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  • Review
  • Open Access
33 Citations
13,913 Views
37 Pages

Salts of hexacyanoferrate II/III anions have been widely used as redox couple probe molecules to determine the characteristics of electrode surfaces. Examples include the assessment of electrocatalysts for energy applications and electrocatalysts for...

  • Article
  • Open Access
51 Citations
12,136 Views
13 Pages

31 January 2024

Understanding electrochemical reactions at the surface of electrodes requires the accurate calculation of key parameters—the transfer coefficient (α), diffusion coefficient (D0), and heterogeneous electron transfer rate constant (k0). The...

  • Article
  • Open Access
16 Citations
11,575 Views
22 Pages

Separation Process of Biodiesel-Product Mixture from Crude Glycerol and Other Contaminants Using Electrically Driven Separation Technique with AC High Voltage

  • Rossarin Ampairojanawong,
  • Ajalaya Boripun,
  • Sayan Ruankon,
  • Thanapong Suwanasri,
  • Kraipat Cheenkachorn and
  • Tawiwan Kangsadan

21 March 2023

Electrically driven separation (EDS) technology with a high voltage (HV) alternating current source (AC) was used to remove glycerol and other contaminants from biodiesel in order to meet the ASTM D6751 and EN 14214 standards. Biodiesel was produced...

  • Review
  • Open Access
21 Citations
9,258 Views
25 Pages

23 March 2023

With the surge of electric vehicles, fast charging has become one of the major challenges for the development of Li-ion and Li metal batteries. The degradation of battery electrodes at fast charging has been identified as among the gating factors. Wh...

  • Review
  • Open Access
8 Citations
8,119 Views
30 Pages

Recent Advancements in Na Super Ionic Conductor-Incorporated Composite Polymer Electrolytes for Sodium-Ion Battery Application

  • Kanya Koothanatham Senthilkumar,
  • Rajagopalan Thiruvengadathan and
  • Ramanujam Brahmadesam Thoopul Srinivasa Raghava

Sodium-ion batteries (SIBs) have garnered significant attention as a cost-effective and sustainable alternative to lithium-ion batteries (LIBs) due to the abundance and eco-friendly extraction of sodium. Despite the larger ionic radius and heavier ma...

  • Review
  • Open Access
14 Citations
7,282 Views
35 Pages

Food quality assessment is becoming a global priority due to population growth and the rise of ionic pollutants derived from anthropogenic sources. However, the current methods used to quantify toxic ions are expensive and their operation is complex....

  • Article
  • Open Access
3 Citations
5,447 Views
18 Pages

Enhanced Performance of Sodium-Ion Battery Cathodes with Ti and V Co-Doped P2-Type Na0.67Fe0.5Mn0.5O2 Materials

  • Trapa Banik,
  • Indranil Bhattacharya,
  • Kirankumar Venkatesan Savunthari,
  • Sanjeev Mukerjee,
  • Webster Adepoju and
  • Abiodun Olatunji

18 October 2024

Manganese- and iron-rich P2-type Na0.67Fe0.5Mn0.5O2 (NFM) has garnered significant interest as a promising cathode candidate due to the natural abundance of Fe and Mn along with a high redox couple of Fe3+/Fe4+ and Mn3+/Mn4+. Despite all these m...

  • Review
  • Open Access
10 Citations
5,229 Views
20 Pages

Iron is a widely used metal due to its low cost and availability, but it is susceptible to corrosion in many circumstances. This corrosion can result in economic and environmental losses, and negatively affect the physical and chemical properties of...

  • Review
  • Open Access
10 Citations
5,175 Views
24 Pages

4 August 2023

Comprehending the interfacial interaction of nanomaterials (NMs) and biological systems is a significant research interest. NMs comprise various nanoparticles (NPs) like carbon nanotubes, graphene oxides, carbon dots, graphite nanopowders, etc. These...

  • Article
  • Open Access
6 Citations
5,021 Views
22 Pages

10 August 2023

Recent advances in commercially available integrated complex impedance spectroscopy controllers have brought rapid increases in the quality of systems available to researchers for wearable and remote patient monitoring applications. As a result, nove...

