was studied. It contains 4-nitrocatechol (4NC) as a complexing chromogenic reagent and benzalkonium chloride (BZC) as a source of heavy cations (BZ+), which are prone to form chloroform-e...
A series of molybdenum(VI) complexes with aryl-functionalized alkyl dihydrazones was prepared by the reaction of [MoO2(acac)2] and the appropriate dihydrazone in methanol. Their solid-state structures were elucidated via single-crystal X-ray diffract...
The discovery of heterogeneous catalysts synthesized in easy, sustainable ways for the valorization of olefins derived from renewable biomass is attractive from environmental, sustainability, and economic viewpoints. Here, an organic–inorganic...
Molybdenum is harmful and useful. The efficiency of molybdenum trade effluent treatment is low and it is difficult to extract and recycle. To solve this problem, a novel membrane chemical reactor with mixed organic-water solvent(MCR-OW) had been used...
Ionic oxidoperoxido-molybdenum(VI) complexes of the type [Cat][MoO(O2)2(pic)], with pic = N,O-chelated picolinate ligand and Cat = monocation, were prepared in high yields (82–95%) from the precursor complex [H3O][MoO(O2)2(pic)] via [H]+ cation...
There is a considerable practical interest in discovering new ways to obtain organomolybdenum heterogeneous catalysts for olefin epoxidation that are easier to recover and reuse and display enhanced productivity. In this study, the complex salt (H2py...
The oxodiperoxo complex MoO(O2)2(tbbpy) (tbbpy = 4,4'-di-tert-butyl-2,2'- bipyridine) was isolated from the reaction of MoO2Cl2(tbbpy) in water under microwaveassisted heating at 120 ºC for 4 h. The structure of the oxodiperoxo complex was determined...
The chemistry of transition metal clusters has been intensively developed in the last decades, leading to the preparation of a number of compounds with promising and practically useful properties. In this context, the present work demonstrates the pr...
The present work is devoted to the study of the mechanism of the process of formation of adhesive oxide-titanium coatings on steel, zinc, and aluminum surfaces. For the first time, the following hypothesis has been confirmed experimentally, namely, t...
Molybdenum blue dispersions were synthesized by reducing an acidic molybdate solution with glucose, hydroquinone and ascorbic acid. The role of the H/Mo molar ratio in the process of formation for molybdenum particles was established. For each reduci...
Herein, we demonstrate a promising method for the synthesis of ultrafine carbide particles using dispersions of molybdenum–tungsten nanoparticles. Dispersions of molybdenum–tungsten blue nanoparticles with different initial molar ratios of molybdenum...
Molybdenum blue dispersions were synthesized by reducing an acidic molybdate solution with glucose, hydroquinone and ascorbic acid. The influence of the H/Mo molar ratio on the rate of formation of molybdenum particles was established. For each reduc...
This work presents a biological remediation process for molybdenum-bearing wastewater which may lead to the fabrication of biogenic Mo chalcogenide particles with (photo)catalytic properties. The process is based on dissimilatory sulphate reduction,...
Molecular molybdenum complexes with sulfur donor ligands are generally studied as soluble model compounds for molybdenum enzymes essential for life. The dioxidomolybdenum(VI) complex with tetradentate aminobisphenolate ligand undergoes a reaction wit...
A promising method for the synthesis of ultrafine carbide particles is the sol–gel method using dispersions of molybdenum–tungsten nanoparticles. For further use, the main properties of molybdenum-blue nanoparticles, including the size, structure, an...
In recent years, much attention has been paid to the development of a new flexible and variable method for molybdenum carbide (Mo2C) synthesis. This work reports the applicability of nano-size clusters of molybdenum blue to molybdenum carbide product...
The molybdenum(0)-carbonyl-triazole complexes [Mo(CO)3(L)3] [L = 1,2,3-triazole (1,2,3-trz) or 1,2,4-triazole (1,2,4-trz)] have been prepared and examined as precursors to molybdenum(VI) oxide catalysts for the epoxidation of cis-cyclooctene. Reactio...
Stable molybdenum blue nanoparticles dispersions were synthesized using ammonium heptamolybdate and ascorbic acid. The effect of molar ratios of reducing agent/Mo and acid/Mo on the speed of formation and stability of the disperse system has been dem...
In this paper, we have developed conditions for the deposition of zirconium oxide coatings from solutions containing hexafluorozirconic acid as well as tungsten and molybdenum salts on a steel base. Based on electrochemical studies, it was shown that...
This study aimed to investigate how an ultralow content of a molybdenum disulfide (MoS2) two-dimensional particle affects the photodegradation mechanism of polystyrene (PS). Here, an accelerated weathering study was presented on neat polystyrene and...
Copper ferrites dopped with molybdenum were studied in an oxidative coupling reaction between methanol and ethanol in the gas phase. The catalysts have been characterized by X-ray diffraction, where the presence of ferrite, magnetite, and tenorite ph...
The oxo-diperoxo molybdenum(VI) complex MoO(O2)2•2QOH (QOH = 8-quinilinol) was prepared and characterized by elemental analysis, IR and UV-Vis spectra. The ionic liquids (ILs) [bmim][BF4], [hydemim][BF4], and [bmim][PF6] were characterized by 1H-NMR...
Aqueous two-phase extraction (APTE) stands out as an environmentally friendly technique for the separation of metal ions. The separation of Re (VII) and Mo (VI) in an aqueous solution was investigated using a novel aqueous two-phase system (ATPS) con...
Industrial wastewater is the main source of an excessive amount of molybdenum (Mo) in natural ecosystems. It is necessary to remove Mo from wastewater before it is discharged into the environment. Molybdate ion(VI) is the most common form of Mo in na...
