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Electrochem, Volume 7, Issue 3

2026 September - 12 articles

Cover Story: Electrodes based on silane-bridged 1 and 2 showed higher K+ selectivity Li+, Na+, Mg2+, and Ca2+ than a commercial bis(benzo-15-crown-5) ionophore. Notably, the 2-ethylhexyl-substituted ionophore exhibited excellent tolerance to strongly acidic media and maintained nearly constant K+/Na+ selectivity for more than 200 days under intermittent dry-storage conditions. These results highlight silane/disiloxane bridging as a useful molecular design strategy for durable, high-performance potassium ionophores. View this paper
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Articles (12)

  • Article
  • Open Access
384 Views
15 Pages

Formazan as a Noninnocent Ligand: Catalytic Activity of [Ni(3-cyano-1,5-mesitylformazanate)((2-mercaptopyridinate)-κN,S)] in Electrochemical Hydrogen Production

  • Tomohiko Hamaguchi,
  • Takahiro Noguchi,
  • Kouhei Kodama,
  • Yuji Yamada and ,
  • Akio Mishima,
  • Ryuta Ishikawa and
  • Satoshi Kawata
  • + 2 authors+ 0 author

Formazanates are the mono-deprotonated form of formazans, which exhibit a notable property of noninnocent behavior. Here, a new nickel–formazanate complex, [Ni(3-cyano-1,5-mesitylformazanate)((2-mercaptopyridinate)-κN,S)], was synthesized...

  • Article
  • Open Access
301 Views
12 Pages

Potassium-selective ionophores with high selectivity and chemical stability are essential for electrochemical sensing in clinical, biological, and environmental analysis. Here, three new silane- and disiloxane-bridged bis(15-crown-5) derivatives&mdas...

  • Article
  • Open Access
614 Views
23 Pages

Experimental Study and Simplified Modelling of 1 kW Proton Exchange Membrane Fuel Cell for Mobile and Stationary Hybrid Systems Optimization

  • Galin Borisov,
  • Ludmil Stoyanov,
  • Ivan Bachev,
  • Zahari Zarkov and ,
  • Vladimir Lazarov and
  • Valentin Milenov
  • + 1 author+ 0 author

The conversion of hydrogen into electricity is a subject of intense interest. Various technologies are available at laboratory level, but in industrial applications, the most established of them is the proton exchange membrane-based fuel cell. This i...

  • Article
  • Open Access
575 Views
18 Pages

Electrochemical Behavior and Cycling-Induced Structural Changes in Benzylammonium Copper Chloride Electrodes for Lithium-Ion Batteries

  • Alfredo Romero-Contreras,
  • Thelma Serrano-Quezada,
  • Miguel Amado-Briseño,
  • Arian Espinosa-Roa and
  • Eduardo Sánchez-Cervantes

This work reports the synthesis of the organic–inorganic copper chloride perovskite (C6H5CH2NH3)2[CuCl4] and its application as an electrode material for lithium-ion batteries. Hybrid copper halide perovskites have emerged as environmentally fr...

  • Review
  • Open Access
664 Views
55 Pages

Due to their remarkable long-term stability, variable bandgap, and relatively high absorption coefficient, copper indium gallium diselenide (CIGS) solar devices are among the most promising photovoltaic technologies due to their compatibility with li...

(This article belongs to the Special Issue Photoelectrochemical Systems for a Sustainable Future: Materials, Mechanisms, and Solar-to-Chemical Conversion)
  • Article
  • Open Access
402 Views
11 Pages

Formulation and Characterization of 3D-Printable Nitrogen- and Metal-Doped Carbon Inks for ORR Electrode Applications

  • Joseph H. Dumont,
  • Marcos M. Hernandez,
  • Shaylynn L. A. Crum,
  • Andre J. Spears and
  • Kwan-Soo Lee

Additive manufacturing provides a fabrication route for electrode components with controlled macrostructure; however, printable carbon inks that also incorporate oxygen reduction reaction active precursors remain underdeveloped. Here, XC-72 carbon wa...