  • Article
  • Open Access
28 Citations
4,745 Views
31 Pages

Trends and Opportunities in Enzyme Biosensors Coupled to Metal-Organic Frameworks (MOFs): An Advanced Bibliometric Analysis

  • Misael Bessa Sales,
  • José Gadelha Lima Neto,
  • Ana Kátia De Sousa Braz,
  • Paulo Gonçalves De Sousa Junior,
  • Rafael Leandro Fernandes Melo,
  • Roberta Bussons Rodrigues Valério,
  • Juliana de França Serpa,
  • Ana Michele Da Silva Lima,
  • Rita Karolinny Chaves De Lima and
  • José Cleiton Sousa dos Santos
  • + 5 authors

The unique properties of metal-organic frameworks (MOFs) such as their large surface area and high porosity have attracted considerable attention in recent decades. The MOFs are a promising class of materials for developing highly efficient biosensor...

  • Article
  • Open Access
12 Citations
4,727 Views
13 Pages

23 October 2023

Diffusion-controlled cyclic voltammograms at fast scan rates show peak shifts, as well as decreases in the peak currents from predicted diffusion-controlled currents, especially when the currents are large in a low concentration of supporting electro...

  • Review
  • Open Access
5 Citations
4,629 Views
34 Pages

This study presents a comprehensive bibliometric analysis of scientific publications on electrochemical etching and electrochemical deposition from 1970 to 2023. Using the Science Citation Index Expanded (SCIE) database, we analysed 5166 publications...

  • Article
  • Open Access
4,524 Views
11 Pages

Influence of Pulsed Reverse Electrodeposition on Mechanical Properties of Ni–W Alloys

  • Zeyu Gu,
  • Jhen-Yang Wu,
  • Yiming Jiang,
  • Tomoyuki Kurioka,
  • Chun-Yi Chen,
  • Hwai-En Lin,
  • Xun Luo,
  • Daisuke Yamane,
  • Masato Sone and
  • Tso-Fu Mark Chang

Ni–W alloys have received considerable interest as a promising structural material for microelectromechanical systems (MEMS) due to their exceptional properties, including hardness, ductility, corrosion resistance, and thermal stability. Howeve...

  • Review
  • Open Access
7 Citations
4,488 Views
27 Pages

10 April 2023

Polysaccharide-based natural polymer electrolyte membranes have had tremendous consideration for the various energy storage operations including wearable electronic and hybrid vehicle industries, due to their unique and predominant qualities. Further...

  • Review
  • Open Access
6 Citations
4,438 Views
9 Pages

Current Updates in Bleomycin-Based Electrochemotherapy for Deep-Seated Soft-Tissue Tumors

  • Aurel Ottlakan,
  • Gyorgy Lazar,
  • Judit Olah,
  • Andras Nagy,
  • Gabor Vass,
  • Marton Vas,
  • Raissa Pereira and
  • Erika Kis

Electrochemotherapy (ECT) has evolved significantly during the last decade, expanding treatment indications from superficial skin lesions to advanced-stage, deep-seated tumors in hard-to-reach areas. Electrodes have also shown steady technological im...

  • Article
  • Open Access
1 Citations
4,271 Views
17 Pages

Determining the Oxidation Stability of Electrolytes for Lithium-Ion Batteries Using Quantum Chemistry and Molecular Dynamics

  • Elizaveta Y. Evshchik,
  • Sophia S. Borisevich,
  • Margarita G. Ilyina,
  • Edward M. Khamitov,
  • Alexander V. Chernyak,
  • Tatiana A. Pugacheva,
  • Valery G. Kolmakov,
  • Olga V. Bushkova and
  • Yuri A. Dobrovolsky

Determining the oxidation potential (OP) of lithium-ion battery (LIB) electrolytes using theoretical methods will significantly speed up and simplify the process of creating a new generation high-voltage battery. The algorithm for calculating OP shou...

  • Communication
  • Open Access
5 Citations
4,235 Views
9 Pages

A study of keracyanin chloride (KC) electrochemical behavior in an aqueous buffer solution using screen-printed carbon electrodes (SPCEs) and glassy carbon electrodes (GCEs) was performed. Cyclic voltammetry (CV) and square-wave voltammetry (SWV) wer...

  • Article
  • Open Access
4 Citations
4,212 Views
11 Pages

Electrocatalytic Reduction of O2 by ITO-IrOx: Implication for Dissolved Oxygen Sensor in the Alkaline Medium

  • Munira Siddika,
  • Md. Mahmudul Hasan,
  • Tahamida A. Oyshi and
  • Mohammad A. Hasnat

23 March 2023

Water pollution has badly affected human health, aquatic life, and the ecosystem. The purity of surface water can be measured in terms of dissolved oxygen (DO) measurements. Hence, it is desirable to have a portable and simple-to-use dissolved oxygen...

  • Review
  • Open Access
5 Citations
4,193 Views
13 Pages

14 August 2023

Plants have a remarkable position among renewable materials because of their abundance, and nearly thousands of tons are consumed worldwide every day. Most unexploited plants and agricultural waste can be a real potential resource system. With increa...