An innovative and eco-friendly one-pot synthesis of bio-based polyurethanes is proposed via the epoxy-ring opening of epoxidized soybean oil (ESO) with methanol, followed by the reaction of methoxy bio-polyols intermediates with 2,6-tolyl-diisocyanat...
Previous studies have demonstrated that underwater low-temperature plasma is effective for synthesizing nanomaterials by generating plasma discharges between metal electrodes submerged in water. This study extends this approach to the one-step synthe...
Titania photocatalysts supported on mesoporous MgO carriers doped with Mo(VI) ions were prepared and characterized by XRD, BET nitrogen adsorption, FT-IR, and EPR methods. The photocatalytic activity was evaluated by bleaching an aqueous dye solution...
The efficient separation of chalcopyrite from molybdenite is crucial for the utilization of copper–molybdenum ores and is inevitably influenced by the presence of metal ions in the pulp. However, the underlying impact mechanisms remain unclear....
Montmorillonite—the most popular mineral of the smectite group—has been recognized as a low-cost, easily available mineral sorbent of heavy metals and other organic and inorganic compounds that pollute water. The aim of this work was to d...
A series of the layered double oxides supported molybdenum oxide catalysts were synthesized and evaluated in the oxidative dehydrogenation of ethane with CO2 (CO2-ODHE). The 22.3 wt% Mo/LDO catalyst delivered a 92.3%selectivity to ethylene and a 7.9%...
Water pollution has becoming an increasingly serious issue, and it has attracted a significant amount of attention from scholars. Here, in order remove heavy metal hexavalent chromium (Cr (VI)) from wastewater, graphitic carbon nitride (g-C3N4) was m...
Organic thin-film solar cells with a conducting polymer (CP)/fullerene (C60) interpenetrating heterojunction structure, fabricated by spin-coating a CP onto a C60 deposit thin film, have been investigated and demonstrated to have high efficiency. The...
Ultrathin MoO3 semiconductor nanostructures have garnered significant interest as a promising nanomaterial for transparent nano- and optoelectronics, owing to their exceptional reactivity. Due to the shortage of knowledge about the electronic and opt...
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Eliminating organic and inorganic pollutants from water is a worldwide concern. In this study, we applied electrochemical oxidation (EO) and adsorption techniques to eliminate ammonia, phenols, and Mo(VI) from aqueous solutions. We analyzed the first...
To investigate the influence of residence time on molybdenum [Mo(VI)] adsorption behavior in soil environments, kinetic batch experiments coupled with X-ray near-edge structure (XANES) spectroscopy were performed for a neutral-pH soil (Webster loam)...
In this work, we report on the development of a computational algorithm that explores the configurational isomer space of bimetallic decametalates with general formula MxM10−x′O28q. For x being a natural number in the range of 0 to 10, th...
The photoreduction of the Mo6+/SiO2 system with CO was investigated in situ, employing a recently developed experimental setup allowing for the acquisition of transmission FT-IR spectra under simultaneous UV irradiation. Carbon monoxide, besides acti...
We report on the MoO3 oxides and their derivatives on microscopic 2H MoS2 flakes oxidized in air and high relative humidity at a moderate temperature range below 410 °C. We combine XPS and AFM measurements such as topography, friction, creation o...
In this explorative work, molybdenum trioxide (MoO3) and representative doped MoO3 materials, i.e., Cu-doped MoO3 (2% Cu, “Cu-MoO3”) and H-doped MoO3 (H0.31MoO3, “H-MoO3”), have been tested for the first time as photocatalysts...
Atomically thin two-dimensional (2D) transition metal dichalcogenides have also attracted immense interest because they exhibit appealing electronic, optical and mechanical properties. In this work, we prepared gold nanoparticle-decorated molybdenum...
In this study, molybdenum disulfide (MoS2) decorated on graphitic carbon nitride (g-C3N4) heterostructure catalysts at various weight ratios (0.5%, 1%, 3%, 10%, w/w) were successfully prepared via a two-step hydrothermal synthesis preparation method....
Molybdenum(VI) catalysts were obtained from methanol or acetonitrile by the reaction of [MoO2(C5H7O2)2] and isonicotinoyl- or nicotinoyl-based aroylhydrazones. Reactions in methanol resulted in the formation of the mononuclear complexes [MoO2(L1–4)(M...
Molybdenum coordination complexes are widely applied due to their biological and pharmacological potential, as well as their performance in different catalytic processes. Parent dioxidomolybdenum Schiff base complexes were prepared via the reaction o...
The short-term mechanical properties of commercial corrosion-resistant nickel alloys based on Ni-Cr (Hastelloy® G-35® or UNS N06035), Ni-Mo (Hastelloy® B-3® or UNS N10675), and Ni-Cr-Mo (VDM® Alloy C-4 or UNS N06455, VDM® Allo...
A study on the selective solvent extraction (SX) of molybdenum (Mo) and rhenium (Re) from two industrial pregnant leach solutions (PLSs) was carried out using Alamine 336 as the extractant and the ionic liquid (IL) 1-octyl-3-methyl Imidazolium bis (t...
1,2,3,4,5-pentathiepines (PTEs) are naturally occurring polysulfides of increasing scientific interest based on their identified pharmacological activities. Artificial PTEs with N-heterocyclic backbones are efficiently synthesized via mediation by a...
Interactions between well-mixed fine powders of As2O3, P2O5, MoO3, WO3 and Nb2O5 at different stoichiometry in quartz ampoules under vacuum at ~1000 °C in the presence of metallic molybdenum (or niobium), over several weeks, led to shiny dichroic cry...
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