  • Article
  • Open Access
513 Views
15 Pages

Poly(3,4-Ethylenedioxythiophene)-Centered TiO2 Hybrid Electrodes for HER- and OER-Relevant Photoelectrochemical Responses

  • Yu Zhou,
  • Tomoyuki Kurioka,
  • Chun-Yi Chen,
  • Yung-Jung Hsu and ,
  • Masato Sone and
  • Tso-Fu Mark Chang
  • + 1 author+ 0 author

Photoelectrochemical (PEC) energy conversion is a promising approach for solar-to-chemical fuel production, but its practical performance is limited by insufficient visible-light utilization and charge-carrier recombination. Here, poly(3,4-ethylenedi...

(This article belongs to the Topic Electrocatalytic Advances for Sustainable Energy)
  • Article
  • Open Access
1 Citations
1,008 Views
10 Pages

Irreversibility of Ag|AgCl Reference Electrodes

  • Koichi Jeremiah Aoki and
  • Jingyuan Chen

An Ag|AgCl redox couple has been thought to work as a reversible reference electrode, although metal dissolution often occurs irreversibly. This report examines the kinetics by means of ac-impedance of AgCl films at the Ag electrode. A brief result i...

  • Review
  • Open Access
837 Views
21 Pages

Anthracycline agents, principally doxorubicin and daunorubicin, are widely used in oncology yet carry a narrow therapeutic index and pronounced interindividual pharmacokinetic variability that exposes patients simultaneously to the risk of subtherape...

  • Article
  • Open Access
1,059 Views
22 Pages

Analysis of the Dynamic Response of a Proton Exchange Membrane (PEM) Fuel Cell Under Variable Load Scenarios

  • Milena L. Zambrano Hernández,
  • Manuel Calderón Godoy,
  • Antonio José Calderón Godoy,
  • Juan Félix González González and ,
  • José Rogelio Fábrega Duque and
  • Jorge Serrano Reyes
  • + 1 author+ 0 author

The dynamics and transient response of fuel cell systems are critical aspects, especially in commercial applications where an immediate response to fluctuating power demands is required. This study presents experimental results obtained from evaluati...

  • Article
  • Open Access
937 Views
27 Pages

Insights into the Interpretation of the Electrochemical Results in HLM||Graphite Lithium-Ion Cells and Understanding of the Degradation Mechanisms

  • Imanol Landa-Medrano,
  • Ane Muguruza-Sánchez,
  • Khryslyn Arano,
  • Galyna Kvasha and ,
  • Pamela C. Smecellato,
  • Susan Sananes-Israel,
  • Elixabete Ayerbe,
  • Hans-Jürgen Grande,
  • Irina Profatilova and
  • Iratxe de Meatza
  • + 5 authors+ 0 author

High lithium and manganese oxides (HLMs), also known as lithium- and manganese-rich oxides (LMR), are an alternative to the state-of-the-art (SoA) cathode materials for Li-ion battery cells due to their high specific capacity, working potential, and...

(This article belongs to the Special Issue Advanced Electrochemical Materials for Next-Generation High-Performance Batteries)
  • Article
  • Open Access
1,164 Views
29 Pages

Cyclic Voltammetric Determination of Paracetamol on a AuNPs-Modified Glassy Carbon Electrode Synthesized from Plant Extract

  • Shaxnoza Rajabova,
  • Nigora Qutlimurotova,
  • Jasur Tursunqulov and
  • Rukhiya Kutlimurotova

Paracetamol (PA) ranks among the most frequently prescribed over-the-counter analgesic and antipyretic agents worldwide; nonetheless, overdose scenarios are associated with severe hepatotoxic and nephrotoxic consequences, while its incomplete metabol...

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Electrochem - ISSN 2673-3293