  • Article
  • Open Access
2 Citations
4,191 Views
39 Pages

The manufacturing of integrated circuits involves multiple steps of chemical mechanical planarization (CMP) involving different materials. Mitigating CMP-induced defects is a main requirement of all CMP schemes. In this context, controlling galvanic...

  • Article
  • Open Access
3 Citations
4,180 Views
14 Pages

The Electrocatalytic Oxygen Evolution Reaction Activity of Rationally Designed NiFe-Based Glycerates

  • Vivek Kumar Singh,
  • Bibhudatta Malik,
  • Rajashree Konar,
  • Efrat Shawat Avraham and
  • Gilbert Daniel Nessim

4 February 2024

The electrocatalytic oxygen evolution reaction (OER) is an arduous step in water splitting due to its slow reaction rate and large overpotential. Herein, we synthesized glycerate-anion-intercalated nickel–iron glycerates (NiFeGs) using a one-st...

  • Article
  • Open Access
4 Citations
4,113 Views
18 Pages

24 April 2023

Ammonium dihydrogen phosphate (ADP) single crystals along with the incorporated 0.5 and 1% L-lysine, an organic molecule which possesses a good nonlinear response, were grown with the vision to meet the requirements of the optoelectronic industry. Th...

  • Article
  • Open Access
6 Citations
3,994 Views
14 Pages

22 February 2023

In this paper, ZnO nanorods were synthesized by the hydrothermal method and used as anodes for zinc-silver batteries. The Tafel and EIS curve analysis results show that ZnO nanorods have better anti-corrosion and charge transport properties than ZnO...

  • Article
  • Open Access
6 Citations
3,954 Views
12 Pages

Chronoamperometric curves for the oxidation of a ferrocenyl derivative via a potential step, calculated using the Cottrell equation, showed less diffusion-controlled currents on a platinum wire electrode. This lower deviation cannot be explained via...

  • Article
  • Open Access
2 Citations
3,925 Views
13 Pages

Reconstruction of Electrochemical Impedance Spectroscopy from Time-Domain Pulses of a 3.7 kWh Lithium-Ion Battery Module

  • Manuel Kasper,
  • Manuel Moertelmaier,
  • Hartmut Popp,
  • Ferry Kienberger and
  • Nawfal Al-Zubaidi R-Smith

We demonstrate the reconstruction of battery electrochemical impedance spectroscopy (EIS) curves from time-domain pulse testing and the distribution of relaxation times (DRT) analysis. In the proposed approach, the DRT directly utilizes measured curr...

  • Article
  • Open Access
7 Citations
3,868 Views
19 Pages

Alkaloid Extract of Ageratina adenophora Stem as Green Inhibitor for Mild Steel Corrosion in One Molar Sulfuric Acid Solution

  • Jamuna Thapa Magar,
  • Indra Kumari Budhathoki,
  • Anil Rajaure,
  • Hari Bhakta Oli and
  • Deval Prasad Bhattarai

Green corrosion inhibitors are of great interest due to their exciting and environmentally friendly behavior in mild steel corrosion control during and after the acid cleaning process. Herein, alkaloids were extracted from the stem of Ageratina adeno...

  • Review
  • Open Access
5 Citations
3,836 Views
16 Pages

Electrochemical-Based Biosensor Platforms in Lab-Chip Models for Point-of-Need Toxicant Analysis

  • Mohana Marimuthu,
  • Vinoth Krishnan,
  • Shailendra Devi Sudhakaran,
  • Sevakumaran Vigneswari,
  • Shanmugam Senthilkumar and
  • Murugan Veerapandian

21 November 2023

The global hazardous waste management market is expected to reach USD 987.51 million by 2027 at a CAGR of 14.48%. The early detection of corrosive, flammable, and infectious toxicants from natural sources or manmade contaminants from different enviro...

  • Article
  • Open Access
7 Citations
3,823 Views
20 Pages

High C-Rate Performant Electrospun LiFePO4/Carbon Nanofiber Self-Standing Cathodes for Lithium-Ion Batteries

  • Debora Maria Conti,
  • Claudia Urru,
  • Giovanna Bruni,
  • Pietro Galinetto,
  • Benedetta Albini,
  • Vittorio Berbenni and
  • Doretta Capsoni

In the present study, LiFePO4/CNF self-standing cathodes for LIBs are synthesized by electrospinning. A lower active material amount (12.3 and 34.5 wt%) is used, compared to the conventional tape-casted cathodes (70–85 wt%). The characterizatio...

  • Article
  • Open Access
3 Citations
3,690 Views
16 Pages

16 October 2024

The lithium-ion battery (LIB) is the key energy storage device for electric transportation. The thick electrode (single-sided areal capacity >4.0 mAh/cm2) design is a straightforward and effective strategy for improving cell energy density by impr...

  • Article
  • Open Access
1 Citations
3,642 Views
12 Pages

Investigation of Ionic Conductivity of Electrolytes for Anode-Free Lithium-Ion Batteries by Impedance Spectroscopy

  • Azhar Abdrakhmanova,
  • Alfira Sabitova,
  • Binur Mussabayeva,
  • Bulbul Bayakhmetova,
  • Zhanna Sharipkhan and
  • Elmira Yermoldina

Anode-free lithium-ion batteries offer a volumetric energy density approximately 60% higher than that of conventional lithium-ion cells. Despite this advantage, they often experience rapid capacity degradation and a limited cycle life. Optimizing ele...

  • Review
  • Open Access
1 Citations
3,609 Views
36 Pages

Water Management Strategies for Proton Exchange Membrane Fuel Cells: A Comprehensive Review

  • Mahfouz Saeed,
  • Mohamed A. El-Hameed,
  • Essa Al-Hajri and
  • Adnan Kabbani

Proton exchange membrane fuel cells (PEMFCs) are a promising clean energy technology due to their zero gas emissions, low operating temperature, and high efficiency. This review synthesizes research from 2015–2025 on (i) materials-level approac...

  • Article
  • Open Access
1 Citations
3,587 Views
12 Pages

8 November 2024

In this study, vanadium (3.5+) electrolyte was prepared for vanadium redox flow batteries (VRFBs) through a reduction reaction using a batch-type hydrothermal reactor, differing from conventional production methods that utilize VOSO4 and V2O5. The st...

  • Review
  • Open Access
6 Citations
3,542 Views
17 Pages

Design and Fabrication of Micro-Electromechanical System (MEMS)-Based μ-DMFC (Direct Methanol Fuel Cells) for Portable Applications: An Outlook

  • Divya Catherin Sesu,
  • Ganesan Narendran,
  • Saraswathi Ramakrishnan,
  • Kumaran Vediappan,
  • Sankaran Esakki Muthu,
  • Sengottaiyan Shanmugan and
  • Karthik Kannan

This review reveals the parameters of next-generation fuel cells for portable applications such as cellular phones, laptops, automobiles, etc. Disputes over issues such as design, fluid dynamics, channel dimensions, thermal management, and water mana...

  • Article
  • Open Access
3 Citations
3,437 Views
15 Pages

A chronically stable electrode material with a low impedance for recording neural activity, and a high charge-injection capacity for functional electro-stimulation is desirable for the fabrication of implantable microelectrode arrays that aim to rest...

  • Communication
  • Open Access
6 Citations
3,403 Views
11 Pages

Enhanced Hydrogen Evolution Reaction of a Zn+2-Stabilized Tungstate Electrocatalyst

  • Dasu Ram Paudel,
  • Gopi Chandra Kaphle,
  • Bhoj Raj Poudel,
  • Mukunda KC,
  • Manjinder Singh and
  • Gunendra Prasad Ojha

Due to their diverse properties and functionalities, cost-effective transition metal-based nanomaterials have been rigorously studied for electrochemical applications. Ultrathin nanosheets have been identified as the most effective electrodes for cat...

  • Article
  • Open Access
1 Citations
3,320 Views
19 Pages

The development of high-performance solid electrolytes is critical to advancing solid-state lithium-ion batteries (SSBs), with lithium lanthanum zirconium oxide (LLZO) emerging as a leading candidate due to its chemical stability and wide electrochem...

  • Article
  • Open Access
2 Citations
3,282 Views
10 Pages

The present study focuses on the electrochemical sensing of amoxicillin (AMX, as a model antibiotic drug) and its interaction with Uropathogenic E. coli (UPEC) bacteria (as a model pathogen) under physiological conditions. The electrochemical sensor...

  • Article
  • Open Access
4 Citations
3,192 Views
13 Pages

20 September 2024

The development of conductive coatings has significant implications for microelectronics and electrochemistry. However, conductive coatings may exhibit different electrochemical properties when prepared on different substrate materials. This research...

  • Review
  • Open Access
8 Citations
3,190 Views
15 Pages

12 December 2023

Aptamers are three-dimensional structures of DNA or RNA that present high affinity and selectivity to specific targets, obtained through in vitro screening. Aptamers are used as biological recognizers in electrochemical biosensors, the so-called apta...

  • Article
  • Open Access
2 Citations
3,171 Views
16 Pages

23 April 2023

This paper focuses on an industrial application where renewable power produced by photovoltaic panels is exploited to feed a pneumatic transport plant. The proposed system requires the careful management of the energy flows involved since it includes...

  • Article
  • Open Access
3,022 Views
17 Pages

Transition Metal Oxides (WO3-ZrO2) as Promoters and Hydrogen Adsorption Modulators in Pt/WO3-ZrO2-C Electrocatalyst for the Reduction of NOx

  • Claudia R. Santiago-Ramírez,
  • Martha L. Hernández-Pichardo,
  • Arturo Manzo-Robledo,
  • Daniel A. Acuña-Leal and
  • Miguel A. Gracia-Pinilla

The electrocatalytic reduction of nitric oxide and nitrogen dioxide (NOx) remains a significant challenge due to the need for stable, efficient, and cost-effective materials. This study presents a novel support system for NOx reduction in alkaline me...

  • Article
  • Open Access
3 Citations
3,017 Views
16 Pages

Electrical Resistance as an Aggregate Characteristic of Coke Properties for Electrochemical and Coke Production

  • Denis Miroshnichenko,
  • Kateryna Shmeltser,
  • Maryna Kormer,
  • Yevhen Soloviov,
  • Serhiy Pyshyev,
  • Bohdan Korchak,
  • Mariia Shved and
  • Yuriy Prysiazhnyi

The influence of the component composition of coal batches and the final temperature of the coking process on the resistivity of coke was studied. Taking into account that the resistivity and reactivity are influenced by some common factors, such as...

  • Article
  • Open Access
1 Citations
2,994 Views
16 Pages

At present, direct carbon fuel cells constitute an emerging energy technology that electrochemically converts solid carbon to electricity with high efficiency. The recent trend of DCFCs fueled with biochar from biomass carbonization as green fuel has...

  • Article
  • Open Access
2 Citations
2,985 Views
12 Pages

28 September 2023

This work was aimed at the development of a sensitive electrochemical detection method for oxycodone in water. Molecularly imprinted electrodes were formed by electro-polymerization process using o-phenylenediamine as a monomer. The electro-polymeriz...

  • Article
  • Open Access
3 Citations
2,909 Views
12 Pages

Graphene-Oxide-Coated CoP2@C Anode Enables High Capacity of Lithium-Ion Batteries

  • Wei Zhang,
  • Hangxuan Xie,
  • Zirui Dou,
  • Zhentao Hao,
  • Qianhui Huang,
  • Ziqi Guo,
  • Chao Wang,
  • Kanghua Miao and
  • Xiongwu Kang

26 October 2023

Cobalt diphosphides (CoP2) show a high theoretical capacity and hold great promise as anode materials for lithium-ion batteries (LIBs). However, the large variation in the volume and structure of CoP2 caused during lithium-ion insertion and extractio...

  • Article
  • Open Access
2 Citations
2,875 Views
13 Pages

A silicon nanoparticle–graphite nanosheet composite was prepared via a facile ball milling process for use as the anode for high-rate lithium-ion batteries. The size effect of Si nanoparticles on the structure and on the lithium-ion battery per...

  • Article
  • Open Access
4 Citations
2,838 Views
11 Pages

Theory for Electrochemical Heat Sources and Exothermic Explosions: The Akbari–Ganji Method

  • Ramalingam Vanaja,
  • Ponraj Jeyabarathi,
  • Lakshmanan Rajendran and
  • Michael Edward Gerard Lyons

5 September 2023

A device that transforms chemical energy into electrical energy is an electrochemical cell. The reaction type inside the cell determines whether it is exothermic or endothermic. This paper discusses the mathematical modelling of exothermic explosions...

  • Article
  • Open Access
2,819 Views
14 Pages

Full Tailored Metal Content NCM Regeneration from Spent Lithium-Ion Battery Mixture Under Mild Condition

  • Alpha Chi Him Tsang,
  • Shaobo Ouyang,
  • Yang Lv,
  • Chi Chung Lee,
  • Chi-Wing Tsang and
  • Xiao-Ying Lu

2 December 2024

Mild conditioned, second-life ternary nickel–cobalt–manganese (NCM) black powder regeneration from spent lithium-ion batteries’ (LIBs) black powder mixture was demonstrated after mild conditioned p-toluenesulphuric acid (PTA)-assist...

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Electrochem - ISSN 2673-3293